Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution
Само за регистроване кориснике
2005
Чланак у часопису (Објављена верзија)
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Приказ свих података о документуАпстракт
The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. A series of electrode containing 34-59 at.% Mo was prepared. Electrodes displayed porous character, and electrochemical impedance spectroscopy was used to characterized real surface area. It was found that within the whole potential region the mechanism of the HER is a consecutive combination of the Volmer step, followed dominantly by a rate controlling Heyrovsky step, while the contribution of the parallel Tafel step is negligible. The kinetic parameters of the HER were determined. With an increase in the molybdenum content, the electrodes become more active, and an increase in the real surface area is observed. The main factor influencing the electrode activity seems to be the real surface area.
Кључне речи:
mechanism / impedance / hydrogen evolution / Fe-Mo electrodes / alkaline solutionИзвор:
Electrochimica Acta, 2005, 50, 28, 5594-5601Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/j.electacta.2005.03.037
ISSN: 0013-4686
WoS: 000232548300016
Scopus: 2-s2.0-24944467726
Институција/група
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Elezović, Nevenka R. AU - Jović, Vladimir D AU - Krstajić, Nedeljko V PY - 2005 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/120 AB - The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. A series of electrode containing 34-59 at.% Mo was prepared. Electrodes displayed porous character, and electrochemical impedance spectroscopy was used to characterized real surface area. It was found that within the whole potential region the mechanism of the HER is a consecutive combination of the Volmer step, followed dominantly by a rate controlling Heyrovsky step, while the contribution of the parallel Tafel step is negligible. The kinetic parameters of the HER were determined. With an increase in the molybdenum content, the electrodes become more active, and an increase in the real surface area is observed. The main factor influencing the electrode activity seems to be the real surface area. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Electrochimica Acta T1 - Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution EP - 5601 IS - 28 SP - 5594 VL - 50 DO - 10.1016/j.electacta.2005.03.037 ER -
@article{ author = "Elezović, Nevenka R. and Jović, Vladimir D and Krstajić, Nedeljko V", year = "2005", abstract = "The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. A series of electrode containing 34-59 at.% Mo was prepared. Electrodes displayed porous character, and electrochemical impedance spectroscopy was used to characterized real surface area. It was found that within the whole potential region the mechanism of the HER is a consecutive combination of the Volmer step, followed dominantly by a rate controlling Heyrovsky step, while the contribution of the parallel Tafel step is negligible. The kinetic parameters of the HER were determined. With an increase in the molybdenum content, the electrodes become more active, and an increase in the real surface area is observed. The main factor influencing the electrode activity seems to be the real surface area.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Electrochimica Acta", title = "Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution", pages = "5601-5594", number = "28", volume = "50", doi = "10.1016/j.electacta.2005.03.037" }
Elezović, N. R., Jović, V. D.,& Krstajić, N. V.. (2005). Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution. in Electrochimica Acta Pergamon-Elsevier Science Ltd, Oxford., 50(28), 5594-5601. https://doi.org/10.1016/j.electacta.2005.03.037
Elezović NR, Jović VD, Krstajić NV. Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution. in Electrochimica Acta. 2005;50(28):5594-5601. doi:10.1016/j.electacta.2005.03.037 .
Elezović, Nevenka R., Jović, Vladimir D, Krstajić, Nedeljko V, "Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution" in Electrochimica Acta, 50, no. 28 (2005):5594-5601, https://doi.org/10.1016/j.electacta.2005.03.037 . .