The mechanisms of reaction of methionine with hydroxyl radical are not fully understood. Here, we unequivocally show using electron paramagnetic resonance spin-trapping spectroscopy and GC-FID and GC-MS, the presence of specific carbon-, nitrogen- and sulfur-centered radicals as intermediates of this reaction, as well as the liberation of methanethiol as a gaseous end product. Taking into account the many roles that methionine has in eco- and biosystems, our results may elucidate redox chemistry of this amino acid and processes that methionine is involved in.
TY - JOUR
AU - Spasojević, Ivan
AU - Bogdanović Pristov, Jelena
AU - Vujisic, Ljubodrag V
AU - Spasić, Mihajlo
PY - 2012
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/545
AB - The mechanisms of reaction of methionine with hydroxyl radical are not fully understood. Here, we unequivocally show using electron paramagnetic resonance spin-trapping spectroscopy and GC-FID and GC-MS, the presence of specific carbon-, nitrogen- and sulfur-centered radicals as intermediates of this reaction, as well as the liberation of methanethiol as a gaseous end product. Taking into account the many roles that methionine has in eco- and biosystems, our results may elucidate redox chemistry of this amino acid and processes that methionine is involved in.
PB - Springer Wien, Wien
T2 - Amino Acids
T1 - The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production
EP - 2445
IS - 6
SP - 2439
VL - 42
DO - 10.1007/s00726-011-1049-1
ER -
@article{
author = "Spasojević, Ivan and Bogdanović Pristov, Jelena and Vujisic, Ljubodrag V and Spasić, Mihajlo",
year = "2012",
abstract = "The mechanisms of reaction of methionine with hydroxyl radical are not fully understood. Here, we unequivocally show using electron paramagnetic resonance spin-trapping spectroscopy and GC-FID and GC-MS, the presence of specific carbon-, nitrogen- and sulfur-centered radicals as intermediates of this reaction, as well as the liberation of methanethiol as a gaseous end product. Taking into account the many roles that methionine has in eco- and biosystems, our results may elucidate redox chemistry of this amino acid and processes that methionine is involved in.",
publisher = "Springer Wien, Wien",
journal = "Amino Acids",
title = "The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production",
pages = "2445-2439",
number = "6",
volume = "42",
doi = "10.1007/s00726-011-1049-1"
}
Spasojević, I., Bogdanović Pristov, J., Vujisic, L. V.,& Spasić, M.. (2012). The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production. in Amino Acids
Springer Wien, Wien., 42(6), 2439-2445.
https://doi.org/10.1007/s00726-011-1049-1
Spasojević I, Bogdanović Pristov J, Vujisic LV, Spasić M. The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production. in Amino Acids. 2012;42(6):2439-2445.
doi:10.1007/s00726-011-1049-1 .
Spasojević, Ivan, Bogdanović Pristov, Jelena, Vujisic, Ljubodrag V, Spasić, Mihajlo, "The reaction of methionine with hydroxyl radical: reactive intermediates and methanethiol production" in Amino Acids, 42, no. 6 (2012):2439-2445,
https://doi.org/10.1007/s00726-011-1049-1 . .
