The phenomenon of a partial 2H -> 1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and IT allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.
Извор:
Journal of Physical Chemistry C, 2011, 115, 50, 24586-24591
Издавач:
Amer Chemical Soc, Washington
Финансирање / пројекти:
ERCEuropean Research Council (ERC)European Commission [INTIF 226639]
TY - JOUR
AU - Enyashin, Andrey N.
AU - Yadgarov, Lena
AU - Houben, Lothar
AU - Popov, Igor
AU - Weidenbach, Marc
AU - Tenne, Reshef
AU - Bar-Sadan, Maya
AU - Seifert, Gotthard
PY - 2011
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/441
AB - The phenomenon of a partial 2H -> 1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and IT allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.
PB - Amer Chemical Soc, Washington
T2 - Journal of Physical Chemistry C
T1 - New Route for Stabilization of 1T-WS2 and MoS2 Phases
EP - 24591
IS - 50
SP - 24586
VL - 115
DO - 10.1021/jp2076325
ER -
@article{
author = "Enyashin, Andrey N. and Yadgarov, Lena and Houben, Lothar and Popov, Igor and Weidenbach, Marc and Tenne, Reshef and Bar-Sadan, Maya and Seifert, Gotthard",
year = "2011",
abstract = "The phenomenon of a partial 2H -> 1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and IT allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry C",
title = "New Route for Stabilization of 1T-WS2 and MoS2 Phases",
pages = "24591-24586",
number = "50",
volume = "115",
doi = "10.1021/jp2076325"
}
Enyashin, A. N., Yadgarov, L., Houben, L., Popov, I., Weidenbach, M., Tenne, R., Bar-Sadan, M.,& Seifert, G.. (2011). New Route for Stabilization of 1T-WS2 and MoS2 Phases. in Journal of Physical Chemistry C
Amer Chemical Soc, Washington., 115(50), 24586-24591.
https://doi.org/10.1021/jp2076325
Enyashin AN, Yadgarov L, Houben L, Popov I, Weidenbach M, Tenne R, Bar-Sadan M, Seifert G. New Route for Stabilization of 1T-WS2 and MoS2 Phases. in Journal of Physical Chemistry C. 2011;115(50):24586-24591.
doi:10.1021/jp2076325 .
Enyashin, Andrey N., Yadgarov, Lena, Houben, Lothar, Popov, Igor, Weidenbach, Marc, Tenne, Reshef, Bar-Sadan, Maya, Seifert, Gotthard, "New Route for Stabilization of 1T-WS2 and MoS2 Phases" in Journal of Physical Chemistry C, 115, no. 50 (2011):24586-24591,
https://doi.org/10.1021/jp2076325 . .
