Structural, microstructural abd ferroelectric properties of Ti-doped YMnO3 ceramics synthesized by polymerization complex method
Authors
Milošević, OliveraLuković Golić, Danijela
Počuča-Nešić, Milica
Dapčević, Aleksandra
Branković, Goran
Branković, Zorica
Zemljak, Olivera
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Yttrium manganite, YMnO3, is a multiferroic material, which exhibits ferroelectric and antiferromagnetic behavior. These properties make it suitable for various applications. Large microcracking and porosity in YMnO3 ceramics strongly affect the material’s ferroelectric response. In this work, the effect of Ti doping on structure, microstructure and ferroelectric properties of YMnO3 ceramics was investigated. The powders YMn1-xTixO3 (x = 0; 0.10; 0.15; 0.20) were prepared by polymerization complex (PC) method from citrate precursors, and calcined at 900 °C for 4 h. The ceramic samples YMnO3 (YMO) and YMn0.9Ti0.1O3 (YMTO10) were obtained after sintering at 1400 °C, YMn0.85Ti0.15O3 (YMTO15) – at 1450 C and YMn0.8Ti0.2O3 (YMTO20) – at 1470 °C, for 2 h. Structural properties and phase composition of sintered samples were analyzed by X-ray diffraction (XRD) and their microstructure by scanning electron microscopy (SEM). Ferroelectric characterization was carried out by measuring of P(E) hy...steresis loops and leakage current density (jl). XRD patterns of all ceramic samples revealed single-phased hexagonal (P63cm) structure. It was observed that Ti-doped YMnO3 ceramic samples have reduced microcracking, inter- and intragranular porosity. Leakage current densities of the
samples YMTO10 and YMTO20 were lower compared to that of sample YMO. YMTO20 showed higher electrical conductivity, but all samples indicated weak ferroelectric response.
Keywords:
Ti-doped YMnO3 / Ferroelectric properties / Ceramics / Microcracks/microporesSource:
5th Conference of The Serbian Society for Ceramic Materials June 11-13, 2019 Belgrade, Serbia 5CSCS-2019, 2019, 133-Publisher:
- Institut za multicisciplinarna istrživanja, Belgrade, Serbia
Funding / projects:
- Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
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Institut za multidisciplinarna istraživanjaTY - CONF AU - Milošević, Olivera AU - Luković Golić, Danijela AU - Počuča-Nešić, Milica AU - Dapčević, Aleksandra AU - Branković, Goran AU - Branković, Zorica AU - Zemljak, Olivera PY - 2019 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/2360 AB - Yttrium manganite, YMnO3, is a multiferroic material, which exhibits ferroelectric and antiferromagnetic behavior. These properties make it suitable for various applications. Large microcracking and porosity in YMnO3 ceramics strongly affect the material’s ferroelectric response. In this work, the effect of Ti doping on structure, microstructure and ferroelectric properties of YMnO3 ceramics was investigated. The powders YMn1-xTixO3 (x = 0; 0.10; 0.15; 0.20) were prepared by polymerization complex (PC) method from citrate precursors, and calcined at 900 °C for 4 h. The ceramic samples YMnO3 (YMO) and YMn0.9Ti0.1O3 (YMTO10) were obtained after sintering at 1400 °C, YMn0.85Ti0.15O3 (YMTO15) – at 1450 C and YMn0.8Ti0.2O3 (YMTO20) – at 1470 °C, for 2 h. Structural properties and phase composition of sintered samples were analyzed by X-ray diffraction (XRD) and their microstructure by scanning electron microscopy (SEM). Ferroelectric characterization was carried out by measuring of P(E) hysteresis loops and leakage current density (jl). XRD patterns of all ceramic samples revealed single-phased hexagonal (P63cm) structure. It was observed that Ti-doped YMnO3 ceramic samples have reduced microcracking, inter- and intragranular porosity. Leakage current densities of the samples YMTO10 and YMTO20 were lower compared to that of sample YMO. YMTO20 showed higher electrical conductivity, but all samples indicated weak ferroelectric response. PB - Institut za multicisciplinarna istrživanja, Belgrade, Serbia C3 - 5th Conference of The Serbian Society for Ceramic Materials June 11-13, 2019 Belgrade, Serbia 5CSCS-2019 T1 - Structural, microstructural abd ferroelectric properties of Ti-doped YMnO3 ceramics synthesized by polymerization complex method SP - 133 UR - https://hdl.handle.net/21.15107/rcub_rimsi_2360 ER -
