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The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy

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2013
640.pdf (495.6Kb)
Authors
Bucko, Mihael M
Lačnjevac, Uroš
Bajat, Jelena B.
Article (Published version)
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Abstract
Additives are necessary in the electrodeposition of Zn-Mn alloys at high current densities, in order to reduce the hydrogen evolution reaction and prevent dendrite formation. The influences of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as additives in the Zn-Mn plating electrolyte, were examined in this study. The characterization of the coatings by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as an examination of the effect of the additives by electrochemical methods, indicated a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, a levelling action could be achieved and the chemical composition of the Zn-Mn alloy tailored by the addition of the proper type and concentration of additive in the plating electrolyte.
Keywords:
Zn-Mn alloy / surface morphology / plating additive / leveller / hydrogen inhibitor
Source:
Journal of the Serbian Chemical Society, 2013, 78, 10, 1569-1581
Publisher:
  • Srpsko hemijsko društvo, Beograd
Funding / projects:
  • Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)

DOI: 10.2298/JSC130118025B

ISSN: 0352-5139

WoS: 000326992100010

Scopus: 2-s2.0-84887595668
[ Google Scholar ]
13
9
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/643
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Bucko, Mihael M
AU  - Lačnjevac, Uroš
AU  - Bajat, Jelena B.
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/643
AB  - Additives are necessary in the electrodeposition of Zn-Mn alloys at high current densities, in order to reduce the hydrogen evolution reaction and prevent dendrite formation. The influences of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as additives in the Zn-Mn plating electrolyte, were examined in this study. The characterization of the coatings by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as an examination of the effect of the additives by electrochemical methods, indicated a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, a levelling action could be achieved and the chemical composition of the Zn-Mn alloy tailored by the addition of the proper type and concentration of additive in the plating electrolyte.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy
EP  - 1581
IS  - 10
SP  - 1569
VL  - 78
DO  - 10.2298/JSC130118025B
ER  - 
@article{
author = "Bucko, Mihael M and Lačnjevac, Uroš and Bajat, Jelena B.",
year = "2013",
abstract = "Additives are necessary in the electrodeposition of Zn-Mn alloys at high current densities, in order to reduce the hydrogen evolution reaction and prevent dendrite formation. The influences of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as additives in the Zn-Mn plating electrolyte, were examined in this study. The characterization of the coatings by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as an examination of the effect of the additives by electrochemical methods, indicated a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, a levelling action could be achieved and the chemical composition of the Zn-Mn alloy tailored by the addition of the proper type and concentration of additive in the plating electrolyte.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy",
pages = "1581-1569",
number = "10",
volume = "78",
doi = "10.2298/JSC130118025B"
}
Bucko, M. M., Lačnjevac, U.,& Bajat, J. B.. (2013). The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 78(10), 1569-1581.
https://doi.org/10.2298/JSC130118025B
Bucko MM, Lačnjevac U, Bajat JB. The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy. in Journal of the Serbian Chemical Society. 2013;78(10):1569-1581.
doi:10.2298/JSC130118025B .
Bucko, Mihael M, Lačnjevac, Uroš, Bajat, Jelena B., "The influence of substituted aromatic aldehydes on the electrodeposition of Zn-Mn alloy" in Journal of the Serbian Chemical Society, 78, no. 10 (2013):1569-1581,
https://doi.org/10.2298/JSC130118025B . .

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