Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders
Аутори
Živojinović, JelenaKosanović, Darko
Blagojevic, Vladimir
Pavlović, Vera
Ćirković, Jovana
Pavlović, Vladimir
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher v...alues of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts.
Кључне речи:
doping / mechanical activation / SrTiO3 powders / microstructureИзвор:
The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022, 2022, 82-Издавач:
- Belgrade : Innovation Center of Faculty of Mechanical Engineering
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200175 (Институт техничких наука САНУ, Београд) (RS-MESTD-inst-2020-200175)
Институција/група
Institut za multidisciplinarna istraživanjaTY - CONF AU - Živojinović, Jelena AU - Kosanović, Darko AU - Blagojevic, Vladimir AU - Pavlović, Vera AU - Ćirković, Jovana AU - Pavlović, Vladimir PY - 2022 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/2946 AB - Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher values of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts. PB - Belgrade : Innovation Center of Faculty of Mechanical Engineering C3 - The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022 T1 - Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders SP - 82 UR - https://hdl.handle.net/21.15107/rcub_rimsi_2946 ER -
@conference{ author = "Živojinović, Jelena and Kosanović, Darko and Blagojevic, Vladimir and Pavlović, Vera and Ćirković, Jovana and Pavlović, Vladimir", year = "2022", abstract = "Manganese doped SrTiO3 powders with various manganese dioxide weight percentages in the range of 1.5, 3 and 6 wp% were prepared by a solid-state method in the presence of mechanical activation (10, 30 and 120 minutes). A systematic investigation by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analisys (PSA), Brunauer-Emmett-Teller (BET) methods and Raman spectroscopy has been undertaken to evaluate the role of dopants on the microstructural and morphological study of the perovskite oxide obtained. The optical properties of the different manganese doped and activated SrTiO3 powders have been also evaluated. Mn insertion in SrTiO3 is discussed considering the possibility for Mn ions to occupy both Ti4+ and Sr2+ sites as well as manganese segregation and Mn incorporation-related non-homogeneities. The results demonstrated that Mn has substituted into the lattice and surface layers of the particles of SrTiO3 powders and the absorption onset shifted to higher values of wavelengths with increasing time of activation and dopant concentration. The lowest value of the band gap (Eg=3.10 eV) was registered with the longest activation for 120 minutes and the highest concentration of dopant (6 wp%). Combining doping with mechanical activation lower values of band gap can be achieved and that fact could be used in subsequent studies to make Mn-SrTiO3 more suitable visible-light photocatalysts.", publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering", journal = "The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022", title = "Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders", pages = "82", url = "https://hdl.handle.net/21.15107/rcub_rimsi_2946" }
Živojinović, J., Kosanović, D., Blagojevic, V., Pavlović, V., Ćirković, J.,& Pavlović, V.. (2022). Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders. in The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022 Belgrade : Innovation Center of Faculty of Mechanical Engineering., 82. https://hdl.handle.net/21.15107/rcub_rimsi_2946
Živojinović J, Kosanović D, Blagojevic V, Pavlović V, Ćirković J, Pavlović V. Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders. in The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022. 2022;:82. https://hdl.handle.net/21.15107/rcub_rimsi_2946 .
Živojinović, Jelena, Kosanović, Darko, Blagojevic, Vladimir, Pavlović, Vera, Ćirković, Jovana, Pavlović, Vladimir, "Influence of MN doping on the evolution of microstructure and optical properties of mechanically activated SrTiO3 powders" in The Book of Abstracts / International Conference of Experimental and Numerical Investigations and New Technologies - CNN TECH 2022 (2022):82, https://hdl.handle.net/21.15107/rcub_rimsi_2946 .