TY  - JOUR
AU  - Nikolic, Nebojša D.
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir G.
AU  - Baščarević, Zvezdana
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1237
AB  - The morphologies of copper dendritic forms obtained in both potentiostatic and galvanostatic regimes of electrolysis with various amounts of the electricity were analyzed by the scanning electron microscopy (SEM) technique. Irrespective of amount of passed electricity, 3D (three dimensional) pine-like dendrites with sharp tips were formed in the potentiostatic regime of electrolysis. On the other hand, the amount of passed electricity had a strong effect on the shape of the 3D pine-like dendrites formed in the galvanostatic regime of electrolysis. Dendrites with sharp tips were formed with smaller amount of passed electricity, while dendrites with globular tips were formed with larger amounts. The change in the shape of the galvanostatically synthesized 3D pine-like dendrites was explained by comparison with copper deposits obtained potentiostatically at overpotentials that corresponded to the final overpotentials during galvanostatic regime of electrolysis for the analyzed amounts of electricity. Based on the similarity of the obtained morphologies at the macro level, it was concluded that the overpotential plays a crucial role in the formation of the electrolytically synthesized dendrites and that the controlled conditions of electrolysis could represent a suitable way for a synthesis of spherical Cu particles by electrolysis.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Overpotential controls the morphology of electrolytically produced copper dendritic forms
EP  - 1220
IS  - 11
SP  - 1209
VL  - 84
DO  - 10.2298/JSC190522066N
ER  - 

@article{
author = "Nikolic, Nebojša D. and Živković, Predrag M. and Pavlović, Miomir G. and Baščarević, Zvezdana",
year = "2019",
abstract = "The morphologies of copper dendritic forms obtained in both potentiostatic and galvanostatic regimes of electrolysis with various amounts of the electricity were analyzed by the scanning electron microscopy (SEM) technique. Irrespective of amount of passed electricity, 3D (three dimensional) pine-like dendrites with sharp tips were formed in the potentiostatic regime of electrolysis. On the other hand, the amount of passed electricity had a strong effect on the shape of the 3D pine-like dendrites formed in the galvanostatic regime of electrolysis. Dendrites with sharp tips were formed with smaller amount of passed electricity, while dendrites with globular tips were formed with larger amounts. The change in the shape of the galvanostatically synthesized 3D pine-like dendrites was explained by comparison with copper deposits obtained potentiostatically at overpotentials that corresponded to the final overpotentials during galvanostatic regime of electrolysis for the analyzed amounts of electricity. Based on the similarity of the obtained morphologies at the macro level, it was concluded that the overpotential plays a crucial role in the formation of the electrolytically synthesized dendrites and that the controlled conditions of electrolysis could represent a suitable way for a synthesis of spherical Cu particles by electrolysis.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Overpotential controls the morphology of electrolytically produced copper dendritic forms",
pages = "1220-1209",
number = "11",
volume = "84",
doi = "10.2298/JSC190522066N"
}

Nikolic, N. D., Živković, P. M., Pavlović, M. G.,& Baščarević, Z.. (2019). Overpotential controls the morphology of electrolytically produced copper dendritic forms. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 84(11), 1209-1220.
https://doi.org/10.2298/JSC190522066N

Nikolic ND, Živković PM, Pavlović MG, Baščarević Z. Overpotential controls the morphology of electrolytically produced copper dendritic forms. in Journal of the Serbian Chemical Society. 2019;84(11):1209-1220.
doi:10.2298/JSC190522066N .

Nikolic, Nebojša D., Živković, Predrag M., Pavlović, Miomir G., Baščarević, Zvezdana, "Overpotential controls the morphology of electrolytically produced copper dendritic forms" in Journal of the Serbian Chemical Society, 84, no. 11 (2019):1209-1220,
https://doi.org/10.2298/JSC190522066N . .

TY  - JOUR
AU  - Nikolic, Nebojša D.
AU  - Živković, Predrag M.
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1028
AB  - The processes of lead and zinc electrodeposition from the very dilute electrolytes were compared by the analysis of polarization characteristics and by the scanning electron microscopic (SEM) analysis of the morphology of the deposits obtained in the galvanostatic regime of electrolysis. The exchange current densities for lead and zinc were estimated by comparison of experimentally obtained polarization curves with the simulated ones obtained for the different the exchange current density to the limiting diffusion current density ratios. Using this way for the estimation of the exchange current density, it is shown that the exchange current density for Pb was more than 1300 times higher than the one for Zn. In this way, it is confirmed that the Pb electrodeposition processes are considerably faster than the Zn electrodeposition processes. The difference in the rate of electrochemical processes was confirmed by a comparison of morphologies of lead and zinc deposits obtained at current densities which corresponded to 0.25 and 0.50 values of the limiting diffusion current densities.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits
EP  - 550
IS  - 5
SP  - 539
VL  - 82
DO  - 10.2298/JSC161114029N
ER  - 

@article{
author = "Nikolic, Nebojša D. and Živković, Predrag M. and Branković, Goran and Pavlović, Miomir G.",
year = "2017",
abstract = "The processes of lead and zinc electrodeposition from the very dilute electrolytes were compared by the analysis of polarization characteristics and by the scanning electron microscopic (SEM) analysis of the morphology of the deposits obtained in the galvanostatic regime of electrolysis. The exchange current densities for lead and zinc were estimated by comparison of experimentally obtained polarization curves with the simulated ones obtained for the different the exchange current density to the limiting diffusion current density ratios. Using this way for the estimation of the exchange current density, it is shown that the exchange current density for Pb was more than 1300 times higher than the one for Zn. In this way, it is confirmed that the Pb electrodeposition processes are considerably faster than the Zn electrodeposition processes. The difference in the rate of electrochemical processes was confirmed by a comparison of morphologies of lead and zinc deposits obtained at current densities which corresponded to 0.25 and 0.50 values of the limiting diffusion current densities.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits",
pages = "550-539",
number = "5",
volume = "82",
doi = "10.2298/JSC161114029N"
}

Nikolic, N. D., Živković, P. M., Branković, G.,& Pavlović, M. G.. (2017). Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(5), 539-550.
https://doi.org/10.2298/JSC161114029N

Nikolic ND, Živković PM, Branković G, Pavlović MG. Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits. in Journal of the Serbian Chemical Society. 2017;82(5):539-550.
doi:10.2298/JSC161114029N .

