Matović, Branko

Link to this page

Authority KeyName Variants
orcid::0000-0001-8022-1863
  • Matović, Branko (27)
Projects
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Nanostrukturni čvrsti rastvori za primenu u elektronici i alternativnim izvorima energije
Physics of nanostructured oxide materials and strongly correlated systems Study of structure-function relationships in the plant cell wall and modifications of the wall structure by enzyme engineering
Magmatism and geodynamics of the Balkan Peninsula from Mesozoic to present day: significance for the formation of metallic and non-metallic mineral deposits Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing
Nanostructured multifunctional materials and nanocomposites Project ID Project Title info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45012/RS//
A.von Humboldt foundationAlexander von Humboldt Foundation bilateral project "Structural anisotropy of plant cell walls of various origin and their constituent polymers, using differential polarized laser scanning microscopy (DP-LSM)''
Humboldt FoundationAlexander von Humboldt Foundation Development of Methods of Monitoring and Removal of Biologically Actives Substances Aimed at Improving the Quality of the Environment
Characterization and application of fungal metabolites and assessment of new biofungicides potential The membranes as sites of interaction between the intracellular and apoplastic environments: studies of the bioenergetics and signaling using biophysical and biochemical techniques.
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200053 (University of Belgrade, Institute for Multidisciplinary Research)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200116 (University of Belgrade, Faculty of Agriculture) Biomarkers in neurodegenerative and malignant processes
Identification of predictive molecular markers for cancer progression, response to therapy and disease outcome Simultaneous Bioremediation and Soilification of Degraded Areas to Preserve Natural Resources of Biologically Active Substances, and Development and Production of Biomaterials and Dietetic Products
Functional, Functionalized and Advanced Nanomaterials Lithium-ion batteries and fuel cells - research and development
Savremena metal-oksidna elektrokeramika i tanki filmovi info:eu-repo/grantAgreement/MESTD/MPN2006-2010/143043/RS//"
National Academy of Sciences of Ukraine [47/2015-2016] SASA project [F-134]

Author's Bibliography

Synthesis, characterization and magnetic properties of spider silk coated with maghemite (gamma-Fe2O3) nanoparticles

Butulija, Svetlana; Spasojević, Vojislav; Branković, Goran; Prekajski-Đorđević, Marija; Radulović, Tamara; Zarubica, Aleksandra; Matović, Branko

(Elsevier, Amsterdam, 2022)

TY  - JOUR
AU  - Butulija, Svetlana
AU  - Spasojević, Vojislav
AU  - Branković, Goran
AU  - Prekajski-Đorđević, Marija
AU  - Radulović, Tamara
AU  - Zarubica, Aleksandra
AU  - Matović, Branko
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1539
AB  - Spider silk-maghemite (SS-gamma-Fe2O3) composite was obtained by simple and fast co-precipitation method at room temperature. The fibers were coated with maghemite nanoparticles with the average size of 25 nm. According to DTA, maghemite NPs contributed the thermal stability of the composite. Magnetic properties of as obtained composite were estimated. At room temperature, the system was is in a superparamagnetic state, while at temperature of 5 K the magnetic moments were blocked. This composite is seen as a novel hybrid material with superparamagnetic properties for possible applications in bioseparation, biosensors, magnetographic printing, magnetic screens, and magnetic filters as well as sensing/actuating components of MEMS.
PB  - Elsevier, Amsterdam
T2  - Materials Letters
T1  - Synthesis, characterization and magnetic properties of spider silk coated with maghemite (gamma-Fe2O3) nanoparticles
VL  - 314
DO  - 10.1016/j.matlet.2022.131856
ER  - 
@article{
author = "Butulija, Svetlana and Spasojević, Vojislav and Branković, Goran and Prekajski-Đorđević, Marija and Radulović, Tamara and Zarubica, Aleksandra and Matović, Branko",
year = "2022",
abstract = "Spider silk-maghemite (SS-gamma-Fe2O3) composite was obtained by simple and fast co-precipitation method at room temperature. The fibers were coated with maghemite nanoparticles with the average size of 25 nm. According to DTA, maghemite NPs contributed the thermal stability of the composite. Magnetic properties of as obtained composite were estimated. At room temperature, the system was is in a superparamagnetic state, while at temperature of 5 K the magnetic moments were blocked. This composite is seen as a novel hybrid material with superparamagnetic properties for possible applications in bioseparation, biosensors, magnetographic printing, magnetic screens, and magnetic filters as well as sensing/actuating components of MEMS.",
publisher = "Elsevier, Amsterdam",
journal = "Materials Letters",
title = "Synthesis, characterization and magnetic properties of spider silk coated with maghemite (gamma-Fe2O3) nanoparticles",
volume = "314",
doi = "10.1016/j.matlet.2022.131856"
}
Butulija, S., Spasojević, V., Branković, G., Prekajski-Đorđević, M., Radulović, T., Zarubica, A.,& Matović, B.. (2022). Synthesis, characterization and magnetic properties of spider silk coated with maghemite (gamma-Fe2O3) nanoparticles. in Materials Letters
Elsevier, Amsterdam., 314.
https://doi.org/10.1016/j.matlet.2022.131856
Butulija S, Spasojević V, Branković G, Prekajski-Đorđević M, Radulović T, Zarubica A, Matović B. Synthesis, characterization and magnetic properties of spider silk coated with maghemite (gamma-Fe2O3) nanoparticles. in Materials Letters. 2022;314.
doi:10.1016/j.matlet.2022.131856 .
Butulija, Svetlana, Spasojević, Vojislav, Branković, Goran, Prekajski-Đorđević, Marija, Radulović, Tamara, Zarubica, Aleksandra, Matović, Branko, "Synthesis, characterization and magnetic properties of spider silk coated with maghemite (gamma-Fe2O3) nanoparticles" in Materials Letters, 314 (2022),
https://doi.org/10.1016/j.matlet.2022.131856 . .
2
2

Cell wall response to UV radiation in needles of Picea omorika

Mitrović, Aleksandra Lj.; Simonović Radosavljević, Jasna; Prokopijević, Miloš; Spasojević, Dragica; Kovacević, Jovana; Prodanović, Olivera; Todorović, Bratislav; Matović, Branko; Stanković, Mira; Maksimović, Vuk; Mutavdžić, Dragosav; Skocic, Milos; Pesic, Mirjana; Prokic, Ljiljana; Radotić, Ksenija

(Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux, 2021)

TY  - JOUR
AU  - Mitrović, Aleksandra Lj.
AU  - Simonović Radosavljević, Jasna
AU  - Prokopijević, Miloš
AU  - Spasojević, Dragica
AU  - Kovacević, Jovana
AU  - Prodanović, Olivera
AU  - Todorović, Bratislav
AU  - Matović, Branko
AU  - Stanković, Mira
AU  - Maksimović, Vuk
AU  - Mutavdžić, Dragosav
AU  - Skocic, Milos
AU  - Pesic, Mirjana
AU  - Prokic, Ljiljana
AU  - Radotić, Ksenija
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1449
AB  - The UV-B represents the minor fraction of the solar spectrum, while UV-C is not contained in natural solar radiation, but both radiation types can cause damaging effects in plants. Cell walls (CWs) are one of the targets for external stressors. Juvenile P. omorika trees were treated either with 21 day-high doses UV-B or with 7 day-UV-C in open-top chambers. Using spectroscopic and biochemical techniques, it was shown that the response to UV radiation includes numerous modifications in needle CW structure: relative content of xylan, xyloglucan, lignin and cellulose decreased; cellulose crystallinity changed; yield of lignin monomers with stronger connection of C=C in side chain with the ring increased; re-distribution of inter- and intra-polymer H-bonds occurred. The recovery was mediated by an increase in the activities and changes in isoform profiles of CW bound covalent peroxidases (POD) and polyphenol oxidases (PO) (UV-B), and ionic POD and covalent PO (UV-C). A connection between activities of specific POD/PO isoforms and phenolic species (m- and p-coumaric acid, pinoresinol and cinnamic acid derivatives) was demonstrated, and supported by changes in the sRNA profile. In vivo fluorometry showed phenolics accumulation in needle epidermal CWs. These results imply transversal connections between polymers and changed mechanical properties of needle CW as a response to UV. The CW alterations enabled maintenance of physiological functions, as indicated by the preserved chlorophyll content and/or organization. The current study provides evidence that in conifers, needle CW response to both UV-B and UV-C includes biochemical modifications and structural remodeling.
PB  - Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux
T2  - Plant Physiology and Biochemistry
T1  - Cell wall response to UV radiation in needles of Picea omorika
EP  - 190
SP  - 176
VL  - 161
DO  - 10.1016/j.plaphy.2021.02.007
ER  - 
@article{
author = "Mitrović, Aleksandra Lj. and Simonović Radosavljević, Jasna and Prokopijević, Miloš and Spasojević, Dragica and Kovacević, Jovana and Prodanović, Olivera and Todorović, Bratislav and Matović, Branko and Stanković, Mira and Maksimović, Vuk and Mutavdžić, Dragosav and Skocic, Milos and Pesic, Mirjana and Prokic, Ljiljana and Radotić, Ksenija",
year = "2021",
abstract = "The UV-B represents the minor fraction of the solar spectrum, while UV-C is not contained in natural solar radiation, but both radiation types can cause damaging effects in plants. Cell walls (CWs) are one of the targets for external stressors. Juvenile P. omorika trees were treated either with 21 day-high doses UV-B or with 7 day-UV-C in open-top chambers. Using spectroscopic and biochemical techniques, it was shown that the response to UV radiation includes numerous modifications in needle CW structure: relative content of xylan, xyloglucan, lignin and cellulose decreased; cellulose crystallinity changed; yield of lignin monomers with stronger connection of C=C in side chain with the ring increased; re-distribution of inter- and intra-polymer H-bonds occurred. The recovery was mediated by an increase in the activities and changes in isoform profiles of CW bound covalent peroxidases (POD) and polyphenol oxidases (PO) (UV-B), and ionic POD and covalent PO (UV-C). A connection between activities of specific POD/PO isoforms and phenolic species (m- and p-coumaric acid, pinoresinol and cinnamic acid derivatives) was demonstrated, and supported by changes in the sRNA profile. In vivo fluorometry showed phenolics accumulation in needle epidermal CWs. These results imply transversal connections between polymers and changed mechanical properties of needle CW as a response to UV. The CW alterations enabled maintenance of physiological functions, as indicated by the preserved chlorophyll content and/or organization. The current study provides evidence that in conifers, needle CW response to both UV-B and UV-C includes biochemical modifications and structural remodeling.",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux",
journal = "Plant Physiology and Biochemistry",
title = "Cell wall response to UV radiation in needles of Picea omorika",
pages = "190-176",
volume = "161",
doi = "10.1016/j.plaphy.2021.02.007"
}
Mitrović, A. Lj., Simonović Radosavljević, J., Prokopijević, M., Spasojević, D., Kovacević, J., Prodanović, O., Todorović, B., Matović, B., Stanković, M., Maksimović, V., Mutavdžić, D., Skocic, M., Pesic, M., Prokic, L.,& Radotić, K.. (2021). Cell wall response to UV radiation in needles of Picea omorika. in Plant Physiology and Biochemistry
Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux., 161, 176-190.
https://doi.org/10.1016/j.plaphy.2021.02.007
Mitrović AL, Simonović Radosavljević J, Prokopijević M, Spasojević D, Kovacević J, Prodanović O, Todorović B, Matović B, Stanković M, Maksimović V, Mutavdžić D, Skocic M, Pesic M, Prokic L, Radotić K. Cell wall response to UV radiation in needles of Picea omorika. in Plant Physiology and Biochemistry. 2021;161:176-190.
doi:10.1016/j.plaphy.2021.02.007 .
Mitrović, Aleksandra Lj., Simonović Radosavljević, Jasna, Prokopijević, Miloš, Spasojević, Dragica, Kovacević, Jovana, Prodanović, Olivera, Todorović, Bratislav, Matović, Branko, Stanković, Mira, Maksimović, Vuk, Mutavdžić, Dragosav, Skocic, Milos, Pesic, Mirjana, Prokic, Ljiljana, Radotić, Ksenija, "Cell wall response to UV radiation in needles of Picea omorika" in Plant Physiology and Biochemistry, 161 (2021):176-190,
https://doi.org/10.1016/j.plaphy.2021.02.007 . .
7
1
5

Coating of cerium oxide nanoparticles with different carbohydrates and their application on plants

Milenković, Ivana; Radotić, Ksenija; Matović, Branko; Prekajski-Đorđević, Marija; Živković, Ljiljana S.; Beškoski, Vladimir

(Faculty of Technology, University of Novi Sad, 2019)

