TY  - JOUR
AU  - Nikolic, Nebojša D
AU  - Pavlović, Ljubica J.
AU  - Branković, Goran
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I
PY  - 2008
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/288
AB  - The ionic equilibrium of the species in the CuSO4-H2SO4-H2O system was employed to systematize the conditions of copper electrodeposition leading to the formation of the honeycomb-like structure. The reason why CuSO4 concentrations higher than 0.15 M are unsuitable for the formation of honeycomb-like structures is shown. The range of H2SO4 concentrations enabling the formation of this type of structure was also determined. The conditions leading to the formation of the honeycomb-like structures are: electrodeposition from solutions with lower concentrations of Cu(II) ions (0.15 M CuSO4 and less) in a concentration range from 0.25 to 1.0 M H2SO4, at a temperature of 18.0 +/- 1.0 degrees C and at overpotentials outside the plateau of the limiting diffusion current density at which hydrogen evolution is vigorous enough to change the hydrodynamic conditions in the near-electrode layer.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition
EP  - 760
IS  - 7
SP  - 753
VL  - 73
DO  - 10.2298/JSC0807753N
ER  - 

@article{
author = "Nikolic, Nebojša D and Pavlović, Ljubica J. and Branković, Goran and Pavlović, Miomir G. and Popov, Konstantin I",
year = "2008",
abstract = "The ionic equilibrium of the species in the CuSO4-H2SO4-H2O system was employed to systematize the conditions of copper electrodeposition leading to the formation of the honeycomb-like structure. The reason why CuSO4 concentrations higher than 0.15 M are unsuitable for the formation of honeycomb-like structures is shown. The range of H2SO4 concentrations enabling the formation of this type of structure was also determined. The conditions leading to the formation of the honeycomb-like structures are: electrodeposition from solutions with lower concentrations of Cu(II) ions (0.15 M CuSO4 and less) in a concentration range from 0.25 to 1.0 M H2SO4, at a temperature of 18.0 +/- 1.0 degrees C and at overpotentials outside the plateau of the limiting diffusion current density at which hydrogen evolution is vigorous enough to change the hydrodynamic conditions in the near-electrode layer.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition",
pages = "760-753",
number = "7",
volume = "73",
doi = "10.2298/JSC0807753N"
}

Nikolic, N. D., Pavlović, L. J., Branković, G., Pavlović, M. G.,& Popov, K. I.. (2008). The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 73(7), 753-760.
https://doi.org/10.2298/JSC0807753N

Nikolic ND, Pavlović LJ, Branković G, Pavlović MG, Popov KI. The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition. in Journal of the Serbian Chemical Society. 2008;73(7):753-760.
doi:10.2298/JSC0807753N .

Nikolic, Nebojša D, Pavlović, Ljubica J., Branković, Goran, Pavlović, Miomir G., Popov, Konstantin I, "The ionic equilibrium in the CuSO4-H2SO4-H2O system and the formation of the honeycomb-like structure during copper electrodeposition" in Journal of the Serbian Chemical Society, 73, no. 7 (2008):753-760,
https://doi.org/10.2298/JSC0807753N . .