Nikolic, Nebojša D., Živković, Predrag M., Branković, Goran, Pavlović, Miomir G., "Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits" in Journal of the Serbian Chemical Society, 82, no. 5 (2017):539-550,
https://doi.org/10.2298/JSC161114029N . .

TY  - BOOK
AU  - Pavlović, Mirjana
AU  - Radotić, Ksenija
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1075
AB  - This book provides a multifaceted look into the world of stem cells and explains the similarities and differences between plant and human stem cells. It explores the intersection between animals and plants and explains their cooperative role in bioengineering studies. The book treats both theoretical and practical aspects of stem cell research. It covers the advantages and limitations of many common applications related to stem cells: their sources, categories, engineering of these cells, reprogramming of their functions, and their role as novel cellular therapeutic approach. Written by experts in the field, the book focuses on aspects of stem cells ranging from expansion-propagation to metabolic reprogramming. It introduces the emergence of cancer stem cells and different modalities in targeted cancer stem cell therapies. It is a valuable source of fresh information for academics and researchers, examining molecular mechanisms of animal and plant stem cell regulation and their usage for therapeutic applications. Students at all levels of medical or engineering backgrounds will enjoy the case studies that illustrate and explain mechanisms, interactions, targeted effects, and multimodal therapeutic approaches. Academics, researchers, and professionals who want to expand their knowledge in this field will find this book an exceptional resource.
PB  - Springer International Publishing
T2  - Animal and Plant Stem Cells: Concepts, Propagation and Engineering
T1  - Animal and Plant Stem Cells: Concepts, Propagation and Engineering
EP  - 234
SP  - 1
DO  - 10.1007/978-3-319-47763-3
ER  - 

@book{
author = "Pavlović, Mirjana and Radotić, Ksenija",
year = "2017",
abstract = "This book provides a multifaceted look into the world of stem cells and explains the similarities and differences between plant and human stem cells. It explores the intersection between animals and plants and explains their cooperative role in bioengineering studies. The book treats both theoretical and practical aspects of stem cell research. It covers the advantages and limitations of many common applications related to stem cells: their sources, categories, engineering of these cells, reprogramming of their functions, and their role as novel cellular therapeutic approach. Written by experts in the field, the book focuses on aspects of stem cells ranging from expansion-propagation to metabolic reprogramming. It introduces the emergence of cancer stem cells and different modalities in targeted cancer stem cell therapies. It is a valuable source of fresh information for academics and researchers, examining molecular mechanisms of animal and plant stem cell regulation and their usage for therapeutic applications. Students at all levels of medical or engineering backgrounds will enjoy the case studies that illustrate and explain mechanisms, interactions, targeted effects, and multimodal therapeutic approaches. Academics, researchers, and professionals who want to expand their knowledge in this field will find this book an exceptional resource.",
publisher = "Springer International Publishing",
journal = "Animal and Plant Stem Cells: Concepts, Propagation and Engineering",
title = "Animal and Plant Stem Cells: Concepts, Propagation and Engineering",
pages = "234-1",
doi = "10.1007/978-3-319-47763-3"
}

Pavlović, M.,& Radotić, K.. (2017). Animal and Plant Stem Cells: Concepts, Propagation and Engineering. in Animal and Plant Stem Cells: Concepts, Propagation and Engineering
Springer International Publishing., 1-234.
https://doi.org/10.1007/978-3-319-47763-3

Pavlović M, Radotić K. Animal and Plant Stem Cells: Concepts, Propagation and Engineering. in Animal and Plant Stem Cells: Concepts, Propagation and Engineering. 2017;:1-234.
doi:10.1007/978-3-319-47763-3 .

Pavlović, Mirjana, Radotić, Ksenija, "Animal and Plant Stem Cells: Concepts, Propagation and Engineering" in Animal and Plant Stem Cells: Concepts, Propagation and Engineering (2017):1-234,
https://doi.org/10.1007/978-3-319-47763-3 . .

TY  - JOUR
AU  - Nikolic, Nebojša D.
AU  - Ivanović, Evica R.
AU  - Branković, Goran
AU  - Lačnjevac, Uroš
AU  - Stevanović, Sanja I.
AU  - Stevanović, Jasmina S.
AU  - Pavlović, Miomir G.
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/859
AB  - Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated forms. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.
PB  - Springer, New York
T2  - Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
T1  - Electrochemical and Crystallographic Aspects of Lead Granular Growth
EP  - 1774
IS  - 4
SP  - 1760
VL  - 46
DO  - 10.1007/s11663-015-0385-z
ER  - 

