The electrodeposited Cd-Co alloys were characterized by the anodic linear sweep voltammetry (ALSV) technique in the solution of 1 M NaCl (pH 2). It is shown that Cd-Co alloys could be deposited with high current efficiency (>90%) from the solution containing 0.2 M boric acid, low concentration of cadmium sulfate (0.01 M and 0.02 M) and high concentration of cobalt sulfate (0.2 M and 0.4 M) under the conditions of convective diffusion (RPM = 1000). The ALSVs were characterized by the presence of three peaks: one corresponding to the dissolution of pure Cd, one corresponding to the dissolution of pure Co and one corresponding to the dissolution of unknown phase formed in the system Cd-Co (since the phase diagram of the Cd-Co, system does not exist in the literature). Depending on the charge and on the alloy composition (amount of Cd and Co) the peak of the unknown phase can either be hardly seen, or can prevail on the ALSV. This phase is formed mainly on the account of Co, but certain li...miting amount of Cd must be deposited for the unknown phase to be formed and seen on the ALSV.
TY - JOUR
AU - Jović, Borka M
AU - Dobrovolska, Ts.
AU - Lačnjevac, Uroš
AU - Krastev, I
AU - Jović, Vladimir D
PY - 2009
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/357
AB - The electrodeposited Cd-Co alloys were characterized by the anodic linear sweep voltammetry (ALSV) technique in the solution of 1 M NaCl (pH 2). It is shown that Cd-Co alloys could be deposited with high current efficiency (>90%) from the solution containing 0.2 M boric acid, low concentration of cadmium sulfate (0.01 M and 0.02 M) and high concentration of cobalt sulfate (0.2 M and 0.4 M) under the conditions of convective diffusion (RPM = 1000). The ALSVs were characterized by the presence of three peaks: one corresponding to the dissolution of pure Cd, one corresponding to the dissolution of pure Co and one corresponding to the dissolution of unknown phase formed in the system Cd-Co (since the phase diagram of the Cd-Co, system does not exist in the literature). Depending on the charge and on the alloy composition (amount of Cd and Co) the peak of the unknown phase can either be hardly seen, or can prevail on the ALSV. This phase is formed mainly on the account of Co, but certain limiting amount of Cd must be deposited for the unknown phase to be formed and seen on the ALSV.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Electrochimica Acta
T1 - Characterization of electrodeposited Cd-Co alloy coatings by anodic linear sweep voltammetry
EP - 7572
IS - 28
SP - 7565
VL - 54
DO - 10.1016/j.electacta.2009.08.025
ER -
@article{
author = "Jović, Borka M and Dobrovolska, Ts. and Lačnjevac, Uroš and Krastev, I and Jović, Vladimir D",
year = "2009",
abstract = "The electrodeposited Cd-Co alloys were characterized by the anodic linear sweep voltammetry (ALSV) technique in the solution of 1 M NaCl (pH 2). It is shown that Cd-Co alloys could be deposited with high current efficiency (>90%) from the solution containing 0.2 M boric acid, low concentration of cadmium sulfate (0.01 M and 0.02 M) and high concentration of cobalt sulfate (0.2 M and 0.4 M) under the conditions of convective diffusion (RPM = 1000). The ALSVs were characterized by the presence of three peaks: one corresponding to the dissolution of pure Cd, one corresponding to the dissolution of pure Co and one corresponding to the dissolution of unknown phase formed in the system Cd-Co (since the phase diagram of the Cd-Co, system does not exist in the literature). Depending on the charge and on the alloy composition (amount of Cd and Co) the peak of the unknown phase can either be hardly seen, or can prevail on the ALSV. This phase is formed mainly on the account of Co, but certain limiting amount of Cd must be deposited for the unknown phase to be formed and seen on the ALSV.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Characterization of electrodeposited Cd-Co alloy coatings by anodic linear sweep voltammetry",
pages = "7572-7565",
number = "28",
volume = "54",
doi = "10.1016/j.electacta.2009.08.025"
}
Jović, B. M., Dobrovolska, Ts., Lačnjevac, U., Krastev, I.,& Jović, V. D.. (2009). Characterization of electrodeposited Cd-Co alloy coatings by anodic linear sweep voltammetry. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 54(28), 7565-7572.
https://doi.org/10.1016/j.electacta.2009.08.025
Jović BM, Dobrovolska T, Lačnjevac U, Krastev I, Jović VD. Characterization of electrodeposited Cd-Co alloy coatings by anodic linear sweep voltammetry. in Electrochimica Acta. 2009;54(28):7565-7572.
doi:10.1016/j.electacta.2009.08.025 .
Jović, Borka M, Dobrovolska, Ts., Lačnjevac, Uroš, Krastev, I, Jović, Vladimir D, "Characterization of electrodeposited Cd-Co alloy coatings by anodic linear sweep voltammetry" in Electrochimica Acta, 54, no. 28 (2009):7565-7572,
https://doi.org/10.1016/j.electacta.2009.08.025 . .