TY  - CONF
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
AU  - Prekajski-Đorđević, Marija
AU  - Živković, Ljiljana S.
AU  - Beškoski, Vladimir
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1857
AB  - Cerium oxide nanoparticles (nCeO2) are nanomaterial with various applications in biomedicine, electronics and cosmetics. The aim of this research was to improve their low suspension stability by coating with carbohydrates - glucose, levan, and pullulan. The coating was performed at different temperatures and coating times, by adding the carbohydrates during or after the synthesis of nCeO2. Characterization of nanoparticles’ powders was performed by X-Ray diffraction analysis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Nanoparticles’ suspension stability was estimated by measuring of zeta potential, hydrodynamic size and turbidity. The difference among coated nCeO2 have been confirmed with FT-IR spectra. The results showed improved stability of the nCeO2 suspension and decreased size of aggregates after carbohydrate coating. Levan- and glucose-coated nCeO2 suspensions showed the best stability. The obtained nCeO2 were used for the investigation of their ecotoxicity on different plant species.
PB  - Faculty of Technology, University of Novi Sad
C3  - 13th Conference for Young Sciences in Ceramics
T1  - Coating of cerium oxide nanoparticles with different carbohydrates and their application on plants
SP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1857
ER  - 
@conference{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko and Prekajski-Đorđević, Marija and Živković, Ljiljana S. and Beškoski, Vladimir",
year = "2019",
abstract = "Cerium oxide nanoparticles (nCeO2) are nanomaterial with various applications in biomedicine, electronics and cosmetics. The aim of this research was to improve their low suspension stability by coating with carbohydrates - glucose, levan, and pullulan. The coating was performed at different temperatures and coating times, by adding the carbohydrates during or after the synthesis of nCeO2. Characterization of nanoparticles’ powders was performed by X-Ray diffraction analysis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Nanoparticles’ suspension stability was estimated by measuring of zeta potential, hydrodynamic size and turbidity. The difference among coated nCeO2 have been confirmed with FT-IR spectra. The results showed improved stability of the nCeO2 suspension and decreased size of aggregates after carbohydrate coating. Levan- and glucose-coated nCeO2 suspensions showed the best stability. The obtained nCeO2 were used for the investigation of their ecotoxicity on different plant species.",
publisher = "Faculty of Technology, University of Novi Sad",
journal = "13th Conference for Young Sciences in Ceramics",
title = "Coating of cerium oxide nanoparticles with different carbohydrates and their application on plants",
pages = "39",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1857"
}
Milenković, I., Radotić, K., Matović, B., Prekajski-Đorđević, M., Živković, L. S.,& Beškoski, V.. (2019). Coating of cerium oxide nanoparticles with different carbohydrates and their application on plants. in 13th Conference for Young Sciences in Ceramics
Faculty of Technology, University of Novi Sad., 39.
https://hdl.handle.net/21.15107/rcub_rimsi_1857
Milenković I, Radotić K, Matović B, Prekajski-Đorđević M, Živković LS, Beškoski V. Coating of cerium oxide nanoparticles with different carbohydrates and their application on plants. in 13th Conference for Young Sciences in Ceramics. 2019;:39.
https://hdl.handle.net/21.15107/rcub_rimsi_1857 .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, Prekajski-Đorđević, Marija, Živković, Ljiljana S., Beškoski, Vladimir, "Coating of cerium oxide nanoparticles with different carbohydrates and their application on plants" in 13th Conference for Young Sciences in Ceramics (2019):39,
https://hdl.handle.net/21.15107/rcub_rimsi_1857 .

Coating of cerium oxide nanoparticles with different carbohydrates

Milenković, Ivana; Radotić, Ksenija; Matović, Branko; Prekajski Đorđević, Marija; Živković, Ljiljana S.; Jakovljević, Dragica; Gojgic-Cvijović, Gordana; Beškoski, Vladimir

(Institute for Multidisciplinary Research, University of Belgrade, 2019)

TY  - CONF
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
AU  - Prekajski Đorđević, Marija
AU  - Živković, Ljiljana S.
AU  - Jakovljević, Dragica
AU  - Gojgic-Cvijović, Gordana
AU  - Beškoski, Vladimir
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1839
AB  - Cerium oxide nanoparticles (nCeO2) are biomaterials with numerous applications in biomedicine, fuel additives and electronics. Since their low stability in aqueous media limited their practical application, the aim of this study was to improve the suspension stability of nCeO2 by coating the particles. Glucose, monosaccharide, and levan and pullulan, microbial polysaccharides, were used as coating material. The coating was attempted under different synthesis conditions, by adding the carbohydrates during (direct coating) or after (subsequent coating) the synthesis of nCeO2. X-Ray diffraction analysis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used for characterization of nanoparticles’ powders. Measuring of hydrodynamic size, zeta potential and turbidity was used for the estimation of nanoparticles’ suspension stability in aqueous media. The success of subsequent coating with carbohydrates and the differences between coated nCeO2 have been proven with FT-IR spectra. Turbidity measurement showed the best stability of levan- and glucose-coated nCeO2 suspensions. It can be concluded that coating with carbohydrates improved the stability of the nCeO2 suspension by decreasing the size of aggregated particles. The obtained results open new horizons for further ecotoxicity investigation and nCeO2 application.
PB  - Institute for Multidisciplinary Research, University of Belgrade
C3  - 5th Conference of the Serbian Society for Ceramic Materials
T1  - Coating of cerium oxide nanoparticles with different carbohydrates
SP  - 57
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1839
ER  - 
@conference{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko and Prekajski Đorđević, Marija and Živković, Ljiljana S. and Jakovljević, Dragica and Gojgic-Cvijović, Gordana and Beškoski, Vladimir",
year = "2019",
abstract = "Cerium oxide nanoparticles (nCeO2) are biomaterials with numerous applications in biomedicine, fuel additives and electronics. Since their low stability in aqueous media limited their practical application, the aim of this study was to improve the suspension stability of nCeO2 by coating the particles. Glucose, monosaccharide, and levan and pullulan, microbial polysaccharides, were used as coating material. The coating was attempted under different synthesis conditions, by adding the carbohydrates during (direct coating) or after (subsequent coating) the synthesis of nCeO2. X-Ray diffraction analysis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used for characterization of nanoparticles’ powders. Measuring of hydrodynamic size, zeta potential and turbidity was used for the estimation of nanoparticles’ suspension stability in aqueous media. The success of subsequent coating with carbohydrates and the differences between coated nCeO2 have been proven with FT-IR spectra. Turbidity measurement showed the best stability of levan- and glucose-coated nCeO2 suspensions. It can be concluded that coating with carbohydrates improved the stability of the nCeO2 suspension by decreasing the size of aggregated particles. The obtained results open new horizons for further ecotoxicity investigation and nCeO2 application.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade",
journal = "5th Conference of the Serbian Society for Ceramic Materials",
title = "Coating of cerium oxide nanoparticles with different carbohydrates",
pages = "57",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1839"
}
Milenković, I., Radotić, K., Matović, B., Prekajski Đorđević, M., Živković, L. S., Jakovljević, D., Gojgic-Cvijović, G.,& Beškoski, V.. (2019). Coating of cerium oxide nanoparticles with different carbohydrates. in 5th Conference of the Serbian Society for Ceramic Materials
Institute for Multidisciplinary Research, University of Belgrade., 57.
https://hdl.handle.net/21.15107/rcub_rimsi_1839
Milenković I, Radotić K, Matović B, Prekajski Đorđević M, Živković LS, Jakovljević D, Gojgic-Cvijović G, Beškoski V. Coating of cerium oxide nanoparticles with different carbohydrates. in 5th Conference of the Serbian Society for Ceramic Materials. 2019;:57.
https://hdl.handle.net/21.15107/rcub_rimsi_1839 .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, Prekajski Đorđević, Marija, Živković, Ljiljana S., Jakovljević, Dragica, Gojgic-Cvijović, Gordana, Beškoski, Vladimir, "Coating of cerium oxide nanoparticles with different carbohydrates" in 5th Conference of the Serbian Society for Ceramic Materials (2019):57,
https://hdl.handle.net/21.15107/rcub_rimsi_1839 .

Improving stability of cerium oxide nanoparticles by microbial polysaccharides coating

Milenković, Ivana; Radotić, Ksenija; Matović, Branko; Prekajski, Marija; Živković, Ljiljana; Jakovljević, Dragica; Gojgic-Cvijović, Gordana; Beskoski, Vladimir P.

(Srpsko hemijsko društvo, Beograd, 2018)

TY  - JOUR
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
AU  - Prekajski, Marija
AU  - Živković, Ljiljana
AU  - Jakovljević, Dragica
AU  - Gojgic-Cvijović, Gordana
AU  - Beskoski, Vladimir P.
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1126
AB  - Cerium oxide (CeO2) nanoparticles (CONPs) are interesting biomaterials with various applications in biomedicine, cosmetics and the pharmaceutical industry, but with limited practical application because of their low stability in aqueous media. The aim of this study was to obtain CONPs with increased stability by coating the particles. Microbial exopolysaccharides (levan, pullulan) and glucose were used to prepare CONPs under different synthesis conditions. Coating was attempted by adding the carbohydrates during (direct coating) or after (subsequent coating) the synthesis of CONPs. The obtained nanoparticles were characterized by X-Ray diffraction analysis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The suspension stability of the uncoated and coated CONPs in aqueous media was evaluated by measuring the hydrodynamic size, zeta potential and turbidity. The FT-IR spectra revealed the differences between coated CONPs and showed the success of subsequent coating with carbohydrates. Coating with carbohydrates improved the stability the CONP suspension by decreasing the size of aggregated particles. The suspensions of levan- and glucose-coated CONPs had the best stability. In this study, CONPs were prepared using non-toxic materials, which were completely environmentally friendly. The obtained results open new horizons for CONP synthesis, improving their biological applications.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Improving stability of cerium oxide nanoparticles by microbial polysaccharides coating
EP  - 757
IS  - 6
SP  - 745
VL  - 83
DO  - 10.2298/JSC171205031M
ER  - 
@article{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko and Prekajski, Marija and Živković, Ljiljana and Jakovljević, Dragica and Gojgic-Cvijović, Gordana and Beskoski, Vladimir P.",
year = "2018",
abstract = "Cerium oxide (CeO2) nanoparticles (CONPs) are interesting biomaterials with various applications in biomedicine, cosmetics and the pharmaceutical industry, but with limited practical application because of their low stability in aqueous media. The aim of this study was to obtain CONPs with increased stability by coating the particles. Microbial exopolysaccharides (levan, pullulan) and glucose were used to prepare CONPs under different synthesis conditions. Coating was attempted by adding the carbohydrates during (direct coating) or after (subsequent coating) the synthesis of CONPs. The obtained nanoparticles were characterized by X-Ray diffraction analysis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The suspension stability of the uncoated and coated CONPs in aqueous media was evaluated by measuring the hydrodynamic size, zeta potential and turbidity. The FT-IR spectra revealed the differences between coated CONPs and showed the success of subsequent coating with carbohydrates. Coating with carbohydrates improved the stability the CONP suspension by decreasing the size of aggregated particles. The suspensions of levan- and glucose-coated CONPs had the best stability. In this study, CONPs were prepared using non-toxic materials, which were completely environmentally friendly. The obtained results open new horizons for CONP synthesis, improving their biological applications.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Improving stability of cerium oxide nanoparticles by microbial polysaccharides coating",
pages = "757-745",
number = "6",
volume = "83",
doi = "10.2298/JSC171205031M"
}
Milenković, I., Radotić, K., Matović, B., Prekajski, M., Živković, L., Jakovljević, D., Gojgic-Cvijović, G.,& Beskoski, V. P.. (2018). Improving stability of cerium oxide nanoparticles by microbial polysaccharides coating. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 83(6), 745-757.
https://doi.org/10.2298/JSC171205031M
Milenković I, Radotić K, Matović B, Prekajski M, Živković L, Jakovljević D, Gojgic-Cvijović G, Beskoski VP. Improving stability of cerium oxide nanoparticles by microbial polysaccharides coating. in Journal of the Serbian Chemical Society. 2018;83(6):745-757.
doi:10.2298/JSC171205031M .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, Prekajski, Marija, Živković, Ljiljana, Jakovljević, Dragica, Gojgic-Cvijović, Gordana, Beskoski, Vladimir P., "Improving stability of cerium oxide nanoparticles by microbial polysaccharides coating" in Journal of the Serbian Chemical Society, 83, no. 6 (2018):745-757,
https://doi.org/10.2298/JSC171205031M . .
13
9
13

Bacterial cellulose-lignin composite hydrogel as a promising agent in chronic wound healing

Zmejkoski, Danica; Spasojević, Dragica; Orlovska, Irina; Kozyrovska, Natalia; Soković, Marina; Glamočlija, Jasmina; Dmitrović, Svetlana; Matović, Branko; Tasić, Nikola; Maksimović, Vuk; Sosnin, Mikhail; Radotić, Ksenija

(Elsevier, Amsterdam, 2018)

