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The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition
dc.creator | Nikolic, Nebojša D | |
dc.creator | Pavlović, Ljubica J. | |
dc.creator | Branković, Goran | |
dc.creator | Pavlović, Miomir G. | |
dc.creator | Popov, Konstantin I | |
dc.date.accessioned | 2022-04-05T14:17:39Z | |
dc.date.available | 2022-04-05T14:17:39Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | http://rimsi.imsi.bg.ac.rs/handle/123456789/288 | |
dc.description.abstract | The ionic equilibrium of the species in the CuSO4-H2SO4-H2O system was employed to systematize the conditions of copper electrodeposition leading to the formation of the honeycomb-like structure. The reason why CuSO4 concentrations higher than 0.15 M are unsuitable for the formation of honeycomb-like structures is shown. The range of H2SO4 concentrations enabling the formation of this type of structure was also determined. The conditions leading to the formation of the honeycomb-like structures are: electrodeposition from solutions with lower concentrations of Cu(II) ions (0.15 M CuSO4 and less) in a concentration range from 0.25 to 1.0 M H2SO4, at a temperature of 18.0 +/- 1.0 degrees C and at overpotentials outside the plateau of the limiting diffusion current density at which hydrogen evolution is vigorous enough to change the hydrodynamic conditions in the near-electrode layer. | en |
dc.publisher | Srpsko hemijsko društvo, Beograd | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | morphology | en |
dc.subject | hydrogen | en |
dc.subject | hydrodynamics | en |
dc.subject | electrolysis | en |
dc.subject | copper | en |
dc.title | The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition | en |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.epage | 760 | |
dc.citation.issue | 7 | |
dc.citation.other | 73(7): 753-760 | |
dc.citation.rank | M23 | |
dc.citation.spage | 753 | |
dc.citation.volume | 73 | |
dc.identifier.doi | 10.2298/JSC0807753N | |
dc.identifier.fulltext | http://rimsi.imsi.bg.ac.rs/bitstream/id/545/285.pdf | |
dc.identifier.scopus | 2-s2.0-47049088388 | |
dc.identifier.wos | 000257846900008 | |
dc.type.version | publishedVersion |