@article{
author = "Nikolic, Nebojša D. and Ivanović, Evica R. and Branković, Goran and Lačnjevac, Uroš and Stevanović, Sanja I. and Stevanović, Jasmina S. and Pavlović, Miomir G.",
year = "2015",
abstract = "Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated forms. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.",
publisher = "Springer, New York",
journal = "Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science",
title = "Electrochemical and Crystallographic Aspects of Lead Granular Growth",
pages = "1774-1760",
number = "4",
volume = "46",
doi = "10.1007/s11663-015-0385-z"
}

Nikolic, N. D., Ivanović, E. R., Branković, G., Lačnjevac, U., Stevanović, S. I., Stevanović, J. S.,& Pavlović, M. G.. (2015). Electrochemical and Crystallographic Aspects of Lead Granular Growth. in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
Springer, New York., 46(4), 1760-1774.
https://doi.org/10.1007/s11663-015-0385-z

Nikolic ND, Ivanović ER, Branković G, Lačnjevac U, Stevanović SI, Stevanović JS, Pavlović MG. Electrochemical and Crystallographic Aspects of Lead Granular Growth. in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science. 2015;46(4):1760-1774.
doi:10.1007/s11663-015-0385-z .

Nikolic, Nebojša D., Ivanović, Evica R., Branković, Goran, Lačnjevac, Uroš, Stevanović, Sanja I., Stevanović, Jasmina S., Pavlović, Miomir G., "Electrochemical and Crystallographic Aspects of Lead Granular Growth" in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 46, no. 4 (2015):1760-1774,
https://doi.org/10.1007/s11663-015-0385-z . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Maksimović, Vesna M
AU  - Branković, Goran
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir G.
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/693
AB  - Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles
EP  - 1395
IS  - 9
SP  - 1387
VL  - 78
DO  - 10.2298/JSC130211034N
ER  - 

@article{
author = "Nikolic, Nebojša D and Maksimović, Vesna M and Branković, Goran and Živković, Predrag M. and Pavlović, Miomir G.",
year = "2013",
abstract = "Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles",
pages = "1395-1387",
number = "9",
volume = "78",
doi = "10.2298/JSC130211034N"
}

Nikolic, N. D., Maksimović, V. M., Branković, G., Živković, P. M.,& Pavlović, M. G.. (2013). Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 78(9), 1387-1395.
https://doi.org/10.2298/JSC130211034N

Nikolic ND, Maksimović VM, Branković G, Živković PM, Pavlović MG. Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society. 2013;78(9):1387-1395.
doi:10.2298/JSC130211034N .

Nikolic, Nebojša D, Maksimović, Vesna M, Branković, Goran, Živković, Predrag M., Pavlović, Miomir G., "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles" in Journal of the Serbian Chemical Society, 78, no. 9 (2013):1387-1395,
https://doi.org/10.2298/JSC130211034N . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/648
AB  - The effect of different current regimes of electrolysis on the micro- and nanostructural characteristics of open porous structures was examined by the analysis of honeycomb-like copper electrodes obtained by constant galvanostatic (DC) electrodeposition and by regimes of pulsating (PC) and reversing (RC) current. An increase in the number of holes fowled by detached hydrogen bubbles, the decrease in wall width between holes and changes in surface morphology around holes from cauliflower-like agglomerates of copper grains to dendrites were observed in the following order: the DC, PC and RC regime. The hole size formed in the RC regime was smaller than the hole size formed in the DC and PC regimes. Analysis of the obtained structural characteristics showed that the specific surface area of the honeycomb-like electrodes was increased by the application of the PC and RC regimes in relation to the DC regime.
PB  - Macedonian Journal of Chemistry and Chemical Engineering
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Effect of the electrolysis regime on the structural characteristics of honeycomb-like electrodes
EP  - 87
IS  - 1
SP  - 79
VL  - 32
DO  - 10.20450/mjcce.2013.112
ER  - 

@article{
author = "Nikolic, Nebojša D and Branković, Goran and Pavlović, Miomir G.",
year = "2013",
abstract = "The effect of different current regimes of electrolysis on the micro- and nanostructural characteristics of open porous structures was examined by the analysis of honeycomb-like copper electrodes obtained by constant galvanostatic (DC) electrodeposition and by regimes of pulsating (PC) and reversing (RC) current. An increase in the number of holes fowled by detached hydrogen bubbles, the decrease in wall width between holes and changes in surface morphology around holes from cauliflower-like agglomerates of copper grains to dendrites were observed in the following order: the DC, PC and RC regime. The hole size formed in the RC regime was smaller than the hole size formed in the DC and PC regimes. Analysis of the obtained structural characteristics showed that the specific surface area of the honeycomb-like electrodes was increased by the application of the PC and RC regimes in relation to the DC regime.",
publisher = "Macedonian Journal of Chemistry and Chemical Engineering",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Effect of the electrolysis regime on the structural characteristics of honeycomb-like electrodes",
pages = "87-79",
number = "1",
volume = "32",
doi = "10.20450/mjcce.2013.112"
}

Nikolic, N. D., Branković, G.,& Pavlović, M. G.. (2013). Effect of the electrolysis regime on the structural characteristics of honeycomb-like electrodes. in Macedonian Journal of Chemistry and Chemical Engineering
Macedonian Journal of Chemistry and Chemical Engineering., 32(1), 79-87.
https://doi.org/10.20450/mjcce.2013.112

Nikolic ND, Branković G, Pavlović MG. Effect of the electrolysis regime on the structural characteristics of honeycomb-like electrodes. in Macedonian Journal of Chemistry and Chemical Engineering. 2013;32(1):79-87.
doi:10.20450/mjcce.2013.112 .