@conference{ author = "Milošević, Olivera and Luković Golić, Danijela and Počuča-Nešić, Milica and Dapčević, Aleksandra and Branković, Goran and Branković, Zorica and Zemljak, Olivera", year = "2019", abstract = "Yttrium manganite, YMnO3, is a multiferroic material, which exhibits ferroelectric and antiferromagnetic behavior. These properties make it suitable for various applications. Large microcracking and porosity in YMnO3 ceramics strongly affect the material’s ferroelectric response. In this work, the effect of Ti doping on structure, microstructure and ferroelectric properties of YMnO3 ceramics was investigated. The powders YMn1-xTixO3 (x = 0; 0.10; 0.15; 0.20) were prepared by polymerization complex (PC) method from citrate precursors, and calcined at 900 °C for 4 h. The ceramic samples YMnO3 (YMO) and YMn0.9Ti0.1O3 (YMTO10) were obtained after sintering at 1400 °C, YMn0.85Ti0.15O3 (YMTO15) – at 1450 C and YMn0.8Ti0.2O3 (YMTO20) – at 1470 °C, for 2 h. Structural properties and phase composition of sintered samples were analyzed by X-ray diffraction (XRD) and their microstructure by scanning electron microscopy (SEM). Ferroelectric characterization was carried out by measuring of P(E) hysteresis loops and leakage current density (jl). XRD patterns of all ceramic samples revealed single-phased hexagonal (P63cm) structure. It was observed that Ti-doped YMnO3 ceramic samples have reduced microcracking, inter- and intragranular porosity. Leakage current densities of the samples YMTO10 and YMTO20 were lower compared to that of sample YMO. YMTO20 showed higher electrical conductivity, but all samples indicated weak ferroelectric response.", publisher = "Institut za multicisciplinarna istrživanja, Belgrade, Serbia", journal = "5th Conference of The Serbian Society for Ceramic Materials June 11-13, 2019 Belgrade, Serbia 5CSCS-2019", title = "Structural, microstructural abd ferroelectric properties of Ti-doped YMnO3 ceramics synthesized by polymerization complex method", pages = "133", url = "https://hdl.handle.net/21.15107/rcub_rimsi_2360" }
Milošević, O., Luković Golić, D., Počuča-Nešić, M., Dapčević, A., Branković, G., Branković, Z.,& Zemljak, O.. (2019). Structural, microstructural abd ferroelectric properties of Ti-doped YMnO3 ceramics synthesized by polymerization complex method. in 5th Conference of The Serbian Society for Ceramic Materials June 11-13, 2019 Belgrade, Serbia 5CSCS-2019 Institut za multicisciplinarna istrživanja, Belgrade, Serbia., 133. https://hdl.handle.net/21.15107/rcub_rimsi_2360
Milošević O, Luković Golić D, Počuča-Nešić M, Dapčević A, Branković G, Branković Z, Zemljak O. Structural, microstructural abd ferroelectric properties of Ti-doped YMnO3 ceramics synthesized by polymerization complex method. in 5th Conference of The Serbian Society for Ceramic Materials June 11-13, 2019 Belgrade, Serbia 5CSCS-2019. 2019;:133. https://hdl.handle.net/21.15107/rcub_rimsi_2360 .
Milošević, Olivera, Luković Golić, Danijela, Počuča-Nešić, Milica, Dapčević, Aleksandra, Branković, Goran, Branković, Zorica, Zemljak, Olivera, "Structural, microstructural abd ferroelectric properties of Ti-doped YMnO3 ceramics synthesized by polymerization complex method" in 5th Conference of The Serbian Society for Ceramic Materials June 11-13, 2019 Belgrade, Serbia 5CSCS-2019 (2019):133, https://hdl.handle.net/21.15107/rcub_rimsi_2360 .