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Supercapacitor electrodes: Is nickel foam the right substrate for active materials?

Dojčinović, Milena; Stojković Simatović, Ivana; Nikolić, Maria Vesna

(MDPI, 2024)

TY  - JOUR
AU  - Dojčinović, Milena
AU  - Stojković Simatović, Ivana
AU  - Nikolić, Maria Vesna
PY  - 2024
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3185
AB  - Ni foam is an extensively used current collector and substrate in investigations of electrochemically active materials such as supercapacitors and electrocatalysts for oxygen and hydrogen evolution reactions. This material is relatively cheap, porous, and conductive and has a large specific surface area, all of which make it a good substrate. We investigated Ni-Mg ferrites and NiMn2O4 as active materials for electrochemical energy storage. These materials, when loaded on Ni foam, gave promising capacitance values: 172 F/g (at 2 mV/s) for NiMn2O4 in 6 M KOH and 242 F/g (at 2 mV/s) for MgFe2O4 in 3 M KOH. Nevertheless, during the authors’ work, many experimental problems occurred. Inconsistencies in the results directed further investigation towards measuring the capacitance of the active materials using GCE and platinum electrodes as substrates to discover if Ni foam was the culprit of the inconsistencies. When non-nickel substrates were used, both NiMn2O4 and MgFe2O4 showed reduced capacitance. Experimental problems associated with the utilization of Ni foam as a substrate for active materials in supercapacitor electrodes are discussed here, combined with other problems already addressed in the scientific literature
PB  - MDPI
T2  - Materials
T1  - Supercapacitor electrodes: Is nickel foam the right substrate for active materials?
IS  - 6
SP  - 1292
VL  - 17
DO  - 10.3390/ma17061292
ER  - 
@article{
author = "Dojčinović, Milena and Stojković Simatović, Ivana and Nikolić, Maria Vesna",
year = "2024",
abstract = "Ni foam is an extensively used current collector and substrate in investigations of electrochemically active materials such as supercapacitors and electrocatalysts for oxygen and hydrogen evolution reactions. This material is relatively cheap, porous, and conductive and has a large specific surface area, all of which make it a good substrate. We investigated Ni-Mg ferrites and NiMn2O4 as active materials for electrochemical energy storage. These materials, when loaded on Ni foam, gave promising capacitance values: 172 F/g (at 2 mV/s) for NiMn2O4 in 6 M KOH and 242 F/g (at 2 mV/s) for MgFe2O4 in 3 M KOH. Nevertheless, during the authors’ work, many experimental problems occurred. Inconsistencies in the results directed further investigation towards measuring the capacitance of the active materials using GCE and platinum electrodes as substrates to discover if Ni foam was the culprit of the inconsistencies. When non-nickel substrates were used, both NiMn2O4 and MgFe2O4 showed reduced capacitance. Experimental problems associated with the utilization of Ni foam as a substrate for active materials in supercapacitor electrodes are discussed here, combined with other problems already addressed in the scientific literature",
publisher = "MDPI",
journal = "Materials",
title = "Supercapacitor electrodes: Is nickel foam the right substrate for active materials?",
number = "6",
pages = "1292",
volume = "17",
doi = "10.3390/ma17061292"
}
Dojčinović, M., Stojković Simatović, I.,& Nikolić, M. V.. (2024). Supercapacitor electrodes: Is nickel foam the right substrate for active materials?. in Materials
MDPI., 17(6), 1292.
https://doi.org/10.3390/ma17061292
Dojčinović M, Stojković Simatović I, Nikolić MV. Supercapacitor electrodes: Is nickel foam the right substrate for active materials?. in Materials. 2024;17(6):1292.
doi:10.3390/ma17061292 .
Dojčinović, Milena, Stojković Simatović, Ivana, Nikolić, Maria Vesna, "Supercapacitor electrodes: Is nickel foam the right substrate for active materials?" in Materials, 17, no. 6 (2024):1292,
https://doi.org/10.3390/ma17061292 . .