Nikolic, Nebojša D, Branković, Goran, Pavlović, Miomir G., "Effect of the electrolysis regime on the structural characteristics of honeycomb-like electrodes" in Macedonian Journal of Chemistry and Chemical Engineering, 32, no. 1 (2013):79-87,
https://doi.org/10.20450/mjcce.2013.112 . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
PY  - 2012
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/609
AB  - In this study the honeycomb-like copper structures electrodeposited by the regime of pulsating overpotential in the second range were analyzed by the technique of scanning electron microscopy. The overpotential amplitude of 1000 mV, deposition pulse of 1 s, and pause durations of 1, 5, 10 and 15 s were selected for the production of this type of structures. The size of holes which remained upon detachment of hydrogen bubbles do not depend on the length of pause duration. On the other hand, the change in morphology of electrodeposited copper around holes from cauliflower-like agglomerates of copper grains to degenerated dendrites is observed when pause duration was increased. Effects of the application of the regime of pulsating overpotential in the second range on the formation of the honeycomb-like structures were less pronounced than the effects attained by the application of the same regime in the millisecond range. However, they were more pronounced than those attained by electrodeposition in the regime of constant potential.
PB  - International Association of Physical Chemists
T2  - Journal of Electrochemical Science and Engineering
T1  - Formation of the honeycomb-like electrodes by the regime of pulsating overpotential in the second range
EP  - 40
IS  - 1
SP  - 33
VL  - 2
DO  - 10.5599/jese.2012.0009
ER  - 

@article{
author = "Nikolic, Nebojša D and Branković, Goran and Pavlović, Miomir G.",
year = "2012",
abstract = "In this study the honeycomb-like copper structures electrodeposited by the regime of pulsating overpotential in the second range were analyzed by the technique of scanning electron microscopy. The overpotential amplitude of 1000 mV, deposition pulse of 1 s, and pause durations of 1, 5, 10 and 15 s were selected for the production of this type of structures. The size of holes which remained upon detachment of hydrogen bubbles do not depend on the length of pause duration. On the other hand, the change in morphology of electrodeposited copper around holes from cauliflower-like agglomerates of copper grains to degenerated dendrites is observed when pause duration was increased. Effects of the application of the regime of pulsating overpotential in the second range on the formation of the honeycomb-like structures were less pronounced than the effects attained by the application of the same regime in the millisecond range. However, they were more pronounced than those attained by electrodeposition in the regime of constant potential.",
publisher = "International Association of Physical Chemists",
journal = "Journal of Electrochemical Science and Engineering",
title = "Formation of the honeycomb-like electrodes by the regime of pulsating overpotential in the second range",
pages = "40-33",
number = "1",
volume = "2",
doi = "10.5599/jese.2012.0009"
}

Nikolic, N. D., Branković, G.,& Pavlović, M. G.. (2012). Formation of the honeycomb-like electrodes by the regime of pulsating overpotential in the second range. in Journal of Electrochemical Science and Engineering
International Association of Physical Chemists., 2(1), 33-40.
https://doi.org/10.5599/jese.2012.0009

Nikolic ND, Branković G, Pavlović MG. Formation of the honeycomb-like electrodes by the regime of pulsating overpotential in the second range. in Journal of Electrochemical Science and Engineering. 2012;2(1):33-40.
doi:10.5599/jese.2012.0009 .

Nikolic, Nebojša D, Branković, Goran, Pavlović, Miomir G., "Formation of the honeycomb-like electrodes by the regime of pulsating overpotential in the second range" in Journal of Electrochemical Science and Engineering, 2, no. 1 (2012):33-40,
https://doi.org/10.5599/jese.2012.0009 . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
PY  - 2012
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/571
AB  - Morphologies of copper powder particles obtained by both potentiostatic and pulsating overpotential (PO) regimes of electrolysis were investigated by the technique of scanning electron microscopy (SEM). Particles of dendritic or cauliflower-like shape were formed in the dependence of the selected parameters of square-waves PO. The obtained particles were compared with those obtained in the constant potentiostatic regime from solutions of different CuSO4 and H2SO4 concentrations. It was shown that the effect of the decreasing deposition pulse was equivalent to the increasing CuSO4 concentration. Pause duration was equivalent to the used concentration of H2SO4, while the overpotential amplitude in the PO regime corresponded to the overpotential of electrodeposition in the constant potentiostatic mode. Morphologies of powdered deposits were grouped in the three hydrogen co-deposition ranges and their formation was discussed in the dependence of the quantity of hydrogen generated at the cathode surface during electrochemical deposition processes.
PB  - Elsevier Science Sa, Lausanne
T2  - Powder Technology
T1  - Correlate between morphology of powder particles obtained by the different regimes of electrolysis and the quantity of evolved hydrogen
EP  - 277
SP  - 271
VL  - 221
DO  - 10.1016/j.powtec.2012.01.014
ER  - 

@article{
author = "Nikolic, Nebojša D and Branković, Goran and Pavlović, Miomir G.",
year = "2012",
abstract = "Morphologies of copper powder particles obtained by both potentiostatic and pulsating overpotential (PO) regimes of electrolysis were investigated by the technique of scanning electron microscopy (SEM). Particles of dendritic or cauliflower-like shape were formed in the dependence of the selected parameters of square-waves PO. The obtained particles were compared with those obtained in the constant potentiostatic regime from solutions of different CuSO4 and H2SO4 concentrations. It was shown that the effect of the decreasing deposition pulse was equivalent to the increasing CuSO4 concentration. Pause duration was equivalent to the used concentration of H2SO4, while the overpotential amplitude in the PO regime corresponded to the overpotential of electrodeposition in the constant potentiostatic mode. Morphologies of powdered deposits were grouped in the three hydrogen co-deposition ranges and their formation was discussed in the dependence of the quantity of hydrogen generated at the cathode surface during electrochemical deposition processes.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Powder Technology",
title = "Correlate between morphology of powder particles obtained by the different regimes of electrolysis and the quantity of evolved hydrogen",
pages = "277-271",
volume = "221",
doi = "10.1016/j.powtec.2012.01.014"
}

