Dojčinović, Milena

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Authority KeyName Variants
orcid::0000-0002-4294-1277
  • Dojčinović, Milena (39)
Projects
Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200053 (University of Belgrade, Institute for Multidisciplinary Research)
info:eu-repo/grantAgreement/MESTD/inst-2020/200053/RS// IMSI Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200175 (Institute of Technical Sciences of SASA, Belgrade)
Lithium-ion batteries and fuel cells - research and development Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200105 (University of Belgrade, Faculty of Mechanical Engineering)
BI-RS-18-19-026] European Union through the European Regional Development Fund-Competitiveness and Cohesion Operational Programme [KK.01.1.1.02.0013]
Integration of PAper-based Nucleic acid testing mEthods into Microfluidic devices for improved biosensing Applications info:eu-repo/grantAgreement/MESTD/inst-2020/200017/RS// Vinca
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) info:eu-repo/grantAgreement/MESTD/inst-2020/200051/RS// IOFH
info:eu-repo/grantAgreement/MESTD/inst-2020/200146/RS// Fizicka hemija Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes
Ministry for Education, Science and Technological Development of the Republic of Serbia project CeNIKS - Croatian Government

Author's Bibliography

ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films

Vasiljević, Zorka Z; Vunduk, Jovana; Dojčinović, Milena; Mišković, Goran; Tadic, Nenad; Vidic, Jasmina; Nikolić, Maria Vesna

(Elsevier, 2024)

TY  - JOUR
AU  - Vasiljević, Zorka Z
AU  - Vunduk, Jovana
AU  - Dojčinović, Milena
AU  - Mišković, Goran
AU  - Tadic, Nenad
AU  - Vidic, Jasmina
AU  - Nikolić, Maria Vesna
PY  - 2024
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3190
AB  - In this paper, we have systematically studied the structural, morphological, and optical properties of Ni-doped TiO2, synthesized via a simple, cost-effective electrospinning method followed by calcination at 500 C. The nanofibers with a core-shell structure were relatively homogeneous, smooth and randomly oriented, and there were no significant differences in fiber diameters due to Ni2+ content. Core loss mapping using electron energy loss spectroscopy confirmed an even distribution of titanium and relatively uniform nickel in the fibers. It was found that doping with 0.5 mol.% Ni2+ decreased the rutile content, while doping with 1 mol.% Ni2+ resulted in a pure anatase phase with a significantly increased specific surface area (36.6 m2/g). Further increase in Ni2+ content (3-10 mol.%) not only prolonged the response of TiO2 nanofibers to visible light, but also increased the specific surface area (49.5 m2/g), decreased crystallite size (7 nm), and increased rutile content in TiO2 (33 wt.%). Photoluminescence analysis revealed that doping TiO2 with different amounts of Ni2+ leads to a gradual decrease of emission spectra intensity and red shift in the maxima positions. The XPS results confirmed that as the Ni2+ content enlarged, the Ti2+ and Ti3+ content increased significantly, effectively promoting the formation of oxygen vacancies. Raman analysis showed that an increase in nickel content (3-5 mol.%) led to a decrease and shift in peak intensity due to Ti3+ formation and also the possible presence of NiTiO3 phases. HRTEM analysis showed that Ni was doped into the substitution sites of both the anatase and rutile TiO2 lattice but had a stronger influence on the distortion of the anatase phase. The obtained results indicate that Ni-doped TiO2 nanofibers are good candidates for photocatalytic applications.
PB  - Elsevier
T2  - Food Packaging and Shelf Life
T1  - ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films
SP  - 101280
VL  - 43
DO  - 10.1016/j.fpsl.2024.101280
ER  - 
@article{
author = "Vasiljević, Zorka Z and Vunduk, Jovana and Dojčinović, Milena and Mišković, Goran and Tadic, Nenad and Vidic, Jasmina and Nikolić, Maria Vesna",
year = "2024",
abstract = "In this paper, we have systematically studied the structural, morphological, and optical properties of Ni-doped TiO2, synthesized via a simple, cost-effective electrospinning method followed by calcination at 500 C. The nanofibers with a core-shell structure were relatively homogeneous, smooth and randomly oriented, and there were no significant differences in fiber diameters due to Ni2+ content. Core loss mapping using electron energy loss spectroscopy confirmed an even distribution of titanium and relatively uniform nickel in the fibers. It was found that doping with 0.5 mol.% Ni2+ decreased the rutile content, while doping with 1 mol.% Ni2+ resulted in a pure anatase phase with a significantly increased specific surface area (36.6 m2/g). Further increase in Ni2+ content (3-10 mol.%) not only prolonged the response of TiO2 nanofibers to visible light, but also increased the specific surface area (49.5 m2/g), decreased crystallite size (7 nm), and increased rutile content in TiO2 (33 wt.%). Photoluminescence analysis revealed that doping TiO2 with different amounts of Ni2+ leads to a gradual decrease of emission spectra intensity and red shift in the maxima positions. The XPS results confirmed that as the Ni2+ content enlarged, the Ti2+ and Ti3+ content increased significantly, effectively promoting the formation of oxygen vacancies. Raman analysis showed that an increase in nickel content (3-5 mol.%) led to a decrease and shift in peak intensity due to Ti3+ formation and also the possible presence of NiTiO3 phases. HRTEM analysis showed that Ni was doped into the substitution sites of both the anatase and rutile TiO2 lattice but had a stronger influence on the distortion of the anatase phase. The obtained results indicate that Ni-doped TiO2 nanofibers are good candidates for photocatalytic applications.",
publisher = "Elsevier",
journal = "Food Packaging and Shelf Life",
title = "ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films",
pages = "101280",
volume = "43",
doi = "10.1016/j.fpsl.2024.101280"
}
Vasiljević, Z. Z., Vunduk, J., Dojčinović, M., Mišković, G., Tadic, N., Vidic, J.,& Nikolić, M. V.. (2024). ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films. in Food Packaging and Shelf Life
Elsevier., 43, 101280.
https://doi.org/10.1016/j.fpsl.2024.101280
Vasiljević ZZ, Vunduk J, Dojčinović M, Mišković G, Tadic N, Vidic J, Nikolić MV. ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films. in Food Packaging and Shelf Life. 2024;43:101280.
doi:10.1016/j.fpsl.2024.101280 .
Vasiljević, Zorka Z, Vunduk, Jovana, Dojčinović, Milena, Mišković, Goran, Tadic, Nenad, Vidic, Jasmina, Nikolić, Maria Vesna, "ZnO and Fe2TiO5 Nanoparticles Obtained by Green Synthesis as Active Components of Alginate Food Packaging Films" in Food Packaging and Shelf Life, 43 (2024):101280,
https://doi.org/10.1016/j.fpsl.2024.101280 . .

Supercapacitor electrodes: Is nickel foam the right substrate for active materials?

Dojčinović, Milena; Stojković Simatović, Ivana; Nikolić, Maria Vesna

(MDPI, 2024)

TY  - JOUR
AU  - Dojčinović, Milena
AU  - Stojković Simatović, Ivana
AU  - Nikolić, Maria Vesna
PY  - 2024
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3185
AB  - Ni foam is an extensively used current collector and substrate in investigations of electrochemically active materials such as supercapacitors and electrocatalysts for oxygen and hydrogen evolution reactions. This material is relatively cheap, porous, and conductive and has a large specific surface area, all of which make it a good substrate. We investigated Ni-Mg ferrites and NiMn2O4 as active materials for electrochemical energy storage. These materials, when loaded on Ni foam, gave promising capacitance values: 172 F/g (at 2 mV/s) for NiMn2O4 in 6 M KOH and 242 F/g (at 2 mV/s) for MgFe2O4 in 3 M KOH. Nevertheless, during the authors’ work, many experimental problems occurred. Inconsistencies in the results directed further investigation towards measuring the capacitance of the active materials using GCE and platinum electrodes as substrates to discover if Ni foam was the culprit of the inconsistencies. When non-nickel substrates were used, both NiMn2O4 and MgFe2O4 showed reduced capacitance. Experimental problems associated with the utilization of Ni foam as a substrate for active materials in supercapacitor electrodes are discussed here, combined with other problems already addressed in the scientific literature
PB  - MDPI
T2  - Materials
T1  - Supercapacitor electrodes: Is nickel foam the right substrate for active materials?
IS  - 6
SP  - 1292
VL  - 17
DO  - 10.3390/ma17061292
ER  - 
@article{
author = "Dojčinović, Milena and Stojković Simatović, Ivana and Nikolić, Maria Vesna",
year = "2024",
abstract = "Ni foam is an extensively used current collector and substrate in investigations of electrochemically active materials such as supercapacitors and electrocatalysts for oxygen and hydrogen evolution reactions. This material is relatively cheap, porous, and conductive and has a large specific surface area, all of which make it a good substrate. We investigated Ni-Mg ferrites and NiMn2O4 as active materials for electrochemical energy storage. These materials, when loaded on Ni foam, gave promising capacitance values: 172 F/g (at 2 mV/s) for NiMn2O4 in 6 M KOH and 242 F/g (at 2 mV/s) for MgFe2O4 in 3 M KOH. Nevertheless, during the authors’ work, many experimental problems occurred. Inconsistencies in the results directed further investigation towards measuring the capacitance of the active materials using GCE and platinum electrodes as substrates to discover if Ni foam was the culprit of the inconsistencies. When non-nickel substrates were used, both NiMn2O4 and MgFe2O4 showed reduced capacitance. Experimental problems associated with the utilization of Ni foam as a substrate for active materials in supercapacitor electrodes are discussed here, combined with other problems already addressed in the scientific literature",
publisher = "MDPI",
journal = "Materials",
title = "Supercapacitor electrodes: Is nickel foam the right substrate for active materials?",
number = "6",
pages = "1292",
volume = "17",
doi = "10.3390/ma17061292"
}
Dojčinović, M., Stojković Simatović, I.,& Nikolić, M. V.. (2024). Supercapacitor electrodes: Is nickel foam the right substrate for active materials?. in Materials
MDPI., 17(6), 1292.
https://doi.org/10.3390/ma17061292
Dojčinović M, Stojković Simatović I, Nikolić MV. Supercapacitor electrodes: Is nickel foam the right substrate for active materials?. in Materials. 2024;17(6):1292.
doi:10.3390/ma17061292 .
Dojčinović, Milena, Stojković Simatović, Ivana, Nikolić, Maria Vesna, "Supercapacitor electrodes: Is nickel foam the right substrate for active materials?" in Materials, 17, no. 6 (2024):1292,
https://doi.org/10.3390/ma17061292 . .

Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5

Vasiljević, Zorka Z; Dojčinović, Milena; Ilić, Nikola; Vujančević, Jelena; Nikolić, Maria Vesna

(Institut za multidisciplinarna istraņivanja Kneza Vińeslava 1, 11000 Belgrade, Serbia, 2023)

TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Ilić, Nikola
AU  - Vujančević, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3177
AB  - Pure phase orthorhombic pseudobrookite (Fe2TiO5) was synthesized using a
modified sol-gel method. Bulk samples were obtained by uniaxial pressing of the
obtained powder into compacts sintered at 900 oC for 2 h. A noticeable NTC
thermistor effect was noted with a B20/55 value of 5747 K and high resistivity of 45
Mcm at 25 oC. A non-linear current-voltage characteristic was observed in the
voltage range (0.2–1100 V) at room temperature (25 oC). Non-saturated (lossy) P-E
loops were obtained at both measured frequencies (100 Hz and 1 kHz) more
expressed for the higher measured frequency, with the maximal polarization of
0.291 mikroC/cm2 and remanent polarization of 0.123 mikroC/cm2 for 20 kV/cm2 and 1 kHz.
Complex impedance measured in the temperature range 20–330 oC enabled analysis
of the contribution of grain boundary and grains to the conduction mechanism. Bulk
conductivity data determined in this temperature range was analyzed using
Jonscher’s universal dielectric response model and showed that the conduction
process followed the nearest neighbor hopping conduction mechanism.
PB  - Institut za multidisciplinarna istraņivanja Kneza Vińeslava 1, 11000 Belgrade, Serbia
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia, 2023
T1  - Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5
SP  - 118
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_3177
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Ilić, Nikola and Vujančević, Jelena and Nikolić, Maria Vesna",
year = "2023",
abstract = "Pure phase orthorhombic pseudobrookite (Fe2TiO5) was synthesized using a
modified sol-gel method. Bulk samples were obtained by uniaxial pressing of the
obtained powder into compacts sintered at 900 oC for 2 h. A noticeable NTC
thermistor effect was noted with a B20/55 value of 5747 K and high resistivity of 45
Mcm at 25 oC. A non-linear current-voltage characteristic was observed in the
voltage range (0.2–1100 V) at room temperature (25 oC). Non-saturated (lossy) P-E
loops were obtained at both measured frequencies (100 Hz and 1 kHz) more
expressed for the higher measured frequency, with the maximal polarization of
0.291 mikroC/cm2 and remanent polarization of 0.123 mikroC/cm2 for 20 kV/cm2 and 1 kHz.
Complex impedance measured in the temperature range 20–330 oC enabled analysis
of the contribution of grain boundary and grains to the conduction mechanism. Bulk
conductivity data determined in this temperature range was analyzed using
Jonscher’s universal dielectric response model and showed that the conduction
process followed the nearest neighbor hopping conduction mechanism.",
publisher = "Institut za multidisciplinarna istraņivanja Kneza Vińeslava 1, 11000 Belgrade, Serbia",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia, 2023",
title = "Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5",
pages = "118",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_3177"
}
Vasiljević, Z. Z., Dojčinović, M., Ilić, N., Vujančević, J.,& Nikolić, M. V.. (2023). Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia, 2023
Institut za multidisciplinarna istraņivanja Kneza Vińeslava 1, 11000 Belgrade, Serbia., 118.
https://hdl.handle.net/21.15107/rcub_rimsi_3177
Vasiljević ZZ, Dojčinović M, Ilić N, Vujančević J, Nikolić MV. Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia, 2023. 2023;:118.
https://hdl.handle.net/21.15107/rcub_rimsi_3177 .
Vasiljević, Zorka Z, Dojčinović, Milena, Ilić, Nikola, Vujančević, Jelena, Nikolić, Maria Vesna, "Investigating NTC thermistor, ferroelectric and electric properties of Fe2TiO5" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia, 2023 (2023):118,
https://hdl.handle.net/21.15107/rcub_rimsi_3177 .

Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4

Dojčinović, Milena; Vasiljević, Zorka Z; Rakočević, Lazar; Pavlović, Vera P.; Ammar, Souad; Vujančević, Jelena; Nikolić, Maria Vesna

(Faculty of Technology, University of Novi Sad, Novi Sad, Serbia, 2023)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Rakočević, Lazar
AU  - Pavlović, Vera P.
AU  - Ammar, Souad
AU  - Vujančević, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2291
AB  - Mixed spinel ferrites MgxNi1-xFe2O4 were synthesized via sol-gel combustion synthesis with citric acid as fuel, followed by calcination at 700 °C for 3 hours. Obtained powders were characterized via X-ray diffraction analysis (XRD), X-ray photoelectron (XPS), FTIR and Raman spectroscopy and FESEM microscopy. Elemental composition was examined via energy dispersive spectroscopy (EDS). Humidity sensing properties were tested by measuring AC impedance in a climactic chamber at 25 °C and in the relative humidity range of 40–90%. Temperature sensing properties were tested by measuring DC resistance at 40% RH in the temperature range 40–90 °C. Synthesized powders were proven to be pure spinel Fd 3m phase with spherical, slightly agglomerated particles. Substitution of Mg with Ni results in structural changes such as a change in inversion parameter and particle agglomeration, which influences sensing properties of the material. Results show that the sensing properties of magnesium ferrite can be improved by incorporating 10% of nickel in the spinel lattice structure. Mg0.9Ni0.1Fe2O4 exhibited higher temperature sensitivity and higher sensitivity towards humidity compared to MgFe2O4, while further substitution of Mg with Ni resulted in the decline of sensing properties, increase in particle size and agglomeration degree.
PB  - Faculty of Technology, University of Novi Sad, Novi Sad, Serbia
C3  - Programme and Book of Abstracts of The 15th Conference for Young Scientists in Ceramics (CYSC-2023)
T1  - Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4
SP  - 62
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2291
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Rakočević, Lazar and Pavlović, Vera P. and Ammar, Souad and Vujančević, Jelena and Nikolić, Maria Vesna",
year = "2023",
abstract = "Mixed spinel ferrites MgxNi1-xFe2O4 were synthesized via sol-gel combustion synthesis with citric acid as fuel, followed by calcination at 700 °C for 3 hours. Obtained powders were characterized via X-ray diffraction analysis (XRD), X-ray photoelectron (XPS), FTIR and Raman spectroscopy and FESEM microscopy. Elemental composition was examined via energy dispersive spectroscopy (EDS). Humidity sensing properties were tested by measuring AC impedance in a climactic chamber at 25 °C and in the relative humidity range of 40–90%. Temperature sensing properties were tested by measuring DC resistance at 40% RH in the temperature range 40–90 °C. Synthesized powders were proven to be pure spinel Fd 3m phase with spherical, slightly agglomerated particles. Substitution of Mg with Ni results in structural changes such as a change in inversion parameter and particle agglomeration, which influences sensing properties of the material. Results show that the sensing properties of magnesium ferrite can be improved by incorporating 10% of nickel in the spinel lattice structure. Mg0.9Ni0.1Fe2O4 exhibited higher temperature sensitivity and higher sensitivity towards humidity compared to MgFe2O4, while further substitution of Mg with Ni resulted in the decline of sensing properties, increase in particle size and agglomeration degree.",
publisher = "Faculty of Technology, University of Novi Sad, Novi Sad, Serbia",
journal = "Programme and Book of Abstracts of The 15th Conference for Young Scientists in Ceramics (CYSC-2023)",
title = "Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4",
pages = "62",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2291"
}
Dojčinović, M., Vasiljević, Z. Z., Rakočević, L., Pavlović, V. P., Ammar, S., Vujančević, J.,& Nikolić, M. V.. (2023). Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4. in Programme and Book of Abstracts of The 15th Conference for Young Scientists in Ceramics (CYSC-2023)
Faculty of Technology, University of Novi Sad, Novi Sad, Serbia., 62.
https://hdl.handle.net/21.15107/rcub_rimsi_2291
Dojčinović M, Vasiljević ZZ, Rakočević L, Pavlović VP, Ammar S, Vujančević J, Nikolić MV. Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4. in Programme and Book of Abstracts of The 15th Conference for Young Scientists in Ceramics (CYSC-2023). 2023;:62.
https://hdl.handle.net/21.15107/rcub_rimsi_2291 .
Dojčinović, Milena, Vasiljević, Zorka Z, Rakočević, Lazar, Pavlović, Vera P., Ammar, Souad, Vujančević, Jelena, Nikolić, Maria Vesna, "Magnesium substitution with nickel and its influence on the sensing properties of MgFe2O4" in Programme and Book of Abstracts of The 15th Conference for Young Scientists in Ceramics (CYSC-2023) (2023):62,
https://hdl.handle.net/21.15107/rcub_rimsi_2291 .

Biosynthesis of ZnO nanoparticles using agro-waste with antibacterial and antioxidant activity

Vasiljević, Zorka Z; Vunduk, Jovana; Dojčinović, Milena; Bartolić, Dragana; Ognjanović, Miloš; Tadic, Nenad; Mišković, Goran; Nikolić, Maria Vesna

(Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Vunduk, Jovana
AU  - Dojčinović, Milena
AU  - Bartolić, Dragana
AU  - Ognjanović, Miloš
AU  - Tadic, Nenad
AU  - Mišković, Goran
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2132
AB  - Green synthesis is a more sustainable option using renewable biomass such as plants as
reducing or stabilizing agents compared to toxic chemical compounds. These biological
substances also behave as capping agents, which control the size and shape of the
nanoparticles. In this work, ZnO nanoparticles (NPs) have been prepared via a simple, low
cost and ecofriendly method using citrus fruit peel and extracts as biological reducing agents.
Zinc nitrate and zinc acetate were used as a source of zinc ions.XRD analysis revealed the
formation of a ZnO wurtzite phase without impurities. Synthesized ZnO NPs with an average
electronic band gap ∼3 eV were obtained and found to have round-like, hexagonal-like or
needle-like structures depending on precursor type. EDS analysis showed a homogeoneous
distribution in Zn and O elements, attributed to single-phase ZnO constituents. Antibacterial
and antioxidant activities of synthesized NPs were evaluated. Obtained results showed that
ZnO synthesized from nitrate precursors are more effective in inhibiting growth of
Salmonella and Staphylococcus Aureus. Antioxidant activity of ZnO NPs determined using
CUPRAC and ABTS assays showed higher activity of ZnO obtained using nitrate precursors.
The maximum scavenging activity of 90% was observed at the concentration of 10 mg/ml
PB  - Serbian Ceramic Society
C3  - Serbian Ceramic Society Conference - ADVANCED CERAMICS AND APPLICATION XI Program and the Book of Abstracts
T1  - Biosynthesis of ZnO nanoparticles using agro-waste with antibacterial and antioxidant activity
SP  - 43
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2132
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Vunduk, Jovana and Dojčinović, Milena and Bartolić, Dragana and Ognjanović, Miloš and Tadic, Nenad and Mišković, Goran and Nikolić, Maria Vesna",
year = "2023",
abstract = "Green synthesis is a more sustainable option using renewable biomass such as plants as
reducing or stabilizing agents compared to toxic chemical compounds. These biological
substances also behave as capping agents, which control the size and shape of the
nanoparticles. In this work, ZnO nanoparticles (NPs) have been prepared via a simple, low
cost and ecofriendly method using citrus fruit peel and extracts as biological reducing agents.
Zinc nitrate and zinc acetate were used as a source of zinc ions.XRD analysis revealed the
formation of a ZnO wurtzite phase without impurities. Synthesized ZnO NPs with an average
electronic band gap ∼3 eV were obtained and found to have round-like, hexagonal-like or
needle-like structures depending on precursor type. EDS analysis showed a homogeoneous
distribution in Zn and O elements, attributed to single-phase ZnO constituents. Antibacterial
and antioxidant activities of synthesized NPs were evaluated. Obtained results showed that
ZnO synthesized from nitrate precursors are more effective in inhibiting growth of
Salmonella and Staphylococcus Aureus. Antioxidant activity of ZnO NPs determined using
CUPRAC and ABTS assays showed higher activity of ZnO obtained using nitrate precursors.
The maximum scavenging activity of 90% was observed at the concentration of 10 mg/ml",
publisher = "Serbian Ceramic Society",
journal = "Serbian Ceramic Society Conference - ADVANCED CERAMICS AND APPLICATION XI Program and the Book of Abstracts",
title = "Biosynthesis of ZnO nanoparticles using agro-waste with antibacterial and antioxidant activity",
pages = "43",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2132"
}
Vasiljević, Z. Z., Vunduk, J., Dojčinović, M., Bartolić, D., Ognjanović, M., Tadic, N., Mišković, G.,& Nikolić, M. V.. (2023). Biosynthesis of ZnO nanoparticles using agro-waste with antibacterial and antioxidant activity. in Serbian Ceramic Society Conference - ADVANCED CERAMICS AND APPLICATION XI Program and the Book of Abstracts
Serbian Ceramic Society., 43.
https://hdl.handle.net/21.15107/rcub_rimsi_2132
Vasiljević ZZ, Vunduk J, Dojčinović M, Bartolić D, Ognjanović M, Tadic N, Mišković G, Nikolić MV. Biosynthesis of ZnO nanoparticles using agro-waste with antibacterial and antioxidant activity. in Serbian Ceramic Society Conference - ADVANCED CERAMICS AND APPLICATION XI Program and the Book of Abstracts. 2023;:43.
https://hdl.handle.net/21.15107/rcub_rimsi_2132 .
Vasiljević, Zorka Z, Vunduk, Jovana, Dojčinović, Milena, Bartolić, Dragana, Ognjanović, Miloš, Tadic, Nenad, Mišković, Goran, Nikolić, Maria Vesna, "Biosynthesis of ZnO nanoparticles using agro-waste with antibacterial and antioxidant activity" in Serbian Ceramic Society Conference - ADVANCED CERAMICS AND APPLICATION XI Program and the Book of Abstracts (2023):43,
https://hdl.handle.net/21.15107/rcub_rimsi_2132 .

Ferroelectric, Magnetic and Dielectric Properties of SrCo0.2Zn0.2Fe11.6O18.8 Hexaferrite Obtained by “One-Pot” Green Sol-Gel Synthesis Utilizing Citrus reticulata Peel Extract

Nikolić, Maria Vesna; Ammar, Souad; Ilić, Nikola; Singh, Charanjeet; Dojčinović, Milena; Jotania, Rajshree

(MDPI, 2023)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Ammar, Souad
AU  - Ilić, Nikola
AU  - Singh, Charanjeet
AU  - Dojčinović, Milena
AU  - Jotania, Rajshree
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2128
AB  - SrCo0.2Zn0.2Fe11.6O18.8 hexaferrite was obtained by a “one-pot” green sol-gel synthesis
method utilizing aqueous mandarin orange (Citrus reticulata) peel extract as an eco-friendly reactant.
The research objective was to analyze the influence of cobalt and zinc co-doping and the synthesis
process on the structure, morphology, magnetic, dielectric and ferroelectric properties of strontium
hexaferrite in view of future applications. Structural and morphological characterization using
X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron
microscopy coupled to energy dispersive X-ray spectrometry (SEM-EDX) confirmed the formation
of a Co and Zn ion incorporated M-type magnetoplumbite with c/a lattice parameter ratio of 3.919
as crystallite nanoplatelets of 32 and 53 nm in thickness and width, respectively. The magnetic
hysteresis loop of the synthesized powder recorded by a vibrating sample magnetometer (VSM) at
room temperature confirmed its ferromagnetic nature with a coercive field (Hc) of 2539 Oe and a
saturation magnetization (Ms) and remanent magnetization (Mr) of 44.6 emu/g and 21.4 emu/g,
respectively. Room temperature ferroelectric loops measured at 100 Hz showed a maximal (Pmax)
and a remanent (Pr) polarization of 195.4 and 31.0 nC/cm2, respectively. Both increased when the
magnitude of the applied electrical field increased in the 1–24 kV/cm range. The dielectric constant
decreased with the frequency increase, in accordance with the Maxwell–Wagner model, while the
conductivity changed according to the Jonscher power law. The complex impedance was modeled
with an equivalent circuit, enabling identification of the dominant contribution of grain boundary
resistance (272.3 MW) and capacitance (7.16 pF).
PB  - MDPI
T2  - Crystals
T1  - Ferroelectric, Magnetic and Dielectric Properties of SrCo0.2Zn0.2Fe11.6O18.8 Hexaferrite Obtained by “One-Pot” Green Sol-Gel Synthesis Utilizing Citrus reticulata Peel Extract
IS  - 1452
VL  - 13
DO  - 10.3390/cryst13101452
ER  - 
@article{
author = "Nikolić, Maria Vesna and Ammar, Souad and Ilić, Nikola and Singh, Charanjeet and Dojčinović, Milena and Jotania, Rajshree",
year = "2023",
abstract = "SrCo0.2Zn0.2Fe11.6O18.8 hexaferrite was obtained by a “one-pot” green sol-gel synthesis
method utilizing aqueous mandarin orange (Citrus reticulata) peel extract as an eco-friendly reactant.
The research objective was to analyze the influence of cobalt and zinc co-doping and the synthesis
process on the structure, morphology, magnetic, dielectric and ferroelectric properties of strontium
hexaferrite in view of future applications. Structural and morphological characterization using
X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron
microscopy coupled to energy dispersive X-ray spectrometry (SEM-EDX) confirmed the formation
of a Co and Zn ion incorporated M-type magnetoplumbite with c/a lattice parameter ratio of 3.919
as crystallite nanoplatelets of 32 and 53 nm in thickness and width, respectively. The magnetic
hysteresis loop of the synthesized powder recorded by a vibrating sample magnetometer (VSM) at
room temperature confirmed its ferromagnetic nature with a coercive field (Hc) of 2539 Oe and a
saturation magnetization (Ms) and remanent magnetization (Mr) of 44.6 emu/g and 21.4 emu/g,
respectively. Room temperature ferroelectric loops measured at 100 Hz showed a maximal (Pmax)
and a remanent (Pr) polarization of 195.4 and 31.0 nC/cm2, respectively. Both increased when the
magnitude of the applied electrical field increased in the 1–24 kV/cm range. The dielectric constant
decreased with the frequency increase, in accordance with the Maxwell–Wagner model, while the
conductivity changed according to the Jonscher power law. The complex impedance was modeled
with an equivalent circuit, enabling identification of the dominant contribution of grain boundary
resistance (272.3 MW) and capacitance (7.16 pF).",
publisher = "MDPI",
journal = "Crystals",
title = "Ferroelectric, Magnetic and Dielectric Properties of SrCo0.2Zn0.2Fe11.6O18.8 Hexaferrite Obtained by “One-Pot” Green Sol-Gel Synthesis Utilizing Citrus reticulata Peel Extract",
number = "1452",
volume = "13",
doi = "10.3390/cryst13101452"
}
Nikolić, M. V., Ammar, S., Ilić, N., Singh, C., Dojčinović, M.,& Jotania, R.. (2023). Ferroelectric, Magnetic and Dielectric Properties of SrCo0.2Zn0.2Fe11.6O18.8 Hexaferrite Obtained by “One-Pot” Green Sol-Gel Synthesis Utilizing Citrus reticulata Peel Extract. in Crystals
MDPI., 13(1452).
https://doi.org/10.3390/cryst13101452
Nikolić MV, Ammar S, Ilić N, Singh C, Dojčinović M, Jotania R. Ferroelectric, Magnetic and Dielectric Properties of SrCo0.2Zn0.2Fe11.6O18.8 Hexaferrite Obtained by “One-Pot” Green Sol-Gel Synthesis Utilizing Citrus reticulata Peel Extract. in Crystals. 2023;13(1452).
doi:10.3390/cryst13101452 .
Nikolić, Maria Vesna, Ammar, Souad, Ilić, Nikola, Singh, Charanjeet, Dojčinović, Milena, Jotania, Rajshree, "Ferroelectric, Magnetic and Dielectric Properties of SrCo0.2Zn0.2Fe11.6O18.8 Hexaferrite Obtained by “One-Pot” Green Sol-Gel Synthesis Utilizing Citrus reticulata Peel Extract" in Crystals, 13, no. 1452 (2023),
https://doi.org/10.3390/cryst13101452 . .

Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites

Dojčinović, Milena; Vasiljević, Zorka Z; Rakočević, Lazar; Pavlović, Vera P.; Ammar, Souad; Vujancevic, Jelena; Nikolić, Maria Vesna

(MDPI (Basel, Switzerland), 2023)

TY  - JOUR
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Rakočević, Lazar
AU  - Pavlović, Vera P.
AU  - Ammar, Souad
AU  - Vujancevic, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1615
AB  - Temperature- and humidity-sensing properties were evaluated of NixMg1-x spinel ferrites (0 ≤ x ≤ 1) synthesized by a sol-gel combustion method using citric acid as fuel and nitrate ions as oxidizing agents. After the exothermic reaction, amorphous powders were calcined at 700 °C   ollowed by characterization with XRD, FTIR, XPS, EDS and Raman spectroscopy and FESEM 
 icroscopy. Synthesized powders were tested as humidity- and temperature-sensing materials in the form of thick films on interdigitated electrodes on alumina substrate in a climatic chamber. The physicochemical investigation of synthesized materials revealed a cubic spinel Fd3m phase, nanosized but agglomerated particles with a partially to completely inverse spinel structure with increasing Ni content. Ni0.1Mg0.9Fe2O4 showed the highest material constant (B30,90) value of 3747 K and temperature sensitivity (α) of −4.08%/K compared to pure magnesium ferrite (B30,90 value of 3426 K and α of −3.73%/K) and the highest average sensitivity towards humidity of 922 kΩ/%RH in the relative humidity (RH) range of 40–90% at the working temperature of 25 °C.
PB  - MDPI (Basel, Switzerland)
T2  - Chemosensors
T1  - Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites
IS  - 1
SP  - 34
VL  - 11
DO  - https://doi.org/10.3390/chemosensors11010034
ER  - 
@article{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Rakočević, Lazar and Pavlović, Vera P. and Ammar, Souad and Vujancevic, Jelena and Nikolić, Maria Vesna",
year = "2023",
abstract = "Temperature- and humidity-sensing properties were evaluated of NixMg1-x spinel ferrites (0 ≤ x ≤ 1) synthesized by a sol-gel combustion method using citric acid as fuel and nitrate ions as oxidizing agents. After the exothermic reaction, amorphous powders were calcined at 700 °C   ollowed by characterization with XRD, FTIR, XPS, EDS and Raman spectroscopy and FESEM 
 icroscopy. Synthesized powders were tested as humidity- and temperature-sensing materials in the form of thick films on interdigitated electrodes on alumina substrate in a climatic chamber. The physicochemical investigation of synthesized materials revealed a cubic spinel Fd3m phase, nanosized but agglomerated particles with a partially to completely inverse spinel structure with increasing Ni content. Ni0.1Mg0.9Fe2O4 showed the highest material constant (B30,90) value of 3747 K and temperature sensitivity (α) of −4.08%/K compared to pure magnesium ferrite (B30,90 value of 3426 K and α of −3.73%/K) and the highest average sensitivity towards humidity of 922 kΩ/%RH in the relative humidity (RH) range of 40–90% at the working temperature of 25 °C.",
publisher = "MDPI (Basel, Switzerland)",
journal = "Chemosensors",
title = "Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites",
number = "1",
pages = "34",
volume = "11",
doi = "https://doi.org/10.3390/chemosensors11010034"
}
Dojčinović, M., Vasiljević, Z. Z., Rakočević, L., Pavlović, V. P., Ammar, S., Vujancevic, J.,& Nikolić, M. V.. (2023). Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites. in Chemosensors
MDPI (Basel, Switzerland)., 11(1), 34.
https://doi.org/https://doi.org/10.3390/chemosensors11010034
Dojčinović M, Vasiljević ZZ, Rakočević L, Pavlović VP, Ammar S, Vujancevic J, Nikolić MV. Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites. in Chemosensors. 2023;11(1):34.
doi:https://doi.org/10.3390/chemosensors11010034 .
Dojčinović, Milena, Vasiljević, Zorka Z, Rakočević, Lazar, Pavlović, Vera P., Ammar, Souad, Vujancevic, Jelena, Nikolić, Maria Vesna, "Humidity and Temperature Sensing of Mixed Nickel–Magnesium Spinel Ferrites" in Chemosensors, 11, no. 1 (2023):34,
https://doi.org/https://doi.org/10.3390/chemosensors11010034 . .

GREEN BIOSYNTHESIS OF ZnO NANOPARTICLES USING AGRO-WASTE AND THEIR ANTIBACTERIAL AND ANTIOXIDANT ACTIVITY

Vasiljević, Zorka Z; Vunduk, Jovana; Dojčinović, Milena; Bartolić, Dragana; Ognjanović, Miloš; Mišković, Goran; Nikolić, Maria Vesna

(University of Novi Sad, Faculty of Technology Novi Sad, 2022)

TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Vunduk, Jovana
AU  - Dojčinović, Milena
AU  - Bartolić, Dragana
AU  - Ognjanović, Miloš
AU  - Mišković, Goran
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1645
AB  - Metal oxide nanomaterials have gained a lot of attention during last decades due to their potential applications in wastewater treatment, energy storage, sensors, food packaging, etc. To date, these materials have been synthesized by different chemical and physical techniques. However many of them employ environmentally unfriendly solvents and toxic chemical compounds. To tackle this problem, use of renewable biomass such as plants and fungi as reducing or stabilizing agents in green synthesis has been considered as more sustainable option compared to toxic chemical compounds. These biological substances also behave as capping agent, which control the size and the shape of the nanoparticles. In this work, ZnO nanoparticles (NPs) have been prepared via simple, low cost and ecofriendly method using citrus fruit peel and extracts, Agaricus bisporus powder and extract as biological reducing agents. Zinc nitrate and zinc acetate were used as source of zinc ions. Structural and optical properties were investigated by X-ray diffraction analysis (XRD), Zeta potential, Fourier Transform Infrared (FTIR) spectroscopy, UV-visible (UV-vis) spectroscopy and Photoluminescence spectroscopy (PL). Morphological features were characterized by Field Emission Scanning Electron microscopy (FESEM) and High Resolution Transmission Electron Microscopy (HRTEM). Antibacterial and antioxidant activity was tested and evaluated.
PB  - University of Novi Sad, Faculty of Technology Novi Sad
C3  - Abstract book / 2nd International Conference on Advanced Production and Processing 2022, Novi Sad
T1  - GREEN BIOSYNTHESIS OF ZnO NANOPARTICLES USING AGRO-WASTE AND THEIR ANTIBACTERIAL AND ANTIOXIDANT ACTIVITY
SP  - 106
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1645
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Vunduk, Jovana and Dojčinović, Milena and Bartolić, Dragana and Ognjanović, Miloš and Mišković, Goran and Nikolić, Maria Vesna",
year = "2022",
abstract = "Metal oxide nanomaterials have gained a lot of attention during last decades due to their potential applications in wastewater treatment, energy storage, sensors, food packaging, etc. To date, these materials have been synthesized by different chemical and physical techniques. However many of them employ environmentally unfriendly solvents and toxic chemical compounds. To tackle this problem, use of renewable biomass such as plants and fungi as reducing or stabilizing agents in green synthesis has been considered as more sustainable option compared to toxic chemical compounds. These biological substances also behave as capping agent, which control the size and the shape of the nanoparticles. In this work, ZnO nanoparticles (NPs) have been prepared via simple, low cost and ecofriendly method using citrus fruit peel and extracts, Agaricus bisporus powder and extract as biological reducing agents. Zinc nitrate and zinc acetate were used as source of zinc ions. Structural and optical properties were investigated by X-ray diffraction analysis (XRD), Zeta potential, Fourier Transform Infrared (FTIR) spectroscopy, UV-visible (UV-vis) spectroscopy and Photoluminescence spectroscopy (PL). Morphological features were characterized by Field Emission Scanning Electron microscopy (FESEM) and High Resolution Transmission Electron Microscopy (HRTEM). Antibacterial and antioxidant activity was tested and evaluated.",
publisher = "University of Novi Sad, Faculty of Technology Novi Sad",
journal = "Abstract book / 2nd International Conference on Advanced Production and Processing 2022, Novi Sad",
title = "GREEN BIOSYNTHESIS OF ZnO NANOPARTICLES USING AGRO-WASTE AND THEIR ANTIBACTERIAL AND ANTIOXIDANT ACTIVITY",
pages = "106",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1645"
}
Vasiljević, Z. Z., Vunduk, J., Dojčinović, M., Bartolić, D., Ognjanović, M., Mišković, G.,& Nikolić, M. V.. (2022). GREEN BIOSYNTHESIS OF ZnO NANOPARTICLES USING AGRO-WASTE AND THEIR ANTIBACTERIAL AND ANTIOXIDANT ACTIVITY. in Abstract book / 2nd International Conference on Advanced Production and Processing 2022, Novi Sad
University of Novi Sad, Faculty of Technology Novi Sad., 106.
https://hdl.handle.net/21.15107/rcub_rimsi_1645
Vasiljević ZZ, Vunduk J, Dojčinović M, Bartolić D, Ognjanović M, Mišković G, Nikolić MV. GREEN BIOSYNTHESIS OF ZnO NANOPARTICLES USING AGRO-WASTE AND THEIR ANTIBACTERIAL AND ANTIOXIDANT ACTIVITY. in Abstract book / 2nd International Conference on Advanced Production and Processing 2022, Novi Sad. 2022;:106.
https://hdl.handle.net/21.15107/rcub_rimsi_1645 .
Vasiljević, Zorka Z, Vunduk, Jovana, Dojčinović, Milena, Bartolić, Dragana, Ognjanović, Miloš, Mišković, Goran, Nikolić, Maria Vesna, "GREEN BIOSYNTHESIS OF ZnO NANOPARTICLES USING AGRO-WASTE AND THEIR ANTIBACTERIAL AND ANTIOXIDANT ACTIVITY" in Abstract book / 2nd International Conference on Advanced Production and Processing 2022, Novi Sad (2022):106,
https://hdl.handle.net/21.15107/rcub_rimsi_1645 .

Nickel manganite-carbonized alginate composite for use as energy storage electrodes

Dojčinović, Milena; Vasiljević, Zorka Z; Tadic, Nenad; Spreitzer, Matjaz; Rakočević, Lazar; Nikolić, Maria Vesna

(Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Tadic, Nenad
AU  - Spreitzer, Matjaz
AU  - Rakočević, Lazar
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1618
AB  - Nickel-manganite is a versatile material used in many technology applications. One of the established uses is as a supercapacitor electrode. The advantage of this type of material is the abundance of required metals, compared to noble metals, the synthesis methods' simplicity, and high redox activity. Metal-oxide battery materials are usually combined with activated carbon to enhance the specific surface area and add to energy storage capacity via surface charge accumulation. In the current work, nickel manganite was synthesized via the sol-gel combustion synthesis method with glycine as fuel and nitrate ions as oxidizers. The post-combustion amorphous powder was calcined at temperatures between 300 and 800 °C. Powders were structurally characterized. Obtained materials were tested as energy storage electrodes in a three-electrode cell setup in 6 M KOH aqueous solution as electrolyte. Methods embedded in electrochemical characterization were cyclic voltammetry (CV), electric impedance spectroscopy (EIS) and constant current chronopotentiometry at different current densities to obtain galvanostatic charge-discharge (GCD) curves. Results show considerable charge storage activity, which can be ascribed to oxido reduction reactions of manganese ions and charge accumulation on the surface of the activated carbon.
PB  - Serbian Academy of Sciences and Arts
C3  - SECOND INTERNATIONAL CONFERENCE ELMINA 2022 Program and Book of Abstracts Publisher:
T1  - Nickel manganite-carbonized alginate composite for use as energy storage electrodes
EP  - 171
SP  - 170
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1618
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Tadic, Nenad and Spreitzer, Matjaz and Rakočević, Lazar and Nikolić, Maria Vesna",
year = "2022",
abstract = "Nickel-manganite is a versatile material used in many technology applications. One of the established uses is as a supercapacitor electrode. The advantage of this type of material is the abundance of required metals, compared to noble metals, the synthesis methods' simplicity, and high redox activity. Metal-oxide battery materials are usually combined with activated carbon to enhance the specific surface area and add to energy storage capacity via surface charge accumulation. In the current work, nickel manganite was synthesized via the sol-gel combustion synthesis method with glycine as fuel and nitrate ions as oxidizers. The post-combustion amorphous powder was calcined at temperatures between 300 and 800 °C. Powders were structurally characterized. Obtained materials were tested as energy storage electrodes in a three-electrode cell setup in 6 M KOH aqueous solution as electrolyte. Methods embedded in electrochemical characterization were cyclic voltammetry (CV), electric impedance spectroscopy (EIS) and constant current chronopotentiometry at different current densities to obtain galvanostatic charge-discharge (GCD) curves. Results show considerable charge storage activity, which can be ascribed to oxido reduction reactions of manganese ions and charge accumulation on the surface of the activated carbon.",
publisher = "Serbian Academy of Sciences and Arts",
journal = "SECOND INTERNATIONAL CONFERENCE ELMINA 2022 Program and Book of Abstracts Publisher:",
title = "Nickel manganite-carbonized alginate composite for use as energy storage electrodes",
pages = "171-170",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1618"
}
Dojčinović, M., Vasiljević, Z. Z., Tadic, N., Spreitzer, M., Rakočević, L.,& Nikolić, M. V.. (2022). Nickel manganite-carbonized alginate composite for use as energy storage electrodes. in SECOND INTERNATIONAL CONFERENCE ELMINA 2022 Program and Book of Abstracts Publisher:
Serbian Academy of Sciences and Arts., 170-171.
https://hdl.handle.net/21.15107/rcub_rimsi_1618
Dojčinović M, Vasiljević ZZ, Tadic N, Spreitzer M, Rakočević L, Nikolić MV. Nickel manganite-carbonized alginate composite for use as energy storage electrodes. in SECOND INTERNATIONAL CONFERENCE ELMINA 2022 Program and Book of Abstracts Publisher:. 2022;:170-171.
https://hdl.handle.net/21.15107/rcub_rimsi_1618 .
Dojčinović, Milena, Vasiljević, Zorka Z, Tadic, Nenad, Spreitzer, Matjaz, Rakočević, Lazar, Nikolić, Maria Vesna, "Nickel manganite-carbonized alginate composite for use as energy storage electrodes" in SECOND INTERNATIONAL CONFERENCE ELMINA 2022 Program and Book of Abstracts Publisher: (2022):170-171,
https://hdl.handle.net/21.15107/rcub_rimsi_1618 .

