Effect of Binder Molecular Weight on Morphology of TiO2 Films Prepared by Tape Casting and Their Photovoltaic Performance
Abstract
Titanium(IV) oxide in the form of anatase has proven to be the best choice for photoanodic material in dye-sensitized solar cells (DSCs). The aim of the work was to study the influence of binder molecular weight on the morphology of deposited films, and consequently, DSC parameters. For this study, five different TiO2 tape casting slips were prepared from commercially available nanoanatase powder and polyethylene glycol (PEG) as a binder. The process of drying and sintering was carefully designed, so that the organic template was slowly decomposed, leaving favorable crack-free, porous structure. It was found that there is an optimal region of binder molecular weight for obtaining homogeneous, non-agglomerated and porous microstructure which is a necessary condition for application of TiO2 films in DSCs.
Keywords:
TiO2 / Tape casting / PEG / Dye-sensitized solar cellSource:
Science of Sintering, 2012, 44, 3, 365-372Publisher:
- Međunarodni Institut za nauku o sinterovanju, Beograd
Funding / projects:
DOI: 10.2298/SOS1203365T
ISSN: 0350-820X
WoS: 000318149200012
Scopus: 2-s2.0-84871209669
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Institution/Community
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Tasić, Nikola AU - Branković, Zorica AU - Marinković-Stanojević, Zorica AU - Branković, Goran PY - 2012 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/567 AB - Titanium(IV) oxide in the form of anatase has proven to be the best choice for photoanodic material in dye-sensitized solar cells (DSCs). The aim of the work was to study the influence of binder molecular weight on the morphology of deposited films, and consequently, DSC parameters. For this study, five different TiO2 tape casting slips were prepared from commercially available nanoanatase powder and polyethylene glycol (PEG) as a binder. The process of drying and sintering was carefully designed, so that the organic template was slowly decomposed, leaving favorable crack-free, porous structure. It was found that there is an optimal region of binder molecular weight for obtaining homogeneous, non-agglomerated and porous microstructure which is a necessary condition for application of TiO2 films in DSCs. PB - Međunarodni Institut za nauku o sinterovanju, Beograd T2 - Science of Sintering T1 - Effect of Binder Molecular Weight on Morphology of TiO2 Films Prepared by Tape Casting and Their Photovoltaic Performance EP - 372 IS - 3 SP - 365 VL - 44 DO - 10.2298/SOS1203365T ER -
@article{ author = "Tasić, Nikola and Branković, Zorica and Marinković-Stanojević, Zorica and Branković, Goran", year = "2012", abstract = "Titanium(IV) oxide in the form of anatase has proven to be the best choice for photoanodic material in dye-sensitized solar cells (DSCs). The aim of the work was to study the influence of binder molecular weight on the morphology of deposited films, and consequently, DSC parameters. For this study, five different TiO2 tape casting slips were prepared from commercially available nanoanatase powder and polyethylene glycol (PEG) as a binder. The process of drying and sintering was carefully designed, so that the organic template was slowly decomposed, leaving favorable crack-free, porous structure. It was found that there is an optimal region of binder molecular weight for obtaining homogeneous, non-agglomerated and porous microstructure which is a necessary condition for application of TiO2 films in DSCs.", publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd", journal = "Science of Sintering", title = "Effect of Binder Molecular Weight on Morphology of TiO2 Films Prepared by Tape Casting and Their Photovoltaic Performance", pages = "372-365", number = "3", volume = "44", doi = "10.2298/SOS1203365T" }
Tasić, N., Branković, Z., Marinković-Stanojević, Z.,& Branković, G.. (2012). Effect of Binder Molecular Weight on Morphology of TiO2 Films Prepared by Tape Casting and Their Photovoltaic Performance. in Science of Sintering Međunarodni Institut za nauku o sinterovanju, Beograd., 44(3), 365-372. https://doi.org/10.2298/SOS1203365T
Tasić N, Branković Z, Marinković-Stanojević Z, Branković G. Effect of Binder Molecular Weight on Morphology of TiO2 Films Prepared by Tape Casting and Their Photovoltaic Performance. in Science of Sintering. 2012;44(3):365-372. doi:10.2298/SOS1203365T .
Tasić, Nikola, Branković, Zorica, Marinković-Stanojević, Zorica, Branković, Goran, "Effect of Binder Molecular Weight on Morphology of TiO2 Films Prepared by Tape Casting and Their Photovoltaic Performance" in Science of Sintering, 44, no. 3 (2012):365-372, https://doi.org/10.2298/SOS1203365T . .