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Mesoporous TiO2 spheres as a photoanodic material in dye-sensitized solar cells

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2018
1147.pdf (1.336Mb)
Authors
Tasić, Nikola
Marinković-Stanojević, Zorica
Branković, Zorica
Žunić, Milan
Lačnjevac, Uroš
Gilic, Martina
Novaković, Tatjana
Branković, Goran
Article (Published version)
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Abstract
Mesoporous TiO2 films with spherical architectures and promising performance in dye-sensitized solar cells (DSSCs) were prepared. The morphology of the films was investigated by scanning electron microscopy. Transmission electron microscopy analysis of the spheres disclosed the elongated shape of sub-20nm primary particles, while BET analysis revealed their high surface area of 135 m(2)/g. Anatase presence was observed in the films based on X-ray diffractometry, selected-area electron diffraction analysis and Raman spectroscopy analyses. Increased light scattering of the spheres in visible region was observed by UV-VIS-NIR spectroscopy. Photovoltaic performance of the operating N719-sensitized cells was tested using electrochemical impedance spectroscopy and current density-voltage (J-V) curves under simulated AMI. 5 spectrum. The 0.25 cm(2) cells exhibited photo-to-electric power efficiency of 4.9%, which is among noteworthy values for DSSCs with similar photoanodic structures.
Keywords:
TiO2 / photoanode / mesoporous spheres / dye-sensitized solar cells (DSSCs)
Source:
Processing and Application of Ceramics, 2018, 12, 4, 374-382
Publisher:
  • Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad
Funding / projects:
  • Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-45007)
  • Bilateral Project between the Republic of Serbia and Republic of Slovenia [451-03-3095/2014-09-32]

DOI: 10.2298/PAC1804374T

ISSN: 1820-6131

WoS: 000457267600010

Scopus: 2-s2.0-85062092986
[ Google Scholar ]
4
3
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/1150
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Tasić, Nikola
AU  - Marinković-Stanojević, Zorica
AU  - Branković, Zorica
AU  - Žunić, Milan
AU  - Lačnjevac, Uroš
AU  - Gilic, Martina
AU  - Novaković, Tatjana
AU  - Branković, Goran
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1150
AB  - Mesoporous TiO2 films with spherical architectures and promising performance in dye-sensitized solar cells (DSSCs) were prepared. The morphology of the films was investigated by scanning electron microscopy. Transmission electron microscopy analysis of the spheres disclosed the elongated shape of sub-20nm primary particles, while BET analysis revealed their high surface area of 135 m(2)/g. Anatase presence was observed in the films based on X-ray diffractometry, selected-area electron diffraction analysis and Raman spectroscopy analyses. Increased light scattering of the spheres in visible region was observed by UV-VIS-NIR spectroscopy. Photovoltaic performance of the operating N719-sensitized cells was tested using electrochemical impedance spectroscopy and current density-voltage (J-V) curves under simulated AMI. 5 spectrum. The 0.25 cm(2) cells exhibited photo-to-electric power efficiency of 4.9%, which is among noteworthy values for DSSCs with similar photoanodic structures.
PB  - Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad
T2  - Processing and Application of Ceramics
T1  - Mesoporous TiO2 spheres as a photoanodic material in dye-sensitized solar cells
EP  - 382
IS  - 4
SP  - 374
VL  - 12
DO  - 10.2298/PAC1804374T
ER  - 
@article{
author = "Tasić, Nikola and Marinković-Stanojević, Zorica and Branković, Zorica and Žunić, Milan and Lačnjevac, Uroš and Gilic, Martina and Novaković, Tatjana and Branković, Goran",
year = "2018",
abstract = "Mesoporous TiO2 films with spherical architectures and promising performance in dye-sensitized solar cells (DSSCs) were prepared. The morphology of the films was investigated by scanning electron microscopy. Transmission electron microscopy analysis of the spheres disclosed the elongated shape of sub-20nm primary particles, while BET analysis revealed their high surface area of 135 m(2)/g. Anatase presence was observed in the films based on X-ray diffractometry, selected-area electron diffraction analysis and Raman spectroscopy analyses. Increased light scattering of the spheres in visible region was observed by UV-VIS-NIR spectroscopy. Photovoltaic performance of the operating N719-sensitized cells was tested using electrochemical impedance spectroscopy and current density-voltage (J-V) curves under simulated AMI. 5 spectrum. The 0.25 cm(2) cells exhibited photo-to-electric power efficiency of 4.9%, which is among noteworthy values for DSSCs with similar photoanodic structures.",
publisher = "Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Mesoporous TiO2 spheres as a photoanodic material in dye-sensitized solar cells",
pages = "382-374",
number = "4",
volume = "12",
doi = "10.2298/PAC1804374T"
}
Tasić, N., Marinković-Stanojević, Z., Branković, Z., Žunić, M., Lačnjevac, U., Gilic, M., Novaković, T.,& Branković, G.. (2018). Mesoporous TiO2 spheres as a photoanodic material in dye-sensitized solar cells. in Processing and Application of Ceramics
Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad., 12(4), 374-382.
https://doi.org/10.2298/PAC1804374T
Tasić N, Marinković-Stanojević Z, Branković Z, Žunić M, Lačnjevac U, Gilic M, Novaković T, Branković G. Mesoporous TiO2 spheres as a photoanodic material in dye-sensitized solar cells. in Processing and Application of Ceramics. 2018;12(4):374-382.
doi:10.2298/PAC1804374T .
Tasić, Nikola, Marinković-Stanojević, Zorica, Branković, Zorica, Žunić, Milan, Lačnjevac, Uroš, Gilic, Martina, Novaković, Tatjana, Branković, Goran, "Mesoporous TiO2 spheres as a photoanodic material in dye-sensitized solar cells" in Processing and Application of Ceramics, 12, no. 4 (2018):374-382,
https://doi.org/10.2298/PAC1804374T . .

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