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Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNaH(2)PO(4)+(1-y)KH2PO4}(aq) System at T=298.15K

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2019
Authors
Ivanović, Tijana
Popović, Daniela Z.
Miladinović, Jelena
Rard, Joseph A.
Miladinović, Zoran P.
Belosević, Svetlana
Trivunac, Katarina
Article (Published version)
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Abstract
Isopiestic measurements have been made for aqueous mixtures of NaH2PO4 and KH2PO4 at T=(298.15 +/- 0.01) K, at NaH2PO4 ionic strength fractions y=(0, 0.19108, 0.38306, 0.58192, and 1), assuming that both electrolytes dissociate as 1:1 electrolytes, using KCl(aq) as the reference standard solution. Model parameters for an extended form of Pitzer's ion-interaction model and also for the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale were evaluated at T=298.15K for NaH2PO4(aq) using the present isopiestic results (13 values), as were those for KH2PO4(aq) using the present isopiestic results (12 values), together with numerous critically-assessed osmotic coefficients for both electrolytes taken from the published literature. The thermodynamic models for KH2PO4(aq) extend to m=2.187molkg(-1), which is slightly above saturation, while those for NaH2PO4(aq) extend to m=7.5molkg(-1), which is below saturation. The 39 osmotic coefficients for the ternary mixtur...es from the present study along with 42 values from a published study were likewise represented with these models, with both the usual Pitzer mixing terms and also Scatchard's neutral-electrolyte model mixing terms being used for the extended ion-interaction model. Two mixing parameters were needed for each of the models, and all three models gave similar quality representations of the experimental results. Maximum differences in calculated values of mean molality-based activity coefficients for these three models are (+/-)(NaH2PO4)0.0080 and (+/-)(KH2PO4)0.0043. The experimental results were also found to nearly conform to Zdanovskii's rule.

Keywords:
Osmotic coefficients / NaH2PO4 / KH2PO4 / Isopiestic measurements / Aqueous solutions / Activity coefficients
Source:
Journal of Solution Chemistry, 2019, 48, 3, 296-328
Publisher:
  • Springer/Plenum Publishers, New York
Funding / projects:
  • New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems (RS-172063)

