Additives are necessary in the electrodeposition of Zn-Mn alloys at high current densities, in order to reduce the hydrogen evolution reaction and prevent dendrite formation. The influences of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as additives in the Zn-Mn plating electrolyte, were examined in this study. The characterization of the coatings by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as an examination of the effect of the additives by electrochemical methods, indicated a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, a levelling action could be achieved and the chemical composition of the Zn-Mn alloy tailored by the addition of the proper type and concentration of additive in the plating electrolyte.
TY - JOUR
AU - Bucko, Mihael M
AU - Lačnjevac, Uroš
AU - Bajat, Jelena B.
PY - 2013
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/643
AB - Additives are necessary in the electrodeposition of Zn-Mn alloys at high current densities, in order to reduce the hydrogen evolution reaction and prevent dendrite formation. The influences of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as additives in the Zn-Mn plating electrolyte, were examined in this study. The characterization of the coatings by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as an examination of the effect of the additives by electrochemical methods, indicated a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, a levelling action could be achieved and the chemical composition of the Zn-Mn alloy tailored by the addition of the proper type and concentration of additive in the plating electrolyte.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy
EP - 1581
IS - 10
SP - 1569
VL - 78
DO - 10.2298/JSC130118025B
ER -
@article{
author = "Bucko, Mihael M and Lačnjevac, Uroš and Bajat, Jelena B.",
year = "2013",
abstract = "Additives are necessary in the electrodeposition of Zn-Mn alloys at high current densities, in order to reduce the hydrogen evolution reaction and prevent dendrite formation. The influences of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as additives in the Zn-Mn plating electrolyte, were examined in this study. The characterization of the coatings by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as an examination of the effect of the additives by electrochemical methods, indicated a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, a levelling action could be achieved and the chemical composition of the Zn-Mn alloy tailored by the addition of the proper type and concentration of additive in the plating electrolyte.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy",
pages = "1581-1569",
number = "10",
volume = "78",
doi = "10.2298/JSC130118025B"
}
Bucko, M. M., Lačnjevac, U.,& Bajat, J. B.. (2013). The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 78(10), 1569-1581.
https://doi.org/10.2298/JSC130118025B
Bucko MM, Lačnjevac U, Bajat JB. The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy. in Journal of the Serbian Chemical Society. 2013;78(10):1569-1581.
doi:10.2298/JSC130118025B .
Bucko, Mihael M, Lačnjevac, Uroš, Bajat, Jelena B., "The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy" in Journal of the Serbian Chemical Society, 78, no. 10 (2013):1569-1581,
https://doi.org/10.2298/JSC130118025B . .