TY  - JOUR
AU  - Zmejkoski, Danica
AU  - Spasojević, Dragica
AU  - Orlovska, Irina
AU  - Kozyrovska, Natalia
AU  - Soković, Marina
AU  - Glamočlija, Jasmina
AU  - Dmitrović, Svetlana
AU  - Matović, Branko
AU  - Tasić, Nikola
AU  - Maksimović, Vuk
AU  - Sosnin, Mikhail
AU  - Radotić, Ksenija
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1157
AB  - Lignins and lignin-derived compounds are known to have antibacterial properties. The wound healing agents in the form of dressings produce faster skin repair and decrease pain in patients. In order to create an efficient antimicrobial agent in the form of dressing in the treatment of chronic wounds, a composite hydrogel of bacterial cellulose (BC) and dehydrogenative polymer of coniferyl alcohol (DHP), BC-DHP, was designed. Novel composite showed inhibitory or bactericidal effects against selected pathogenic bacteria, including clinically isolated ones. The highest release rate of DHP was in the first hour, while after 24 h there was still slow release of small amounts of DHP from BC-DHP during 72 h monitoring. High-performance liquid chromatography coupled with mass-spectrometry showed that BC-DHP releases DHP oligomers, which are proposed to be antimicrobially active DHP fractions. Scanning electron microscopy and atomic force microscopy micrographs proved a dose-dependent interaction of DHP with BC, which resulted in a decrease of the pore number and size in the cellulose membrane. The Fourier-transform infrared absorption spectra of the BC-DHP showed that DHP was partly bound to the BC matrix. The swelling and crystallinity degree were dose-dependent. All obtained results confirmed BC-DHP composite as a promising hydrogel for wounds healing.
PB  - Elsevier, Amsterdam
T2  - International Journal of Biological Macromolecules
T1  - Bacterial cellulose-lignin composite hydrogel as a promising agent in chronic wound healing
EP  - 503
SP  - 494
VL  - 118
DO  - 10.1016/j.ijbiomac.2018.06.067
ER  - 
@article{
author = "Zmejkoski, Danica and Spasojević, Dragica and Orlovska, Irina and Kozyrovska, Natalia and Soković, Marina and Glamočlija, Jasmina and Dmitrović, Svetlana and Matović, Branko and Tasić, Nikola and Maksimović, Vuk and Sosnin, Mikhail and Radotić, Ksenija",
year = "2018",
abstract = "Lignins and lignin-derived compounds are known to have antibacterial properties. The wound healing agents in the form of dressings produce faster skin repair and decrease pain in patients. In order to create an efficient antimicrobial agent in the form of dressing in the treatment of chronic wounds, a composite hydrogel of bacterial cellulose (BC) and dehydrogenative polymer of coniferyl alcohol (DHP), BC-DHP, was designed. Novel composite showed inhibitory or bactericidal effects against selected pathogenic bacteria, including clinically isolated ones. The highest release rate of DHP was in the first hour, while after 24 h there was still slow release of small amounts of DHP from BC-DHP during 72 h monitoring. High-performance liquid chromatography coupled with mass-spectrometry showed that BC-DHP releases DHP oligomers, which are proposed to be antimicrobially active DHP fractions. Scanning electron microscopy and atomic force microscopy micrographs proved a dose-dependent interaction of DHP with BC, which resulted in a decrease of the pore number and size in the cellulose membrane. The Fourier-transform infrared absorption spectra of the BC-DHP showed that DHP was partly bound to the BC matrix. The swelling and crystallinity degree were dose-dependent. All obtained results confirmed BC-DHP composite as a promising hydrogel for wounds healing.",
publisher = "Elsevier, Amsterdam",
journal = "International Journal of Biological Macromolecules",
title = "Bacterial cellulose-lignin composite hydrogel as a promising agent in chronic wound healing",
pages = "503-494",
volume = "118",
doi = "10.1016/j.ijbiomac.2018.06.067"
}
Zmejkoski, D., Spasojević, D., Orlovska, I., Kozyrovska, N., Soković, M., Glamočlija, J., Dmitrović, S., Matović, B., Tasić, N., Maksimović, V., Sosnin, M.,& Radotić, K.. (2018). Bacterial cellulose-lignin composite hydrogel as a promising agent in chronic wound healing. in International Journal of Biological Macromolecules
Elsevier, Amsterdam., 118, 494-503.
https://doi.org/10.1016/j.ijbiomac.2018.06.067
Zmejkoski D, Spasojević D, Orlovska I, Kozyrovska N, Soković M, Glamočlija J, Dmitrović S, Matović B, Tasić N, Maksimović V, Sosnin M, Radotić K. Bacterial cellulose-lignin composite hydrogel as a promising agent in chronic wound healing. in International Journal of Biological Macromolecules. 2018;118:494-503.
doi:10.1016/j.ijbiomac.2018.06.067 .
Zmejkoski, Danica, Spasojević, Dragica, Orlovska, Irina, Kozyrovska, Natalia, Soković, Marina, Glamočlija, Jasmina, Dmitrović, Svetlana, Matović, Branko, Tasić, Nikola, Maksimović, Vuk, Sosnin, Mikhail, Radotić, Ksenija, "Bacterial cellulose-lignin composite hydrogel as a promising agent in chronic wound healing" in International Journal of Biological Macromolecules, 118 (2018):494-503,
https://doi.org/10.1016/j.ijbiomac.2018.06.067 . .
6
121
56
123

Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers

Dmitrović, Svetlana; Prekajski, Marija; Jokic, Bojan; Branković, Goran; Zarubica, Aleksandra; Zikic, Vladimir; Matović, Branko

(Savez hemijskih inženjera, Beograd, 2018)

TY  - JOUR
AU  - Dmitrović, Svetlana
AU  - Prekajski, Marija
AU  - Jokic, Bojan
AU  - Branković, Goran
AU  - Zarubica, Aleksandra
AU  - Zikic, Vladimir
AU  - Matović, Branko
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1132
AB  - Spider silk fibers, collected from Pholcus Phalangioides spider were used as a template for obtaining magnesium oxide (MgO, periclase) as well as magnesium hydroxide (Mg(OH)(2), brucite) fibers. Magnesium oxide fibers were obtained in a simple manner by heat induced decomposition of magnesium salt (MgCl2) in the presence of the spider silk fibers, while magnesium hydroxide fibers were synthesized by hydration of MgO fibers at 50, 70 and 90 degrees C, for 48 and 96 h. According to Scanning electron microscopy (SEM), dimensions of spider silk fibers determined the dimension of synthesized MgO fibers, while for Mg(OH)(2) fibers, the average diameter was increased with prolonging the hydration period. The surface of Mg(OH)(2) fibers was noticed to be covered with brucite in a form of plates. X-Ray diffraction (XRD) analysis showed that MgO fibers were single-phased (the pure magnesium oxide fibers were obtained), while Mg(OH)(2) fibers were two-or single-phased brucite depending on incubation period, and/or incubation temperature.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska Industrija
T1  - Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers
EP  - 28
IS  - 1
SP  - 23
VL  - 72
DO  - 10.2298/HEMIND170404018D
ER  - 
@article{
author = "Dmitrović, Svetlana and Prekajski, Marija and Jokic, Bojan and Branković, Goran and Zarubica, Aleksandra and Zikic, Vladimir and Matović, Branko",
year = "2018",
abstract = "Spider silk fibers, collected from Pholcus Phalangioides spider were used as a template for obtaining magnesium oxide (MgO, periclase) as well as magnesium hydroxide (Mg(OH)(2), brucite) fibers. Magnesium oxide fibers were obtained in a simple manner by heat induced decomposition of magnesium salt (MgCl2) in the presence of the spider silk fibers, while magnesium hydroxide fibers were synthesized by hydration of MgO fibers at 50, 70 and 90 degrees C, for 48 and 96 h. According to Scanning electron microscopy (SEM), dimensions of spider silk fibers determined the dimension of synthesized MgO fibers, while for Mg(OH)(2) fibers, the average diameter was increased with prolonging the hydration period. The surface of Mg(OH)(2) fibers was noticed to be covered with brucite in a form of plates. X-Ray diffraction (XRD) analysis showed that MgO fibers were single-phased (the pure magnesium oxide fibers were obtained), while Mg(OH)(2) fibers were two-or single-phased brucite depending on incubation period, and/or incubation temperature.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska Industrija",
title = "Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers",
pages = "28-23",
number = "1",
volume = "72",
doi = "10.2298/HEMIND170404018D"
}
Dmitrović, S., Prekajski, M., Jokic, B., Branković, G., Zarubica, A., Zikic, V.,& Matović, B.. (2018). Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers. in Hemijska Industrija
Savez hemijskih inženjera, Beograd., 72(1), 23-28.
https://doi.org/10.2298/HEMIND170404018D
Dmitrović S, Prekajski M, Jokic B, Branković G, Zarubica A, Zikic V, Matović B. Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers. in Hemijska Industrija. 2018;72(1):23-28.
doi:10.2298/HEMIND170404018D .
Dmitrović, Svetlana, Prekajski, Marija, Jokic, Bojan, Branković, Goran, Zarubica, Aleksandra, Zikic, Vladimir, Matović, Branko, "Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers" in Hemijska Industrija, 72, no. 1 (2018):23-28,
https://doi.org/10.2298/HEMIND170404018D . .
1
1

Influence of synthesis conditions on morphological features of SBA-15

Kokunesoski, Maja; Saponjic, Aleksandra; Baščarević, Zvezdana; Rakočević, Zlatko; Saponjic, Djordje; Matović, Branko; Babić, Biljana

(Institute for Multidisciplinary Research, University of Belgrade, 2017)

TY  - CONF
AU  - Kokunesoski, Maja
AU  - Saponjic, Aleksandra
AU  - Baščarević, Zvezdana
AU  - Rakočević, Zlatko
AU  - Saponjic, Djordje
AU  - Matović, Branko
AU  - Babić, Biljana
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2980
AB  - Mesoporous SBA-15 materials, of high specific surface area, (~700 m2 g−1), were synthesized by using block copolymer Pluronic P123 as a template and tetraethoxysilane as a silica source. The obtained materials were characterized by X-ray diffraction, scanning electron microscopy (SEM), energy dispersive X-ray (EDS) analysis, and atomic force microscopy (AFM). It was found that small modifications of synthesis conditions influenced morphological features of the synthesized SBA-15 samples. The SEM analysis has shown that the SBA-15 synthesized at a lower temperature and a longer time of reaction (80 °C, 48 h) provided elongated rod-shaped grains about 1μm long. The other sample synthesized at a higher temperature and a shorter time of reaction (100 °C, 24 h) has rounded grains and grains of regular spherical shape with diameters up to 2 μm. The EDS analysis confirmed that the particles of both synthesized samples were of SiO2 content. In addition, the AFM analysis has shown different surface morphologies of the materials synthesized under various conditions.
PB  - Institute for Multidisciplinary Research, University of Belgrade
C3  - 4CSCS-2017 : 4th Conference of the Serbian Ceramic Materials : program and the book of abstracts; June 14-16, Belgrade
T1  - Influence of synthesis conditions on morphological features of SBA-15
EP  - 53
SP  - 53
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2980
ER  - 
@conference{
author = "Kokunesoski, Maja and Saponjic, Aleksandra and Baščarević, Zvezdana and Rakočević, Zlatko and Saponjic, Djordje and Matović, Branko and Babić, Biljana",
year = "2017",
abstract = "Mesoporous SBA-15 materials, of high specific surface area, (~700 m2 g−1), were synthesized by using block copolymer Pluronic P123 as a template and tetraethoxysilane as a silica source. The obtained materials were characterized by X-ray diffraction, scanning electron microscopy (SEM), energy dispersive X-ray (EDS) analysis, and atomic force microscopy (AFM). It was found that small modifications of synthesis conditions influenced morphological features of the synthesized SBA-15 samples. The SEM analysis has shown that the SBA-15 synthesized at a lower temperature and a longer time of reaction (80 °C, 48 h) provided elongated rod-shaped grains about 1μm long. The other sample synthesized at a higher temperature and a shorter time of reaction (100 °C, 24 h) has rounded grains and grains of regular spherical shape with diameters up to 2 μm. The EDS analysis confirmed that the particles of both synthesized samples were of SiO2 content. In addition, the AFM analysis has shown different surface morphologies of the materials synthesized under various conditions.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade",
journal = "4CSCS-2017 : 4th Conference of the Serbian Ceramic Materials : program and the book of abstracts; June 14-16, Belgrade",
title = "Influence of synthesis conditions on morphological features of SBA-15",
pages = "53-53",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2980"
}
Kokunesoski, M., Saponjic, A., Baščarević, Z., Rakočević, Z., Saponjic, D., Matović, B.,& Babić, B.. (2017). Influence of synthesis conditions on morphological features of SBA-15. in 4CSCS-2017 : 4th Conference of the Serbian Ceramic Materials : program and the book of abstracts; June 14-16, Belgrade
Institute for Multidisciplinary Research, University of Belgrade., 53-53.
https://hdl.handle.net/21.15107/rcub_rimsi_2980
Kokunesoski M, Saponjic A, Baščarević Z, Rakočević Z, Saponjic D, Matović B, Babić B. Influence of synthesis conditions on morphological features of SBA-15. in 4CSCS-2017 : 4th Conference of the Serbian Ceramic Materials : program and the book of abstracts; June 14-16, Belgrade. 2017;:53-53.
https://hdl.handle.net/21.15107/rcub_rimsi_2980 .
Kokunesoski, Maja, Saponjic, Aleksandra, Baščarević, Zvezdana, Rakočević, Zlatko, Saponjic, Djordje, Matović, Branko, Babić, Biljana, "Influence of synthesis conditions on morphological features of SBA-15" in 4CSCS-2017 : 4th Conference of the Serbian Ceramic Materials : program and the book of abstracts; June 14-16, Belgrade (2017):53-53,
https://hdl.handle.net/21.15107/rcub_rimsi_2980 .

Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition

Stojadinović, Bojan; Dohcević-Mitrović, Zorana; Stepanenko, Dimitrije; Rosić, Milena; Petronijević, Ivan; Tasić, Nikola; Ilić, Nikola; Matović, Branko; Stojanović, Biljana D

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Stojadinović, Bojan
AU  - Dohcević-Mitrović, Zorana
AU  - Stepanenko, Dimitrije
AU  - Rosić, Milena
AU  - Petronijević, Ivan
AU  - Tasić, Nikola
AU  - Ilić, Nikola
AU  - Matović, Branko
AU  - Stojanović, Biljana D
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1062
AB  - We have studied Ho-doped BiFeO3 nanopowders (Bi1-xHoxFeO3, x = 0-0.15), prepared via sol-gel method, in order to analyse the effect of substitution-driven structural transition on dielectric and ferroelectric properties of bismuth ferrite. X-ray diffraction and Raman study demonstrated that an increased Ho concentration (x >= 0.1) has induced gradual phase transition from rhombohedral to orthorhombic phase. The frequency dependent permittivity of Bi1-xHoxFeO3 nanopowders was analysed within a model which incorporates Debye-like dielectric response and dc and ac conductivity contributions based on universal dielectric response. It was shown that influence of leakage current and grain boundary/interface effects on dielectric and ferroelectric properties was substantially reduced in biphasic Bi1-xHoxFeO3 (x > 0.1) samples. The electrical performance of Bi0.85Ho0.15FeO3 sample, for which orthorhombic phase prevailed, was significantly improved and Bi0.85Ho0.15FeO3 has sustained strong applied electric fields (up to 100 kV/cm) without breakdown. Under strong external fields, the polarization exhibited strong frequency dependence. The low-frequency remnant polarization and coercive field of Bi0.85Ho0.15FeO3 were significantly enhanced. It was proposed that defect dipolar polarization substantially contributed to the intrinsic polarization of Bi0.85Ho0.15FeO3 under strong electric fields at low frequencies.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition
EP  - 16538
IS  - 18
SP  - 16531
VL  - 43
DO  - 10.1016/j.ceramint.2017.09.038
ER  - 
@article{
author = "Stojadinović, Bojan and Dohcević-Mitrović, Zorana and Stepanenko, Dimitrije and Rosić, Milena and Petronijević, Ivan and Tasić, Nikola and Ilić, Nikola and Matović, Branko and Stojanović, Biljana D",
year = "2017",
abstract = "We have studied Ho-doped BiFeO3 nanopowders (Bi1-xHoxFeO3, x = 0-0.15), prepared via sol-gel method, in order to analyse the effect of substitution-driven structural transition on dielectric and ferroelectric properties of bismuth ferrite. X-ray diffraction and Raman study demonstrated that an increased Ho concentration (x >= 0.1) has induced gradual phase transition from rhombohedral to orthorhombic phase. The frequency dependent permittivity of Bi1-xHoxFeO3 nanopowders was analysed within a model which incorporates Debye-like dielectric response and dc and ac conductivity contributions based on universal dielectric response. It was shown that influence of leakage current and grain boundary/interface effects on dielectric and ferroelectric properties was substantially reduced in biphasic Bi1-xHoxFeO3 (x > 0.1) samples. The electrical performance of Bi0.85Ho0.15FeO3 sample, for which orthorhombic phase prevailed, was significantly improved and Bi0.85Ho0.15FeO3 has sustained strong applied electric fields (up to 100 kV/cm) without breakdown. Under strong external fields, the polarization exhibited strong frequency dependence. The low-frequency remnant polarization and coercive field of Bi0.85Ho0.15FeO3 were significantly enhanced. It was proposed that defect dipolar polarization substantially contributed to the intrinsic polarization of Bi0.85Ho0.15FeO3 under strong electric fields at low frequencies.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition",
pages = "16538-16531",
number = "18",
volume = "43",
doi = "10.1016/j.ceramint.2017.09.038"
}
Stojadinović, B., Dohcević-Mitrović, Z., Stepanenko, D., Rosić, M., Petronijević, I., Tasić, N., Ilić, N., Matović, B.,& Stojanović, B. D.. (2017). Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(18), 16531-16538.
https://doi.org/10.1016/j.ceramint.2017.09.038
Stojadinović B, Dohcević-Mitrović Z, Stepanenko D, Rosić M, Petronijević I, Tasić N, Ilić N, Matović B, Stojanović BD. Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition. in Ceramics International. 2017;43(18):16531-16538.
doi:10.1016/j.ceramint.2017.09.038 .
Stojadinović, Bojan, Dohcević-Mitrović, Zorana, Stepanenko, Dimitrije, Rosić, Milena, Petronijević, Ivan, Tasić, Nikola, Ilić, Nikola, Matović, Branko, Stojanović, Biljana D, "Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition" in Ceramics International, 43, no. 18 (2017):16531-16538,
https://doi.org/10.1016/j.ceramint.2017.09.038 . .
18
12
18

Photoluminescent properties of spider silk coated with Eu-doped nanoceria

Dmitrović, Svetlana; Nikolic, Marko G.; Jelenković, Branislav; Prekajski, Marija; Rabasović, Mihailo; Zarubica, Aleksandra; Branković, Goran; Matović, Branko

(Springer, Dordrecht, 2017)

TY  - JOUR
AU  - Dmitrović, Svetlana
AU  - Nikolic, Marko G.
AU  - Jelenković, Branislav
AU  - Prekajski, Marija
AU  - Rabasović, Mihailo
AU  - Zarubica, Aleksandra
AU  - Branković, Goran
AU  - Matović, Branko
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1056
AB  - Spider dragline silk was coated with pure as well as Eu-doped ceria nanopowders at the room temperature. The treatment was done by immersion of the spider silkmesh into aqueous solutions of cerium nitrate (Ce(NO3)(3)) and ammonium hydroxide (NH4OH). Depending on the relationship between Ce3+ ion and ammonium hydroxide concentration, coated fibers exhibited a different thickness. Obtained materials were studied by means of FESEM. It was found that ceria nanoparticles of average size of 3 nm were coated along spider thread. X-ray diffraction (XRD) and selected-area electron diffraction (SAED) confirmed crystal nature of nanoparticle coating of spider silk. By using Williamson-Hall plots, crystallite size and strain were estimated. EDS measurement confirmed the presence of Eu in spider-Eu-doped ceria composite, and according to FTIR analysis, the interaction between CeO2 and spider silk was proposed. The morphology of obtained composite was observed by TEM. The photoluminescence emission spectra of spider silk coated with Eu-doped ceria were measured with two different excitations of 385 and 466 nm. The two-photon excited auto-fluorescence of spider silk coated with Eu-doped ceria was detected using a nonlinear laser scanning microscope. Obtained composite has a potential as a fluorescent labeling material in diverse applications.
PB  - Springer, Dordrecht
T2  - Journal of Nanoparticle Research
T1  - Photoluminescent properties of spider silk coated with Eu-doped nanoceria
IS  - 2
VL  - 19
DO  - 10.1007/s11051-017-3750-9
ER  - 
@article{
author = "Dmitrović, Svetlana and Nikolic, Marko G. and Jelenković, Branislav and Prekajski, Marija and Rabasović, Mihailo and Zarubica, Aleksandra and Branković, Goran and Matović, Branko",
year = "2017",
abstract = "Spider dragline silk was coated with pure as well as Eu-doped ceria nanopowders at the room temperature. The treatment was done by immersion of the spider silkmesh into aqueous solutions of cerium nitrate (Ce(NO3)(3)) and ammonium hydroxide (NH4OH). Depending on the relationship between Ce3+ ion and ammonium hydroxide concentration, coated fibers exhibited a different thickness. Obtained materials were studied by means of FESEM. It was found that ceria nanoparticles of average size of 3 nm were coated along spider thread. X-ray diffraction (XRD) and selected-area electron diffraction (SAED) confirmed crystal nature of nanoparticle coating of spider silk. By using Williamson-Hall plots, crystallite size and strain were estimated. EDS measurement confirmed the presence of Eu in spider-Eu-doped ceria composite, and according to FTIR analysis, the interaction between CeO2 and spider silk was proposed. The morphology of obtained composite was observed by TEM. The photoluminescence emission spectra of spider silk coated with Eu-doped ceria were measured with two different excitations of 385 and 466 nm. The two-photon excited auto-fluorescence of spider silk coated with Eu-doped ceria was detected using a nonlinear laser scanning microscope. Obtained composite has a potential as a fluorescent labeling material in diverse applications.",
publisher = "Springer, Dordrecht",
journal = "Journal of Nanoparticle Research",
title = "Photoluminescent properties of spider silk coated with Eu-doped nanoceria",
number = "2",
volume = "19",
doi = "10.1007/s11051-017-3750-9"
}
Dmitrović, S., Nikolic, M. G., Jelenković, B., Prekajski, M., Rabasović, M., Zarubica, A., Branković, G.,& Matović, B.. (2017). Photoluminescent properties of spider silk coated with Eu-doped nanoceria. in Journal of Nanoparticle Research
Springer, Dordrecht., 19(2).
https://doi.org/10.1007/s11051-017-3750-9
Dmitrović S, Nikolic MG, Jelenković B, Prekajski M, Rabasović M, Zarubica A, Branković G, Matović B. Photoluminescent properties of spider silk coated with Eu-doped nanoceria. in Journal of Nanoparticle Research. 2017;19(2).
doi:10.1007/s11051-017-3750-9 .
Dmitrović, Svetlana, Nikolic, Marko G., Jelenković, Branislav, Prekajski, Marija, Rabasović, Mihailo, Zarubica, Aleksandra, Branković, Goran, Matović, Branko, "Photoluminescent properties of spider silk coated with Eu-doped nanoceria" in Journal of Nanoparticle Research, 19, no. 2 (2017),
https://doi.org/10.1007/s11051-017-3750-9 . .
3
2
3

The effect of nanoceria’s coating on their suspension stability

Milenković, Ivana; Radotić, Ksenija; Matović, Branko; Beškoski, Vladimir

(Serbian Chemical Society, 2016)

TY  - CONF
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
AU  - Beškoski, Vladimir
PY  - 2016
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1838
AB  - Cerium oxide nanoparticles CeO2 (nanoceria) is interesting biomaterial due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on its surface. This dual behavior of nanoceria represents a great pharmacological potential, such as improving the treatment of cancers, drug delivery and catalysis. Nanoceria can protect healthy cells from oxidative stress because they are potent free radical scavenger, but they also show cytotoxicity after prolonged exposure of cells to higher concentrations. The main problem of their further biomedical application is their low solubility in water, which could be improved by coating of nanoparticles. The aim of this study was to develop appropriate methods for coating CeO2 nanoparticles with three different carbohydrates and testing the effect of coating on their suspension stability. For nanoparticles characterisation were used X-Ray and FTIR spectroscopy and SEM (scanning electron microscopy). The effect of nanoparticles' coating on their suspension stability were investigated by measuring turbidity.
PB  - Serbian Chemical Society
C3  - Fourth Conference of Young Chemists of Serbia
T1  - The effect of nanoceria’s coating on their suspension stability
SP  - 86
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1838
ER  - 
@conference{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko and Beškoski, Vladimir",
year = "2016",
abstract = "Cerium oxide nanoparticles CeO2 (nanoceria) is interesting biomaterial due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on its surface. This dual behavior of nanoceria represents a great pharmacological potential, such as improving the treatment of cancers, drug delivery and catalysis. Nanoceria can protect healthy cells from oxidative stress because they are potent free radical scavenger, but they also show cytotoxicity after prolonged exposure of cells to higher concentrations. The main problem of their further biomedical application is their low solubility in water, which could be improved by coating of nanoparticles. The aim of this study was to develop appropriate methods for coating CeO2 nanoparticles with three different carbohydrates and testing the effect of coating on their suspension stability. For nanoparticles characterisation were used X-Ray and FTIR spectroscopy and SEM (scanning electron microscopy). The effect of nanoparticles' coating on their suspension stability were investigated by measuring turbidity.",
publisher = "Serbian Chemical Society",
journal = "Fourth Conference of Young Chemists of Serbia",
title = "The effect of nanoceria’s coating on their suspension stability",
pages = "86",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1838"
}
Milenković, I., Radotić, K., Matović, B.,& Beškoski, V.. (2016). The effect of nanoceria’s coating on their suspension stability. in Fourth Conference of Young Chemists of Serbia
Serbian Chemical Society., 86.
https://hdl.handle.net/21.15107/rcub_rimsi_1838
Milenković I, Radotić K, Matović B, Beškoski V. The effect of nanoceria’s coating on their suspension stability. in Fourth Conference of Young Chemists of Serbia. 2016;:86.
https://hdl.handle.net/21.15107/rcub_rimsi_1838 .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, Beškoski, Vladimir, "The effect of nanoceria’s coating on their suspension stability" in Fourth Conference of Young Chemists of Serbia (2016):86,
https://hdl.handle.net/21.15107/rcub_rimsi_1838 .

