Structural, optical and photocatalytic properties of BiFeO3 nanoparticles
Authors
Cirkovic, JovanaLuković Golić, Danijela

Radojkovic, Aleksandar
Dapčević, Aleksandra
Tasic, Nikola
Jovanović, Jelena

Čizmić, Mirta
Brankovic, Goran
Brankovic, Zorica
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BiFeO3 (BFO) precursor powder was synthesized by ultrasound asissted sol–gel route at relatively low temperature, starting from Bi-nitrate, Fe-nitrate, and ethylene glycol. Structural, optical, and photocatalytic properties of the obtained powder were investigated. X-ray diffraction analysis confirmed that thermal treatment of precursor powder at 500 °C led to formation of pure phase BiFeO3. BFO is p-type semiconductor where determined band gap was 2.20 eV, indicating its potential application as visible-light-response photocatalyst. Mott-Schottky measurements were performed to determine flat band potential and position of valence and conduction bands. Obtained BFO powder is used for photocatalytic degradation of typical organic azo dye Mordant Blue 9 in concentration of 50 mg/l. Measurements were performed for different times of irradiation and pH of the dye solution. Photodegradation products were analyzied by HPLC technique, and mechanism of photocatalytic degradation of organic dye... was proposed.
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The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia, 2019, 95-Publisher:
- Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia
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Institut za multidisciplinarna istraživanjaTY - CONF AU - Cirkovic, Jovana AU - Luković Golić, Danijela AU - Radojkovic, Aleksandar AU - Dapčević, Aleksandra AU - Tasic, Nikola AU - Jovanović, Jelena AU - Čizmić, Mirta AU - Brankovic, Goran AU - Brankovic, Zorica PY - 2019 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1775 AB - BiFeO3 (BFO) precursor powder was synthesized by ultrasound asissted sol–gel route at relatively low temperature, starting from Bi-nitrate, Fe-nitrate, and ethylene glycol. Structural, optical, and photocatalytic properties of the obtained powder were investigated. X-ray diffraction analysis confirmed that thermal treatment of precursor powder at 500 °C led to formation of pure phase BiFeO3. BFO is p-type semiconductor where determined band gap was 2.20 eV, indicating its potential application as visible-light-response photocatalyst. Mott-Schottky measurements were performed to determine flat band potential and position of valence and conduction bands. Obtained BFO powder is used for photocatalytic degradation of typical organic azo dye Mordant Blue 9 in concentration of 50 mg/l. Measurements were performed for different times of irradiation and pH of the dye solution. Photodegradation products were analyzied by HPLC technique, and mechanism of photocatalytic degradation of organic dye was proposed. PB - Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia C3 - The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia T1 - Structural, optical and photocatalytic properties of BiFeO3 nanoparticles SP - 95 UR - https://hdl.handle.net/21.15107/rcub_rimsi_1775 ER -
@conference{ author = "Cirkovic, Jovana and Luković Golić, Danijela and Radojkovic, Aleksandar and Dapčević, Aleksandra and Tasic, Nikola and Jovanović, Jelena and Čizmić, Mirta and Brankovic, Goran and Brankovic, Zorica", year = "2019", abstract = "BiFeO3 (BFO) precursor powder was synthesized by ultrasound asissted sol–gel route at relatively low temperature, starting from Bi-nitrate, Fe-nitrate, and ethylene glycol. Structural, optical, and photocatalytic properties of the obtained powder were investigated. X-ray diffraction analysis confirmed that thermal treatment of precursor powder at 500 °C led to formation of pure phase BiFeO3. BFO is p-type semiconductor where determined band gap was 2.20 eV, indicating its potential application as visible-light-response photocatalyst. Mott-Schottky measurements were performed to determine flat band potential and position of valence and conduction bands. Obtained BFO powder is used for photocatalytic degradation of typical organic azo dye Mordant Blue 9 in concentration of 50 mg/l. Measurements were performed for different times of irradiation and pH of the dye solution. Photodegradation products were analyzied by HPLC technique, and mechanism of photocatalytic degradation of organic dye was proposed.", publisher = "Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia", journal = "The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia", title = "Structural, optical and photocatalytic properties of BiFeO3 nanoparticles", pages = "95", url = "https://hdl.handle.net/21.15107/rcub_rimsi_1775" }
Cirkovic, J., Luković Golić, D., Radojkovic, A., Dapčević, A., Tasic, N., Jovanović, J., Čizmić, M., Brankovic, G.,& Brankovic, Z.. (2019). Structural, optical and photocatalytic properties of BiFeO3 nanoparticles. in The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia Institute for Multidisciplinary Research, University of Belgrade Kneza Višeslava 1, 11000 Belgrade, Serbia., 95. https://hdl.handle.net/21.15107/rcub_rimsi_1775
Cirkovic J, Luković Golić D, Radojkovic A, Dapčević A, Tasic N, Jovanović J, Čizmić M, Brankovic G, Brankovic Z. Structural, optical and photocatalytic properties of BiFeO3 nanoparticles. in The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia. 2019;:95. https://hdl.handle.net/21.15107/rcub_rimsi_1775 .
Cirkovic, Jovana, Luković Golić, Danijela, Radojkovic, Aleksandar, Dapčević, Aleksandra, Tasic, Nikola, Jovanović, Jelena, Čizmić, Mirta, Brankovic, Goran, Brankovic, Zorica, "Structural, optical and photocatalytic properties of BiFeO3 nanoparticles" in The 5th International Conference of the Serbian Society for Ceramic Materials: 5CSCS-2019, Belgrade, Serbia (2019):95, https://hdl.handle.net/21.15107/rcub_rimsi_1775 .