Nikolic, N. D., Branković, G.,& Pavlović, M. G.. (2012). Correlate between morphology of powder particles obtained by the different regimes of electrolysis and the quantity of evolved hydrogen. in Powder Technology
Elsevier Science Sa, Lausanne., 221, 271-277.
https://doi.org/10.1016/j.powtec.2012.01.014

Nikolic ND, Branković G, Pavlović MG. Correlate between morphology of powder particles obtained by the different regimes of electrolysis and the quantity of evolved hydrogen. in Powder Technology. 2012;221:271-277.
doi:10.1016/j.powtec.2012.01.014 .

Nikolic, Nebojša D, Branković, Goran, Pavlović, Miomir G., "Correlate between morphology of powder particles obtained by the different regimes of electrolysis and the quantity of evolved hydrogen" in Powder Technology, 221 (2012):271-277,
https://doi.org/10.1016/j.powtec.2012.01.014 . .

TY  - JOUR
AU  - Maksimović, Vesna M
AU  - Lačnjevac, Uroš
AU  - Stoiljković, Milovan M
AU  - Pavlović, Miomir G.
AU  - Jović, Vladimir D
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/452
AB  - The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centered cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner.
PB  - Elsevier Science Inc, New York
T2  - Materials Characterization
T1  - Morphology and composition of Ni-Co electrodeposited powders
EP  - 1179
IS  - 12
SP  - 1173
VL  - 62
DO  - 10.1016/j.matchar.2011.09.001
ER  - 

@article{
author = "Maksimović, Vesna M and Lačnjevac, Uroš and Stoiljković, Milovan M and Pavlović, Miomir G. and Jović, Vladimir D",
year = "2011",
abstract = "The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centered cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner.",
publisher = "Elsevier Science Inc, New York",
journal = "Materials Characterization",
title = "Morphology and composition of Ni-Co electrodeposited powders",
pages = "1179-1173",
number = "12",
volume = "62",
doi = "10.1016/j.matchar.2011.09.001"
}

Maksimović, V. M., Lačnjevac, U., Stoiljković, M. M., Pavlović, M. G.,& Jović, V. D.. (2011). Morphology and composition of Ni-Co electrodeposited powders. in Materials Characterization
Elsevier Science Inc, New York., 62(12), 1173-1179.
https://doi.org/10.1016/j.matchar.2011.09.001

Maksimović VM, Lačnjevac U, Stoiljković MM, Pavlović MG, Jović VD. Morphology and composition of Ni-Co electrodeposited powders. in Materials Characterization. 2011;62(12):1173-1179.
doi:10.1016/j.matchar.2011.09.001 .

Maksimović, Vesna M, Lačnjevac, Uroš, Stoiljković, Milovan M, Pavlović, Miomir G., Jović, Vladimir D, "Morphology and composition of Ni-Co electrodeposited powders" in Materials Characterization, 62, no. 12 (2011):1173-1179,
https://doi.org/10.1016/j.matchar.2011.09.001 . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Branković, Goran
AU  - Maksimović, Vesna M
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I
PY  - 2010
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/416
AB  - Electrodeposition of copper by pulsating overpotential (PO) regime in the range of hydrogen co-deposition was examined by scanning electron microscopy. It was found that the increase of the pause-to-pulse ratio produced a strong effect on the morphology of electrodeposited copper. Honeycomb-like copper structures were formed with the pause-to-pulse ratios up to 5. Up to this value of the pause-to-pulse ratio, the diameter of the holes formed by attached hydrogen bubbles was decreasing, while their number was increasing by the application of PO regime. The compactness of the formed honeycomb-like structures was also increasing with the increasing pause duration. The increase of the pause-to-pulse ratio suppressed a coalescence of neighboring hydrogen bubbles. Copper dendrites in the interior of the holes and at their shoulders were formed with the higher pause-to-pulse ratios. The size of the formed dendrites, as well as their number, increased with the increasing pause duration. Depth of holes was decreasing with the increasing pause duration. The increased compactness of the obtained structures was explained by the use of a set of equations describing the effect of square-wave PO on electrodeposition process.
PB  - Springer, New York
T2  - Journal of Solid State Electrochemistry
T1  - Application of pulsating overpotential regime on the formation of copper deposits in the range of hydrogen co-deposition
EP  - 338
IS  - 2
SP  - 331
VL  - 14
DO  - 10.1007/s10008-009-0842-1
ER  - 

@article{
author = "Nikolic, Nebojša D and Branković, Goran and Maksimović, Vesna M and Pavlović, Miomir G. and Popov, Konstantin I",
year = "2010",
abstract = "Electrodeposition of copper by pulsating overpotential (PO) regime in the range of hydrogen co-deposition was examined by scanning electron microscopy. It was found that the increase of the pause-to-pulse ratio produced a strong effect on the morphology of electrodeposited copper. Honeycomb-like copper structures were formed with the pause-to-pulse ratios up to 5. Up to this value of the pause-to-pulse ratio, the diameter of the holes formed by attached hydrogen bubbles was decreasing, while their number was increasing by the application of PO regime. The compactness of the formed honeycomb-like structures was also increasing with the increasing pause duration. The increase of the pause-to-pulse ratio suppressed a coalescence of neighboring hydrogen bubbles. Copper dendrites in the interior of the holes and at their shoulders were formed with the higher pause-to-pulse ratios. The size of the formed dendrites, as well as their number, increased with the increasing pause duration. Depth of holes was decreasing with the increasing pause duration. The increased compactness of the obtained structures was explained by the use of a set of equations describing the effect of square-wave PO on electrodeposition process.",
publisher = "Springer, New York",
journal = "Journal of Solid State Electrochemistry",
title = "Application of pulsating overpotential regime on the formation of copper deposits in the range of hydrogen co-deposition",
pages = "338-331",
number = "2",
volume = "14",
doi = "10.1007/s10008-009-0842-1"
}