The methods of nanoceria’s coating for improving their biomedical application

Milenković, Ivana; Radotić, Ksenija; Matović, Branko

(Institute of Molecular Genetics and Genetic Engineering, University of Belgrade, 2016)

TY  - JOUR
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
PY  - 2016
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1879
AB  - Due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on its surface, CeO2 (nanoceria) is the most important rare-earth oxide and potent free radical scavenger. These nanoparticles can collect reactive oxygen species (ROS) and protect healthy cells from oxidative stress, but they also show cytotoxicity after prolonged exposure of cells to higher concentrations. This dual behavior of nanoceria represents a great pharmacological potential, such as improving the treatment of cancers, drug delivery and catalysis. The aim of this study was to develop of appropriate methods for synthesizing these nanoparticles, which was particularly challenging because of their low solubility. To facilitate nanoparticle’s entry into the cells, we further coated these nanoparticles with the addition of carbohydrate (glucose, levan or pullulan) in the reaction mixture during and after the synthesis of nanoceria. We investigated which of two applied methods of synthesis gave more soluble ceria nanoparticles in order to improve their biomedical application.
PB  - Institute of Molecular Genetics and Genetic Engineering, University of Belgrade
T2  - 2nd Belgrade International Molecular Life Science Conference for Students
T1  - The methods of nanoceria’s coating for improving their biomedical application
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1879
ER  - 
@article{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko",
year = "2016",
abstract = "Due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on its surface, CeO2 (nanoceria) is the most important rare-earth oxide and potent free radical scavenger. These nanoparticles can collect reactive oxygen species (ROS) and protect healthy cells from oxidative stress, but they also show cytotoxicity after prolonged exposure of cells to higher concentrations. This dual behavior of nanoceria represents a great pharmacological potential, such as improving the treatment of cancers, drug delivery and catalysis. The aim of this study was to develop of appropriate methods for synthesizing these nanoparticles, which was particularly challenging because of their low solubility. To facilitate nanoparticle’s entry into the cells, we further coated these nanoparticles with the addition of carbohydrate (glucose, levan or pullulan) in the reaction mixture during and after the synthesis of nanoceria. We investigated which of two applied methods of synthesis gave more soluble ceria nanoparticles in order to improve their biomedical application.",
publisher = "Institute of Molecular Genetics and Genetic Engineering, University of Belgrade",
journal = "2nd Belgrade International Molecular Life Science Conference for Students",
title = "The methods of nanoceria’s coating for improving their biomedical application",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1879"
}
Milenković, I., Radotić, K.,& Matović, B.. (2016). The methods of nanoceria’s coating for improving their biomedical application. in 2nd Belgrade International Molecular Life Science Conference for Students
Institute of Molecular Genetics and Genetic Engineering, University of Belgrade..
https://hdl.handle.net/21.15107/rcub_rimsi_1879
Milenković I, Radotić K, Matović B. The methods of nanoceria’s coating for improving their biomedical application. in 2nd Belgrade International Molecular Life Science Conference for Students. 2016;.
https://hdl.handle.net/21.15107/rcub_rimsi_1879 .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, "The methods of nanoceria’s coating for improving their biomedical application" in 2nd Belgrade International Molecular Life Science Conference for Students (2016),
https://hdl.handle.net/21.15107/rcub_rimsi_1879 .

Comparison of macromolecular interactions in the cell walls of hardwood, softwood and maize by fluorescence and FTIR spectroscopy, differential polarization laser scanning microscopy and X-ray diffraction

Đikanović, Daniela; Devečerski, Aleksandar B; Steinbach, Gabor; Simonović Radosavljević, Jasna; Matović, Branko; Garab, Gyozo; Kalauzi, Aleksandar; Radotić, Ksenija

(Springer, New York, 2016)

TY  - JOUR
AU  - Đikanović, Daniela
AU  - Devečerski, Aleksandar B
AU  - Steinbach, Gabor
AU  - Simonović Radosavljević, Jasna
AU  - Matović, Branko
AU  - Garab, Gyozo
AU  - Kalauzi, Aleksandar
AU  - Radotić, Ksenija
PY  - 2016
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1021
AB  - Interactions between macromolecules in the cell walls of different plant origin were compared, namely spruce wood (Picea omorika (PaniA double dagger) PurkiAe) as an example of softwood, maple wood (Acer platanoides L.) as a hardwood and maize stems (Zea mays L.) as a herbaceous plant from the grass family and widely used agricultural plant. Interactions of macromolecules in isolated cell walls from the three species were compared by using Fourier transform infrared spectroscopy, X-ray diffraction and fluorescence spectroscopy. Linear dichroism of the cell walls was observed by using differential polarization laser scanning microscope (DP-LSM), which provides information of macromolecular order. This method has not previously been used for comparison of the cell walls of various plant origins. It was shown that the maize cell walls have higher amount of hydrogen bonds that lead to more regular packing of cellulose molecules, simpler structure of lignin, and a higher crystallinity of the cell wall in relation to the walls of woody plants. DP-LSM and fluorescence spectroscopy results indicate that maize has simpler and more ordered structure than both woody species. The results of this work provide new data for comparison of the cell wall properties that may be important for selection of appropriate plant for possible applications as a source of biomass. This may be a contribution to the development of efficient deconstruction and separation technologies that enable release of sugar and aromatic compounds from the cell wall macromolecular structure.
PB  - Springer, New York
T2  - Wood Science and Technology
T1  - Comparison of macromolecular interactions in the cell walls of hardwood, softwood and maize by fluorescence and FTIR spectroscopy, differential polarization laser scanning microscopy and X-ray diffraction
EP  - 566
IS  - 3
SP  - 547
VL  - 50
DO  - 10.1007/s00226-015-0792-y
ER  - 
@article{
author = "Đikanović, Daniela and Devečerski, Aleksandar B and Steinbach, Gabor and Simonović Radosavljević, Jasna and Matović, Branko and Garab, Gyozo and Kalauzi, Aleksandar and Radotić, Ksenija",
year = "2016",
abstract = "Interactions between macromolecules in the cell walls of different plant origin were compared, namely spruce wood (Picea omorika (PaniA double dagger) PurkiAe) as an example of softwood, maple wood (Acer platanoides L.) as a hardwood and maize stems (Zea mays L.) as a herbaceous plant from the grass family and widely used agricultural plant. Interactions of macromolecules in isolated cell walls from the three species were compared by using Fourier transform infrared spectroscopy, X-ray diffraction and fluorescence spectroscopy. Linear dichroism of the cell walls was observed by using differential polarization laser scanning microscope (DP-LSM), which provides information of macromolecular order. This method has not previously been used for comparison of the cell walls of various plant origins. It was shown that the maize cell walls have higher amount of hydrogen bonds that lead to more regular packing of cellulose molecules, simpler structure of lignin, and a higher crystallinity of the cell wall in relation to the walls of woody plants. DP-LSM and fluorescence spectroscopy results indicate that maize has simpler and more ordered structure than both woody species. The results of this work provide new data for comparison of the cell wall properties that may be important for selection of appropriate plant for possible applications as a source of biomass. This may be a contribution to the development of efficient deconstruction and separation technologies that enable release of sugar and aromatic compounds from the cell wall macromolecular structure.",
publisher = "Springer, New York",
journal = "Wood Science and Technology",
title = "Comparison of macromolecular interactions in the cell walls of hardwood, softwood and maize by fluorescence and FTIR spectroscopy, differential polarization laser scanning microscopy and X-ray diffraction",
pages = "566-547",
number = "3",
volume = "50",
doi = "10.1007/s00226-015-0792-y"
}
Đikanović, D., Devečerski, A. B., Steinbach, G., Simonović Radosavljević, J., Matović, B., Garab, G., Kalauzi, A.,& Radotić, K.. (2016). Comparison of macromolecular interactions in the cell walls of hardwood, softwood and maize by fluorescence and FTIR spectroscopy, differential polarization laser scanning microscopy and X-ray diffraction. in Wood Science and Technology
Springer, New York., 50(3), 547-566.
https://doi.org/10.1007/s00226-015-0792-y
Đikanović D, Devečerski AB, Steinbach G, Simonović Radosavljević J, Matović B, Garab G, Kalauzi A, Radotić K. Comparison of macromolecular interactions in the cell walls of hardwood, softwood and maize by fluorescence and FTIR spectroscopy, differential polarization laser scanning microscopy and X-ray diffraction. in Wood Science and Technology. 2016;50(3):547-566.
doi:10.1007/s00226-015-0792-y .
Đikanović, Daniela, Devečerski, Aleksandar B, Steinbach, Gabor, Simonović Radosavljević, Jasna, Matović, Branko, Garab, Gyozo, Kalauzi, Aleksandar, Radotić, Ksenija, "Comparison of macromolecular interactions in the cell walls of hardwood, softwood and maize by fluorescence and FTIR spectroscopy, differential polarization laser scanning microscopy and X-ray diffraction" in Wood Science and Technology, 50, no. 3 (2016):547-566,
https://doi.org/10.1007/s00226-015-0792-y . .
15
10
16

Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route

Tomic, N.; Grujic-Brojcin, M.; Fincur, N.; Abramović, B.; Simović, Bojana; Krstic, J.; Matović, Branko; Šćepanović, Maja

(Elsevier Science Sa, Lausanne, 2015)

TY  - JOUR
AU  - Tomic, N.
AU  - Grujic-Brojcin, M.
AU  - Fincur, N.
AU  - Abramović, B.
AU  - Simović, Bojana
AU  - Krstic, J.
AU  - Matović, Branko
AU  - Šćepanović, Maja
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/842
AB  - Two series of nanocrystalline brookite-type powders have been synthesized by using combined sal gel hydrothermal method with titanium tetrachloride (TiCI4) as a precursor and hydrothermal temperature and reaction time varied in the range of 120-200 degrees C and 12-48 h, respectively. The effects of chosen synthesis parameters on structural, morphological and optical properties of synthesized powders have been investigated by the XRPD, SEM, EDS and BET measurements, as well Raman spectroscopy and spectroscopic ellipsometry. The XRPD results have shown that pure brookite phase, with mean crystallite size of -33 nm, has been obtained only in the sample synthesized at 200 degrees C, after 24 h of hydrothermal process. In all other samples anatase phase also appears, whereas rutile and sodium titanate phases have been noticed in the samples synthesized at lower temperatures. The presence of different titania phases has also been confirmed and analyzed by Raman scattering measurements. The SEM measurements have shown spindle-like particles in brookite-rich samples synthesized at 200 degrees C, whereas BET measurements have detected mesoporous structure in these samples. The properties of synthesized powders have been correlated to their photocatalytic efficiency, tested in degradation of alprazolam, one of the 5th generation benzodiazepines. The sample consisted of pure brookite has shown the highest efficiency in the photodegradation of alprazolam, practically equal to the activity of Degussa P25.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Chemistry and Physics
T1  - Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route
EP  - 528
SP  - 518
VL  - 163
DO  - 10.1016/j.matchemphys.2015.08.008
ER  - 
@article{
author = "Tomic, N. and Grujic-Brojcin, M. and Fincur, N. and Abramović, B. and Simović, Bojana and Krstic, J. and Matović, Branko and Šćepanović, Maja",
year = "2015",
abstract = "Two series of nanocrystalline brookite-type powders have been synthesized by using combined sal gel hydrothermal method with titanium tetrachloride (TiCI4) as a precursor and hydrothermal temperature and reaction time varied in the range of 120-200 degrees C and 12-48 h, respectively. The effects of chosen synthesis parameters on structural, morphological and optical properties of synthesized powders have been investigated by the XRPD, SEM, EDS and BET measurements, as well Raman spectroscopy and spectroscopic ellipsometry. The XRPD results have shown that pure brookite phase, with mean crystallite size of -33 nm, has been obtained only in the sample synthesized at 200 degrees C, after 24 h of hydrothermal process. In all other samples anatase phase also appears, whereas rutile and sodium titanate phases have been noticed in the samples synthesized at lower temperatures. The presence of different titania phases has also been confirmed and analyzed by Raman scattering measurements. The SEM measurements have shown spindle-like particles in brookite-rich samples synthesized at 200 degrees C, whereas BET measurements have detected mesoporous structure in these samples. The properties of synthesized powders have been correlated to their photocatalytic efficiency, tested in degradation of alprazolam, one of the 5th generation benzodiazepines. The sample consisted of pure brookite has shown the highest efficiency in the photodegradation of alprazolam, practically equal to the activity of Degussa P25.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Chemistry and Physics",
title = "Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route",
pages = "528-518",
volume = "163",
doi = "10.1016/j.matchemphys.2015.08.008"
}
Tomic, N., Grujic-Brojcin, M., Fincur, N., Abramović, B., Simović, B., Krstic, J., Matović, B.,& Šćepanović, M.. (2015). Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route. in Materials Chemistry and Physics
Elsevier Science Sa, Lausanne., 163, 518-528.
https://doi.org/10.1016/j.matchemphys.2015.08.008
Tomic N, Grujic-Brojcin M, Fincur N, Abramović B, Simović B, Krstic J, Matović B, Šćepanović M. Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route. in Materials Chemistry and Physics. 2015;163:518-528.
doi:10.1016/j.matchemphys.2015.08.008 .
Tomic, N., Grujic-Brojcin, M., Fincur, N., Abramović, B., Simović, Bojana, Krstic, J., Matović, Branko, Šćepanović, Maja, "Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route" in Materials Chemistry and Physics, 163 (2015):518-528,
https://doi.org/10.1016/j.matchemphys.2015.08.008 . .
35
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37

Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC

Stojmenović, M.; Bošković, Snežana B; Žunić, Milan; Babić, Biljana M.; Matović, Branko; Bajuk-Bogdanović, Danica; Mentus, S.