NATURE OF PHOTOCATALYSIS IN BiFeO3 SUSPENSIONS – HETEROGENEOUS, HOMOGENEOUS OR DYE-SENSITIZED?

Ilić, Nikola; Dojčinović, Milena; Vijatović Petrović, Mirjana; Bobić, Jelena; Džunuzović, Adis; Radojković, Aleksandar

(Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia, 2022)

TY  - CONF
AU  - Ilić, Nikola
AU  - Dojčinović, Milena
AU  - Vijatović Petrović, Mirjana
AU  - Bobić, Jelena
AU  - Džunuzović, Adis
AU  - Radojković, Aleksandar
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2526
AB  - Bismuth ferrite (BiFeO3) powders were synthesized by auto-combustion
method. To decrease the quantity of active phase and improve the specific surface
area, composites of BiFeO3 and natural porose materials (diatomaceous earth and
cuttlebone) were prepared by chemical method from solution and calcined at low
temperature. Such obtained powders were used as adsorbents and photocatalysts in
methylene blue water solutions. Nature of photocatalysis under visible and UV-Vis
light was examined under different pH conditions and presence of hydrogen
peroxide, dissolved iron(III), oxalates and some other ions. Methylene blue is
capable to absorb sunlight and insert electrons into semiconductor, so possibility of
this way achieved dye-sensitization was studied [1]. Composites expressed better
properties than individual components confirming the synergetic effect [2]. Acidic
conditions were more suitable for decolorization, so possible Fenton reaction based
homogeneous catalysis was also considered.
PB  - Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - 6th Conference of The Serbian Society for Ceramic Materials, Belgrade, Serbia, 28-29 June 2022
T1  - NATURE OF PHOTOCATALYSIS IN BiFeO3 SUSPENSIONS – HETEROGENEOUS, HOMOGENEOUS OR DYE-SENSITIZED?
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2526
ER  - 
@conference{
author = "Ilić, Nikola and Dojčinović, Milena and Vijatović Petrović, Mirjana and Bobić, Jelena and Džunuzović, Adis and Radojković, Aleksandar",
year = "2022",
abstract = "Bismuth ferrite (BiFeO3) powders were synthesized by auto-combustion
method. To decrease the quantity of active phase and improve the specific surface
area, composites of BiFeO3 and natural porose materials (diatomaceous earth and
cuttlebone) were prepared by chemical method from solution and calcined at low
temperature. Such obtained powders were used as adsorbents and photocatalysts in
methylene blue water solutions. Nature of photocatalysis under visible and UV-Vis
light was examined under different pH conditions and presence of hydrogen
peroxide, dissolved iron(III), oxalates and some other ions. Methylene blue is
capable to absorb sunlight and insert electrons into semiconductor, so possibility of
this way achieved dye-sensitization was studied [1]. Composites expressed better
properties than individual components confirming the synergetic effect [2]. Acidic
conditions were more suitable for decolorization, so possible Fenton reaction based
homogeneous catalysis was also considered.",
publisher = "Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "6th Conference of The Serbian Society for Ceramic Materials, Belgrade, Serbia, 28-29 June 2022",
title = "NATURE OF PHOTOCATALYSIS IN BiFeO3 SUSPENSIONS – HETEROGENEOUS, HOMOGENEOUS OR DYE-SENSITIZED?",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2526"
}
Ilić, N., Dojčinović, M., Vijatović Petrović, M., Bobić, J., Džunuzović, A.,& Radojković, A.. (2022). NATURE OF PHOTOCATALYSIS IN BiFeO3 SUSPENSIONS – HETEROGENEOUS, HOMOGENEOUS OR DYE-SENSITIZED?. in 6th Conference of The Serbian Society for Ceramic Materials, Belgrade, Serbia, 28-29 June 2022
Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_rimsi_2526
Ilić N, Dojčinović M, Vijatović Petrović M, Bobić J, Džunuzović A, Radojković A. NATURE OF PHOTOCATALYSIS IN BiFeO3 SUSPENSIONS – HETEROGENEOUS, HOMOGENEOUS OR DYE-SENSITIZED?. in 6th Conference of The Serbian Society for Ceramic Materials, Belgrade, Serbia, 28-29 June 2022. 2022;.
https://hdl.handle.net/21.15107/rcub_rimsi_2526 .
Ilić, Nikola, Dojčinović, Milena, Vijatović Petrović, Mirjana, Bobić, Jelena, Džunuzović, Adis, Radojković, Aleksandar, "NATURE OF PHOTOCATALYSIS IN BiFeO3 SUSPENSIONS – HETEROGENEOUS, HOMOGENEOUS OR DYE-SENSITIZED?" in 6th Conference of The Serbian Society for Ceramic Materials, Belgrade, Serbia, 28-29 June 2022 (2022),
https://hdl.handle.net/21.15107/rcub_rimsi_2526 .

Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors

Dojčinović, Milena; Vasiljević, Zorka Z; Tadic, Nenad; Krstic, Jugoslav; Nikolić, Maria Vesna

(Krakow : Agencja Reklamowa EURO GRAPHIC, 2022)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Tadic, Nenad
AU  - Krstic, Jugoslav
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1617
AB  - Transition metal oxides (TMOs) are promising materials because of their specific properties enabling their application in energy solutions, such as their pseudocapacitive behavior enabling utilization as electrode materials in supercapacitors. Activated carbon is a material well known as an electric double layer capacitor (EDLC). Bringing together the two different capacitor materials- TMOs as pseudocapacitors and carbon materials as EDL capacitors is the goal for generating future generation supercapacitors. Nickel manganite is a material of interest because of various oxidation states of manganese which provide its reactivity in oxidoreduction reactions, enhancing the pseudocapacitive behavior. Herein, we synthesized nano-sized nickel manganite by a sol-gel combustion synthesis process using glycine as fuel and subsequent calcination process. The structure and morphology of synthesized material was investigated via XRD, FESEM, and FTIR spectroscopy. Specific surface area and was determined from measured nitrogen 
 desorption/desorption isotherms. Activated carbon was obtained by pyrolytic carbonization of alginate hydrogel in nitrogen atmosphere and activation with KOH. The material was combined with synthesized NiMn2O4 nanopowder and tested as supercapacitor electrode. The second alternative was incorporating NiMn2O4 powder into alginate hydrogel, followed by pyrolysis in nitrogen atmosphere to obtain a NiMn2O4 -activated
carbon composite. The obtained materials were electrochemically characterized with cyclic voltammetry (LV) and galvanostatic chronopotentiometry to get galvanostatic charge-discharge curves. We calculated high specific capacitance values ranging to several hundred F/g, showing our hybrid material is a promising electrode in a supercapacitor system.
PB  - Krakow : Agencja Reklamowa EURO GRAPHIC
PB  - Krakow : Polskie Towarzystwo Ceramiczne
C3  - Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022
T1  - Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors
SP  - 404
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1617
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Tadic, Nenad and Krstic, Jugoslav and Nikolić, Maria Vesna",
year = "2022",
abstract = "Transition metal oxides (TMOs) are promising materials because of their specific properties enabling their application in energy solutions, such as their pseudocapacitive behavior enabling utilization as electrode materials in supercapacitors. Activated carbon is a material well known as an electric double layer capacitor (EDLC). Bringing together the two different capacitor materials- TMOs as pseudocapacitors and carbon materials as EDL capacitors is the goal for generating future generation supercapacitors. Nickel manganite is a material of interest because of various oxidation states of manganese which provide its reactivity in oxidoreduction reactions, enhancing the pseudocapacitive behavior. Herein, we synthesized nano-sized nickel manganite by a sol-gel combustion synthesis process using glycine as fuel and subsequent calcination process. The structure and morphology of synthesized material was investigated via XRD, FESEM, and FTIR spectroscopy. Specific surface area and was determined from measured nitrogen 
 desorption/desorption isotherms. Activated carbon was obtained by pyrolytic carbonization of alginate hydrogel in nitrogen atmosphere and activation with KOH. The material was combined with synthesized NiMn2O4 nanopowder and tested as supercapacitor electrode. The second alternative was incorporating NiMn2O4 powder into alginate hydrogel, followed by pyrolysis in nitrogen atmosphere to obtain a NiMn2O4 -activated
carbon composite. The obtained materials were electrochemically characterized with cyclic voltammetry (LV) and galvanostatic chronopotentiometry to get galvanostatic charge-discharge curves. We calculated high specific capacitance values ranging to several hundred F/g, showing our hybrid material is a promising electrode in a supercapacitor system.",
publisher = "Krakow : Agencja Reklamowa EURO GRAPHIC, Krakow : Polskie Towarzystwo Ceramiczne",
journal = "Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022",
title = "Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors",
pages = "404",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1617"
}
Dojčinović, M., Vasiljević, Z. Z., Tadic, N., Krstic, J.,& Nikolić, M. V.. (2022). Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors. in Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022
Krakow : Agencja Reklamowa EURO GRAPHIC., 404.
https://hdl.handle.net/21.15107/rcub_rimsi_1617
Dojčinović M, Vasiljević ZZ, Tadic N, Krstic J, Nikolić MV. Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors. in Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022. 2022;:404.
https://hdl.handle.net/21.15107/rcub_rimsi_1617 .
Dojčinović, Milena, Vasiljević, Zorka Z, Tadic, Nenad, Krstic, Jugoslav, Nikolić, Maria Vesna, "Alginate-derived activated carbon hybridized with NiMn2O4 for use in supercapacitors" in Abstract Book / Ceramics in Europe 2022, Krakow, 10-14 July, 2022 (2022):404,
https://hdl.handle.net/21.15107/rcub_rimsi_1617 .

Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes

Dojčinović, Milena; Vasiljević, Zorka Z; Pavlović, Vera P.; Vujančević, Jelena; Tadić, Nenad B.; Nikolić, Maria Vesna

(Belgrade : University of Belgrade, Faculty of Physical Chemistry, 2022)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - https://dais.sanu.ac.rs/123456789/13642
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1611
AB  - Problems that countries all over the world have in common are dependence of economy and energy production on fossil fuels. There is a growing need for energy production and storage routes that are safe for the environment, renewable, efficient and cheap. One of the directions in which science is moving forward is discovering materials suitable for use in batteries and supercapacitors to improve their operating potential, electrical capacity or biocompatibility. The objective is also to synthesize materials for batteries or supercapacitors that are cheap, consist of earth abundant elements and have high electrochemical activity.In this work, mixed nickel-magnesium ferrites NixMg1−xFe2O4, with x being 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1, were synthesized via sol-gel combustion synthesis with citric acid used as fuel and nitrate ions used as oxidizing agents. Combusted powders were calcined at 700 °C. The structure and morphology of the powders were characterized with X-ray diffraction method (XRD), field emission scanning electron microscopy (FESEM), Raman and FTIR spectroscopy. The band gap was calculated by using UV/Vis diffuse reflectance spectroscopy (DRS). Samples were cast on nickel foam and tested as energy storage materials in a three-electrode setup in 3 M KOH aqueous solution as electrolyte. The methods used were cyclic voltammetry (CV) and constant current chronopotentiometry to obtain galvanostatic charge-discharge (GCD) curves. Results show that all of the synthesized materials show battery-type charge storage in alkaline electrolyte due to the formation of metal cation oxyhydroxides. With increasing nickel content, electrochemical activity drops. The highest value of capacity, 34.3 mA h g-1 at the current density of 500 mA g-1 is ascribed to magnesium ferrite, MgFe2O4.
PB  - Belgrade : University of Belgrade, Faculty of Physical Chemistry
C3  - Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
T1  - Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes
EP  - 47
SP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_dais_13642
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Pavlović, Vera P. and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2022",
abstract = "Problems that countries all over the world have in common are dependence of economy and energy production on fossil fuels. There is a growing need for energy production and storage routes that are safe for the environment, renewable, efficient and cheap. One of the directions in which science is moving forward is discovering materials suitable for use in batteries and supercapacitors to improve their operating potential, electrical capacity or biocompatibility. The objective is also to synthesize materials for batteries or supercapacitors that are cheap, consist of earth abundant elements and have high electrochemical activity.In this work, mixed nickel-magnesium ferrites NixMg1−xFe2O4, with x being 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1, were synthesized via sol-gel combustion synthesis with citric acid used as fuel and nitrate ions used as oxidizing agents. Combusted powders were calcined at 700 °C. The structure and morphology of the powders were characterized with X-ray diffraction method (XRD), field emission scanning electron microscopy (FESEM), Raman and FTIR spectroscopy. The band gap was calculated by using UV/Vis diffuse reflectance spectroscopy (DRS). Samples were cast on nickel foam and tested as energy storage materials in a three-electrode setup in 3 M KOH aqueous solution as electrolyte. The methods used were cyclic voltammetry (CV) and constant current chronopotentiometry to obtain galvanostatic charge-discharge (GCD) curves. Results show that all of the synthesized materials show battery-type charge storage in alkaline electrolyte due to the formation of metal cation oxyhydroxides. With increasing nickel content, electrochemical activity drops. The highest value of capacity, 34.3 mA h g-1 at the current density of 500 mA g-1 is ascribed to magnesium ferrite, MgFe2O4.",
publisher = "Belgrade : University of Belgrade, Faculty of Physical Chemistry",
journal = "Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022",
title = "Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes",
pages = "47-47",
url = "https://hdl.handle.net/21.15107/rcub_dais_13642"
}
Dojčinović, M., Vasiljević, Z. Z., Pavlović, V. P., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2022). Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
Belgrade : University of Belgrade, Faculty of Physical Chemistry., 47-47.
https://hdl.handle.net/21.15107/rcub_dais_13642
Dojčinović M, Vasiljević ZZ, Pavlović VP, Vujančević J, Tadić NB, Nikolić MV. Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022. 2022;:47-47.
https://hdl.handle.net/21.15107/rcub_dais_13642 .
Dojčinović, Milena, Vasiljević, Zorka Z, Pavlović, Vera P., Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "Mixed Ni-Mg Spinel Ferrites Used as Materials for Charge Storage Electrodes" in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022 (2022):47-47,
https://hdl.handle.net/21.15107/rcub_dais_13642 .

Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application

Rizzoto, Francesco; Vasiljević, Zorka Z; Stanojević, Gordana; Dojčinović, Milena; Jankovic-Castvan, Ivona; Vujancevic, Jelena; Tadic, Nenad; Branković, Goran; MAGNIEZ, Aurélie; Vidic, Jasmina; Nikolić, Maria Vesna

(Elsevier, 2022)

TY  - JOUR
AU  - Rizzoto, Francesco
AU  - Vasiljević, Zorka Z
AU  - Stanojević, Gordana
AU  - Dojčinović, Milena
AU  - Jankovic-Castvan, Ivona
AU  - Vujancevic, Jelena
AU  - Tadic, Nenad
AU  - Branković, Goran
AU  - MAGNIEZ, Aurélie
AU  - Vidic, Jasmina
AU  - Nikolić, Maria Vesna
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1584
AB  - An emerging technology of active packaging enables prolongation of food shelf life by limiting the oxygen transfer and the reactivity of free radicals, which both destruct food freshness. In this work, Fe2TiO5 nanoparticles were synthesized using a modified sol–gel method and evaluated as an enforcement of alginate food packaging film. Pure phase Fe2TiO5 nanoparticles had an average particle size of 44 nm and rhombohedral morphology. Fe2TiO5 nanoparticles induce no cell damage of human Caco-2 epithelial cells and show no inhibitory effect towards growth of a panel of bacterial strains, suggesting good biocompatibility. Films obtained by incorporation of Fe2TiO5 nanoparticles into alginate using the solvent casting method show no migration of iron or titanium ions from films to food simulants again suggesting their safety as a packaging material. Fe2TiO5 nanoparticles also showed strong antioxidant efficiency as determined using the DPPḢ assay, and confirmed further in a preservation test on fresh fruit.
PB  - Elsevier
T2  - Food Chemistry
T1  - Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application
VL  - 390
DO  - 10.1016/j.foodchem.2022.133198
ER  - 
@article{
author = "Rizzoto, Francesco and Vasiljević, Zorka Z and Stanojević, Gordana and Dojčinović, Milena and Jankovic-Castvan, Ivona and Vujancevic, Jelena and Tadic, Nenad and Branković, Goran and MAGNIEZ, Aurélie and Vidic, Jasmina and Nikolić, Maria Vesna",
year = "2022",
abstract = "An emerging technology of active packaging enables prolongation of food shelf life by limiting the oxygen transfer and the reactivity of free radicals, which both destruct food freshness. In this work, Fe2TiO5 nanoparticles were synthesized using a modified sol–gel method and evaluated as an enforcement of alginate food packaging film. Pure phase Fe2TiO5 nanoparticles had an average particle size of 44 nm and rhombohedral morphology. Fe2TiO5 nanoparticles induce no cell damage of human Caco-2 epithelial cells and show no inhibitory effect towards growth of a panel of bacterial strains, suggesting good biocompatibility. Films obtained by incorporation of Fe2TiO5 nanoparticles into alginate using the solvent casting method show no migration of iron or titanium ions from films to food simulants again suggesting their safety as a packaging material. Fe2TiO5 nanoparticles also showed strong antioxidant efficiency as determined using the DPPḢ assay, and confirmed further in a preservation test on fresh fruit.",
publisher = "Elsevier",
journal = "Food Chemistry",
title = "Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application",
volume = "390",
doi = "10.1016/j.foodchem.2022.133198"
}
Rizzoto, F., Vasiljević, Z. Z., Stanojević, G., Dojčinović, M., Jankovic-Castvan, I., Vujancevic, J., Tadic, N., Branković, G., MAGNIEZ, A., Vidic, J.,& Nikolić, M. V.. (2022). Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application. in Food Chemistry
Elsevier., 390.
https://doi.org/10.1016/j.foodchem.2022.133198
Rizzoto F, Vasiljević ZZ, Stanojević G, Dojčinović M, Jankovic-Castvan I, Vujancevic J, Tadic N, Branković G, MAGNIEZ A, Vidic J, Nikolić MV. Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application. in Food Chemistry. 2022;390.
doi:10.1016/j.foodchem.2022.133198 .
Rizzoto, Francesco, Vasiljević, Zorka Z, Stanojević, Gordana, Dojčinović, Milena, Jankovic-Castvan, Ivona, Vujancevic, Jelena, Tadic, Nenad, Branković, Goran, MAGNIEZ, Aurélie, Vidic, Jasmina, Nikolić, Maria Vesna, "Antioxidant and cell-friendly Fe2TiO5 nanoparticles for food packaging application" in Food Chemistry, 390 (2022),
https://doi.org/10.1016/j.foodchem.2022.133198 . .
10

INFLUENCE OF CALCINATION TEMPERATURE ON THE STRUCTURE, MORPHOLOGY AND OPTICAL PROPERTIES OF ELECTROSPUN PSEUDOBROOKITE NANOFIBERS

Vasiljević, Zorka Z; Dojčinović, Milena; Vujancevic, Jelena; Spreitzer, Matjaz; Kovač, Janez; Jankovic-Castvan, Ivona; Bartolić, Dragana; Markovic, Smilja; Tadic, Nenad; Nikolić, Maria Vesna

(University of Novi Sad, Faculty of Technology Novi Sad, 2021)

TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Vujancevic, Jelena
AU  - Spreitzer, Matjaz
AU  - Kovač, Janez
AU  - Jankovic-Castvan, Ivona
AU  - Bartolić, Dragana
AU  - Markovic, Smilja
AU  - Tadic, Nenad
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2197
AB  - Novel crystalline iron-titanate fibers were synthesized for the first time to the best of our knowledge, through a simple, low cost electrospinning method followed by calcination treatment at different temperatures (500–750 °C for 3 h and at 500 °C for 6 h and at 550 °C for 4 h). The fibers were prepared from a precursor solution containing polyvinylpyrrolidone (PVP), iron(III) nonahydrate, titanium isopropoxide, N,N-Dimethylformamide and ethanol. As spun fibers were smooth, straight, beadless and uniform forming a nonwoven fibrous mat, with an average diameter of ca. 205 nm. Upon calcination in air the PVP matrice was removed and XRD and FTIR analysis showed that the duration of the calcination process, besides the temperature, had a direct influence on phase formation. Pure phase of pseudobrookite was obtained at 600 °C, 500 °C for 6 h and at 550 °C for 4 h. In addition, the morphology of obtained nanofibers was directly affected by the calcination temperature. The surface of fibers obtained after calcination was no longer smooth and the fiber diameter decreased due to complete degradation of PVP. At 700 oC and 750 °C, fibers were thicker which can be attributed to growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles. All samples exhibited a type IV nitrogen adsorption isotherm with a type- H3 indicating slit-shaped mesoporous structure. The BET surface areas of 500 oC for 6 h, 550 oC for 4 h and 600 oC for 3 h were estimated to be 62, 38.7 and 33.2 m2/g, respectively.
PB  - University of Novi Sad, Faculty of Technology Novi Sad
C3  - Abstract book/14th ECerS conference for young scientist in ceramics
T1  - INFLUENCE OF CALCINATION TEMPERATURE ON THE STRUCTURE, MORPHOLOGY AND OPTICAL PROPERTIES OF ELECTROSPUN PSEUDOBROOKITE NANOFIBERS
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2197
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Vujancevic, Jelena and Spreitzer, Matjaz and Kovač, Janez and Jankovic-Castvan, Ivona and Bartolić, Dragana and Markovic, Smilja and Tadic, Nenad and Nikolić, Maria Vesna",
year = "2021",
abstract = "Novel crystalline iron-titanate fibers were synthesized for the first time to the best of our knowledge, through a simple, low cost electrospinning method followed by calcination treatment at different temperatures (500–750 °C for 3 h and at 500 °C for 6 h and at 550 °C for 4 h). The fibers were prepared from a precursor solution containing polyvinylpyrrolidone (PVP), iron(III) nonahydrate, titanium isopropoxide, N,N-Dimethylformamide and ethanol. As spun fibers were smooth, straight, beadless and uniform forming a nonwoven fibrous mat, with an average diameter of ca. 205 nm. Upon calcination in air the PVP matrice was removed and XRD and FTIR analysis showed that the duration of the calcination process, besides the temperature, had a direct influence on phase formation. Pure phase of pseudobrookite was obtained at 600 °C, 500 °C for 6 h and at 550 °C for 4 h. In addition, the morphology of obtained nanofibers was directly affected by the calcination temperature. The surface of fibers obtained after calcination was no longer smooth and the fiber diameter decreased due to complete degradation of PVP. At 700 oC and 750 °C, fibers were thicker which can be attributed to growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles. All samples exhibited a type IV nitrogen adsorption isotherm with a type- H3 indicating slit-shaped mesoporous structure. The BET surface areas of 500 oC for 6 h, 550 oC for 4 h and 600 oC for 3 h were estimated to be 62, 38.7 and 33.2 m2/g, respectively.",
publisher = "University of Novi Sad, Faculty of Technology Novi Sad",
journal = "Abstract book/14th ECerS conference for young scientist in ceramics",
title = "INFLUENCE OF CALCINATION TEMPERATURE ON THE STRUCTURE, MORPHOLOGY AND OPTICAL PROPERTIES OF ELECTROSPUN PSEUDOBROOKITE NANOFIBERS",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2197"
}
Vasiljević, Z. Z., Dojčinović, M., Vujancevic, J., Spreitzer, M., Kovač, J., Jankovic-Castvan, I., Bartolić, D., Markovic, S., Tadic, N.,& Nikolić, M. V.. (2021). INFLUENCE OF CALCINATION TEMPERATURE ON THE STRUCTURE, MORPHOLOGY AND OPTICAL PROPERTIES OF ELECTROSPUN PSEUDOBROOKITE NANOFIBERS. in Abstract book/14th ECerS conference for young scientist in ceramics
University of Novi Sad, Faculty of Technology Novi Sad..
https://hdl.handle.net/21.15107/rcub_rimsi_2197
Vasiljević ZZ, Dojčinović M, Vujancevic J, Spreitzer M, Kovač J, Jankovic-Castvan I, Bartolić D, Markovic S, Tadic N, Nikolić MV. INFLUENCE OF CALCINATION TEMPERATURE ON THE STRUCTURE, MORPHOLOGY AND OPTICAL PROPERTIES OF ELECTROSPUN PSEUDOBROOKITE NANOFIBERS. in Abstract book/14th ECerS conference for young scientist in ceramics. 2021;.
https://hdl.handle.net/21.15107/rcub_rimsi_2197 .
Vasiljević, Zorka Z, Dojčinović, Milena, Vujancevic, Jelena, Spreitzer, Matjaz, Kovač, Janez, Jankovic-Castvan, Ivona, Bartolić, Dragana, Markovic, Smilja, Tadic, Nenad, Nikolić, Maria Vesna, "INFLUENCE OF CALCINATION TEMPERATURE ON THE STRUCTURE, MORPHOLOGY AND OPTICAL PROPERTIES OF ELECTROSPUN PSEUDOBROOKITE NANOFIBERS" in Abstract book/14th ECerS conference for young scientist in ceramics (2021),
https://hdl.handle.net/21.15107/rcub_rimsi_2197 .

Synthesis, structure and electrochemical performance of NiMn2O4

Dojčinović, Milena; Vasiljević, Zorka Z; Tadić, Nenad B.; Krstić, Jugoslav B.; Marković, Smilja; Spreitzer, Matjaž; Kovač, Janez; Nikolić, Maria Vesna

(Novi Sad : Faculty of Technology, 2021)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Tadić, Nenad B.
AU  - Krstić, Jugoslav B.
AU  - Marković, Smilja
AU  - Spreitzer, Matjaž
AU  - Kovač, Janez
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/12397
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1630
AB  - NiMn2O4, with a cubic spinel structure and numerous and various applications in modern technology, were synthesized with two synthetic routes: sol-gel combustion method with glycine as fuel and electrospinning method with polyvinylpyrrolidone (PVP). Both amorphous powders from sol-gel synthesis and as-spun fibers from electrospinning synthesis were calcined, electrospun fibers at 400 °C and the sol-gel synthesized powders at 800 °C. Electrospun fibers were previously characterized with DTA-TGA to investigate the influence of thermal process on a polymer fiber.The obtained powders were characterized accordingly. Structural analysis was done via X-ray diffraction (XRD) and results show spinel structure with no impurity. The texture and morphology was investigated via N2 physisorption and transmission electron microscopy (TEM), respectively. Chemical states of elements were investigated by X-ray photoelectron spectroscopy (XPS). The electrochemical performance of the synthesized materials as supercapacitors was tested via cyclic voltammetry (CV), electric impedance spectroscopy (EIS), and chronopotentiometry (CP) to aquire galvanostatic charge-discharge (GCD) curves. Experiments were done in 6 M KOH solution with nickel foam as a working electrode. The results show good electrochemical capacity circa 200 F/g, with the potential for further structural improvement of the materials.
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad
T1  - Synthesis, structure and electrochemical performance of NiMn2O4
EP  - 81
SP  - 81
UR  - https://hdl.handle.net/21.15107/rcub_dais_12397
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Tadić, Nenad B. and Krstić, Jugoslav B. and Marković, Smilja and Spreitzer, Matjaž and Kovač, Janez and Nikolić, Maria Vesna",
year = "2021",
abstract = "NiMn2O4, with a cubic spinel structure and numerous and various applications in modern technology, were synthesized with two synthetic routes: sol-gel combustion method with glycine as fuel and electrospinning method with polyvinylpyrrolidone (PVP). Both amorphous powders from sol-gel synthesis and as-spun fibers from electrospinning synthesis were calcined, electrospun fibers at 400 °C and the sol-gel synthesized powders at 800 °C. Electrospun fibers were previously characterized with DTA-TGA to investigate the influence of thermal process on a polymer fiber.The obtained powders were characterized accordingly. Structural analysis was done via X-ray diffraction (XRD) and results show spinel structure with no impurity. The texture and morphology was investigated via N2 physisorption and transmission electron microscopy (TEM), respectively. Chemical states of elements were investigated by X-ray photoelectron spectroscopy (XPS). The electrochemical performance of the synthesized materials as supercapacitors was tested via cyclic voltammetry (CV), electric impedance spectroscopy (EIS), and chronopotentiometry (CP) to aquire galvanostatic charge-discharge (GCD) curves. Experiments were done in 6 M KOH solution with nickel foam as a working electrode. The results show good electrochemical capacity circa 200 F/g, with the potential for further structural improvement of the materials.",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad",
title = "Synthesis, structure and electrochemical performance of NiMn2O4",
pages = "81-81",
url = "https://hdl.handle.net/21.15107/rcub_dais_12397"
}
Dojčinović, M., Vasiljević, Z. Z., Tadić, N. B., Krstić, J. B., Marković, S., Spreitzer, M., Kovač, J.,& Nikolić, M. V.. (2021). Synthesis, structure and electrochemical performance of NiMn2O4. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad
Novi Sad : Faculty of Technology., 81-81.
https://hdl.handle.net/21.15107/rcub_dais_12397
Dojčinović M, Vasiljević ZZ, Tadić NB, Krstić JB, Marković S, Spreitzer M, Kovač J, Nikolić MV. Synthesis, structure and electrochemical performance of NiMn2O4. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad. 2021;:81-81.
https://hdl.handle.net/21.15107/rcub_dais_12397 .
Dojčinović, Milena, Vasiljević, Zorka Z, Tadić, Nenad B., Krstić, Jugoslav B., Marković, Smilja, Spreitzer, Matjaž, Kovač, Janez, Nikolić, Maria Vesna, "Synthesis, structure and electrochemical performance of NiMn2O4" in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad (2021):81-81,
https://hdl.handle.net/21.15107/rcub_dais_12397 .

