Pavlović, Vera

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  • Pavlović, Vera (1)
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Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders

Živojinović, Jelena; Kosanović, Darko; Blagojevic, Vladimir; Pavlović, Vera; Ćirković, Jovana; Pavlović, Vladimir

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2022)

TY  - CONF
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Blagojevic, Vladimir
AU  - Pavlović, Vera
AU  - Ćirković, Jovana
AU  - Pavlović, Vladimir
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2946
AB  - Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher values of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022
T1  - Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders
SP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2946
ER  - 
@conference{
author = "Živojinović, Jelena and Kosanović, Darko and Blagojevic, Vladimir and Pavlović, Vera and Ćirković, Jovana and Pavlović, Vladimir",
year = "2022",
abstract = "Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher values of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022",
title = "Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders",
pages = "82",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2946"
}
Živojinović, J., Kosanović, D., Blagojevic, V., Pavlović, V., Ćirković, J.,& Pavlović, V.. (2022). Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders. in The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 82.
https://hdl.handle.net/21.15107/rcub_rimsi_2946
Živojinović J, Kosanović D, Blagojevic V, Pavlović V, Ćirković J, Pavlović V. Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders. in The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022. 2022;:82.
https://hdl.handle.net/21.15107/rcub_rimsi_2946 .
Živojinović, Jelena, Kosanović, Darko, Blagojevic, Vladimir, Pavlović, Vera, Ćirković, Jovana, Pavlović, Vladimir, "Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders" in The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022 (2022):82,
https://hdl.handle.net/21.15107/rcub_rimsi_2946 .