(Elsevier Science Sa, Lausanne, 2015)

TY  - JOUR
AU  - Stojmenović, M.
AU  - Bošković, Snežana B
AU  - Žunić, Milan
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Bajuk-Bogdanović, Danica
AU  - Mentus, S.
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/872
AB  - A series of four different powders ceria doped Ce1-xErxO2-delta (0.05  lt = x  lt = 0.20) were synthesized by applying self-propagating reaction at room temperature (SPRT method). SPRT procedure is based on the self-propagating room temperature reaction between metal nitrates and sodium hydroxide, wherein the reaction is spontaneous and terminates extremely fast. The method is known to assure very precise stoichiometry of the final product in comparison with a tailored composition. XRPD, Raman spectroscopy, TEM and BET measurements were used to characterize the nanopowders at room temperature. It was shown that all obtained powders were single phase solid solutions with a fluorite-type crystal structure and all powder particles have nanometric size (about 3-4 nm). Densification was performed at 1550 degrees C, in an air atmosphere for 2 h. XRPD, SEM and complex impedance method measurements were carried out on sintered samples. Single phase form was evidenced for each sintered materials. The best value of conductivity at 700 degrees C amounted to 1.10 x 10(-2) Omega(-1) cm(-1) for Ce0.85Er0.O-3(2-delta) sample. Corresponding activation energies of conductivity amounted to 0.28 eV in the temperature range 500-700 degrees C.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Chemistry and Physics
T1  - Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC
EP  - 431
SP  - 422
VL  - 153
DO  - 10.1016/j.matchemphys.2015.01.036
ER  - 
@article{
author = "Stojmenović, M. and Bošković, Snežana B and Žunić, Milan and Babić, Biljana M. and Matović, Branko and Bajuk-Bogdanović, Danica and Mentus, S.",
year = "2015",
abstract = "A series of four different powders ceria doped Ce1-xErxO2-delta (0.05  lt = x  lt = 0.20) were synthesized by applying self-propagating reaction at room temperature (SPRT method). SPRT procedure is based on the self-propagating room temperature reaction between metal nitrates and sodium hydroxide, wherein the reaction is spontaneous and terminates extremely fast. The method is known to assure very precise stoichiometry of the final product in comparison with a tailored composition. XRPD, Raman spectroscopy, TEM and BET measurements were used to characterize the nanopowders at room temperature. It was shown that all obtained powders were single phase solid solutions with a fluorite-type crystal structure and all powder particles have nanometric size (about 3-4 nm). Densification was performed at 1550 degrees C, in an air atmosphere for 2 h. XRPD, SEM and complex impedance method measurements were carried out on sintered samples. Single phase form was evidenced for each sintered materials. The best value of conductivity at 700 degrees C amounted to 1.10 x 10(-2) Omega(-1) cm(-1) for Ce0.85Er0.O-3(2-delta) sample. Corresponding activation energies of conductivity amounted to 0.28 eV in the temperature range 500-700 degrees C.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Chemistry and Physics",
title = "Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC",
pages = "431-422",
volume = "153",
doi = "10.1016/j.matchemphys.2015.01.036"
}
Stojmenović, M., Bošković, S. B., Žunić, M., Babić, B. M., Matović, B., Bajuk-Bogdanović, D.,& Mentus, S.. (2015). Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC. in Materials Chemistry and Physics
Elsevier Science Sa, Lausanne., 153, 422-431.
https://doi.org/10.1016/j.matchemphys.2015.01.036
Stojmenović M, Bošković SB, Žunić M, Babić BM, Matović B, Bajuk-Bogdanović D, Mentus S. Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC. in Materials Chemistry and Physics. 2015;153:422-431.
doi:10.1016/j.matchemphys.2015.01.036 .
Stojmenović, M., Bošković, Snežana B, Žunić, Milan, Babić, Biljana M., Matović, Branko, Bajuk-Bogdanović, Danica, Mentus, S., "Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC" in Materials Chemistry and Physics, 153 (2015):422-431,
https://doi.org/10.1016/j.matchemphys.2015.01.036 . .
18
19
23

The methods for nanoceria’s coating in order to improve its solubility

Milenković, Ivana; Radotić, Ksenija; Matović, Branko

(Scientific association for development and affirmation of new technologies, 2015)

TY  - CONF
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1826
AB  - CeO2 (nanoceria) is the most important rare-earth oxide and potent free radical scavenger, due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on its surface. These nanoparticles can collect reactive oxygen species (ROS) and protect healthy cells from oxidative stress, but they also show cytotoxicity. This dual behavior of nanoceria represents a great pharmacological potential, such as improving the treatment of cancers, drug delivery and catalysis. We established the method for synthesizing these nanoparticles, which was particularly challenging because of their low solubility. To facilitate nanoparticle’s entry into the cells, we further coated these nanoparticles with the addition of carbohydrate (glucose, levan or pullulan) in the reaction mixture during and after the synthesis of nanoceria. We investigated by which of two applied methods of synthesis gave more soluble ceria nanoparticles.
PB  - Scientific association for development and affirmation of new technologies
C3  - 2nd International Conference ’’Modern methods of testing and evaluation in science’’
T1  - The methods for nanoceria’s coating in order to improve its solubility
SP  - 208
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1826
ER  - 
@conference{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko",
year = "2015",
abstract = "CeO2 (nanoceria) is the most important rare-earth oxide and potent free radical scavenger, due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on its surface. These nanoparticles can collect reactive oxygen species (ROS) and protect healthy cells from oxidative stress, but they also show cytotoxicity. This dual behavior of nanoceria represents a great pharmacological potential, such as improving the treatment of cancers, drug delivery and catalysis. We established the method for synthesizing these nanoparticles, which was particularly challenging because of their low solubility. To facilitate nanoparticle’s entry into the cells, we further coated these nanoparticles with the addition of carbohydrate (glucose, levan or pullulan) in the reaction mixture during and after the synthesis of nanoceria. We investigated by which of two applied methods of synthesis gave more soluble ceria nanoparticles.",
publisher = "Scientific association for development and affirmation of new technologies",
journal = "2nd International Conference ’’Modern methods of testing and evaluation in science’’",
title = "The methods for nanoceria’s coating in order to improve its solubility",
pages = "208",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1826"
}
Milenković, I., Radotić, K.,& Matović, B.. (2015). The methods for nanoceria’s coating in order to improve its solubility. in 2nd International Conference ’’Modern methods of testing and evaluation in science’’
Scientific association for development and affirmation of new technologies., 208.
https://hdl.handle.net/21.15107/rcub_rimsi_1826
Milenković I, Radotić K, Matović B. The methods for nanoceria’s coating in order to improve its solubility. in 2nd International Conference ’’Modern methods of testing and evaluation in science’’. 2015;:208.
https://hdl.handle.net/21.15107/rcub_rimsi_1826 .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, "The methods for nanoceria’s coating in order to improve its solubility" in 2nd International Conference ’’Modern methods of testing and evaluation in science’’ (2015):208,
https://hdl.handle.net/21.15107/rcub_rimsi_1826 .

Anticancer properties of nanoceria

Milenković, Ivana; Radotić, Ksenija; Matović, Branko

(International Max Planck Research School for Molecular Biology in Gottingen, 2015)

TY  - CONF
AU  - Milenković, Ivana
AU  - Radotić, Ksenija
AU  - Matović, Branko
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1841
AB  - CeO2 (nanoceria) is the most important rare-earth oxide, which application is rapidly emerging. These nanoparticles are potent free radical scavengers, due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on their surface. These ions are promising candidates for improving the treatment of cancers, drug delivery and catalysis. First, they collect reactive oxygen species (ROS) and protect healthy cells from oxidative stress. Also, they show cytotoxicity, which can be manipulated for treatment of cancer cells by inducing targeted cell death with minimal toxicity to surrounding healthy cells. This dual behavior of nanoceria presents a great pharmacological potential. We established the method for synthesizing these nanoparticles. This was particularly challenging because of their low solubility. We further coated these nanoparticles with glucose to facilitate entry into the cells. Untill now, anticancer properties of nanoceria have been poorly characterized. Hence, the aim of this work was to investigate the cytotoxic effect of nanoceria in several cancer cell lines. Nanoceria can be beneficial for the improvement of cancer treatments and a promising candidate for further medical aplication.
PB  - International Max Planck Research School for Molecular Biology in Gottingen
C3  - 12th International PhD Student Symposium Horizons in Molecular Biology
T1  - Anticancer properties of nanoceria
SP  - 101
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1841
ER  - 
@conference{
author = "Milenković, Ivana and Radotić, Ksenija and Matović, Branko",
year = "2015",
abstract = "CeO2 (nanoceria) is the most important rare-earth oxide, which application is rapidly emerging. These nanoparticles are potent free radical scavengers, due to coexistence of Ce3+ and Ce4+ ions and formation of oxygen vacancies on their surface. These ions are promising candidates for improving the treatment of cancers, drug delivery and catalysis. First, they collect reactive oxygen species (ROS) and protect healthy cells from oxidative stress. Also, they show cytotoxicity, which can be manipulated for treatment of cancer cells by inducing targeted cell death with minimal toxicity to surrounding healthy cells. This dual behavior of nanoceria presents a great pharmacological potential. We established the method for synthesizing these nanoparticles. This was particularly challenging because of their low solubility. We further coated these nanoparticles with glucose to facilitate entry into the cells. Untill now, anticancer properties of nanoceria have been poorly characterized. Hence, the aim of this work was to investigate the cytotoxic effect of nanoceria in several cancer cell lines. Nanoceria can be beneficial for the improvement of cancer treatments and a promising candidate for further medical aplication.",
publisher = "International Max Planck Research School for Molecular Biology in Gottingen",
journal = "12th International PhD Student Symposium Horizons in Molecular Biology",
title = "Anticancer properties of nanoceria",
pages = "101",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1841"
}
Milenković, I., Radotić, K.,& Matović, B.. (2015). Anticancer properties of nanoceria. in 12th International PhD Student Symposium Horizons in Molecular Biology
International Max Planck Research School for Molecular Biology in Gottingen., 101.
https://hdl.handle.net/21.15107/rcub_rimsi_1841
Milenković I, Radotić K, Matović B. Anticancer properties of nanoceria. in 12th International PhD Student Symposium Horizons in Molecular Biology. 2015;:101.
https://hdl.handle.net/21.15107/rcub_rimsi_1841 .
Milenković, Ivana, Radotić, Ksenija, Matović, Branko, "Anticancer properties of nanoceria" in 12th International PhD Student Symposium Horizons in Molecular Biology (2015):101,
https://hdl.handle.net/21.15107/rcub_rimsi_1841 .

Anti-cancer effects of cerium oxide nanoparticles and its intracellular redox activity

Pesic, Milica; Podolski-Renic, Ana; Stojković, Sonja; Matović, Branko; Zmejkoski, Danica; Kojić, Vesna; Bogdanović, Gordana; Pavicević, Aleksandra; Mojović, Miloš; Savić, Aleksandar G; Milenković, Ivana; Kalauzi, Aleksandar; Radotić, Ksenija

(Elsevier Ireland Ltd, Clare, 2015)

TY  - JOUR
AU  - Pesic, Milica
AU  - Podolski-Renic, Ana
AU  - Stojković, Sonja
AU  - Matović, Branko
AU  - Zmejkoski, Danica
AU  - Kojić, Vesna
AU  - Bogdanović, Gordana
AU  - Pavicević, Aleksandra
AU  - Mojović, Miloš
AU  - Savić, Aleksandar G
AU  - Milenković, Ivana
AU  - Kalauzi, Aleksandar
AU  - Radotić, Ksenija
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/931
AB  - Data on medical applications of cerium oxide nanoparticles CeO2 (CONP) are promising, yet information regarding their action in cells is incomplete and there are conflicting reports about in vitro toxicity. Herein, we have studied cytotoxic effect of CONP in several cancer and normal cell lines and their potential to change intracellular redox status. The IC50 was achieved only in two of eight tested cell lines, melanoma 518A2 and colorectal adenocarcinoma HT-29. Self-propagating room temperature method was applied to produce CONP with an average crystalline size of 4 nm. The results confirmed presence of Ce3+ and O2- vacancies. The induction of cell death by CONP and the production of reactive oxygen species (ROS) were analyzed by flow-cytometry. Free radicals related antioxidant capacity of the cells was studied by the reduction of stable free radical TEMPONE using electron spin resonance spectroscopy. CONP showed low or moderate cytotoxicity in cancer cell lines: adenocarcinoma DLD1 and multi-drug resistant DLD1-TxR, non-small cell lung carcinoma NCI-H460 and multi-drug resistant NCI-H460/R, while normal cell lines (keratinocytes HaCaT, lung fetal fibroblasts MRC-5) were insensitive. The most sensitive were 518A2 melanoma and HT-29 colorectal adenocarcinoma cell lines, with the IC50 values being between 100 and 200 mu M. Decreased rate of TEMPONE reduction and increased production of certain ROS species (peroxynitrite and hydrogen peroxide anion) indicates that free radical metabolism, thus redox status was changed, and antioxidant capacity damaged in the CONP treated 518A2 and HT-29 cells. In conclusion, changes in intracellular redox status induced by CONP are partly attributed to the prooxidant activity of the nanoparticles. Further, ROS induced cell damages might eventually lead to the cell death. However, low inhibitory potential of CONP in the other human cell lines tested indicates that CONP may be safe for human usage in industry and medicine.
PB  - Elsevier Ireland Ltd, Clare
T2  - Chemico-Biological Interactions
T1  - Anti-cancer effects of cerium oxide nanoparticles and its intracellular redox activity
EP  - 93
SP  - 85
VL  - 232
DO  - 10.1016/j.cbi.2015.03.013
ER  - 
@article{
author = "Pesic, Milica and Podolski-Renic, Ana and Stojković, Sonja and Matović, Branko and Zmejkoski, Danica and Kojić, Vesna and Bogdanović, Gordana and Pavicević, Aleksandra and Mojović, Miloš and Savić, Aleksandar G and Milenković, Ivana and Kalauzi, Aleksandar and Radotić, Ksenija",
year = "2015",
abstract = "Data on medical applications of cerium oxide nanoparticles CeO2 (CONP) are promising, yet information regarding their action in cells is incomplete and there are conflicting reports about in vitro toxicity. Herein, we have studied cytotoxic effect of CONP in several cancer and normal cell lines and their potential to change intracellular redox status. The IC50 was achieved only in two of eight tested cell lines, melanoma 518A2 and colorectal adenocarcinoma HT-29. Self-propagating room temperature method was applied to produce CONP with an average crystalline size of 4 nm. The results confirmed presence of Ce3+ and O2- vacancies. The induction of cell death by CONP and the production of reactive oxygen species (ROS) were analyzed by flow-cytometry. Free radicals related antioxidant capacity of the cells was studied by the reduction of stable free radical TEMPONE using electron spin resonance spectroscopy. CONP showed low or moderate cytotoxicity in cancer cell lines: adenocarcinoma DLD1 and multi-drug resistant DLD1-TxR, non-small cell lung carcinoma NCI-H460 and multi-drug resistant NCI-H460/R, while normal cell lines (keratinocytes HaCaT, lung fetal fibroblasts MRC-5) were insensitive. The most sensitive were 518A2 melanoma and HT-29 colorectal adenocarcinoma cell lines, with the IC50 values being between 100 and 200 mu M. Decreased rate of TEMPONE reduction and increased production of certain ROS species (peroxynitrite and hydrogen peroxide anion) indicates that free radical metabolism, thus redox status was changed, and antioxidant capacity damaged in the CONP treated 518A2 and HT-29 cells. In conclusion, changes in intracellular redox status induced by CONP are partly attributed to the prooxidant activity of the nanoparticles. Further, ROS induced cell damages might eventually lead to the cell death. However, low inhibitory potential of CONP in the other human cell lines tested indicates that CONP may be safe for human usage in industry and medicine.",
publisher = "Elsevier Ireland Ltd, Clare",
journal = "Chemico-Biological Interactions",
title = "Anti-cancer effects of cerium oxide nanoparticles and its intracellular redox activity",
pages = "93-85",
volume = "232",
doi = "10.1016/j.cbi.2015.03.013"
}
Pesic, M., Podolski-Renic, A., Stojković, S., Matović, B., Zmejkoski, D., Kojić, V., Bogdanović, G., Pavicević, A., Mojović, M., Savić, A. G., Milenković, I., Kalauzi, A.,& Radotić, K.. (2015). Anti-cancer effects of cerium oxide nanoparticles and its intracellular redox activity. in Chemico-Biological Interactions
Elsevier Ireland Ltd, Clare., 232, 85-93.
https://doi.org/10.1016/j.cbi.2015.03.013
Pesic M, Podolski-Renic A, Stojković S, Matović B, Zmejkoski D, Kojić V, Bogdanović G, Pavicević A, Mojović M, Savić AG, Milenković I, Kalauzi A, Radotić K. Anti-cancer effects of cerium oxide nanoparticles and its intracellular redox activity. in Chemico-Biological Interactions. 2015;232:85-93.
doi:10.1016/j.cbi.2015.03.013 .
Pesic, Milica, Podolski-Renic, Ana, Stojković, Sonja, Matović, Branko, Zmejkoski, Danica, Kojić, Vesna, Bogdanović, Gordana, Pavicević, Aleksandra, Mojović, Miloš, Savić, Aleksandar G, Milenković, Ivana, Kalauzi, Aleksandar, Radotić, Ksenija, "Anti-cancer effects of cerium oxide nanoparticles and its intracellular redox activity" in Chemico-Biological Interactions, 232 (2015):85-93,
https://doi.org/10.1016/j.cbi.2015.03.013 . .
136
85
136