Mixed Mg-Co spinel ferrites: Structure, morphology, magnetic and photocatalytic properties

Dojčinović, Milena; Vasiljević, Zorka Z; Pavlović, Vera P.; Barisic, Dario; Pajić, Damir; Tadić, Nenad B.; Nikolić, Maria Vesna

(Elsevier Science Sa, Lausanne, 2021)

TY  - JOUR
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Pavlović, Vera P.
AU  - Barisic, Dario
AU  - Pajić, Damir
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1451
AB  - CoxMg1-xFe2O4 (where x was 0.0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1) spinel ferrites were synthesized by the sol-gel combustion method using citric acid as fuel, following the rules of propellant chemistry. Amorphous powders were then calcined at 700 degrees C for 3 h. Structural analysis by X-Ray diffraction (XRD), FTIR and Raman spectroscopy confirmed the formation of a cubic spinel structure where the cation distribution and inversion degree depended on the Co2+ and Mg2+ ion content. Accordingly, the lattice parameter varied between 8.3703 angstrom (MgFe2O4) and 8.3919 A (Co-0.9 Mg0.1Fe2O4) as did the crystallite size, from 34 nm (Co0.1Mg0.9Fe2O4) to 48 nm (Co0.9Mg0.1Fe2O4). Scanning electron microscopy (SEM) showed the formation of multigrain agglomerates. Determined values of the maximal and remanent magnetization, as well as coercive field, depended on the Co2+ and Mg2+ ion content and increased with substitution of diamagnetic Mg2+ ions with magnetic Co2+ ions. Most impressive is the increase of the coercive field from 74 Oe for MgFe2O4 to 1000 Oe for CoFe2O4, as well as an increase of magnetization in the field of 10 kOe from 27.4 emu g(-1) to 75.7 emu g(-1). The determined optical band gaps from UV/Vis DRS measurements showed a strong dependence on cation content, morphology, and crystallite size, decreasing from 2.09 eV for MgFe2O4 to 1.42 eV for CoFe2O4. The photocatalytic efficiency of as-synthesized ferrites was investigated by monitoring photocatalytic degradation of Methylene Blue (MB) under natural sunlight, and artificial light source emitting visible light. Different conditions of MB degradation such as photocatalyst loading, molar concentration of MB, and pH values were investigated. Results have shown that under both visible light and natural sunlight, excessive amounts of cobalt retarded the photocatalytic process. Co0.9Mg0.1Fe2O4 showed considerable activity (74.5% after 4 h) that is unexpected but possibly connected to structural anomalies. The best photocatalytic activity under natural sunlight was achieved by MgFe204 (82% after 4 h), while the best photocatalytic activity under visible light was achieved by Co0.1Mg0.9Fe2O4 (79% after 4 h).
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Mixed Mg-Co spinel ferrites: Structure, morphology, magnetic and photocatalytic properties
VL  - 855
DO  - 10.1016/j.jallcom.2020.157429
ER  - 
@article{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Pavlović, Vera P. and Barisic, Dario and Pajić, Damir and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2021",
abstract = "CoxMg1-xFe2O4 (where x was 0.0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1) spinel ferrites were synthesized by the sol-gel combustion method using citric acid as fuel, following the rules of propellant chemistry. Amorphous powders were then calcined at 700 degrees C for 3 h. Structural analysis by X-Ray diffraction (XRD), FTIR and Raman spectroscopy confirmed the formation of a cubic spinel structure where the cation distribution and inversion degree depended on the Co2+ and Mg2+ ion content. Accordingly, the lattice parameter varied between 8.3703 angstrom (MgFe2O4) and 8.3919 A (Co-0.9 Mg0.1Fe2O4) as did the crystallite size, from 34 nm (Co0.1Mg0.9Fe2O4) to 48 nm (Co0.9Mg0.1Fe2O4). Scanning electron microscopy (SEM) showed the formation of multigrain agglomerates. Determined values of the maximal and remanent magnetization, as well as coercive field, depended on the Co2+ and Mg2+ ion content and increased with substitution of diamagnetic Mg2+ ions with magnetic Co2+ ions. Most impressive is the increase of the coercive field from 74 Oe for MgFe2O4 to 1000 Oe for CoFe2O4, as well as an increase of magnetization in the field of 10 kOe from 27.4 emu g(-1) to 75.7 emu g(-1). The determined optical band gaps from UV/Vis DRS measurements showed a strong dependence on cation content, morphology, and crystallite size, decreasing from 2.09 eV for MgFe2O4 to 1.42 eV for CoFe2O4. The photocatalytic efficiency of as-synthesized ferrites was investigated by monitoring photocatalytic degradation of Methylene Blue (MB) under natural sunlight, and artificial light source emitting visible light. Different conditions of MB degradation such as photocatalyst loading, molar concentration of MB, and pH values were investigated. Results have shown that under both visible light and natural sunlight, excessive amounts of cobalt retarded the photocatalytic process. Co0.9Mg0.1Fe2O4 showed considerable activity (74.5% after 4 h) that is unexpected but possibly connected to structural anomalies. The best photocatalytic activity under natural sunlight was achieved by MgFe204 (82% after 4 h), while the best photocatalytic activity under visible light was achieved by Co0.1Mg0.9Fe2O4 (79% after 4 h).",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Mixed Mg-Co spinel ferrites: Structure, morphology, magnetic and photocatalytic properties",
volume = "855",
doi = "10.1016/j.jallcom.2020.157429"
}
Dojčinović, M., Vasiljević, Z. Z., Pavlović, V. P., Barisic, D., Pajić, D., Tadić, N. B.,& Nikolić, M. V.. (2021). Mixed Mg-Co spinel ferrites: Structure, morphology, magnetic and photocatalytic properties. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 855.
https://doi.org/10.1016/j.jallcom.2020.157429
Dojčinović M, Vasiljević ZZ, Pavlović VP, Barisic D, Pajić D, Tadić NB, Nikolić MV. Mixed Mg-Co spinel ferrites: Structure, morphology, magnetic and photocatalytic properties. in Journal of Alloys and Compounds. 2021;855.
doi:10.1016/j.jallcom.2020.157429 .
Dojčinović, Milena, Vasiljević, Zorka Z, Pavlović, Vera P., Barisic, Dario, Pajić, Damir, Tadić, Nenad B., Nikolić, Maria Vesna, "Mixed Mg-Co spinel ferrites: Structure, morphology, magnetic and photocatalytic properties" in Journal of Alloys and Compounds, 855 (2021),
https://doi.org/10.1016/j.jallcom.2020.157429 . .
80
76

Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing

Dojčinović, Milena; Vasiljević, Zorka Z; Krstic, Jugoslav B.; Vujančević, Jelena; Marković, Smilja; Tadić, Nenad B.; Nikolić, Maria Vesna

(MDPI, Basel, 2021)

TY  - JOUR
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Krstic, Jugoslav B.
AU  - Vujančević, Jelena
AU  - Marković, Smilja
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1436
AB  - Nickel manganite nanocrystalline fibers were obtained by electrospinning and subsequent calcination at 400 degrees C. As-spun fibers were characterized by TG/DTA, Scanning Electron Microscopy and FT-IR spectroscopy analysis. X-ray diffraction and FT-IR spectroscopy analysis confirmed the formation of nickel manganite with a cubic spinel structure, while N-2 physisorption at 77 K enabled determination of the BET specific surface area as 25.3 m(2)/g and (BJH) mesopore volume as 21.5 m(2)/g. The material constant (B) of the nanocrystalline nickel manganite fibers applied by drop-casting on test interdigitated electrodes on alumina substrate, dried at room temperature, was determined as 4379 K in the 20-50 degrees C temperature range and a temperature sensitivity of -4.95%/K at room temperature (25 degrees C). The change of impedance with relative humidity was monitored at 25 and 50 degrees C for a relative humidity (RH) change of 40 to 90% in the 42 Hz pi 1 MHz frequency range. At 100 Hz and 25 degrees C, the sensitivity of 327.36 +/- 80.12 k omega/%RH was determined, showing that nickel manganite obtained by electrospinning has potential as a multifunctional material for combined humidity and temperature sensing.
PB  - MDPI, Basel
T2  - Sensors
T1  - Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing
IS  - 13
VL  - 21
DO  - 10.3390/s21134357
ER  - 
@article{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Krstic, Jugoslav B. and Vujančević, Jelena and Marković, Smilja and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2021",
abstract = "Nickel manganite nanocrystalline fibers were obtained by electrospinning and subsequent calcination at 400 degrees C. As-spun fibers were characterized by TG/DTA, Scanning Electron Microscopy and FT-IR spectroscopy analysis. X-ray diffraction and FT-IR spectroscopy analysis confirmed the formation of nickel manganite with a cubic spinel structure, while N-2 physisorption at 77 K enabled determination of the BET specific surface area as 25.3 m(2)/g and (BJH) mesopore volume as 21.5 m(2)/g. The material constant (B) of the nanocrystalline nickel manganite fibers applied by drop-casting on test interdigitated electrodes on alumina substrate, dried at room temperature, was determined as 4379 K in the 20-50 degrees C temperature range and a temperature sensitivity of -4.95%/K at room temperature (25 degrees C). The change of impedance with relative humidity was monitored at 25 and 50 degrees C for a relative humidity (RH) change of 40 to 90% in the 42 Hz pi 1 MHz frequency range. At 100 Hz and 25 degrees C, the sensitivity of 327.36 +/- 80.12 k omega/%RH was determined, showing that nickel manganite obtained by electrospinning has potential as a multifunctional material for combined humidity and temperature sensing.",
publisher = "MDPI, Basel",
journal = "Sensors",
title = "Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing",
number = "13",
volume = "21",
doi = "10.3390/s21134357"
}
Dojčinović, M., Vasiljević, Z. Z., Krstic, J. B., Vujančević, J., Marković, S., Tadić, N. B.,& Nikolić, M. V.. (2021). Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing. in Sensors
MDPI, Basel., 21(13).
https://doi.org/10.3390/s21134357
Dojčinović M, Vasiljević ZZ, Krstic JB, Vujančević J, Marković S, Tadić NB, Nikolić MV. Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing. in Sensors. 2021;21(13).
doi:10.3390/s21134357 .
Dojčinović, Milena, Vasiljević, Zorka Z, Krstic, Jugoslav B., Vujančević, Jelena, Marković, Smilja, Tadić, Nenad B., Nikolić, Maria Vesna, "Electrospun Nickel Manganite (NiMn2O4) Nanocrystalline Fibers for Humidity and Temperature Sensing" in Sensors, 21, no. 13 (2021),
https://doi.org/10.3390/s21134357 . .
9
1
8

Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers

Vasiljević, Zorka Z; Dojčinović, Milena; Vujančević, Jelena; Spreitzer, Matjaz; Kovač, Janez; Bartolić, Dragana; Marković, Smilja; Jankovic-Castvan, Ivona; Tadić, Nenad B.; Nikolić, Maria Vesna

(Royal Soc Chemistry, Cambridge, 2021)

TY  - JOUR
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Spreitzer, Matjaz
AU  - Kovač, Janez
AU  - Bartolić, Dragana
AU  - Marković, Smilja
AU  - Jankovic-Castvan, Ivona
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1403
AB  - Nanostructured Fe2TiO5 (pseudobrookite), a mixed metal oxide material holds significant promise for utilization in energy and environmental applications. However, its full application is still hindered due to the difficulty to synthesize monophasic Fe2TiO5 with high crystallinity and a large specific surface area. Herein, Fe2TiO5 nanofibers were synthesized via a versatile and low-cost electrospinning method, followed by a calcination process at different temperatures. We found a significant effect of the calcination process and its duration on the crystalline phase in the form of either pseudobrookite or pseudobrookite-hematite-rutile and the morphology of calcined nanofibers. The crystallite size increased whereas the specific surface area decreased with an increase in calcination temperature. At higher temperatures, the growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles was noted. The highest specific surface area was obtained for the sample calcined at 500 degrees C for 6 h (S-BET = 64.4 m(2) g(-1)). This work opens new opportunities in the synthesis of Fe2TiO5 nanostructures using the electrospinning method and a subsequent optimized calcination process for energy-related applications.
PB  - Royal Soc Chemistry, Cambridge
T2  - RSC Advances
T1  - Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers
EP  - 32368
IS  - 51
SP  - 32358
VL  - 11
DO  - 10.1039/d1ra05748k
ER  - 
@article{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Vujančević, Jelena and Spreitzer, Matjaz and Kovač, Janez and Bartolić, Dragana and Marković, Smilja and Jankovic-Castvan, Ivona and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2021",
abstract = "Nanostructured Fe2TiO5 (pseudobrookite), a mixed metal oxide material holds significant promise for utilization in energy and environmental applications. However, its full application is still hindered due to the difficulty to synthesize monophasic Fe2TiO5 with high crystallinity and a large specific surface area. Herein, Fe2TiO5 nanofibers were synthesized via a versatile and low-cost electrospinning method, followed by a calcination process at different temperatures. We found a significant effect of the calcination process and its duration on the crystalline phase in the form of either pseudobrookite or pseudobrookite-hematite-rutile and the morphology of calcined nanofibers. The crystallite size increased whereas the specific surface area decreased with an increase in calcination temperature. At higher temperatures, the growth of Fe2TiO5 nanoparticles and simultaneous coalescence of small particles was noted. The highest specific surface area was obtained for the sample calcined at 500 degrees C for 6 h (S-BET = 64.4 m(2) g(-1)). This work opens new opportunities in the synthesis of Fe2TiO5 nanostructures using the electrospinning method and a subsequent optimized calcination process for energy-related applications.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "RSC Advances",
title = "Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers",
pages = "32368-32358",
number = "51",
volume = "11",
doi = "10.1039/d1ra05748k"
}
Vasiljević, Z. Z., Dojčinović, M., Vujančević, J., Spreitzer, M., Kovač, J., Bartolić, D., Marković, S., Jankovic-Castvan, I., Tadić, N. B.,& Nikolić, M. V.. (2021). Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers. in RSC Advances
Royal Soc Chemistry, Cambridge., 11(51), 32358-32368.
https://doi.org/10.1039/d1ra05748k
Vasiljević ZZ, Dojčinović M, Vujančević J, Spreitzer M, Kovač J, Bartolić D, Marković S, Jankovic-Castvan I, Tadić NB, Nikolić MV. Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers. in RSC Advances. 2021;11(51):32358-32368.
doi:10.1039/d1ra05748k .
Vasiljević, Zorka Z, Dojčinović, Milena, Vujančević, Jelena, Spreitzer, Matjaz, Kovač, Janez, Bartolić, Dragana, Marković, Smilja, Jankovic-Castvan, Ivona, Tadić, Nenad B., Nikolić, Maria Vesna, "Exploring the impact of calcination parameters on the crystal structure, morphology, and optical properties of electrospun Fe2TiO5 nanofibers" in RSC Advances, 11, no. 51 (2021):32358-32368,
https://doi.org/10.1039/d1ra05748k . .
12
12

Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing

Dojčinović, Milena; Vasiljević, Zorka Z; Kovač, Janez; Tadić, Nenad B.; Nikolić, Maria Vesna

(MDPI, Basel, 2021)

TY  - JOUR
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Kovač, Janez
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1400
AB  - Nanocrystalline nickel manganite (NiMn2O4) powder with a pure cubic spinel phase structure was synthesized via sol-gel combustion and characterized with XRD, FT-IR, XPS and SEM. The powder was mixed with sodium alginate gel to form a nano-biocomposite gel, dried at room temperature to form a thick film and characterized with FT-IR and SEM. DC resistance and AC impedance of sensor test structures obtained by drop casting the nano-biocomposite gel onto test interdigitated PdAg electrodes on an alumina substrate were measured in the temperature range of 20-50 degrees C at a constant relative humidity (RH) of 50% and at room temperature (25 degrees C) in the RH range of 40-90%. The material constant obtained from the measured decrease in resistance with temperature was determined to be 4523 K, while the temperature sensitivity at room temperature (25 degrees C) was -5.09%/K. Analysis of the complex impedance plots showed a dominant influence of grains. The decrease in complex impedance with increase in temperature confirmed the negative temperature coefficient effect. The grain resistance and grain relaxation frequency were determined using an equivalent circuit. The activation energy for conduction was determined as 0.45 eV from the temperature dependence of the grain resistance according to the small polaron hopping model, while the activation energy for relaxation was 0.43 eV determined from the Arrhenius dependence of the grain relaxation frequency on temperature.
PB  - MDPI, Basel
T2  - Chemosensors
T1  - Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing
IS  - 9
VL  - 9
DO  - 10.3390/chemosensors9090241
ER  - 
@article{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Kovač, Janez and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2021",
abstract = "Nanocrystalline nickel manganite (NiMn2O4) powder with a pure cubic spinel phase structure was synthesized via sol-gel combustion and characterized with XRD, FT-IR, XPS and SEM. The powder was mixed with sodium alginate gel to form a nano-biocomposite gel, dried at room temperature to form a thick film and characterized with FT-IR and SEM. DC resistance and AC impedance of sensor test structures obtained by drop casting the nano-biocomposite gel onto test interdigitated PdAg electrodes on an alumina substrate were measured in the temperature range of 20-50 degrees C at a constant relative humidity (RH) of 50% and at room temperature (25 degrees C) in the RH range of 40-90%. The material constant obtained from the measured decrease in resistance with temperature was determined to be 4523 K, while the temperature sensitivity at room temperature (25 degrees C) was -5.09%/K. Analysis of the complex impedance plots showed a dominant influence of grains. The decrease in complex impedance with increase in temperature confirmed the negative temperature coefficient effect. The grain resistance and grain relaxation frequency were determined using an equivalent circuit. The activation energy for conduction was determined as 0.45 eV from the temperature dependence of the grain resistance according to the small polaron hopping model, while the activation energy for relaxation was 0.43 eV determined from the Arrhenius dependence of the grain relaxation frequency on temperature.",
publisher = "MDPI, Basel",
journal = "Chemosensors",
title = "Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing",
number = "9",
volume = "9",
doi = "10.3390/chemosensors9090241"
}
Dojčinović, M., Vasiljević, Z. Z., Kovač, J., Tadić, N. B.,& Nikolić, M. V.. (2021). Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing. in Chemosensors
MDPI, Basel., 9(9).
https://doi.org/10.3390/chemosensors9090241
Dojčinović M, Vasiljević ZZ, Kovač J, Tadić NB, Nikolić MV. Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing. in Chemosensors. 2021;9(9).
doi:10.3390/chemosensors9090241 .
Dojčinović, Milena, Vasiljević, Zorka Z, Kovač, Janez, Tadić, Nenad B., Nikolić, Maria Vesna, "Nickel Manganite-Sodium Alginate Nano-Biocomposite for Temperature Sensing" in Chemosensors, 9, no. 9 (2021),
https://doi.org/10.3390/chemosensors9090241 . .
7
7

Use of FeMnO3 as a Catalyst in the Water Splitting Reaction

Dojčinović, Milena; Vasiljević, Zorka Z; Ribić, Vesna; Mravik, Željko; Stojković Simatović, Ivana; Nikolić, Maria Vesna

(2020)

TY  - CONF
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Ribić, Vesna
AU  - Mravik, Željko
AU  - Stojković Simatović, Ivana
AU  - Nikolić, Maria Vesna
PY  - 2020
C3  - 71st Annual Meeting of the International Society of Electrochemistry
T1  - Use of FeMnO3 as a Catalyst in the Water Splitting Reaction
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1552
ER  - 
@conference{
author = "Dojčinović, Milena and Vasiljević, Zorka Z and Ribić, Vesna and Mravik, Željko and Stojković Simatović, Ivana and Nikolić, Maria Vesna",
year = "2020",
journal = "71st Annual Meeting of the International Society of Electrochemistry",
title = "Use of FeMnO3 as a Catalyst in the Water Splitting Reaction",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1552"
}
Dojčinović, M., Vasiljević, Z. Z., Ribić, V., Mravik, Ž., Stojković Simatović, I.,& Nikolić, M. V.. (2020). Use of FeMnO3 as a Catalyst in the Water Splitting Reaction. in 71st Annual Meeting of the International Society of Electrochemistry.
https://hdl.handle.net/21.15107/rcub_rimsi_1552
Dojčinović M, Vasiljević ZZ, Ribić V, Mravik Ž, Stojković Simatović I, Nikolić MV. Use of FeMnO3 as a Catalyst in the Water Splitting Reaction. in 71st Annual Meeting of the International Society of Electrochemistry. 2020;.
https://hdl.handle.net/21.15107/rcub_rimsi_1552 .
Dojčinović, Milena, Vasiljević, Zorka Z, Ribić, Vesna, Mravik, Željko, Stojković Simatović, Ivana, Nikolić, Maria Vesna, "Use of FeMnO3 as a Catalyst in the Water Splitting Reaction" in 71st Annual Meeting of the International Society of Electrochemistry (2020),
https://hdl.handle.net/21.15107/rcub_rimsi_1552 .

Synthesis and antibacterial activity of iron manganite (FeMnO3) particles against the environmental bacterium Bacillus subtilis

Vasiljević, Zorka Z; Dojčinović, Milena; Krstic, Jugoslav B.; Ribić, Vesna; Tadić, Nenad B.; Ognjanović, Milos; Auger, Sandrine; Vidic, Jasmina; Nikolić, Maria Vesna

(Royal Soc Chemistry, Cambridge, 2020)

TY  - JOUR
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Krstic, Jugoslav B.
AU  - Ribić, Vesna
AU  - Tadić, Nenad B.
AU  - Ognjanović, Milos
AU  - Auger, Sandrine
AU  - Vidic, Jasmina
AU  - Nikolić, Maria Vesna
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1360
AB  - Nanocrystalline iron manganite powder was synthesized using the sol-gel combustion process, with glycine as fuel. It was further calcined at 900 degrees C for 8 h, resulting in the formation of a loose cubic FeMnO3 powder with a small specific surface area, net-like structure and plate-like particles as confirmed by XRD, N-2 physisorption, FESEM and TEM analyses. The metal ion release was studied by ICP-OES and showed that less than 10 ppb of Fe or Mn ions were released by leaching in water, but 0.36 ppm Fe and 3.69 ppm Mn was found in LB (Luria-Bertani) bacterial medium. The generation of reactive oxygen species (ROS) was monitored in distilled water and bacterial medium and showed that FeMnO3 particles do not generate O-2 & x2d9;(-) ions with or without UV irradiation, but synthesize H2O2 and show an antioxidative effect. Besides the higher stability of FeMnO3 particles in aqueous solution they showed an inhibitory effect on Bacillus subtilis growth in LB medium even at low concentrations (0.01 mg ml(-1)), but not in BHI medium even at 1 mg ml(-1). This study points out that the mechanism of antibacterial action of engineered metal oxides needs continued investigation and specific experimental controls.
PB  - Royal Soc Chemistry, Cambridge
T2  - RSC Advances
T1  - Synthesis and antibacterial activity of iron manganite (FeMnO3) particles against the environmental bacterium Bacillus subtilis
EP  - 13888
IS  - 23
SP  - 13879
VL  - 10
DO  - 10.1039/d0ra01809k
ER  - 
@article{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Krstic, Jugoslav B. and Ribić, Vesna and Tadić, Nenad B. and Ognjanović, Milos and Auger, Sandrine and Vidic, Jasmina and Nikolić, Maria Vesna",
year = "2020",
abstract = "Nanocrystalline iron manganite powder was synthesized using the sol-gel combustion process, with glycine as fuel. It was further calcined at 900 degrees C for 8 h, resulting in the formation of a loose cubic FeMnO3 powder with a small specific surface area, net-like structure and plate-like particles as confirmed by XRD, N-2 physisorption, FESEM and TEM analyses. The metal ion release was studied by ICP-OES and showed that less than 10 ppb of Fe or Mn ions were released by leaching in water, but 0.36 ppm Fe and 3.69 ppm Mn was found in LB (Luria-Bertani) bacterial medium. The generation of reactive oxygen species (ROS) was monitored in distilled water and bacterial medium and showed that FeMnO3 particles do not generate O-2 & x2d9;(-) ions with or without UV irradiation, but synthesize H2O2 and show an antioxidative effect. Besides the higher stability of FeMnO3 particles in aqueous solution they showed an inhibitory effect on Bacillus subtilis growth in LB medium even at low concentrations (0.01 mg ml(-1)), but not in BHI medium even at 1 mg ml(-1). This study points out that the mechanism of antibacterial action of engineered metal oxides needs continued investigation and specific experimental controls.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "RSC Advances",
title = "Synthesis and antibacterial activity of iron manganite (FeMnO3) particles against the environmental bacterium Bacillus subtilis",
pages = "13888-13879",
number = "23",
volume = "10",
doi = "10.1039/d0ra01809k"
}
Vasiljević, Z. Z., Dojčinović, M., Krstic, J. B., Ribić, V., Tadić, N. B., Ognjanović, M., Auger, S., Vidic, J.,& Nikolić, M. V.. (2020). Synthesis and antibacterial activity of iron manganite (FeMnO3) particles against the environmental bacterium Bacillus subtilis. in RSC Advances
Royal Soc Chemistry, Cambridge., 10(23), 13879-13888.
https://doi.org/10.1039/d0ra01809k
Vasiljević ZZ, Dojčinović M, Krstic JB, Ribić V, Tadić NB, Ognjanović M, Auger S, Vidic J, Nikolić MV. Synthesis and antibacterial activity of iron manganite (FeMnO3) particles against the environmental bacterium Bacillus subtilis. in RSC Advances. 2020;10(23):13879-13888.
doi:10.1039/d0ra01809k .
Vasiljević, Zorka Z, Dojčinović, Milena, Krstic, Jugoslav B., Ribić, Vesna, Tadić, Nenad B., Ognjanović, Milos, Auger, Sandrine, Vidic, Jasmina, Nikolić, Maria Vesna, "Synthesis and antibacterial activity of iron manganite (FeMnO3) particles against the environmental bacterium Bacillus subtilis" in RSC Advances, 10, no. 23 (2020):13879-13888,
https://doi.org/10.1039/d0ra01809k . .
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Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method

Vasiljević, Zorka Z; Dojčinović, Milena; Vujančević, Jelena; Jankovic-Castvan, I.; Ognjanović, M.; Tadić, Nenad B.; Stojadinović, S.; Branković, Goran; Nikolić, Maria Vesna

(Royal Soc, London, 2020)