Nikolic, N. D., Branković, G., Maksimović, V. M., Pavlović, M. G.,& Popov, K. I.. (2010). Application of pulsating overpotential regime on the formation of copper deposits in the range of hydrogen co-deposition. in Journal of Solid State Electrochemistry
Springer, New York., 14(2), 331-338.
https://doi.org/10.1007/s10008-009-0842-1

Nikolic ND, Branković G, Maksimović VM, Pavlović MG, Popov KI. Application of pulsating overpotential regime on the formation of copper deposits in the range of hydrogen co-deposition. in Journal of Solid State Electrochemistry. 2010;14(2):331-338.
doi:10.1007/s10008-009-0842-1 .

Nikolic, Nebojša D, Branković, Goran, Maksimović, Vesna M, Pavlović, Miomir G., Popov, Konstantin I, "Application of pulsating overpotential regime on the formation of copper deposits in the range of hydrogen co-deposition" in Journal of Solid State Electrochemistry, 14, no. 2 (2010):331-338,
https://doi.org/10.1007/s10008-009-0842-1 . .

TY  - JOUR
AU  - Nikolic, Nebojša D.
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/353
AB  - The formation of honeycomb-like structures in the pulsating overpotential (PO) regime was examined by scanning electron microscopy (SEM). The honeycomb-like structures obtained with a square-wave PO of different pause to pulse ratios were compared to the one obtained in the constant potentiostatic regime. Increasing the pause to pulse ratio led to a decrease of the diameter of the holes formed by attached hydrogen bubbles, as well as to an increase in the number of holes formed at the surface area of copper electrodes. The size of the agglomerates of copper grains, of which the walls of the holes were constructed, was reduced with increasing duration of the pause. Also, the uniformity of the honeycomb-like structures was increased by application of the PO regime. It was shown that the effects attained by application of this regime were comparable with those obtained by electrodeposition in a constant potential regime with the addition of specific additives.
PB  - Elsevier Science Inc, New York
T2  - Electrochemistry Communications
T1  - The effects of the pause to pulse ratio in the regime of pulsating overpotential on the formation of honeycomb-like structures
EP  - 424
IS  - 2
SP  - 421
VL  - 11
DO  - 10.1016/j.elecom.2008.12.007
ER  - 

@article{
author = "Nikolic, Nebojša D. and Branković, Goran and Pavlović, Miomir G. and Popov, Konstantin I",
year = "2009",
abstract = "The formation of honeycomb-like structures in the pulsating overpotential (PO) regime was examined by scanning electron microscopy (SEM). The honeycomb-like structures obtained with a square-wave PO of different pause to pulse ratios were compared to the one obtained in the constant potentiostatic regime. Increasing the pause to pulse ratio led to a decrease of the diameter of the holes formed by attached hydrogen bubbles, as well as to an increase in the number of holes formed at the surface area of copper electrodes. The size of the agglomerates of copper grains, of which the walls of the holes were constructed, was reduced with increasing duration of the pause. Also, the uniformity of the honeycomb-like structures was increased by application of the PO regime. It was shown that the effects attained by application of this regime were comparable with those obtained by electrodeposition in a constant potential regime with the addition of specific additives.",
publisher = "Elsevier Science Inc, New York",
journal = "Electrochemistry Communications",
title = "The effects of the pause to pulse ratio in the regime of pulsating overpotential on the formation of honeycomb-like structures",
pages = "424-421",
number = "2",
volume = "11",
doi = "10.1016/j.elecom.2008.12.007"
}

Nikolic, N. D., Branković, G., Pavlović, M. G.,& Popov, K. I.. (2009). The effects of the pause to pulse ratio in the regime of pulsating overpotential on the formation of honeycomb-like structures. in Electrochemistry Communications
Elsevier Science Inc, New York., 11(2), 421-424.
https://doi.org/10.1016/j.elecom.2008.12.007

Nikolic ND, Branković G, Pavlović MG, Popov KI. The effects of the pause to pulse ratio in the regime of pulsating overpotential on the formation of honeycomb-like structures. in Electrochemistry Communications. 2009;11(2):421-424.
doi:10.1016/j.elecom.2008.12.007 .

Nikolic, Nebojša D., Branković, Goran, Pavlović, Miomir G., Popov, Konstantin I, "The effects of the pause to pulse ratio in the regime of pulsating overpotential on the formation of honeycomb-like structures" in Electrochemistry Communications, 11, no. 2 (2009):421-424,
https://doi.org/10.1016/j.elecom.2008.12.007 . .

