Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution
Authors
Bobić, JelenaIlić, Nikola
Kaliyaperumal Veerapandiyan, Vignaswaran
Vijatović Petrović, Mirjana
Džunuzović, Adis
Vukmirovic, Jelena
Deluca, Marco
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The search for multiferroic materials combining electric and magnetic properties in a single phase has attracted
a lot of attention in the perspective of future magnetoelectronic devices. A handful of single phase multiferroics
have been discovered so far, and most of them are not suitable for practical applications at present, either
because the room temperature polarization/magnetization is too small or their mutual coupling is too weak.
One of the most important single-phase multiferroic material with Aurivillius structure is Bi5Ti3FeO15 (BFT)
which generally yields a magnetoelectric coupling above room temperature. The main lack of this material is
high electrical conductivity and hence the lower ferro-electromagnetic properties. Since BFT has the capability
to host ions of different size, multiferroic properties could be improved by using dopants or ionic substitutions
on different A and B-sites of the structure.
To this respect, Co2+ and Y3+ doped BFT were prepared by th...e solid state reaction method according to formulas:
Bi1-xYxTi3FeO15 (x=0.1, 0.2, 0.3) and BiTi3Fe1-yCoyO15(y=0.1, 0.3, 0.5). Slightly improve of ferroelectric properties
was noticed with 0.3 mol% of Co while replacement of Bi3+ with Y3+ causes a reduction in orbital hybridization
between Bi 6sand O 2s/2porbitals leading to a decrease in electric polarization as a vector sum of all dipole
moments. Magnetic measurements confirm the antiferromagnetic nature of pure and Y doped ceramics while
Co-doped samples exhibit a typical ferromagnetic loop reveals the existence of FM interactions in these samples.
The largest Mr value appears in samples doped with 3 mol% of Co (Mr of 0.084 emu/g and Hc of 287 Oe). Raman
spectroscopy confirmed that Y prefer to replace Bi ions in the pseudo-perovkite layers while Co ions enter into
the lattice and occupy the Fe site inside of oxygen octahedral.
Keywords:
Aurivillius structure / Magnetic measurements / Raman spectroscop / multiferroic properties / Bi5Ti3FeO15Source:
Electroceramics XVII, 2020, Darmstadt, 24-28 August 2020, Online Conference, 2020Publisher:
- Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference
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Institut za multidisciplinarna istraživanjaTY - CONF AU - Bobić, Jelena AU - Ilić, Nikola AU - Kaliyaperumal Veerapandiyan, Vignaswaran AU - Vijatović Petrović, Mirjana AU - Džunuzović, Adis AU - Vukmirovic, Jelena AU - Deluca, Marco PY - 2020 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/2513 AB - The search for multiferroic materials combining electric and magnetic properties in a single phase has attracted a lot of attention in the perspective of future magnetoelectronic devices. A handful of single phase multiferroics have been discovered so far, and most of them are not suitable for practical applications at present, either because the room temperature polarization/magnetization is too small or their mutual coupling is too weak. One of the most important single-phase multiferroic material with Aurivillius structure is Bi5Ti3FeO15 (BFT) which generally yields a magnetoelectric coupling above room temperature. The main lack of this material is high electrical conductivity and hence the lower ferro-electromagnetic properties. Since BFT has the capability to host ions of different size, multiferroic properties could be improved by using dopants or ionic substitutions on different A and B-sites of the structure. To this respect, Co2+ and Y3+ doped BFT were prepared by the solid state reaction method according to formulas: Bi1-xYxTi3FeO15 (x=0.1, 0.2, 0.3) and BiTi3Fe1-yCoyO15(y=0.1, 0.3, 0.5). Slightly improve of ferroelectric properties was noticed with 0.3 mol% of Co while replacement of Bi3+ with Y3+ causes a reduction in orbital hybridization between Bi 6sand O 2s/2porbitals leading to a decrease in electric polarization as a vector sum of all dipole moments. Magnetic