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Evaluation of the composition and morphology of a WTi/Si system processed by a picosecond laser

Authorized Users Only
2012
Authors
Petrović, Suzana M
Perusko, Davor B
Radovic-Bogdanović, I
Branković, Goran
Cekada, M
Gaković, Biljana M
Jaksic, M
Trtica, Milan S
Milosavljević, Momir S
Article (Published version)
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Abstract
In this work we studied the influence of laser radiation on the composition, structure and morphology of WTi thin films deposited on n-type (100) silicon wafers. The films were deposited by d.c. sputtering from a 70:30 at% W-Ti target, using Ar ions, to a thickness of similar to 190 nm. Irradiation was performed with a pulsed Nd:YAG laser operating at 1064 nm, whereas the pulse duration was 150 ps. Laser fluences of 3.2 and 5.9 J/cm(2) were found to be sufficient for modification of the WTi/silicon target system. The results show: (i) ablation of WTi thin film and a Si substrate in the central zone of spots, (ii) appearance of hydrodynamic features like resolidified material, (iii) partial ablation of the WTi thin film at the periphery and (iv) appearance of thin film cracks at the far periphery. On the non-ablated areas, the laser modification induced changes in composition, such as inter-mixing of components at the WTi/Si interface with formation of silicides in both metals. Surface ...oxidation was the dominant process in the ablated areas, which is demonstrated by the presence of a SiO2 phase.

Keywords:
WTi coating / surface modification / oxidation / microstructure / interface
Source:
Metals and Materials International, 2012, 18, 3, 457-463
Publisher:
  • Korean Inst Metals Materials, Seoul
Funding / projects:
  • Slovenian Research AgencySlovenian Research Agency - Slovenia
  • Ministry of Science, Education and Sports of the Republic of CroatiaMinistry of Science, Education and Sports, Republic of Croatia
  • Effects of laser radiation and plasma on novel materials in their synthesis, modification, and analysis (RS-172019)
  • Fabrication and characterization of nano-photonic functional structrues in biomedicine and informatics (RS-45016)

DOI: 10.1007/s12540-012-3012-4

ISSN: 1598-9623

WoS: 000305689900012

Scopus: 2-s2.0-84863816228
[ Google Scholar ]
1
1
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/532
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Petrović, Suzana M
AU  - Perusko, Davor B
AU  - Radovic-Bogdanović, I
AU  - Branković, Goran
AU  - Cekada, M
AU  - Gaković, Biljana M
AU  - Jaksic, M
AU  - Trtica, Milan S
AU  - Milosavljević, Momir S
PY  - 2012
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/532
AB  - In this work we studied the influence of laser radiation on the composition, structure and morphology of WTi thin films deposited on n-type (100) silicon wafers. The films were deposited by d.c. sputtering from a 70:30 at% W-Ti target, using Ar ions, to a thickness of similar to 190 nm. Irradiation was performed with a pulsed Nd:YAG laser operating at 1064 nm, whereas the pulse duration was 150 ps. Laser fluences of 3.2 and 5.9 J/cm(2) were found to be sufficient for modification of the WTi/silicon target system. The results show: (i) ablation of WTi thin film and a Si substrate in the central zone of spots, (ii) appearance of hydrodynamic features like resolidified material, (iii) partial ablation of the WTi thin film at the periphery and (iv) appearance of thin film cracks at the far periphery. On the non-ablated areas, the laser modification induced changes in composition, such as inter-mixing of components at the WTi/Si interface with formation of silicides in both metals. Surface oxidation was the dominant process in the ablated areas, which is demonstrated by the presence of a SiO2 phase.
PB  - Korean Inst Metals Materials, Seoul
T2  - Metals and Materials International
T1  - Evaluation of the composition and morphology of a WTi/Si system processed by a picosecond laser
EP  - 463
IS  - 3
SP  - 457
VL  - 18
DO  - 10.1007/s12540-012-3012-4
ER  - 
@article{
author = "Petrović, Suzana M and Perusko, Davor B and Radovic-Bogdanović, I and Branković, Goran and Cekada, M and Gaković, Biljana M and Jaksic, M and Trtica, Milan S and Milosavljević, Momir S",
year = "2012",
abstract = "In this work we studied the influence of laser radiation on the composition, structure and morphology of WTi thin films deposited on n-type (100) silicon wafers. The films were deposited by d.c. sputtering from a 70:30 at% W-Ti target, using Ar ions, to a thickness of similar to 190 nm. Irradiation was performed with a pulsed Nd:YAG laser operating at 1064 nm, whereas the pulse duration was 150 ps. Laser fluences of 3.2 and 5.9 J/cm(2) were found to be sufficient for modification of the WTi/silicon target system. The results show: (i) ablation of WTi thin film and a Si substrate in the central zone of spots, (ii) appearance of hydrodynamic features like resolidified material, (iii) partial ablation of the WTi thin film at the periphery and (iv) appearance of thin film cracks at the far periphery. On the non-ablated areas, the laser modification induced changes in composition, such as inter-mixing of components at the WTi/Si interface with formation of silicides in both metals. Surface oxidation was the dominant process in the ablated areas, which is demonstrated by the presence of a SiO2 phase.",
publisher = "Korean Inst Metals Materials, Seoul",
journal = "Metals and Materials International",
title = "Evaluation of the composition and morphology of a WTi/Si system processed by a picosecond laser",
pages = "463-457",
number = "3",
volume = "18",
doi = "10.1007/s12540-012-3012-4"
}
Petrović, S. M., Perusko, D. B., Radovic-Bogdanović, I., Branković, G., Cekada, M., Gaković, B. M., Jaksic, M., Trtica, M. S.,& Milosavljević, M. S.. (2012). Evaluation of the composition and morphology of a WTi/Si system processed by a picosecond laser. in Metals and Materials International
Korean Inst Metals Materials, Seoul., 18(3), 457-463.
https://doi.org/10.1007/s12540-012-3012-4
Petrović SM, Perusko DB, Radovic-Bogdanović I, Branković G, Cekada M, Gaković BM, Jaksic M, Trtica MS, Milosavljević MS. Evaluation of the composition and morphology of a WTi/Si system processed by a picosecond laser. in Metals and Materials International. 2012;18(3):457-463.
doi:10.1007/s12540-012-3012-4 .
Petrović, Suzana M, Perusko, Davor B, Radovic-Bogdanović, I, Branković, Goran, Cekada, M, Gaković, Biljana M, Jaksic, M, Trtica, Milan S, Milosavljević, Momir S, "Evaluation of the composition and morphology of a WTi/Si system processed by a picosecond laser" in Metals and Materials International, 18, no. 3 (2012):457-463,
https://doi.org/10.1007/s12540-012-3012-4 . .

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