Antimony doped barium titanate powders were synthesized by polymeric precursors method based on modified Pechini process. Obtained powders were pressed and sintered at 1300 degrees C for 8 h. XRD analysis showed the formation of tetragonal crystal structure in barium titanate ceramics. The decrease of tetragonality was noticed with antimony concentration increase. The influence of antimony concentration on structure change, grain size reduction and microstructure development was analyzed. Dielectric behavior of pure and antimony doped ceramics showed the change from classical to diffuse ferroelectric material. A modified Curie-Weiss law was used to explore the connection between doping level and the degree of diffuseness of phase transition. The analysis of impedance at higher temperatures showed the presence of both grain interior and grain boundary effects. Modest PTCR jump was observed in the doped barium titanate ceramics.
TY - JOUR
AU - Vijatović-Petrović, Mirjana
AU - Bobić, Jelena
AU - Banys, J
AU - Stojanović, Biljana D
PY - 2013
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/728
AB - Antimony doped barium titanate powders were synthesized by polymeric precursors method based on modified Pechini process. Obtained powders were pressed and sintered at 1300 degrees C for 8 h. XRD analysis showed the formation of tetragonal crystal structure in barium titanate ceramics. The decrease of tetragonality was noticed with antimony concentration increase. The influence of antimony concentration on structure change, grain size reduction and microstructure development was analyzed. Dielectric behavior of pure and antimony doped ceramics showed the change from classical to diffuse ferroelectric material. A modified Curie-Weiss law was used to explore the connection between doping level and the degree of diffuseness of phase transition. The analysis of impedance at higher temperatures showed the presence of both grain interior and grain boundary effects. Modest PTCR jump was observed in the doped barium titanate ceramics.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Materials Research Bulletin
T1 - Electrical properties of antimony doped barium titanate ceramics
EP - 3772
IS - 10
SP - 3766
VL - 48
DO - 10.1016/j.materresbull.2013.05.103
ER -
@article{
author = "Vijatović-Petrović, Mirjana and Bobić, Jelena and Banys, J and Stojanović, Biljana D",
year = "2013",
abstract = "Antimony doped barium titanate powders were synthesized by polymeric precursors method based on modified Pechini process. Obtained powders were pressed and sintered at 1300 degrees C for 8 h. XRD analysis showed the formation of tetragonal crystal structure in barium titanate ceramics. The decrease of tetragonality was noticed with antimony concentration increase. The influence of antimony concentration on structure change, grain size reduction and microstructure development was analyzed. Dielectric behavior of pure and antimony doped ceramics showed the change from classical to diffuse ferroelectric material. A modified Curie-Weiss law was used to explore the connection between doping level and the degree of diffuseness of phase transition. The analysis of impedance at higher temperatures showed the presence of both grain interior and grain boundary effects. Modest PTCR jump was observed in the doped barium titanate ceramics.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Materials Research Bulletin",
title = "Electrical properties of antimony doped barium titanate ceramics",
pages = "3772-3766",
number = "10",
volume = "48",
doi = "10.1016/j.materresbull.2013.05.103"
}
Vijatović-Petrović, M., Bobić, J., Banys, J.,& Stojanović, B. D.. (2013). Electrical properties of antimony doped barium titanate ceramics. in Materials Research Bulletin
Pergamon-Elsevier Science Ltd, Oxford., 48(10), 3766-3772.
https://doi.org/10.1016/j.materresbull.2013.05.103
Vijatović-Petrović M, Bobić J, Banys J, Stojanović BD. Electrical properties of antimony doped barium titanate ceramics. in Materials Research Bulletin. 2013;48(10):3766-3772.
doi:10.1016/j.materresbull.2013.05.103 .
Vijatović-Petrović, Mirjana, Bobić, Jelena, Banys, J, Stojanović, Biljana D, "Electrical properties of antimony doped barium titanate ceramics" in Materials Research Bulletin, 48, no. 10 (2013):3766-3772,
https://doi.org/10.1016/j.materresbull.2013.05.103 . .
