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Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition

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Authors
di Bartolomeo, Elisabetta
Žunić, Milan
Chevallier, Laure
D'Epifanio, Alessandra
Licoccia, Silvia
Traversa, E.
Article (Published version)
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Abstract
Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.
Keywords:
F / Electrophoretic depositions / Electrolyte films / Electrochemical impedance spectroscopy measurements / Electrical property / Composite cathode / Cathode materials / Anode-supported / Anode substrate
Source:
ECS Transactions, 2009, 25, 2 PART 1, 577-584

DOI: 10.1149/1.3205569

ISSN: 1938-5862

Scopus: 2-s2.0-77649251241
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7
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/317
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - di Bartolomeo, Elisabetta
AU  - Žunić, Milan
AU  - Chevallier, Laure
AU  - D'Epifanio, Alessandra
AU  - Licoccia, Silvia
AU  - Traversa, E.
PY  - 2009
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/317
AB  - Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.
T2  - ECS Transactions
T1  - Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition
EP  - 584
IS  - 2 PART 1
SP  - 577
VL  - 25
DO  - 10.1149/1.3205569
ER  - 
@article{
author = "di Bartolomeo, Elisabetta and Žunić, Milan and Chevallier, Laure and D'Epifanio, Alessandra and Licoccia, Silvia and Traversa, E.",
year = "2009",
abstract = "Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.",
journal = "ECS Transactions",
title = "Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition",
pages = "584-577",
number = "2 PART 1",
volume = "25",
doi = "10.1149/1.3205569"
}
di Bartolomeo, E., Žunić, M., Chevallier, L., D'Epifanio, A., Licoccia, S.,& Traversa, E.. (2009). Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition. in ECS Transactions, 25(2 PART 1), 577-584.
https://doi.org/10.1149/1.3205569
di Bartolomeo E, Žunić M, Chevallier L, D'Epifanio A, Licoccia S, Traversa E. Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition. in ECS Transactions. 2009;25(2 PART 1):577-584.
doi:10.1149/1.3205569 .
di Bartolomeo, Elisabetta, Žunić, Milan, Chevallier, Laure, D'Epifanio, Alessandra, Licoccia, Silvia, Traversa, E., "Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition" in ECS Transactions, 25, no. 2 PART 1 (2009):577-584,
https://doi.org/10.1149/1.3205569 . .

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