Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries
2021
Authors
Sencanski, JelenaNikolić, Nenad
Nedic, Zoran
Maksimović, Jelena
Blagojević, Stevan
Pagnacco, Maja
Article (Published version)
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Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides an examination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions of lithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR, and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueous solution of LiNO3 are approximately 40 mAh g(-1). Compared to the capacity of similar to 35 mAh g(-1) obtained for commercially used transition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the "green" development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (similar to 73 mA h g(-1)) compared to that of Li-salt, it is unstable and fades during cycling. The possible... explanation of the electrochemical behavior of purpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.
Keywords:
purpurin / organic cathode material / aqueous Li-ion and Na-ion batteriesSource:
Journal of the Electrochemical Society, 2021, 168, 10Publisher:
- Electrochemical Soc Inc, Pennington
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200051 (Institute of General and Physical Chemistry, Belgrade) (RS-200051)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200053 (University of Belgrade, Institute for Multidisciplinary Research) (RS-200053)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-200146)
DOI: 10.1149/1945-7111/ac3043
ISSN: 0013-4651
WoS: 000711650500001
Scopus: 2-s2.0-85118880927
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Institut za multidisciplinarna istraživanjaTY - JOUR AU - Sencanski, Jelena AU - Nikolić, Nenad AU - Nedic, Zoran AU - Maksimović, Jelena AU - Blagojević, Stevan AU - Pagnacco, Maja PY - 2021 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1469 AB - Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides an examination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions of lithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR, and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueous solution of LiNO3 are approximately 40 mAh g(-1). Compared to the capacity of similar to 35 mAh g(-1) obtained for commercially used transition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the "green" development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (similar to 73 mA h g(-1)) compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior of purpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail. PB - Electrochemical Soc Inc, Pennington T2 - Journal of the Electrochemical Society T1 - Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries IS - 10 VL - 168 DO - 10.1149/1945-7111/ac3043 ER -
@article{ author = "Sencanski, Jelena and Nikolić, Nenad and Nedic, Zoran and Maksimović, Jelena and Blagojević, Stevan and Pagnacco, Maja", year = "2021", abstract = "Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides an examination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions of lithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR, and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueous solution of LiNO3 are approximately 40 mAh g(-1). Compared to the capacity of similar to 35 mAh g(-1) obtained for commercially used transition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the "green" development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (similar to 73 mA h g(-1)) compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior of purpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.", publisher = "Electrochemical Soc Inc, Pennington", journal = "Journal of the Electrochemical Society", title = "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries", number = "10", volume = "168", doi = "10.1149/1945-7111/ac3043" }
Sencanski, J., Nikolić, N., Nedic, Z., Maksimović, J., Blagojević, S.,& Pagnacco, M.. (2021). Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of the Electrochemical Society Electrochemical Soc Inc, Pennington., 168(10). https://doi.org/10.1149/1945-7111/ac3043
Sencanski J, Nikolić N, Nedic Z, Maksimović J, Blagojević S, Pagnacco M. Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of the Electrochemical Society. 2021;168(10). doi:10.1149/1945-7111/ac3043 .
Sencanski, Jelena, Nikolić, Nenad, Nedic, Zoran, Maksimović, Jelena, Blagojević, Stevan, Pagnacco, Maja, "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries" in Journal of the Electrochemical Society, 168, no. 10 (2021), https://doi.org/10.1149/1945-7111/ac3043 . .