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Structural, optical and photocatalytic properties of BiFeO3 nanoparticles

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2019
5CSCS-2019-95.pdf (956.9Kb)
Authors
Cirkovic, Jovana
Luković Golić, Danijela
Radojkovic, Aleksandar
Dapčević, Aleksandra
Tasic, Nikola
Jovanović, Jelena
Čizmić, Mirta
Brankovic, Goran
Brankovic, Zorica
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Abstract
BiFeO3 (BFO) precursor powder was synthesized by ultrasound asissted sol–gel route at relatively low temperature, starting from Bi-nitrate, Fe-nitrate, and ethylene glycol. Structural, optical, and photocatalytic properties of the obtained powder were investigated. X-ray diffraction analysis confirmed that thermal treatment of precursor powder at 500 °C led to formation of pure phase BiFeO3. BFO is p-type semiconductor where determined band gap was 2.20 eV, indicating its potential application as visible-light-response photocatalyst. Mott-Schottky measurements were performed to determine flat band potential and position of valence and conduction bands. Obtained BFO powder is used for photocatalytic degradation of typical organic azo dye Mordant Blue 9 in concentration of 50 mg/l. Measurements were performed for different times of irradiation and pH of the dye solution. Photodegradation products were analyzied by HPLC technique, and mechanism of photocatalytic degradation of organic dye... was proposed.

Source:
The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia, 2019, 95-
Publisher:
  • Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
Funding / projects:
  • Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-45007)

ISBN: 978-86-80109-22-0

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_rimsi_1775
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/1775
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - CONF
AU  - Cirkovic, Jovana
AU  - Luković Golić, Danijela
AU  - Radojkovic, Aleksandar
AU  - Dapčević, Aleksandra
AU  - Tasic, Nikola
AU  - Jovanović, Jelena
AU  - Čizmić, Mirta
AU  - Brankovic, Goran
AU  - Brankovic, Zorica
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1775
AB  - BiFeO3 (BFO) precursor powder was synthesized by ultrasound asissted sol–gel route at relatively low temperature, starting from Bi-nitrate, Fe-nitrate, and ethylene glycol. Structural, optical, and photocatalytic properties of the obtained powder were investigated. X-ray diffraction analysis confirmed that thermal treatment of precursor powder at 500 °C led to formation of pure phase BiFeO3. BFO is p-type semiconductor where determined band gap was 2.20 eV, indicating its potential application as visible-light-response photocatalyst. Mott-Schottky measurements were performed to determine flat band potential and position of valence and conduction bands. Obtained BFO powder is used for photocatalytic degradation of typical organic azo dye Mordant Blue 9 in concentration of 50 mg/l. Measurements were performed for different times of irradiation and pH of the dye solution. Photodegradation products were analyzied by HPLC technique, and mechanism of photocatalytic degradation of organic dye was proposed.
PB  - Institute for Multidisciplinary Research, University of Belgrade  Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia
T1  - Structural, optical and photocatalytic properties of BiFeO3 nanoparticles
SP  - 95
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1775
ER  - 
@conference{
author = "Cirkovic, Jovana and Luković Golić, Danijela and Radojkovic, Aleksandar and Dapčević, Aleksandra and Tasic, Nikola and Jovanović, Jelena and Čizmić, Mirta and Brankovic, Goran and Brankovic, Zorica",
year = "2019",
abstract = "BiFeO3 (BFO) precursor powder was synthesized by ultrasound asissted sol–gel route at relatively low temperature, starting from Bi-nitrate, Fe-nitrate, and ethylene glycol. Structural, optical, and photocatalytic properties of the obtained powder were investigated. X-ray diffraction analysis confirmed that thermal treatment of precursor powder at 500 °C led to formation of pure phase BiFeO3. BFO is p-type semiconductor where determined band gap was 2.20 eV, indicating its potential application as visible-light-response photocatalyst. Mott-Schottky measurements were performed to determine flat band potential and position of valence and conduction bands. Obtained BFO powder is used for photocatalytic degradation of typical organic azo dye Mordant Blue 9 in concentration of 50 mg/l. Measurements were performed for different times of irradiation and pH of the dye solution. Photodegradation products were analyzied by HPLC technique, and mechanism of photocatalytic degradation of organic dye was proposed.",
publisher = "Institute for Multidisciplinary Research, University of Belgrade  Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia",
title = "Structural, optical and photocatalytic properties of BiFeO3 nanoparticles",
pages = "95",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1775"
}
Cirkovic, J., Luković Golić, D., Radojkovic, A., Dapčević, A., Tasic, N., Jovanović, J., Čizmić, M., Brankovic, G.,& Brankovic, Z.. (2019). Structural, optical and photocatalytic properties of BiFeO3 nanoparticles. in The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia
Institute for Multidisciplinary Research, University of Belgrade  Kneza Višeslava 1, 11000 Belgrade, Serbia., 95.
https://hdl.handle.net/21.15107/rcub_rimsi_1775
Cirkovic J, Luković Golić D, Radojkovic A, Dapčević A, Tasic N, Jovanović J, Čizmić M, Brankovic G, Brankovic Z. Structural, optical and photocatalytic properties of BiFeO3 nanoparticles. in The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia. 2019;:95.
https://hdl.handle.net/21.15107/rcub_rimsi_1775 .
Cirkovic, Jovana, Luković Golić, Danijela, Radojkovic, Aleksandar, Dapčević, Aleksandra, Tasic, Nikola, Jovanović, Jelena, Čizmić, Mirta, Brankovic, Goran, Brankovic, Zorica, "Structural, optical and photocatalytic properties of BiFeO3 nanoparticles" in The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia (2019):95,
https://hdl.handle.net/21.15107/rcub_rimsi_1775 .

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