TY  - JOUR
AU  - Nikolic, Nebojša D.
AU  - Branković, Goran
AU  - Maksimović, Vesna M
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/307
AB  - Electrodeposition of copper by pulsating overpotential (PO) regime in the hydrogen co-deposition range was examined by the determination of the average current efficiency of hydrogen evolution and by microscopic analysis of the morphology of the formed deposits. The techniques of scanning electron microscopy (SEM) and optical microscopy were used for the structural analysis of the copper deposits. Honeycomb-like electrodes were formed with an amplitude overpotential of 1000 mV, a pause of 10 ms, and deposition pulses of 3, 5, 10 and 20 ms. Holes formed by attached hydrogen bubbles were surrounded by dendrites (for deposition pulses of 3 and 5 ms) or agglomerates of copper grains (for 10 and 20 ms). In an interval of deposition pulses between 3 and 10 ms, the length of deposition pulse did not affect the size, number and depth of holes. The change of morphology of copper formed around holes was discussed by the effect of quantity of evolved hydrogen on effectiveness of stirring of solution in the near-electrode layer. The application of square-wave PO with the shorter deposition pulses enabled energy savings in the production of such copper electrodes. For example, the applied deposition pulse of 3 ms enabled energy saving of about 15% in relation to the copper electrode obtained with a deposition pulse of 10 ms (for the unchanged number, size and depth of holes).
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Electroanalytical Chemistry
T1  - Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes
EP  - 119
IS  - 2
SP  - 111
VL  - 635
DO  - 10.1016/j.jelechem.2009.08.005
ER  - 

@article{
author = "Nikolic, Nebojša D. and Branković, Goran and Maksimović, Vesna M and Pavlović, Miomir G. and Popov, Konstantin I",
year = "2009",
abstract = "Electrodeposition of copper by pulsating overpotential (PO) regime in the hydrogen co-deposition range was examined by the determination of the average current efficiency of hydrogen evolution and by microscopic analysis of the morphology of the formed deposits. The techniques of scanning electron microscopy (SEM) and optical microscopy were used for the structural analysis of the copper deposits. Honeycomb-like electrodes were formed with an amplitude overpotential of 1000 mV, a pause of 10 ms, and deposition pulses of 3, 5, 10 and 20 ms. Holes formed by attached hydrogen bubbles were surrounded by dendrites (for deposition pulses of 3 and 5 ms) or agglomerates of copper grains (for 10 and 20 ms). In an interval of deposition pulses between 3 and 10 ms, the length of deposition pulse did not affect the size, number and depth of holes. The change of morphology of copper formed around holes was discussed by the effect of quantity of evolved hydrogen on effectiveness of stirring of solution in the near-electrode layer. The application of square-wave PO with the shorter deposition pulses enabled energy savings in the production of such copper electrodes. For example, the applied deposition pulse of 3 ms enabled energy saving of about 15% in relation to the copper electrode obtained with a deposition pulse of 10 ms (for the unchanged number, size and depth of holes).",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Electroanalytical Chemistry",
title = "Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes",
pages = "119-111",
number = "2",
volume = "635",
doi = "10.1016/j.jelechem.2009.08.005"
}

Nikolic, N. D., Branković, G., Maksimović, V. M., Pavlović, M. G.,& Popov, K. I.. (2009). Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes. in Journal of Electroanalytical Chemistry
Elsevier Science Sa, Lausanne., 635(2), 111-119.
https://doi.org/10.1016/j.jelechem.2009.08.005

Nikolic ND, Branković G, Maksimović VM, Pavlović MG, Popov KI. Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes. in Journal of Electroanalytical Chemistry. 2009;635(2):111-119.
doi:10.1016/j.jelechem.2009.08.005 .

Nikolic, Nebojša D., Branković, Goran, Maksimović, Vesna M, Pavlović, Miomir G., Popov, Konstantin I, "Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes" in Journal of Electroanalytical Chemistry, 635, no. 2 (2009):111-119,
https://doi.org/10.1016/j.jelechem.2009.08.005 . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Pavlović, Ljubica J.
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I
PY  - 2008
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/288
AB  - The ionic equilibrium of the species in the CuSO4-H2SO4-H2O system was employed to systematize the conditions of copper electrodeposition leading to the formation of the honeycomb-like structure. The reason why CuSO4 concentrations higher than 0.15 M are unsuitable for the formation of honeycomb-like structures is shown. The range of H2SO4 concentrations enabling the formation of this type of structure was also determined. The conditions leading to the formation of the honeycomb-like structures are: electrodeposition from solutions with lower concentrations of Cu(II) ions (0.15 M CuSO4 and less) in a concentration range from 0.25 to 1.0 M H2SO4, at a temperature of 18.0 +/- 1.0 degrees C and at overpotentials outside the plateau of the limiting diffusion current density at which hydrogen evolution is vigorous enough to change the hydrodynamic conditions in the near-electrode layer.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition
EP  - 760
IS  - 7
SP  - 753
VL  - 73
DO  - 10.2298/JSC0807753N
ER  - 

@article{
author = "Nikolic, Nebojša D and Pavlović, Ljubica J. and Branković, Goran and Pavlović, Miomir G. and Popov, Konstantin I",
year = "2008",
abstract = "The ionic equilibrium of the species in the CuSO4-H2SO4-H2O system was employed to systematize the conditions of copper electrodeposition leading to the formation of the honeycomb-like structure. The reason why CuSO4 concentrations higher than 0.15 M are unsuitable for the formation of honeycomb-like structures is shown. The range of H2SO4 concentrations enabling the formation of this type of structure was also determined. The conditions leading to the formation of the honeycomb-like structures are: electrodeposition from solutions with lower concentrations of Cu(II) ions (0.15 M CuSO4 and less) in a concentration range from 0.25 to 1.0 M H2SO4, at a temperature of 18.0 +/- 1.0 degrees C and at overpotentials outside the plateau of the limiting diffusion current density at which hydrogen evolution is vigorous enough to change the hydrodynamic conditions in the near-electrode layer.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition",
pages = "760-753",
number = "7",
volume = "73",
doi = "10.2298/JSC0807753N"
}

Nikolic, N. D., Pavlović, L. J., Branković, G., Pavlović, M. G.,& Popov, K. I.. (2008). The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 73(7), 753-760.
https://doi.org/10.2298/JSC0807753N

Nikolic ND, Pavlović LJ, Branković G, Pavlović MG, Popov KI. The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition. in Journal of the Serbian Chemical Society. 2008;73(7):753-760.
doi:10.2298/JSC0807753N .