TY  - JOUR
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Jankovic-Castvan, I.
AU  - Ognjanović, M.
AU  - Tadić, Nenad B.
AU  - Stojadinović, S.
AU  - Branković, Goran
AU  - Nikolić, Maria Vesna
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1352
AB  - The aim of this work was to synthesize semiconducting oxide nanoparticles using a simple method with low production cost to be applied in natural sunlight for photocatalytic degradation of pollutants in waste water. Iron titanate (Fe2TiO5) nanoparticles with an orthorhombic structure were successfully synthesized using a modified sol-gel method and calcination at 750 degrees C. The as-prepared Fe2TiO5 nanoparticles exhibited a moderate specific surface area. The mesoporous Fe2TiO5 nanoparticles possessed strong absorption in the visible-light region and the band gap was estimated to be around 2.16 eV. The photocatalytic activity was evaluated by the degradation of methylene blue under natural sunlight. The effect of parameters such as the amount of catalyst, initial concentration of the dye and pH of the dye solution on the removal efficiency of methylene blue was investigated. Fe2TiO5 showed high degradation efficiency in a strong alkaline medium that can be the result of the facilitated formation of OH radicals due to an increased concentration of hydroxyl ions.
PB  - Royal Soc, London
T2  - Royal Society Open Science
T1  - Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method
IS  - 9
VL  - 7
DO  - 10.1098/rsos.200708
ER  - 
@article{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Vujančević, Jelena and Jankovic-Castvan, I. and Ognjanović, M. and Tadić, Nenad B. and Stojadinović, S. and Branković, Goran and Nikolić, Maria Vesna",
year = "2020",
abstract = "The aim of this work was to synthesize semiconducting oxide nanoparticles using a simple method with low production cost to be applied in natural sunlight for photocatalytic degradation of pollutants in waste water. Iron titanate (Fe2TiO5) nanoparticles with an orthorhombic structure were successfully synthesized using a modified sol-gel method and calcination at 750 degrees C. The as-prepared Fe2TiO5 nanoparticles exhibited a moderate specific surface area. The mesoporous Fe2TiO5 nanoparticles possessed strong absorption in the visible-light region and the band gap was estimated to be around 2.16 eV. The photocatalytic activity was evaluated by the degradation of methylene blue under natural sunlight. The effect of parameters such as the amount of catalyst, initial concentration of the dye and pH of the dye solution on the removal efficiency of methylene blue was investigated. Fe2TiO5 showed high degradation efficiency in a strong alkaline medium that can be the result of the facilitated formation of OH radicals due to an increased concentration of hydroxyl ions.",
publisher = "Royal Soc, London",
journal = "Royal Society Open Science",
title = "Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method",
number = "9",
volume = "7",
doi = "10.1098/rsos.200708"
}
Vasiljević, Z. Z., Dojčinović, M., Vujančević, J., Jankovic-Castvan, I., Ognjanović, M., Tadić, N. B., Stojadinović, S., Branković, G.,& Nikolić, M. V.. (2020). Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method. in Royal Society Open Science
Royal Soc, London., 7(9).
https://doi.org/10.1098/rsos.200708
Vasiljević ZZ, Dojčinović M, Vujančević J, Jankovic-Castvan I, Ognjanović M, Tadić NB, Stojadinović S, Branković G, Nikolić MV. Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method. in Royal Society Open Science. 2020;7(9).
doi:10.1098/rsos.200708 .
Vasiljević, Zorka Z, Dojčinović, Milena, Vujančević, Jelena, Jankovic-Castvan, I., Ognjanović, M., Tadić, Nenad B., Stojadinović, S., Branković, Goran, Nikolić, Maria Vesna, "Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method" in Royal Society Open Science, 7, no. 9 (2020),
https://doi.org/10.1098/rsos.200708 . .
1
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162

Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material

Nikolić, Maria Vesna; Dojčinović, Milena; Vasiljević, Zorka Z; Luković, Miloljub; Labus, Nebojša J.

(Institute of Electrical and Electronics Engineers Inc., 2020)

TY  - JOUR
AU  - Nikolić, Maria Vesna
AU  - Dojčinović, Milena
AU  - Vasiljević, Zorka Z
AU  - Luković, Miloljub
AU  - Labus, Nebojša J.
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1348
AB  - Nanocomposite Zn2SnO4/SnO2 powder was obtained by solid state synthesis from homogenized starting nanopowders of ZnO and SnO2, mixed in the 1:1 molar ratio, structurally and morphologically characterized using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Thick film paste was made by adding organic vehicles to the obtained powder. Three to five layers (layer thickness approx. 12 mu m) were screen printed on alumina substrate with small test PdAg electrodes and fired at 600 degrees C for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing. Impedance response was studied at the working temperatures of 25 and 50 degrees C in a humidity chamber where the relative humidity (RH) was 30-90% and measured frequency 42 Hz - 1 MHz. With increase in film thickness the overall sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 M Omega (60 mu m), from 23.4 to 0.25 M Omega (48 mu m) and from 6.8 to 0.02 M Omega (36 mu m) at 25 degrees C, while at 50 degrees C and also 100 Hz it reduced from 14 M Omega to 0.72 \text{M}\Omega (48 mu m) for RH 30 and 90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for application in humidity sensing.
PB  - Institute of Electrical and Electronics Engineers Inc.
T2  - IEEE Sensors Journal
T1  - Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material
EP  - 7516
IS  - 14
SP  - 7509
VL  - 20
DO  - 10.1109/JSEN.2020.2983135
ER  - 
@article{
author = "Nikolić, Maria Vesna and Dojčinović, Milena and Vasiljević, Zorka Z and Luković, Miloljub and Labus, Nebojša J.",
year = "2020",
abstract = "Nanocomposite Zn2SnO4/SnO2 powder was obtained by solid state synthesis from homogenized starting nanopowders of ZnO and SnO2, mixed in the 1:1 molar ratio, structurally and morphologically characterized using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Thick film paste was made by adding organic vehicles to the obtained powder. Three to five layers (layer thickness approx. 12 mu m) were screen printed on alumina substrate with small test PdAg electrodes and fired at 600 degrees C for 30 minutes. SEM analysis confirmed formation of a porous structure suitable for humidity sensing. Impedance response was studied at the working temperatures of 25 and 50 degrees C in a humidity chamber where the relative humidity (RH) was 30-90% and measured frequency 42 Hz - 1 MHz. With increase in film thickness the overall sensor impedance increased. It reduced at 100 Hz from 36 to 0.25 M Omega (60 mu m), from 23.4 to 0.25 M Omega (48 mu m) and from 6.8 to 0.02 M Omega (36 mu m) at 25 degrees C, while at 50 degrees C and also 100 Hz it reduced from 14 M Omega to 0.72 \text{M}\Omega (48 mu m) for RH 30 and 90%, respectively. The response (8 s) and recovery (10 s) was fast, showing that this nanocomposite has potential for application in humidity sensing.",
publisher = "Institute of Electrical and Electronics Engineers Inc.",
journal = "IEEE Sensors Journal",
title = "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material",
pages = "7516-7509",
number = "14",
volume = "20",
doi = "10.1109/JSEN.2020.2983135"
}
Nikolić, M. V., Dojčinović, M., Vasiljević, Z. Z., Luković, M.,& Labus, N. J.. (2020). Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal
Institute of Electrical and Electronics Engineers Inc.., 20(14), 7509-7516.
https://doi.org/10.1109/JSEN.2020.2983135
Nikolić MV, Dojčinović M, Vasiljević ZZ, Luković M, Labus NJ. Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material. in IEEE Sensors Journal. 2020;20(14):7509-7516.
doi:10.1109/JSEN.2020.2983135 .
Nikolić, Maria Vesna, Dojčinović, Milena, Vasiljević, Zorka Z, Luković, Miloljub, Labus, Nebojša J., "Nanocomposite Zn2SnO4/SnO2 Thick Films as a Humidity Sensing Material" in IEEE Sensors Journal, 20, no. 14 (2020):7509-7516,
https://doi.org/10.1109/JSEN.2020.2983135 . .
10
5
7

Impact of Microstructure on Humidity Influence on Complex Impedance of Iron Manganite

Nikolić, Maria Vesna; Vasiljević, Zorka Z; Dojčinović, Milena; Vujančević, Jelena; Radovanović, M.

(IEEE Computer Society, 2020)

TY  - CONF
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Radovanović, M.
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1308
AB  - This work deals with our continued research of oxide materials for potential application in gas/humidity sensing. We have made thick film samples using iron manganite powder synthesized by a so/-gel combustion method with a net-like structure, by screen printing on alumina substrate with PdAg interdigitated electrodes. The thick film samples were fired at two temperatures 600 and 800 degrees C. The powder morphology was retained and only the organic compounds in the paste were burnt-out at 600 degrees C, while at 800 degrees C the thick film surface morphology was different where grain growth and individual particles can he observed, We measured complex impedance in a temperature and humidity chamber at room temperature (25 degrees C) in the relative humidity range 30-90% and frequency 100 Hz 1 MHz. The thick,film surface morphology has a significant influence on the effect of humidity on complex impedance. The complex impedance of thick films fired at 600 degrees C was high and did not decrease noticeably with increase in relative humidity (M., except for RH 80 and 90%, while thick film samples fired at 800 degrees C had an overall lower impedance that reduced more noticeably with increase in RH 40-70% and even more for RH 80 and 90%.
PB  - IEEE Computer Society
C3  - Proceedings of the International Spring Seminar on Electronics Technology
T1  - Impact of Microstructure on Humidity Influence on Complex Impedance of Iron Manganite
VL  - 2020-May
DO  - 10.1109/ISSE49702.2020.9120967
ER  - 
@conference{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Z and Dojčinović, Milena and Vujančević, Jelena and Radovanović, M.",
year = "2020",
abstract = "This work deals with our continued research of oxide materials for potential application in gas/humidity sensing. We have made thick film samples using iron manganite powder synthesized by a so/-gel combustion method with a net-like structure, by screen printing on alumina substrate with PdAg interdigitated electrodes. The thick film samples were fired at two temperatures 600 and 800 degrees C. The powder morphology was retained and only the organic compounds in the paste were burnt-out at 600 degrees C, while at 800 degrees C the thick film surface morphology was different where grain growth and individual particles can he observed, We measured complex impedance in a temperature and humidity chamber at room temperature (25 degrees C) in the relative humidity range 30-90% and frequency 100 Hz 1 MHz. The thick,film surface morphology has a significant influence on the effect of humidity on complex impedance. The complex impedance of thick films fired at 600 degrees C was high and did not decrease noticeably with increase in relative humidity (M., except for RH 80 and 90%, while thick film samples fired at 800 degrees C had an overall lower impedance that reduced more noticeably with increase in RH 40-70% and even more for RH 80 and 90%.",
publisher = "IEEE Computer Society",
journal = "Proceedings of the International Spring Seminar on Electronics Technology",
title = "Impact of Microstructure on Humidity Influence on Complex Impedance of Iron Manganite",
volume = "2020-May",
doi = "10.1109/ISSE49702.2020.9120967"
}
Nikolić, M. V., Vasiljević, Z. Z., Dojčinović, M., Vujančević, J.,& Radovanović, M.. (2020). Impact of Microstructure on Humidity Influence on Complex Impedance of Iron Manganite. in Proceedings of the International Spring Seminar on Electronics Technology
IEEE Computer Society., 2020-May.
https://doi.org/10.1109/ISSE49702.2020.9120967
Nikolić MV, Vasiljević ZZ, Dojčinović M, Vujančević J, Radovanović M. Impact of Microstructure on Humidity Influence on Complex Impedance of Iron Manganite. in Proceedings of the International Spring Seminar on Electronics Technology. 2020;2020-May.
doi:10.1109/ISSE49702.2020.9120967 .
Nikolić, Maria Vesna, Vasiljević, Zorka Z, Dojčinović, Milena, Vujančević, Jelena, Radovanović, M., "Impact of Microstructure on Humidity Influence on Complex Impedance of Iron Manganite" in Proceedings of the International Spring Seminar on Electronics Technology, 2020-May (2020),
https://doi.org/10.1109/ISSE49702.2020.9120967 . .

Nanocrystalline Nickel Manganite Synthesis by Sol-Gel Combustion for Flexible Temperature Sensors

Nikolić, Maria Vesna; Vasiljević, Zorka Z; Dojčinović, Milena; Tadić, Nenad B.; Radovanović, M.; Stojanović, Goran M

(Institute of Electrical and Electronics Engineers Inc., 2020)

TY  - CONF
AU  - Nikolić, Maria Vesna
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Tadić, Nenad B.
AU  - Radovanović, M.
AU  - Stojanović, Goran M
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1305
AB  - Nanocrystalline nickel manganite (NiMn2O4) was obtained by sol-gel combustion using glycine as fuel, followed by calcination at 800°C. X-ray diffraction (XRD) analysis confirmed the formation of a pure cubic spinel structure with a crystallite size of 54.5 nm. Scanning electron microscopy (SEM) of the obtained nickel manganite powder showed porous nanocrystalline morphology. The material constant (B) of the obtained nickel manganite powder applied as paste and dried at 100°C was determined as 4812 K in the temperature range 20-50°C, confirming potential application in flexible temperature sensors.
PB  - Institute of Electrical and Electronics Engineers Inc.
C3  - FLEPS 2020 - IEEE International Conference on Flexible and Printable Sensors and Systems
T1  - Nanocrystalline Nickel Manganite Synthesis by Sol-Gel Combustion for Flexible Temperature Sensors
DO  - 10.1109/FLEPS49123.2020.9239569
ER  - 
@conference{
author = "Nikolić, Maria Vesna and Vasiljević, Zorka Z and Dojčinović, Milena and Tadić, Nenad B. and Radovanović, M. and Stojanović, Goran M",
year = "2020",
abstract = "Nanocrystalline nickel manganite (NiMn2O4) was obtained by sol-gel combustion using glycine as fuel, followed by calcination at 800°C. X-ray diffraction (XRD) analysis confirmed the formation of a pure cubic spinel structure with a crystallite size of 54.5 nm. Scanning electron microscopy (SEM) of the obtained nickel manganite powder showed porous nanocrystalline morphology. The material constant (B) of the obtained nickel manganite powder applied as paste and dried at 100°C was determined as 4812 K in the temperature range 20-50°C, confirming potential application in flexible temperature sensors.",
publisher = "Institute of Electrical and Electronics Engineers Inc.",
journal = "FLEPS 2020 - IEEE International Conference on Flexible and Printable Sensors and Systems",
title = "Nanocrystalline Nickel Manganite Synthesis by Sol-Gel Combustion for Flexible Temperature Sensors",
doi = "10.1109/FLEPS49123.2020.9239569"
}
Nikolić, M. V., Vasiljević, Z. Z., Dojčinović, M., Tadić, N. B., Radovanović, M.,& Stojanović, G. M.. (2020). Nanocrystalline Nickel Manganite Synthesis by Sol-Gel Combustion for Flexible Temperature Sensors. in FLEPS 2020 - IEEE International Conference on Flexible and Printable Sensors and Systems
Institute of Electrical and Electronics Engineers Inc...
https://doi.org/10.1109/FLEPS49123.2020.9239569
Nikolić MV, Vasiljević ZZ, Dojčinović M, Tadić NB, Radovanović M, Stojanović GM. Nanocrystalline Nickel Manganite Synthesis by Sol-Gel Combustion for Flexible Temperature Sensors. in FLEPS 2020 - IEEE International Conference on Flexible and Printable Sensors and Systems. 2020;.
doi:10.1109/FLEPS49123.2020.9239569 .
Nikolić, Maria Vesna, Vasiljević, Zorka Z, Dojčinović, Milena, Tadić, Nenad B., Radovanović, M., Stojanović, Goran M, "Nanocrystalline Nickel Manganite Synthesis by Sol-Gel Combustion for Flexible Temperature Sensors" in FLEPS 2020 - IEEE International Conference on Flexible and Printable Sensors and Systems (2020),
https://doi.org/10.1109/FLEPS49123.2020.9239569 . .
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