Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition
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di Bartolomeo, Elisabetta
Žunić, Milan

Chevallier, Laure
D'Epifanio, Alessandra
Licoccia, Silvia
Traversa, E.
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Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.
Keywords:
F / Electrophoretic depositions / Electrolyte films / Electrochemical impedance spectroscopy measurements / Electrical property / Composite cathode / Cathode materials / Anode-supported / Anode substrateSource:
ECS Transactions, 2009, 25, 2 PART 1, 577-584Collections
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Institut za multidisciplinarna istraživanjaTY - JOUR AU - di Bartolomeo, Elisabetta AU - Žunić, Milan AU - Chevallier, Laure AU - D'Epifanio, Alessandra AU - Licoccia, Silvia AU - Traversa, E. PY - 2009 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/317 AB - Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C. T2 - ECS Transactions T1 - Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition EP - 584 IS - 2 PART 1 SP - 577 VL - 25 DO - 10.1149/1.3205569 ER -
@article{ author = "di Bartolomeo, Elisabetta and Žunić, Milan and Chevallier, Laure and D'Epifanio, Alessandra and Licoccia, Silvia and Traversa, E.", year = "2009", abstract = "Anode-supported proton conducting solid oxide fuel cells (SOFCs) were fabricated by using electrophoretic deposition (EPD) for the electrolyte film deposition. BaCe0.9Y0.1O3-δ (BCY10) thick films were deposited on NiO-BCY10 substrates. The influence of the EPD parameters on the microstructure and electrical properties of BCY10 thick films was investigated. The anode substrates and electrolyte deposits were co-sintered at 1550°C for 2 h to obtain a dense electrolyte thick film, while keeping a suitable porosity in the anode. Innovative composites with La 0.8Sr0.2 Co0.8Fe0.2O3 (LSCF)-BaCe0.9Yb0.1O3-δ (10YbBC) composition were used as cathode materials. Prototype SOFCs were prepared by depositing the composite cathode on the co-sintered half cells. Fuel cell tests and electrochemical impedance spectroscopy (EIS) measurements were performed in the 550-700°C temperature range. The maximum power density of 296 mW cm -2 was achieved at 700°C.", journal = "ECS Transactions", title = "Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition", pages = "584-577", number = "2 PART 1", volume = "25", doi = "10.1149/1.3205569" }
di Bartolomeo, E., Žunić, M., Chevallier, L., D'Epifanio, A., Licoccia, S.,& Traversa, E.. (2009). Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition. in ECS Transactions, 25(2 PART 1), 577-584. https://doi.org/10.1149/1.3205569
di Bartolomeo E, Žunić M, Chevallier L, D'Epifanio A, Licoccia S, Traversa E. Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition. in ECS Transactions. 2009;25(2 PART 1):577-584. doi:10.1149/1.3205569 .
di Bartolomeo, Elisabetta, Žunić, Milan, Chevallier, Laure, D'Epifanio, Alessandra, Licoccia, Silvia, Traversa, E., "Fabrication of proton conducting solid oxide fuel cell by using electrophoretic deposition" in ECS Transactions, 25, no. 2 PART 1 (2009):577-584, https://doi.org/10.1149/1.3205569 . .