Nikolic, Nebojša D, Pavlović, Ljubica J., Branković, Goran, Pavlović, Miomir G., Popov, Konstantin I, "The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition" in Journal of the Serbian Chemical Society, 73, no. 7 (2008):753-760,
https://doi.org/10.2298/JSC0807753N . .

TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I
PY  - 2008
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/284
AB  - Formation of irregular deposits by electrodeposition from acid sulfate solutions of various H2SO4 concentrations was examined by the determination of the average current efficiency of hydrogen evolution and by the scanning electron microscopic (SEM) analysis of the copper deposits morphology. Copper dendrites were the dominant morphological form obtained at overpotentials corresponding to the plateaus of the limiting diffusion current density. The number of the formed dendrites was increasing with the decreasing H2SO4 concentration. Holes formed due to the attached hydrogen bubbles were the basic morphological form of electrodeposited copper from all analyzed copper sulfate solutions at overpotentials outside the plateau of the limiting diffusion current density. The honeycomb-like structures (holes of the detached hydrogen bubbles with cauliflower-like agglomerates of copper grains between them) were formed if electrodepositions were performed from 0.15 M CuSO4 in both 0.250 M and 1.0 M H2SO4. On the other hand, aside from the holes and cauliflower-like forms, electrodeposition from 0.15 M CuSO4 in 0.125 M H2SO4 led to the formation of degenerated dendrites and dendritic particles inside channels formed of evolved hydrogen. Holes with shoulders of degenerated dendrites were also formed. The formation of different morphological forms under hydrogen co-deposition was discussed in the terms of hydrodynamic conditions in the near-electrode layer using the values for the break-off diameter of hydrogen bubbles.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Electroanalytical Chemistry
T1  - The effect of hydrogen co-deposition on the morphology of copper electrodeposits. II. Correlation between the properties of electrolytic solutions and the quantity of evolved hydrogen
EP  - 21
IS  - 1
SP  - 13
VL  - 621
DO  - 10.1016/j.jelechem.2008.04.006
ER  - 

@article{
author = "Nikolic, Nebojša D and Branković, Goran and Pavlović, Miomir G. and Popov, Konstantin I",
year = "2008",
abstract = "Formation of irregular deposits by electrodeposition from acid sulfate solutions of various H2SO4 concentrations was examined by the determination of the average current efficiency of hydrogen evolution and by the scanning electron microscopic (SEM) analysis of the copper deposits morphology. Copper dendrites were the dominant morphological form obtained at overpotentials corresponding to the plateaus of the limiting diffusion current density. The number of the formed dendrites was increasing with the decreasing H2SO4 concentration. Holes formed due to the attached hydrogen bubbles were the basic morphological form of electrodeposited copper from all analyzed copper sulfate solutions at overpotentials outside the plateau of the limiting diffusion current density. The honeycomb-like structures (holes of the detached hydrogen bubbles with cauliflower-like agglomerates of copper grains between them) were formed if electrodepositions were performed from 0.15 M CuSO4 in both 0.250 M and 1.0 M H2SO4. On the other hand, aside from the holes and cauliflower-like forms, electrodeposition from 0.15 M CuSO4 in 0.125 M H2SO4 led to the formation of degenerated dendrites and dendritic particles inside channels formed of evolved hydrogen. Holes with shoulders of degenerated dendrites were also formed. The formation of different morphological forms under hydrogen co-deposition was discussed in the terms of hydrodynamic conditions in the near-electrode layer using the values for the break-off diameter of hydrogen bubbles.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Electroanalytical Chemistry",
title = "The effect of hydrogen co-deposition on the morphology of copper electrodeposits. II. Correlation between the properties of electrolytic solutions and the quantity of evolved hydrogen",
pages = "21-13",
number = "1",
volume = "621",
doi = "10.1016/j.jelechem.2008.04.006"
}

Nikolic, N. D., Branković, G., Pavlović, M. G.,& Popov, K. I.. (2008). The effect of hydrogen co-deposition on the morphology of copper electrodeposits. II. Correlation between the properties of electrolytic solutions and the quantity of evolved hydrogen. in Journal of Electroanalytical Chemistry
Elsevier Science Sa, Lausanne., 621(1), 13-21.
https://doi.org/10.1016/j.jelechem.2008.04.006

Nikolic ND, Branković G, Pavlović MG, Popov KI. The effect of hydrogen co-deposition on the morphology of copper electrodeposits. II. Correlation between the properties of electrolytic solutions and the quantity of evolved hydrogen. in Journal of Electroanalytical Chemistry. 2008;621(1):13-21.
doi:10.1016/j.jelechem.2008.04.006 .

Nikolic, Nebojša D, Branković, Goran, Pavlović, Miomir G., Popov, Konstantin I, "The effect of hydrogen co-deposition on the morphology of copper electrodeposits. II. Correlation between the properties of electrolytic solutions and the quantity of evolved hydrogen" in Journal of Electroanalytical Chemistry, 621, no. 1 (2008):13-21,
https://doi.org/10.1016/j.jelechem.2008.04.006 . .