Electrochemical and Crystallographic Aspects of Lead Granular Growth
Authorized Users Only
2015
Authors
Nikolic, Nebojša D.
Ivanović, Evica R.
Branković, Goran

Lačnjevac, Uroš

Stevanović, Sanja I.
Stevanović, Jasmina S.

Pavlović, Miomir G.
Article (Published version)

Metadata
Show full item recordAbstract
Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated form...s. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.
Keywords:
granular growth / twinned particles / lead / electrodeposition / scanning electron microscopy / XRD / single crystalsSource:
Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 2015, 46, 4, 1760-1774Publisher:
- Springer, New York
Funding / projects:
DOI: 10.1007/s11663-015-0385-z
ISSN: 1073-5615
WoS: 000359022000025
Scopus: 2-s2.0-84938743026
Collections
Institution/Community
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Nikolic, Nebojša D. AU - Ivanović, Evica R. AU - Branković, Goran AU - Lačnjevac, Uroš AU - Stevanović, Sanja I. AU - Stevanović, Jasmina S. AU - Pavlović, Miomir G. PY - 2015 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/859 AB - Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated forms. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization. PB - Springer, New York T2 - Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science T1 - Electrochemical and Crystallographic Aspects of Lead Granular Growth EP - 1774 IS - 4 SP - 1760 VL - 46 DO - 10.1007/s11663-015-0385-z ER -
@article{ author = "Nikolic, Nebojša D. and Ivanović, Evica R. and Branković, Goran and Lačnjevac, Uroš and Stevanović, Sanja I. and Stevanović, Jasmina S. and Pavlović, Miomir G.", year = "2015", abstract = "Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated forms. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.", publisher = "Springer, New York", journal = "Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science", title = "Electrochemical and Crystallographic Aspects of Lead Granular Growth", pages = "1774-1760", number = "4", volume = "46", doi = "10.1007/s11663-015-0385-z" }
Nikolic, N. D., Ivanović, E. R., Branković, G., Lačnjevac, U., Stevanović, S. I., Stevanović, J. S.,& Pavlović, M. G.. (2015). Electrochemical and Crystallographic Aspects of Lead Granular Growth. in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science Springer, New York., 46(4), 1760-1774. https://doi.org/10.1007/s11663-015-0385-z
Nikolic ND, Ivanović ER, Branković G, Lačnjevac U, Stevanović SI, Stevanović JS, Pavlović MG. Electrochemical and Crystallographic Aspects of Lead Granular Growth. in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science. 2015;46(4):1760-1774. doi:10.1007/s11663-015-0385-z .
Nikolic, Nebojša D., Ivanović, Evica R., Branković, Goran, Lačnjevac, Uroš, Stevanović, Sanja I., Stevanović, Jasmina S., Pavlović, Miomir G., "Electrochemical and Crystallographic Aspects of Lead Granular Growth" in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 46, no. 4 (2015):1760-1774, https://doi.org/10.1007/s11663-015-0385-z . .