Synthesis and characterization of tungsten carbide fine powders

Luković, Jelena; Babić, Biljana M.; Bucevac, Dusan; Prekajski, Marija; Pantic, Jelena; Baščarević, Zvezdana; Matović, Branko

(Elsevier Sci Ltd, Oxford, 2015)

TY  - JOUR
AU  - Luković, Jelena
AU  - Babić, Biljana M.
AU  - Bucevac, Dusan
AU  - Prekajski, Marija
AU  - Pantic, Jelena
AU  - Baščarević, Zvezdana
AU  - Matović, Branko
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/899
AB  - Fine tungsten carbide (WC) powder was prepared by solid state reaction between tungsten powder (W) and activated carbon cloth as a new carbon (C) source. The effect of temperature and time of heat treatment as well as the effect of C/W ratio on WC phase formation was studied. The results obtained by X-ray powder diffraction (XRPD) show that obtained powder is single WC. Microstructure and morphology was determinate by means of scanning electron microscopy (SEM). Brunauer-Emmett-Teller (BET) method was used for examining specific surface area and texture of obtained powders. It was found that WC powder was successfully synthesized in excess carbon after eight-hour heat treatment at relatively low temperature (1000 degrees C).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Synthesis and characterization of tungsten carbide fine powders
EP  - 1277
IS  - 1
SP  - 1271
VL  - 41
DO  - 10.1016/j.ceramint.2014.09.057
ER  - 
@article{
author = "Luković, Jelena and Babić, Biljana M. and Bucevac, Dusan and Prekajski, Marija and Pantic, Jelena and Baščarević, Zvezdana and Matović, Branko",
year = "2015",
abstract = "Fine tungsten carbide (WC) powder was prepared by solid state reaction between tungsten powder (W) and activated carbon cloth as a new carbon (C) source. The effect of temperature and time of heat treatment as well as the effect of C/W ratio on WC phase formation was studied. The results obtained by X-ray powder diffraction (XRPD) show that obtained powder is single WC. Microstructure and morphology was determinate by means of scanning electron microscopy (SEM). Brunauer-Emmett-Teller (BET) method was used for examining specific surface area and texture of obtained powders. It was found that WC powder was successfully synthesized in excess carbon after eight-hour heat treatment at relatively low temperature (1000 degrees C).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Synthesis and characterization of tungsten carbide fine powders",
pages = "1277-1271",
number = "1",
volume = "41",
doi = "10.1016/j.ceramint.2014.09.057"
}
Luković, J., Babić, B. M., Bucevac, D., Prekajski, M., Pantic, J., Baščarević, Z.,& Matović, B.. (2015). Synthesis and characterization of tungsten carbide fine powders. in Ceramics International
Elsevier Sci Ltd, Oxford., 41(1), 1271-1277.
https://doi.org/10.1016/j.ceramint.2014.09.057
Luković J, Babić BM, Bucevac D, Prekajski M, Pantic J, Baščarević Z, Matović B. Synthesis and characterization of tungsten carbide fine powders. in Ceramics International. 2015;41(1):1271-1277.
doi:10.1016/j.ceramint.2014.09.057 .
Luković, Jelena, Babić, Biljana M., Bucevac, Dusan, Prekajski, Marija, Pantic, Jelena, Baščarević, Zvezdana, Matović, Branko, "Synthesis and characterization of tungsten carbide fine powders" in Ceramics International, 41, no. 1 (2015):1271-1277,
https://doi.org/10.1016/j.ceramint.2014.09.057 . .
37
21
37

Sintering and electrical properties of Ce1-xBixO2-delta solid solution

Prekajski, Marija; Stojmenović, M.; Radojković, Aleksandar; Branković, Goran; Oraon, H.; Subasri, R.; Matović, Branko

(Elsevier Science Sa, Lausanne, 2014)

TY  - JOUR
AU  - Prekajski, Marija
AU  - Stojmenović, M.
AU  - Radojković, Aleksandar
AU  - Branković, Goran
AU  - Oraon, H.
AU  - Subasri, R.
AU  - Matović, Branko
PY  - 2014
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/804
AB  - Solid solution Ce1-xBixO2-delta nanopowders with the composition of x = 0.1-0.5 were synthesized by using Self Propagating Room Temperature procedure (SPRT). The results obtained by XRPD show that synthesized samples were single-phase solid solution at room temperature. Powders were densified by using Conventional (CS) and Microwave (MS) Sintering techniques at different temperatures, in an air atmosphere for 1 h. Scanning electron microscopy (SEM) and complex impedance method measurements were carried out on sintered samples. Maximum achieved density was for sample with Ce0.80Bi0.20O2-delta composition for both applied sintering techniques. The highest conductivity was obtained for the ceramic composition Ce0.80Bi0.20O2-delta sintered by microwave technique at 700 degrees C.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Sintering and electrical properties of Ce1-xBixO2-delta solid solution
EP  - 568
SP  - 563
VL  - 617
DO  - 10.1016/j.jallcom.2014.08.090
ER  - 
@article{
author = "Prekajski, Marija and Stojmenović, M. and Radojković, Aleksandar and Branković, Goran and Oraon, H. and Subasri, R. and Matović, Branko",
year = "2014",
abstract = "Solid solution Ce1-xBixO2-delta nanopowders with the composition of x = 0.1-0.5 were synthesized by using Self Propagating Room Temperature procedure (SPRT). The results obtained by XRPD show that synthesized samples were single-phase solid solution at room temperature. Powders were densified by using Conventional (CS) and Microwave (MS) Sintering techniques at different temperatures, in an air atmosphere for 1 h. Scanning electron microscopy (SEM) and complex impedance method measurements were carried out on sintered samples. Maximum achieved density was for sample with Ce0.80Bi0.20O2-delta composition for both applied sintering techniques. The highest conductivity was obtained for the ceramic composition Ce0.80Bi0.20O2-delta sintered by microwave technique at 700 degrees C.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Sintering and electrical properties of Ce1-xBixO2-delta solid solution",
pages = "568-563",
volume = "617",
doi = "10.1016/j.jallcom.2014.08.090"
}
Prekajski, M., Stojmenović, M., Radojković, A., Branković, G., Oraon, H., Subasri, R.,& Matović, B.. (2014). Sintering and electrical properties of Ce1-xBixO2-delta solid solution. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 617, 563-568.
https://doi.org/10.1016/j.jallcom.2014.08.090
Prekajski M, Stojmenović M, Radojković A, Branković G, Oraon H, Subasri R, Matović B. Sintering and electrical properties of Ce1-xBixO2-delta solid solution. in Journal of Alloys and Compounds. 2014;617:563-568.
doi:10.1016/j.jallcom.2014.08.090 .
Prekajski, Marija, Stojmenović, M., Radojković, Aleksandar, Branković, Goran, Oraon, H., Subasri, R., Matović, Branko, "Sintering and electrical properties of Ce1-xBixO2-delta solid solution" in Journal of Alloys and Compounds, 617 (2014):563-568,
https://doi.org/10.1016/j.jallcom.2014.08.090 . .
17
14
18

Influence of mechanical activation on sphene based ceramic material synthesis

Pantic, Jelena R; Kremenović, Aleksandar S; Dosen, Anja M; Prekajski, Marija; Stanković, Nadezda G; Baščarević, Zvezdana; Matović, Branko

(Elsevier Sci Ltd, Oxford, 2013)

TY  - JOUR
AU  - Pantic, Jelena R
AU  - Kremenović, Aleksandar S
AU  - Dosen, Anja M
AU  - Prekajski, Marija
AU  - Stanković, Nadezda G
AU  - Baščarević, Zvezdana
AU  - Matović, Branko
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/689
AB  - Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibromilling for homogenization and activation of precursors. The mechanochemical process initially yielded amorphous powders, which on further calcination, crystallized to yield sphene ceramic. The evolution of the phase composition with thermal treatment was investigated by X-ray powder diffraction (XRPD). Powder morphology and particle size distribution were analyzed by scanning electron microscopy (SEM) and laser diffraction, respectively. Rietveld refinement was employed to get the structural information of the synthesized powder. Densification and microstructure evolution was determined by means of density and scanning electron microscopy (SEM). The most favorable conditions for mechanical activation and synthesis of sphene based ceramic material are reported.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Influence of mechanical activation on sphene based ceramic material synthesis
EP  - 488
IS  - 1
SP  - 483
VL  - 39
DO  - 10.1016/j.ceramint.2012.06.052
ER  - 
@article{
author = "Pantic, Jelena R and Kremenović, Aleksandar S and Dosen, Anja M and Prekajski, Marija and Stanković, Nadezda G and Baščarević, Zvezdana and Matović, Branko",
year = "2013",
abstract = "Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibromilling for homogenization and activation of precursors. The mechanochemical process initially yielded amorphous powders, which on further calcination, crystallized to yield sphene ceramic. The evolution of the phase composition with thermal treatment was investigated by X-ray powder diffraction (XRPD). Powder morphology and particle size distribution were analyzed by scanning electron microscopy (SEM) and laser diffraction, respectively. Rietveld refinement was employed to get the structural information of the synthesized powder. Densification and microstructure evolution was determined by means of density and scanning electron microscopy (SEM). The most favorable conditions for mechanical activation and synthesis of sphene based ceramic material are reported.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Influence of mechanical activation on sphene based ceramic material synthesis",
pages = "488-483",
number = "1",
volume = "39",
doi = "10.1016/j.ceramint.2012.06.052"
}
Pantic, J. R., Kremenović, A. S., Dosen, A. M., Prekajski, M., Stanković, N. G., Baščarević, Z.,& Matović, B.. (2013). Influence of mechanical activation on sphene based ceramic material synthesis. in Ceramics International
Elsevier Sci Ltd, Oxford., 39(1), 483-488.
https://doi.org/10.1016/j.ceramint.2012.06.052
Pantic JR, Kremenović AS, Dosen AM, Prekajski M, Stanković NG, Baščarević Z, Matović B. Influence of mechanical activation on sphene based ceramic material synthesis. in Ceramics International. 2013;39(1):483-488.
doi:10.1016/j.ceramint.2012.06.052 .
Pantic, Jelena R, Kremenović, Aleksandar S, Dosen, Anja M, Prekajski, Marija, Stanković, Nadezda G, Baščarević, Zvezdana, Matović, Branko, "Influence of mechanical activation on sphene based ceramic material synthesis" in Ceramics International, 39, no. 1 (2013):483-488,
https://doi.org/10.1016/j.ceramint.2012.06.052 . .
10
11
12

Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria

Bucevac, Dusan; Radojković, Aleksandar; Miljković, Miroslav M; Babić, Biljana M.; Matović, Branko

(Elsevier Sci Ltd, Oxford, 2013)