DOI: 10.1007/s10953-018-0839-4

ISSN: 0095-9782

WoS: 000462984100003

Scopus: 2-s2.0-85057604777
[ Google Scholar ]
4
3
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/1259
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Ivanović, Tijana
AU  - Popović, Daniela Z.
AU  - Miladinović, Jelena
AU  - Rard, Joseph A.
AU  - Miladinović, Zoran P.
AU  - Belosević, Svetlana
AU  - Trivunac, Katarina
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1259
AB  - Isopiestic measurements have been made for aqueous mixtures of NaH2PO4 and KH2PO4 at T=(298.15 +/- 0.01) K, at NaH2PO4 ionic strength fractions y=(0, 0.19108, 0.38306, 0.58192, and 1), assuming that both electrolytes dissociate as 1:1 electrolytes, using KCl(aq) as the reference standard solution. Model parameters for an extended form of Pitzer's ion-interaction model and also for the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale were evaluated at T=298.15K for NaH2PO4(aq) using the present isopiestic results (13 values), as were those for KH2PO4(aq) using the present isopiestic results (12 values), together with numerous critically-assessed osmotic coefficients for both electrolytes taken from the published literature. The thermodynamic models for KH2PO4(aq) extend to m=2.187molkg(-1), which is slightly above saturation, while those for NaH2PO4(aq) extend to m=7.5molkg(-1), which is below saturation. The 39 osmotic coefficients for the ternary mixtures from the present study along with 42 values from a published study were likewise represented with these models, with both the usual Pitzer mixing terms and also Scatchard's neutral-electrolyte model mixing terms being used for the extended ion-interaction model. Two mixing parameters were needed for each of the models, and all three models gave similar quality representations of the experimental results. Maximum differences in calculated values of mean molality-based activity coefficients for these three models are (+/-)(NaH2PO4)0.0080 and (+/-)(KH2PO4)0.0043. The experimental results were also found to nearly conform to Zdanovskii's rule.
PB  - Springer/Plenum Publishers, New York
T2  - Journal of Solution Chemistry
T1  - Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNaH(2)PO(4)+(1-y)KH2PO4}(aq) System at T=298.15K
EP  - 328
IS  - 3
SP  - 296
VL  - 48
DO  - 10.1007/s10953-018-0839-4
ER  - 
@article{
author = "Ivanović, Tijana and Popović, Daniela Z. and Miladinović, Jelena and Rard, Joseph A. and Miladinović, Zoran P. and Belosević, Svetlana and Trivunac, Katarina",
year = "2019",
abstract = "Isopiestic measurements have been made for aqueous mixtures of NaH2PO4 and KH2PO4 at T=(298.15 +/- 0.01) K, at NaH2PO4 ionic strength fractions y=(0, 0.19108, 0.38306, 0.58192, and 1), assuming that both electrolytes dissociate as 1:1 electrolytes, using KCl(aq) as the reference standard solution. Model parameters for an extended form of Pitzer's ion-interaction model and also for the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale were evaluated at T=298.15K for NaH2PO4(aq) using the present isopiestic results (13 values), as were those for KH2PO4(aq) using the present isopiestic results (12 values), together with numerous critically-assessed osmotic coefficients for both electrolytes taken from the published literature. The thermodynamic models for KH2PO4(aq) extend to m=2.187molkg(-1), which is slightly above saturation, while those for NaH2PO4(aq) extend to m=7.5molkg(-1), which is below saturation. The 39 osmotic coefficients for the ternary mixtures from the present study along with 42 values from a published study were likewise represented with these models, with both the usual Pitzer mixing terms and also Scatchard's neutral-electrolyte model mixing terms being used for the extended ion-interaction model. Two mixing parameters were needed for each of the models, and all three models gave similar quality representations of the experimental results. Maximum differences in calculated values of mean molality-based activity coefficients for these three models are (+/-)(NaH2PO4)0.0080 and (+/-)(KH2PO4)0.0043. The experimental results were also found to nearly conform to Zdanovskii's rule.",
publisher = "Springer/Plenum Publishers, New York",
journal = "Journal of Solution Chemistry",
title = "Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNaH(2)PO(4)+(1-y)KH2PO4}(aq) System at T=298.15K",
pages = "328-296",
number = "3",
volume = "48",
doi = "10.1007/s10953-018-0839-4"
}
Ivanović, T., Popović, D. Z., Miladinović, J., Rard, J. A., Miladinović, Z. P., Belosević, S.,& Trivunac, K.. (2019). Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNaH(2)PO(4)+(1-y)KH2PO4}(aq) System at T=298.15K. in Journal of Solution Chemistry
Springer/Plenum Publishers, New York., 48(3), 296-328.
https://doi.org/10.1007/s10953-018-0839-4
Ivanović T, Popović DZ, Miladinović J, Rard JA, Miladinović ZP, Belosević S, Trivunac K. Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNaH(2)PO(4)+(1-y)KH2PO4}(aq) System at T=298.15K. in Journal of Solution Chemistry. 2019;48(3):296-328.
doi:10.1007/s10953-018-0839-4 .
Ivanović, Tijana, Popović, Daniela Z., Miladinović, Jelena, Rard, Joseph A., Miladinović, Zoran P., Belosević, Svetlana, Trivunac, Katarina, "Isopiestic Determination of the Osmotic and Activity Coefficients of the {yNaH(2)PO(4)+(1-y)KH2PO4}(aq) System at T=298.15K" in Journal of Solution Chemistry, 48, no. 3 (2019):296-328,
https://doi.org/10.1007/s10953-018-0839-4 . .

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