KIT-5-Assisted Synthesis of Mesoporous SnO2 for High-Performance Humidity Sensors with a Swift Response/Recovery Speed
Autori
Vojisavljević, KatarinaSavić, Slavica M.
Počuča-Nešić, Milica
Hodžić, Aden
Kriechbaum, Manfred
Ribić, Vesna
Rečnik, Aleksander
Mitrović, Jelena
Branković, Goran
Djokic, Veljko
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Developing highly efficient semiconductor metal oxide (SMOX) sensors capable of accurate and fast responses to environmental humidity is still a challenging task. In addition to a not so pronounced sensitivity to relative humidity change, most of the SMOXs cannot meet the criteria of real-time humidity sensing due to their long response/recovery time. The way to tackle this problem is to control adsorption/desorption processes, i.e., water-vapor molecular dynamics, over the sensor’s active layer through the powder and pore morphology design. With this in mind, a KIT-5-mediated synthesis was used to achieve mesoporous tin (IV) oxide replica (SnO2-R) with controlled pore size and ordering through template inversion and compared with a sol-gel synthesized powder (SnO2-SG). Unlike SnO2-SG, SnO2-R possessed a high specific surface area and quite an open pore structure, similar to the KIT-5, as observed by TEM, BET and SWAXS analyses. According to TEM, SnO2-R consisted of fine-grained globul...ar particles and some percent of exaggerated, grown twinned crystals. The distinctive morphology of the SnO2-R-based sensor, with its specific pore structure and an increased number of oxygen-related defects associated with the powder preparation process and detected at the sensor surface by XPS analysis, contributed to excellent humidity sensing performances at room temperature, comprised of a low hysteresis error (3.7%), sensitivity of 406.8 kΩ/RH% and swift response/recovery speed (4 s/6 s).
Ključne reči:
mesoporous silica template; / transmission electron microscopy; / small- and wide-angle X-ray scattering; / tin-dioxide thick-film humidity sensor; / X-ray photoelectron spectroscopy; / response–recovery behaviorIzvor:
Molecules, 2023, 28, 4, 1754-Izdavač:
- MDPI
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200053 (Univerzitet u Beogradu, Institut za multidisciplinarna istraživanja) (RS-MESTD-inst-2020-200053)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200358 (BioSense institut) (RS-MESTD-inst-2020-200358)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200135 (Univerzitet u Beogradu, Tehnološko-metalurški fakultet) (RS-MESTD-inst-2020-200135)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200287 (Inovacioni centar Tehnološko-metalurškog fakulteta u Beogradu doo) (RS-MESTD-inst-2020-200287)
- Slovenian-Serbian bilateral Project BI-RS/16-17-053
- Slovenian-Serbian bilateral Project BI-RS/18-19-026
- European Union’s Horizon 2020 research and innovation program No. 823717- ESTEEM3
- CERIC ERIC internal research project: Nano Analytics for Pharmaceutics
Institucija/grupa
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Vojisavljević, Katarina AU - Savić, Slavica M. AU - Počuča-Nešić, Milica AU - Hodžić, Aden AU - Kriechbaum, Manfred AU - Ribić, Vesna AU - Rečnik, Aleksander AU - Mitrović, Jelena AU - Branković, Goran AU - Djokic, Veljko PY - 2023 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1860 AB - Developing highly efficient semiconductor metal oxide (SMOX) sensors capable of accurate and fast responses to environmental humidity is still a challenging task. In addition to a not so pronounced sensitivity to relative humidity change, most of the SMOXs cannot meet the criteria of real-time humidity sensing due to their long response/recovery time. The way to tackle this problem is to control adsorption/desorption processes, i.e., water-vapor molecular dynamics, over the sensor’s active layer through the powder and pore morphology design. With this in mind, a KIT-5-mediated synthesis was used to achieve mesoporous tin (IV) oxide replica (SnO2-R) with controlled pore size and ordering through template inversion