CONTRIBUTION OF DIFFERENT INTERACTIONS TO THE EXCESS GIBBS ENERGY OF MIXING IN AQUEOUS ELECTROLYTE SOLUTIONS
Abstract
The thermodynamic properties of the mixed electrolyte solutions are conveniently described in terms of excess quantities. The excess Gibbs energy of mixing, presents the difference between the excess free energy of a mixed electrolyte solution and free energies of the individual binary electrolyte solutions at the same temperature, pressure and total ionic strength. In this paper the excess Gibbs energy of mixing is calculated for series of mixed electrolyte solutions and possible pairs, triplets, quads or even higher order multiplets were discussed in respect to Scatchard’s mixing parameter values.
Keywords:
Scatchard’s neutral-electrolyte model / activity coefficients / excess Gibbs energySource:
Physical chemistry 2022, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings), 2021, 51-54Publisher:
- Society of Physical Chemists of Serbia
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200287 (Innovation Center of the Faculty of Technology and Metallurgy) (RS-MESTD-inst-2020-200287)
Collections
Institution/Community
Institut za multidisciplinarna istraživanjaTY - CONF AU - Popović, Daniela Ž. AU - Ivanović, Tijana G. AU - Miladinović, Jelena AU - Miladinović, Zoran PY - 2021 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/3098 AB - The thermodynamic properties of the mixed electrolyte solutions are conveniently described in terms of excess quantities. The excess Gibbs energy of mixing, presents the difference between the excess free energy of a mixed electrolyte solution and free energies of the individual binary electrolyte solutions at the same temperature, pressure and total ionic strength. In this paper the excess Gibbs energy of mixing is calculated for series of mixed electrolyte solutions and possible pairs, triplets, quads or even higher order multiplets were discussed in respect to Scatchard’s mixing parameter values. PB - Society of Physical Chemists of Serbia C3 - Physical chemistry 2022, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings) T1 - CONTRIBUTION OF DIFFERENT INTERACTIONS TO THE EXCESS GIBBS ENERGY OF MIXING IN AQUEOUS ELECTROLYTE SOLUTIONS EP - 54 SP - 51 UR - https://hdl.handle.net/21.15107/rcub_rimsi_3098 ER -
@conference{ author = "Popović, Daniela Ž. and Ivanović, Tijana G. and Miladinović, Jelena and Miladinović, Zoran", year = "2021", abstract = "The thermodynamic properties of the mixed electrolyte solutions are conveniently described in terms of excess quantities. The excess Gibbs energy of mixing, presents the difference between the excess free energy of a mixed electrolyte solution and free energies of the individual binary electrolyte solutions at the same temperature, pressure and total ionic strength. In this paper the excess Gibbs energy of mixing is calculated for series of mixed electrolyte solutions and possible pairs, triplets, quads or even higher order multiplets were discussed in respect to Scatchard’s mixing parameter values.", publisher = "Society of Physical Chemists of Serbia", journal = "Physical chemistry 2022, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings)", title = "CONTRIBUTION OF DIFFERENT INTERACTIONS TO THE EXCESS GIBBS ENERGY OF MIXING IN AQUEOUS ELECTROLYTE SOLUTIONS", pages = "54-51", url = "https://hdl.handle.net/21.15107/rcub_rimsi_3098" }
Popović, D. Ž., Ivanović, T. G., Miladinović, J.,& Miladinović, Z.. (2021). CONTRIBUTION OF DIFFERENT INTERACTIONS TO THE EXCESS GIBBS ENERGY OF MIXING IN AQUEOUS ELECTROLYTE SOLUTIONS. in Physical chemistry 2022, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings) Society of Physical Chemists of Serbia., 51-54. https://hdl.handle.net/21.15107/rcub_rimsi_3098
Popović DŽ, Ivanović TG, Miladinović J, Miladinović Z. CONTRIBUTION OF DIFFERENT INTERACTIONS TO THE EXCESS GIBBS ENERGY OF MIXING IN AQUEOUS ELECTROLYTE SOLUTIONS. in Physical chemistry 2022, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings). 2021;:51-54. https://hdl.handle.net/21.15107/rcub_rimsi_3098 .
Popović, Daniela Ž., Ivanović, Tijana G., Miladinović, Jelena, Miladinović, Zoran, "CONTRIBUTION OF DIFFERENT INTERACTIONS TO THE EXCESS GIBBS ENERGY OF MIXING IN AQUEOUS ELECTROLYTE SOLUTIONS" in Physical chemistry 2022, 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings) (2021):51-54, https://hdl.handle.net/21.15107/rcub_rimsi_3098 .