TY  - JOUR
AU  - Bucevac, Dusan
AU  - Radojković, Aleksandar
AU  - Miljković, Miroslav M
AU  - Babić, Biljana M.
AU  - Matović, Branko
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/699
AB  - Dense Ce0.8Sm0.1Gd0.1O2-delta electrolytes were fabricated by sintering of CeO2 solid solutions which were prepared from metal nitrates and NaOH using self propagating room temperature synthesis (SPRT). Three different routes were employed to obtain CeO2 solid solution powders: (I) hand mixing of reactants, (II) ball milling of reactants and (III) ball milling of Ce0.8Sm0.2O2-delta and Ce0.8Gd0.2O2-delta solid solutions previously prepared by ball milling of corresponding nitrates and NaOH. Density measurements showed that ball milling, which is more convenient than hand mixing, is an effective way to obtain almost full dense samples after presureless sintering at 1550 degrees C for 1 h. These samples had larger grain size and consequently higher conductivity than the samples obtained by hand mixing. The highest conductivity of 2.704 x 10(-2) (Omega cm)(-1) was measured at 700 degrees C in a sample prepared by route II. It was found that reduced grain size in samples obtained by hand mixing leads to a decrease in grain boundary conductivity and therefore decrease in the total conductivity. The results showed that mixing of single doped ceria solid solutions improved densification and inhibited grain growth.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria
EP  - 3611
IS  - 4
SP  - 3603
VL  - 39
DO  - 10.1016/j.ceramint.2012.10.188
ER  - 
@article{
author = "Bucevac, Dusan and Radojković, Aleksandar and Miljković, Miroslav M and Babić, Biljana M. and Matović, Branko",
year = "2013",
abstract = "Dense Ce0.8Sm0.1Gd0.1O2-delta electrolytes were fabricated by sintering of CeO2 solid solutions which were prepared from metal nitrates and NaOH using self propagating room temperature synthesis (SPRT). Three different routes were employed to obtain CeO2 solid solution powders: (I) hand mixing of reactants, (II) ball milling of reactants and (III) ball milling of Ce0.8Sm0.2O2-delta and Ce0.8Gd0.2O2-delta solid solutions previously prepared by ball milling of corresponding nitrates and NaOH. Density measurements showed that ball milling, which is more convenient than hand mixing, is an effective way to obtain almost full dense samples after presureless sintering at 1550 degrees C for 1 h. These samples had larger grain size and consequently higher conductivity than the samples obtained by hand mixing. The highest conductivity of 2.704 x 10(-2) (Omega cm)(-1) was measured at 700 degrees C in a sample prepared by route II. It was found that reduced grain size in samples obtained by hand mixing leads to a decrease in grain boundary conductivity and therefore decrease in the total conductivity. The results showed that mixing of single doped ceria solid solutions improved densification and inhibited grain growth.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria",
pages = "3611-3603",
number = "4",
volume = "39",
doi = "10.1016/j.ceramint.2012.10.188"
}
Bucevac, D., Radojković, A., Miljković, M. M., Babić, B. M.,& Matović, B.. (2013). Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria. in Ceramics International
Elsevier Sci Ltd, Oxford., 39(4), 3603-3611.
https://doi.org/10.1016/j.ceramint.2012.10.188
Bucevac D, Radojković A, Miljković MM, Babić BM, Matović B. Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria. in Ceramics International. 2013;39(4):3603-3611.
doi:10.1016/j.ceramint.2012.10.188 .
Bucevac, Dusan, Radojković, Aleksandar, Miljković, Miroslav M, Babić, Biljana M., Matović, Branko, "Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria" in Ceramics International, 39, no. 4 (2013):3603-3611,
https://doi.org/10.1016/j.ceramint.2012.10.188 . .
8
9
9

Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4

Kljajević, Ljiljana; Matović, Branko; Nenadović, Snežana; Baščarević, Zvezdana; Cvjetičanin, Nikola; Devečerski, Aleksandar B

(2011)

TY  - JOUR
AU  - Kljajević, Ljiljana
AU  - Matović, Branko
AU  - Nenadović, Snežana
AU  - Baščarević, Zvezdana
AU  - Cvjetičanin, Nikola
AU  - Devečerski, Aleksandar B
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2929
AB  - The zirconia/silicon carbide (ZrO2 /SiC) and ZrO2 powders are prepared by carbothermal reduction of natural mineral zircon (ZrSiO4). The zircon powder was mixed with activated carbon as a reducing agent and heat treated in a controlled flow atmosphere of Ar. Phase evolution and phase content were followed as a function of temperature (1573–1973 K) and C/ZrSiO4 ratio (C/ZrSiO4 = 1, 4, 5 and 7), by means of ex-situ X-ray diffraction and SEM/EDS analysis. By varying the temperature and C/ZrSiO4 ratio, different powder compositions were obtained (m-ZrO2; m-ZrO2/c-ZrO2; c-ZrO2; c-ZrO2/SiC).
T2  - Processing and Application of Ceramics
T1  - Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4
EP  - 112
IS  - 2
SP  - 103
VL  - 5
DO  - 10.2298/pac1102103k
ER  - 
@article{
author = "Kljajević, Ljiljana and Matović, Branko and Nenadović, Snežana and Baščarević, Zvezdana and Cvjetičanin, Nikola and Devečerski, Aleksandar B",
year = "2011",
abstract = "The zirconia/silicon carbide (ZrO2 /SiC) and ZrO2 powders are prepared by carbothermal reduction of natural mineral zircon (ZrSiO4). The zircon powder was mixed with activated carbon as a reducing agent and heat treated in a controlled flow atmosphere of Ar. Phase evolution and phase content were followed as a function of temperature (1573–1973 K) and C/ZrSiO4 ratio (C/ZrSiO4 = 1, 4, 5 and 7), by means of ex-situ X-ray diffraction and SEM/EDS analysis. By varying the temperature and C/ZrSiO4 ratio, different powder compositions were obtained (m-ZrO2; m-ZrO2/c-ZrO2; c-ZrO2; c-ZrO2/SiC).",
journal = "Processing and Application of Ceramics",
title = "Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4",
pages = "112-103",
number = "2",
volume = "5",
doi = "10.2298/pac1102103k"
}
Kljajević, L., Matović, B., Nenadović, S., Baščarević, Z., Cvjetičanin, N.,& Devečerski, A. B.. (2011). Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4. in Processing and Application of Ceramics, 5(2), 103-112.
https://doi.org/10.2298/pac1102103k
Kljajević L, Matović B, Nenadović S, Baščarević Z, Cvjetičanin N, Devečerski AB. Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4. in Processing and Application of Ceramics. 2011;5(2):103-112.
doi:10.2298/pac1102103k .
Kljajević, Ljiljana, Matović, Branko, Nenadović, Snežana, Baščarević, Zvezdana, Cvjetičanin, Nikola, Devečerski, Aleksandar B, "Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4" in Processing and Application of Ceramics, 5, no. 2 (2011):103-112,
https://doi.org/10.2298/pac1102103k . .
5

Preparation, sintering and electrical properties of nano-grained multidoped ceria

Bošković, Snežana B; Zec, Slavica P; Branković, Goran; Branković, Zorica; Devečerski, Aleksandar B; Matović, Branko; Aldinger, F

(Elsevier Sci Ltd, Oxford, 2010)

TY  - JOUR
AU  - Bošković, Snežana B
AU  - Zec, Slavica P
AU  - Branković, Goran
AU  - Branković, Zorica
AU  - Devečerski, Aleksandar B
AU  - Matović, Branko
AU  - Aldinger, F
PY  - 2010
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/411
AB  - Multiply doped ceria nanopowders were synthesized by applying MGNP (modified glycine/nitrate procedure). The overall concentration of dopants was kept constant (x = 0.2) whereby Gd ion as the main dopant was gradually substituted by Sm and by Sm + Y. The compositions of solid solutions were calculated by applying defect model introducing anion vacancy radius. Characterization of powders involved BET, TEM, XRD and chemical analyses. Densification was performed at 1500 degrees C, in an oxygen atmosphere for 1 h. The results showed that with increasing number of dopants, specific surface area of powders increased, followed by decrease of crystallite and grain sizes. Densification degree was also found to rise with increasing number of dopants. According to impedance measurements it was found that ionic conductivity was the highest 1.14 x 10(-3) S cm(-1) at 450 degrees C in sample doped with Gd, Sm and Y simultaneously.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Preparation, sintering and electrical properties of nano-grained multidoped ceria
EP  - 127
IS  - 1
SP  - 121
VL  - 36
DO  - 10.1016/j.ceramint.2009.07.015
ER  - 
@article{
author = "Bošković, Snežana B and Zec, Slavica P and Branković, Goran and Branković, Zorica and Devečerski, Aleksandar B and Matović, Branko and Aldinger, F",
year = "2010",
abstract = "Multiply doped ceria nanopowders were synthesized by applying MGNP (modified glycine/nitrate procedure). The overall concentration of dopants was kept constant (x = 0.2) whereby Gd ion as the main dopant was gradually substituted by Sm and by Sm + Y. The compositions of solid solutions were calculated by applying defect model introducing anion vacancy radius. Characterization of powders involved BET, TEM, XRD and chemical analyses. Densification was performed at 1500 degrees C, in an oxygen atmosphere for 1 h. The results showed that with increasing number of dopants, specific surface area of powders increased, followed by decrease of crystallite and grain sizes. Densification degree was also found to rise with increasing number of dopants. According to impedance measurements it was found that ionic conductivity was the highest 1.14 x 10(-3) S cm(-1) at 450 degrees C in sample doped with Gd, Sm and Y simultaneously.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Preparation, sintering and electrical properties of nano-grained multidoped ceria",
pages = "127-121",
number = "1",
volume = "36",
doi = "10.1016/j.ceramint.2009.07.015"
}
Bošković, S. B., Zec, S. P., Branković, G., Branković, Z., Devečerski, A. B., Matović, B.,& Aldinger, F.. (2010). Preparation, sintering and electrical properties of nano-grained multidoped ceria. in Ceramics International
Elsevier Sci Ltd, Oxford., 36(1), 121-127.
https://doi.org/10.1016/j.ceramint.2009.07.015
Bošković SB, Zec SP, Branković G, Branković Z, Devečerski AB, Matović B, Aldinger F. Preparation, sintering and electrical properties of nano-grained multidoped ceria. in Ceramics International. 2010;36(1):121-127.
doi:10.1016/j.ceramint.2009.07.015 .
Bošković, Snežana B, Zec, Slavica P, Branković, Goran, Branković, Zorica, Devečerski, Aleksandar B, Matović, Branko, Aldinger, F, "Preparation, sintering and electrical properties of nano-grained multidoped ceria" in Ceramics International, 36, no. 1 (2010):121-127,
https://doi.org/10.1016/j.ceramint.2009.07.015 . .
12
12
12

Study of the cell wall structure in conifer and weed species, using X ray diffraction and fluorescence spectroscopy

Radotić, Ksenija; Đikanović, Daniela; Simonović, Jasna; Mutavdžić, Dragosav; Bogdanović Pristov, Jelena; Jeremić, Milorad; Branković, Goran; Luković Golić, Danijela; Matović, Branko

(2009)

TY  - CONF
AU  - Radotić, Ksenija
AU  - Đikanović, Daniela
AU  - Simonović, Jasna
AU  - Mutavdžić, Dragosav
AU  - Bogdanović Pristov, Jelena
AU  - Jeremić, Milorad
AU  - Branković, Goran
AU  - Luković Golić, Danijela
AU  - Matović, Branko
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2968
C3  - Workshop Experimental and computational methods in wood micromechanics
T1  - Study of the cell wall structure in conifer and weed species, using X ray diffraction and fluorescence spectroscopy
SP  - 34
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2968
ER  - 
@conference{
author = "Radotić, Ksenija and Đikanović, Daniela and Simonović, Jasna and Mutavdžić, Dragosav and Bogdanović Pristov, Jelena and Jeremić, Milorad and Branković, Goran and Luković Golić, Danijela and Matović, Branko",
year = "2009",
journal = "Workshop Experimental and computational methods in wood micromechanics",
title = "Study of the cell wall structure in conifer and weed species, using X ray diffraction and fluorescence spectroscopy",
pages = "34",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2968"
}
Radotić, K., Đikanović, D., Simonović, J., Mutavdžić, D., Bogdanović Pristov, J., Jeremić, M., Branković, G., Luković Golić, D.,& Matović, B.. (2009). Study of the cell wall structure in conifer and weed species, using X ray diffraction and fluorescence spectroscopy. in Workshop Experimental and computational methods in wood micromechanics, 34.
https://hdl.handle.net/21.15107/rcub_rimsi_2968
Radotić K, Đikanović D, Simonović J, Mutavdžić D, Bogdanović Pristov J, Jeremić M, Branković G, Luković Golić D, Matović B. Study of the cell wall structure in conifer and weed species, using X ray diffraction and fluorescence spectroscopy. in Workshop Experimental and computational methods in wood micromechanics. 2009;:34.
https://hdl.handle.net/21.15107/rcub_rimsi_2968 .
Radotić, Ksenija, Đikanović, Daniela, Simonović, Jasna, Mutavdžić, Dragosav, Bogdanović Pristov, Jelena, Jeremić, Milorad, Branković, Goran, Luković Golić, Danijela, Matović, Branko, "Study of the cell wall structure in conifer and weed species, using X ray diffraction and fluorescence spectroscopy" in Workshop Experimental and computational methods in wood micromechanics (2009):34,
https://hdl.handle.net/21.15107/rcub_rimsi_2968 .