and compared with a sol-gel synthesized powder (SnO2-SG). Unlike SnO2-SG, SnO2-R possessed a high specific surface area and quite an open pore structure, similar to the KIT-5, as observed by TEM, BET and SWAXS analyses. According to TEM, SnO2-R consisted of fine-grained globular particles and some percent of exaggerated, grown twinned crystals. The distinctive morphology of the SnO2-R-based sensor, with its specific pore structure and an increased number of oxygen-related defects associated with the powder preparation process and detected at the sensor surface by XPS analysis, contributed to excellent humidity sensing performances at room temperature, comprised of a low hysteresis error (3.7%), sensitivity of 406.8 kΩ/RH% and swift response/recovery speed (4 s/6 s). PB - MDPI T2 - Molecules T1 - KIT-5-Assisted Synthesis of Mesoporous SnO2 for High-Performance Humidity Sensors with a Swift Response/Recovery Speed IS - 4 SP - 1754 VL - 28 DO - 10.3390/molecules28041754 ER -
@article{ author = "Vojisavljević, Katarina and Savić, Slavica M. and Počuča-Nešić, Milica and Hodžić, Aden and Kriechbaum, Manfred and Ribić, Vesna and Rečnik, Aleksander and Mitrović, Jelena and Branković, Goran and Djokic, Veljko", year = "2023", abstract = "Developing highly efficient semiconductor metal oxide (SMOX) sensors capable of accurate and fast responses to environmental humidity is still a challenging task. In addition to a not so pronounced sensitivity to relative humidity change, most of the SMOXs cannot meet the criteria of real-time humidity sensing due to their long response/recovery time. The way to tackle this problem is to control adsorption/desorption processes, i.e., water-vapor molecular dynamics, over the sensor’s active layer through the powder and pore morphology design. With this in mind, a KIT-5-mediated synthesis was used to achieve mesoporous tin (IV) oxide replica (SnO2-R) with controlled pore size and ordering through template inversion and compared with a sol-gel synthesized powder (SnO2-SG). Unlike SnO2-SG, SnO2-R possessed a high specific surface area and quite an open pore structure, similar to the KIT-5, as observed by TEM, BET and SWAXS analyses. According to TEM, SnO2-R consisted of fine-grained globular particles and some percent of exaggerated, grown twinned crystals. The distinctive morphology of the SnO2-R-based sensor, with its specific pore structure and an increased number of oxygen-related defects associated with the powder preparation process and detected at the sensor surface by XPS analysis, contributed to excellent humidity sensing performances at room temperature, comprised of a low hysteresis error (3.7%), sensitivity of 406.8 kΩ/RH% and swift response/recovery speed (4 s/6 s).", publisher = "MDPI", journal = "Molecules", title = "KIT-5-Assisted Synthesis of Mesoporous SnO2 for High-Performance Humidity Sensors with a Swift Response/Recovery Speed", number = "4", pages = "1754", volume = "28", doi = "10.3390/molecules28041754" }
Vojisavljević, K., Savić, S. M., Počuča-Nešić, M., Hodžić, A., Kriechbaum, M., Ribić, V., Rečnik, A., Mitrović, J., Branković, G.,& Djokic, V.. (2023). KIT-5-Assisted Synthesis of Mesoporous SnO2 for High-Performance Humidity Sensors with a Swift Response/Recovery Speed. in Molecules MDPI., 28(4), 1754. https://doi.org/10.3390/molecules28041754
Vojisavljević K, Savić SM, Počuča-Nešić M, Hodžić A, Kriechbaum M, Ribić V, Rečnik A, Mitrović J, Branković G, Djokic V. KIT-5-Assisted Synthesis of Mesoporous SnO2 for High-Performance Humidity Sensors with a Swift Response/Recovery Speed. in Molecules. 2023;28(4):1754. doi:10.3390/molecules28041754 .
Vojisavljević, Katarina, Savić, Slavica M., Počuča-Nešić, Milica, Hodžić, Aden, Kriechbaum, Manfred, Ribić, Vesna, Rečnik, Aleksander, Mitrović, Jelena, Branković, Goran, Djokic, Veljko, "KIT-5-Assisted Synthesis of Mesoporous SnO2 for High-Performance Humidity Sensors with a Swift Response/Recovery Speed" in Molecules, 28, no. 4 (2023):1754, https://doi.org/10.3390/molecules28041754 . .