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The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles

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2019
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Authors
Vasiljević, Zorka Z
Dojčinović, Milena
Vujančević, Jelena
Tadić, Nenad B.
Nikolić, Maria Vesna
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Abstract
In this study, pseudobrookite (Fe2TiO5) nanoparticles were fabricated by a modified sol-gel method using Fe(NO3)39H2O and Ti(OC3H7)4 as starting reagents and ethanol as solvent. Oxalic acid was used as a chelating agent while cetyltrimethyammonium bromide (CTAB) and citric monohydrate were used as surfactants. Structral and morphological characterization using X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis confirmed the formation of pseudobrookite nanoparticles. As synthetized Fe2TiO5 nanoparticles were utilized as photocatalysts for decolorisation of Methylene blue (MB) under visible light irradiation. It was observed that the adsorption of MB onto Fe2TiO5 nanoparticles is strongly dependent on the solution pH. Maximum decolorozation was observed for Fe2TiO5 nanoparticles prepared with CTAB under alcaline conditions (pH=10.5).
Keywords:
pseudobrookite / Fe2TiO5 / nanoparticles / sol-gel / photocatalysis / methylene blue
Source:
Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019, 2019, 130-130
Publisher:
  • Belgrade : Materials Research Society of Serbia
Funding / projects:
  • Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-45007)

ISBN: 978-86-919111-4-0

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_dais_6673
URI
https://dais.sanu.ac.rs/123456789/6673
http://rimsi.imsi.bg.ac.rs/handle/123456789/1619
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Tadić, Nenad B.
AU  - Nikolić, Maria Vesna
PY  - 2019
UR  - https://dais.sanu.ac.rs/123456789/6673
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1619
AB  - In this study, pseudobrookite (Fe2TiO5) nanoparticles were fabricated by a modified sol-gel method using Fe(NO3)39H2O and Ti(OC3H7)4 as starting reagents and ethanol as solvent. Oxalic acid was used as a chelating agent while cetyltrimethyammonium bromide (CTAB) and citric monohydrate were used as surfactants. Structral and morphological characterization using X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis confirmed the formation of pseudobrookite nanoparticles. As synthetized Fe2TiO5 nanoparticles were utilized as photocatalysts for decolorisation of Methylene blue (MB) under visible light irradiation. It was observed that the adsorption of MB onto Fe2TiO5 nanoparticles is strongly dependent on the solution pH. Maximum decolorozation was observed for Fe2TiO5 nanoparticles prepared with CTAB under alcaline conditions (pH=10.5).
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
T1  - The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles
EP  - 130
SP  - 130
UR  - https://hdl.handle.net/21.15107/rcub_dais_6673
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Vujančević, Jelena and Tadić, Nenad B. and Nikolić, Maria Vesna",
year = "2019",
abstract = "In this study, pseudobrookite (Fe2TiO5) nanoparticles were fabricated by a modified sol-gel method using Fe(NO3)39H2O and Ti(OC3H7)4 as starting reagents and ethanol as solvent. Oxalic acid was used as a chelating agent while cetyltrimethyammonium bromide (CTAB) and citric monohydrate were used as surfactants. Structral and morphological characterization using X-Ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) analysis confirmed the formation of pseudobrookite nanoparticles. As synthetized Fe2TiO5 nanoparticles were utilized as photocatalysts for decolorisation of Methylene blue (MB) under visible light irradiation. It was observed that the adsorption of MB onto Fe2TiO5 nanoparticles is strongly dependent on the solution pH. Maximum decolorozation was observed for Fe2TiO5 nanoparticles prepared with CTAB under alcaline conditions (pH=10.5).",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019",
title = "The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles",
pages = "130-130",
url = "https://hdl.handle.net/21.15107/rcub_dais_6673"
}
Vasiljević, Z. Z., Dojčinović, M., Vujančević, J., Tadić, N. B.,& Nikolić, M. V.. (2019). The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019
Belgrade : Materials Research Society of Serbia., 130-130.
https://hdl.handle.net/21.15107/rcub_dais_6673
Vasiljević ZZ, Dojčinović M, Vujančević J, Tadić NB, Nikolić MV. The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles. in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019. 2019;:130-130.
https://hdl.handle.net/21.15107/rcub_dais_6673 .
Vasiljević, Zorka Z, Dojčinović, Milena, Vujančević, Jelena, Tadić, Nenad B., Nikolić, Maria Vesna, "The effect of pH on visible-light photocatalytic properties of pseudobrookite nanoparticles" in Programme and The Book of abstracts / Twenty-first Annual Conference YUCOMAT 2019 & Eleventh World Round Table Conference on Sintering WRTCS 2019, Herceg Novi, Montenegro, September 2-6, 2019 (2019):130-130,
https://hdl.handle.net/21.15107/rcub_dais_6673 .

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