measurements confirm the antiferromagnetic nature of pure and Y doped ceramics while Co-doped samples exhibit a typical ferromagnetic loop reveals the existence of FM interactions in these samples. The largest Mr value appears in samples doped with 3 mol% of Co (Mr of 0.084 emu/g and Hc of 287 Oe). Raman spectroscopy confirmed that Y prefer to replace Bi ions in the pseudo-perovkite layers while Co ions enter into the lattice and occupy the Fe site inside of oxygen octahedral. PB - Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference C3 - Electroceramics XVII, 2020, Darmstadt, 24-28 August 2020, Online Conference T1 - Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution UR - https://hdl.handle.net/21.15107/rcub_rimsi_2513 ER -
@conference{ author = "Bobić, Jelena and Ilić, Nikola and Kaliyaperumal Veerapandiyan, Vignaswaran and Vijatović Petrović, Mirjana and Džunuzović, Adis and Vukmirovic, Jelena and Deluca, Marco", year = "2020", abstract = "The search for multiferroic materials combining electric and magnetic properties in a single phase has attracted a lot of attention in the perspective of future magnetoelectronic devices. A handful of single phase multiferroics have been discovered so far, and most of them are not suitable for practical applications at present, either because the room temperature polarization/magnetization is too small or their mutual coupling is too weak. One of the most important single-phase multiferroic material with Aurivillius structure is Bi5Ti3FeO15 (BFT) which generally yields a magnetoelectric coupling above room temperature. The main lack of this material is high electrical conductivity and hence the lower ferro-electromagnetic properties. Since BFT has the capability to host ions of different size, multiferroic properties could be improved by using dopants or ionic substitutions on different A and B-sites of the structure. To this respect, Co2+ and Y3+ doped BFT were prepared by the solid state reaction method according to formulas: Bi1-xYxTi3FeO15 (x=0.1, 0.2, 0.3) and BiTi3Fe1-yCoyO15(y=0.1, 0.3, 0.5). Slightly improve of ferroelectric properties was noticed with 0.3 mol% of Co while replacement of Bi3+ with Y3+ causes a reduction in orbital hybridization between Bi 6sand O 2s/2porbitals leading to a decrease in electric polarization as a vector sum of all dipole moments. Magnetic measurements confirm the antiferromagnetic nature of pure and Y doped ceramics while Co-doped samples exhibit a typical ferromagnetic loop reveals the existence of FM interactions in these samples. The largest Mr value appears in samples doped with 3 mol% of Co (Mr of 0.084 emu/g and Hc of 287 Oe). Raman spectroscopy confirmed that Y prefer to replace Bi ions in the pseudo-perovkite layers while Co ions enter into the lattice and occupy the Fe site inside of oxygen octahedral.", publisher = "Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference", journal = "Electroceramics XVII, 2020, Darmstadt, 24-28 August 2020, Online Conference", title = "Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution", url = "https://hdl.handle.net/21.15107/rcub_rimsi_2513" }
Bobić, J., Ilić, N., Kaliyaperumal Veerapandiyan, V., Vijatović Petrović, M., Džunuzović, A., Vukmirovic, J.,& Deluca, M.. (2020). Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution. in Electroceramics XVII, 2020, Darmstadt, 24-28 August 2020, Online Conference Electroceramics XVII 2020, Darmstadt, 24-28 August 2020, Online Conference.. https://hdl.handle.net/21.15107/rcub_rimsi_2513
Bobić J, Ilić N, Kaliyaperumal Veerapandiyan V, Vijatović Petrović M, Džunuzović A, Vukmirovic J, Deluca M. Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution. in Electroceramics XVII, 2020, Darmstadt, 24-28 August 2020, Online Conference. 2020;. https://hdl.handle.net/21.15107/rcub_rimsi_2513 .
Bobić, Jelena, Ilić, Nikola, Kaliyaperumal Veerapandiyan, Vignaswaran, Vijatović Petrović, Mirjana, Džunuzović, Adis, Vukmirovic, Jelena, Deluca, Marco, "Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution" in Electroceramics XVII, 2020, Darmstadt, 24-28 August 2020, Online Conference (2020), https://hdl.handle.net/21.15107/rcub_rimsi_2513 .