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Raman Responses in Mechanically Activated BaTiO3

Authorized Users Only
2014
Authors
Pavlović, Vera P.
Nikolić, Maria Vesna
Pavlović, Vladimir B
Blanusa, Jovan L
Stevanović, Suzana
Mitic, Vojislav V
Šćepanović, Maja
Vlahović, Branislav
Article (Published version)
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Abstract
The structure and lattice dynamics of mechanically activated BaTiO3 was investigated in this study. Phonon behavior and crystal structure stability of the obtained nanocrystalline BaTiO3 were discussed from the view point of crystallite size effects and microstrains induced by mechanical activation. A systematic study of Raman responses indicates that mechanical activation has a distinct influence on BaTiO3 lattice spectra affecting the intensity, width, and position of Raman modes. The measured Raman spectra were deconvoluted and phonon parameters were estimated. It has been established that applied mechanical activation leads to a significant decrease in the mean crystallites size, but nevertheless enables formation of tetragonal nanocrystalline BaTiO3.
Keywords:
BaTiO3 / Raman spectroscopy / mechanical activation
Source:
Journal of the American Ceramic Society, 2014, 97, 2, 601-608
Publisher:
  • Wiley, Hoboken
Funding / projects:
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)
  • NSF CRESTNational Science Foundation (NSF)NSF- Directorate for Education & Human Resources (EHR) [HRD0833184]
  • NASANational Aeronautics & Space Administration (NASA) [NNX09AVO7A]

DOI: 10.1111/jace.12423

ISSN: 0002-7820

WoS: 000330684200040

Scopus: 2-s2.0-84893961044
[ Google Scholar ]
18
15
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/761
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Nikolić, Maria Vesna
AU  - Pavlović, Vladimir B
AU  - Blanusa, Jovan L
AU  - Stevanović, Suzana
AU  - Mitic, Vojislav V
AU  - Šćepanović, Maja
AU  - Vlahović, Branislav
PY  - 2014
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/761
AB  - The structure and lattice dynamics of mechanically activated BaTiO3 was investigated in this study. Phonon behavior and crystal structure stability of the obtained nanocrystalline BaTiO3 were discussed from the view point of crystallite size effects and microstrains induced by mechanical activation. A systematic study of Raman responses indicates that mechanical activation has a distinct influence on BaTiO3 lattice spectra affecting the intensity, width, and position of Raman modes. The measured Raman spectra were deconvoluted and phonon parameters were estimated. It has been established that applied mechanical activation leads to a significant decrease in the mean crystallites size, but nevertheless enables formation of tetragonal nanocrystalline BaTiO3.
PB  - Wiley, Hoboken
T2  - Journal of the American Ceramic Society
T1  - Raman Responses in Mechanically Activated BaTiO3
EP  - 608
IS  - 2
SP  - 601
VL  - 97
DO  - 10.1111/jace.12423
ER  - 
@article{
author = "Pavlović, Vera P. and Nikolić, Maria Vesna and Pavlović, Vladimir B and Blanusa, Jovan L and Stevanović, Suzana and Mitic, Vojislav V and Šćepanović, Maja and Vlahović, Branislav",
year = "2014",
abstract = "The structure and lattice dynamics of mechanically activated BaTiO3 was investigated in this study. Phonon behavior and crystal structure stability of the obtained nanocrystalline BaTiO3 were discussed from the view point of crystallite size effects and microstrains induced by mechanical activation. A systematic study of Raman responses indicates that mechanical activation has a distinct influence on BaTiO3 lattice spectra affecting the intensity, width, and position of Raman modes. The measured Raman spectra were deconvoluted and phonon parameters were estimated. It has been established that applied mechanical activation leads to a significant decrease in the mean crystallites size, but nevertheless enables formation of tetragonal nanocrystalline BaTiO3.",
publisher = "Wiley, Hoboken",
journal = "Journal of the American Ceramic Society",
title = "Raman Responses in Mechanically Activated BaTiO3",
pages = "608-601",
number = "2",
volume = "97",
doi = "10.1111/jace.12423"
}
Pavlović, V. P., Nikolić, M. V., Pavlović, V. B., Blanusa, J. L., Stevanović, S., Mitic, V. V., Šćepanović, M.,& Vlahović, B.. (2014). Raman Responses in Mechanically Activated BaTiO3. in Journal of the American Ceramic Society
Wiley, Hoboken., 97(2), 601-608.
https://doi.org/10.1111/jace.12423
Pavlović VP, Nikolić MV, Pavlović VB, Blanusa JL, Stevanović S, Mitic VV, Šćepanović M, Vlahović B. Raman Responses in Mechanically Activated BaTiO3. in Journal of the American Ceramic Society. 2014;97(2):601-608.
doi:10.1111/jace.12423 .
Pavlović, Vera P., Nikolić, Maria Vesna, Pavlović, Vladimir B, Blanusa, Jovan L, Stevanović, Suzana, Mitic, Vojislav V, Šćepanović, Maja, Vlahović, Branislav, "Raman Responses in Mechanically Activated BaTiO3" in Journal of the American Ceramic Society, 97, no. 2 (2014):601-608,
https://doi.org/10.1111/jace.12423 . .

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