Surface optical phonon and multi - phonon transitions in YVO4: Eu3+ nanopowders
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2021
Authors
Mitric, J.Paunović, Novica
Mitric, M.
Ćirković, Jovana

Gilic, M.
Romčević, Maja
Romčević, Nebojša
Article (Published version)

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In this paper two methods of preparation of yttrium orthovanadate nanopowders were presented: Solid State Reaction (top - down approach) and Solution Combustion Synthesis (bottom - up approach). For starting structural characterization, X - Ray Powder Diffraction (XPRD) and Field Emission Scanning Electron Microscopy (FESEM) were used. We report the change in reflection spectra in europium doped YVO4 nanopowders with comparison to its bulk analog. In UV-Vis reflection spectra we consider the change in values of band gap in these structures, after resizing it from bulk to nanomaterial. In Far - Infrared (FIR) reflection spectra, we registered the existence of Surface Optical Phonon (SOP) and different multi - phonon processes which alter the reflection spectra of bulk YVO4 . The influence of Eu ions is reflected through multi - phonon processes that occur and are connected with energy transfer from YVO4 lattice to Eu ions. All IR spectra were modeled using classical oscillator model wit...h Drude part added which takes into account the free carrier contribution. Since our samples are distinctively inhomogeneous materials, we use Effective Medium theory in Maxwell Garnett approximation to model its effective dieletric function.
Keywords:
Yttrium orthovanadate / Vis spectroscopy / uv / Surface optical phonon / Phonon / Multi / Infrared spectroscopy / EuropiumSource:
Physica E-Low-Dimensional Systems & Nanostructures, 2021, 134Publisher:
- Elsevier, Amsterdam
Funding / projects:
- Institute of Physics Belgrade
- Ministry of Education, Sci-ence, and Technological Development of the Republic of SerbiaMinistry of Education, Science & Technological Development, Serbia
DOI: 10.1016/j.physe.2021.114923
ISSN: 1386-9477
WoS: 000694713400005
Scopus: 2-s2.0-85112486503
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Institut za multidisciplinarna istraživanjaTY - JOUR AU - Mitric, J. AU - Paunović, Novica AU - Mitric, M. AU - Ćirković, Jovana AU - Gilic, M. AU - Romčević, Maja AU - Romčević, Nebojša PY - 2021 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1467 AB - In this paper two methods of preparation of yttrium orthovanadate nanopowders were presented: Solid State Reaction (top - down approach) and Solution Combustion Synthesis (bottom - up approach). For starting structural characterization, X - Ray Powder Diffraction (XPRD) and Field Emission Scanning Electron Microscopy (FESEM) were used. We report the change in reflection spectra in europium doped YVO4 nanopowders with comparison to its bulk analog. In UV-Vis reflection spectra we consider the change in values of band gap in these structures, after resizing it from bulk to nanomaterial. In Far - Infrared (FIR) reflection spectra, we registered the existence of Surface Optical Phonon (SOP) and different multi - phonon processes which alter the reflection spectra of bulk YVO4 . The influence of Eu ions is reflected through multi - phonon processes that occur and are connected with energy transfer from YVO4 lattice to Eu ions. All IR spectra were modeled using classical oscillator model with Drude part added which takes into account the free carrier contribution. Since our samples are distinctively inhomogeneous materials, we use Effective Medium theory in Maxwell Garnett approximation to model its effective dieletric function. PB - Elsevier, Amsterdam T2 - Physica E-Low-Dimensional Systems & Nanostructures T1 - Surface optical phonon and multi - phonon transitions in YVO4: Eu3+ nanopowders VL - 134 DO - 10.1016/j.physe.2021.114923 ER -
@article{ author = "Mitric, J. and Paunović, Novica and Mitric, M. and Ćirković, Jovana and Gilic, M. and Romčević, Maja and Romčević, Nebojša", year = "2021", abstract = "In this paper two methods of preparation of yttrium orthovanadate nanopowders were presented: Solid State Reaction (top - down approach) and Solution Combustion Synthesis (bottom - up approach). For starting structural characterization, X - Ray Powder Diffraction (XPRD) and Field Emission Scanning Electron Microscopy (FESEM) were used. We report the change in reflection spectra in europium doped YVO4 nanopowders with comparison to its bulk analog. In UV-Vis reflection spectra we consider the change in values of band gap in these structures, after resizing it from bulk to nanomaterial. In Far - Infrared (FIR) reflection spectra, we registered the existence of Surface Optical Phonon (SOP) and different multi - phonon processes which alter the reflection spectra of bulk YVO4 . The influence of Eu ions is reflected through multi - phonon processes that occur and are connected with energy transfer from YVO4 lattice to Eu ions. All IR spectra were modeled using classical oscillator model with Drude part added which takes into account the free carrier contribution. Since our samples are distinctively inhomogeneous materials, we use Effective Medium theory in Maxwell Garnett approximation to model its effective dieletric function.", publisher = "Elsevier, Amsterdam", journal = "Physica E-Low-Dimensional Systems & Nanostructures", title = "Surface optical phonon and multi - phonon transitions in YVO4: Eu3+ nanopowders", volume = "134", doi = "10.1016/j.physe.2021.114923" }
Mitric, J., Paunović, N., Mitric, M., Ćirković, J., Gilic, M., Romčević, M.,& Romčević, N.. (2021). Surface optical phonon and multi - phonon transitions in YVO4: Eu3+ nanopowders. in Physica E-Low-Dimensional Systems & Nanostructures Elsevier, Amsterdam., 134. https://doi.org/10.1016/j.physe.2021.114923
Mitric J, Paunović N, Mitric M, Ćirković J, Gilic M, Romčević M, Romčević N. Surface optical phonon and multi - phonon transitions in YVO4: Eu3+ nanopowders. in Physica E-Low-Dimensional Systems & Nanostructures. 2021;134. doi:10.1016/j.physe.2021.114923 .
Mitric, J., Paunović, Novica, Mitric, M., Ćirković, Jovana, Gilic, M., Romčević, Maja, Romčević, Nebojša, "Surface optical phonon and multi - phonon transitions in YVO4: Eu3+ nanopowders" in Physica E-Low-Dimensional Systems & Nanostructures, 134 (2021), https://doi.org/10.1016/j.physe.2021.114923 . .