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Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts

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2018
10.1016@j.electacta.2018.02.121.pdf (11.86Mb)
Аутори
Cvetković, Vesna S.
Vukicević, Nataša M.
Nikolic, Nebojša D.
Branković, Goran
Barudzija, Tanja S.
Jovicević, Jovan N.
Чланак у часопису (Рецензирана верзија)
Метаподаци
Приказ свих података о документу
Апстракт
The processes of electrochemical deposition of magnesium oxide/hydroxide on glassy carbon (GC) electrode from magnesium nitrate hexahydrate melt have been investigated. A novel procedure predicting a possibility of direct formation of magnesium oxide during electrodeposition from the nitrate melt used is reported. XRD analysis of the obtained deposits showed the formation of magnesium oxide along with magnesium hydroxide. The electrodeposition of magnesium oxide/hydroxide commences in magnesium underpotential (UPD) and continues through the magnesium overpotential (OPD) region. Network of individual or intertwined very thin needles as well as those grouped in flower-like aggregates or honeycomb-like structures were formed in both magnesium UPD and OPD regions. Formation of the long needles was explained through theories of mechanisms of dendrite formation. Hydrogen evolution commences in the magnesium OPD region and increases with the applied overpotential. Holes observed in the deposi...t originated from the detached hydrogen bubbles. The number, shape and size of the hole strongly depended on both the applied cathodic potential and the hold time of electrodeposition. Magnesium oxides/hydroxides syntheses taking part simultaneously at various applied potentials are a result of reactions between magnesium cations and products of water and nitrate anions reduction processes. Chemical reactions responsible for direct formation of magnesium oxide observed are those of magnesium ions and oxygen ions, formed by nitrate reduction taking part in the close vicinity of the working electrode.

Кључне речи:
Needles / Melt / Magnesium oxide/hydroxide / Honeycomb / Electrodeposition
Извор:
Electrochimica Acta, 2018, 268, 494-502
Издавач:
  • Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
  • Електрохемијска синтеза и карактеризација наноструктурираних функционалних материјала за примену у новим технологијама (RS-172046)
  • Нов приступ дизајнирању материјала за конверзију и складиштење енергије (RS-172060)
Напомена:
  • This is the peered reviev version of the paper: Cvetković, V. S., Vukicević, N. M., Nikolic, N. D., Branković, G., Barudzija, T. S.,& Jovicević, J. N.. (2018). Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts. in Electrochimica Acta Pergamon-Elsevier Science Ltd, Oxford., 268, 494-502. https://doi.org/10.1016/j.electacta.2018.02.121 conv_1310

DOI: 10.1016/j.electacta.2018.02.121

ISSN: 0013-4686

WoS: 000427657600054

Scopus: 2-s2.0-85042638607
[ Google Scholar ]
26
16
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/1146
Колекције
  • Radovi istraživača / Researchers’ publications
Институција/група
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Vukicević, Nataša M.
AU  - Nikolic, Nebojša D.
AU  - Branković, Goran
AU  - Barudzija, Tanja S.
AU  - Jovicević, Jovan N.
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1146
AB  - The processes of electrochemical deposition of magnesium oxide/hydroxide on glassy carbon (GC) electrode from magnesium nitrate hexahydrate melt have been investigated. A novel procedure predicting a possibility of direct formation of magnesium oxide during electrodeposition from the nitrate melt used is reported. XRD analysis of the obtained deposits showed the formation of magnesium oxide along with magnesium hydroxide. The electrodeposition of magnesium oxide/hydroxide commences in magnesium underpotential (UPD) and continues through the magnesium overpotential (OPD) region. Network of individual or intertwined very thin needles as well as those grouped in flower-like aggregates or honeycomb-like structures were formed in both magnesium UPD and OPD regions. Formation of the long needles was explained through theories of mechanisms of dendrite formation. Hydrogen evolution commences in the magnesium OPD region and increases with the applied overpotential. Holes observed in the deposit originated from the detached hydrogen bubbles. The number, shape and size of the hole strongly depended on both the applied cathodic potential and the hold time of electrodeposition. Magnesium oxides/hydroxides syntheses taking part simultaneously at various applied potentials are a result of reactions between magnesium cations and products of water and nitrate anions reduction processes. Chemical reactions responsible for direct formation of magnesium oxide observed are those of magnesium ions and oxygen ions, formed by nitrate reduction taking part in the close vicinity of the working electrode.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts
EP  - 502
SP  - 494
VL  - 268
DO  - 10.1016/j.electacta.2018.02.121
ER  - 
@article{
author = "Cvetković, Vesna S. and Vukicević, Nataša M. and Nikolic, Nebojša D. and Branković, Goran and Barudzija, Tanja S. and Jovicević, Jovan N.",
year = "2018",
abstract = "The processes of electrochemical deposition of magnesium oxide/hydroxide on glassy carbon (GC) electrode from magnesium nitrate hexahydrate melt have been investigated. A novel procedure predicting a possibility of direct formation of magnesium oxide during electrodeposition from the nitrate melt used is reported. XRD analysis of the obtained deposits showed the formation of magnesium oxide along with magnesium hydroxide. The electrodeposition of magnesium oxide/hydroxide commences in magnesium underpotential (UPD) and continues through the magnesium overpotential (OPD) region. Network of individual or intertwined very thin needles as well as those grouped in flower-like aggregates or honeycomb-like structures were formed in both magnesium UPD and OPD regions. Formation of the long needles was explained through theories of mechanisms of dendrite formation. Hydrogen evolution commences in the magnesium OPD region and increases with the applied overpotential. Holes observed in the deposit originated from the detached hydrogen bubbles. The number, shape and size of the hole strongly depended on both the applied cathodic potential and the hold time of electrodeposition. Magnesium oxides/hydroxides syntheses taking part simultaneously at various applied potentials are a result of reactions between magnesium cations and products of water and nitrate anions reduction processes. Chemical reactions responsible for direct formation of magnesium oxide observed are those of magnesium ions and oxygen ions, formed by nitrate reduction taking part in the close vicinity of the working electrode.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts",
pages = "502-494",
volume = "268",
doi = "10.1016/j.electacta.2018.02.121"
}
Cvetković, V. S., Vukicević, N. M., Nikolic, N. D., Branković, G., Barudzija, T. S.,& Jovicević, J. N.. (2018). Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 268, 494-502.
https://doi.org/10.1016/j.electacta.2018.02.121
Cvetković VS, Vukicević NM, Nikolic ND, Branković G, Barudzija TS, Jovicević JN. Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts. in Electrochimica Acta. 2018;268:494-502.
doi:10.1016/j.electacta.2018.02.121 .
Cvetković, Vesna S., Vukicević, Nataša M., Nikolic, Nebojša D., Branković, Goran, Barudzija, Tanja S., Jovicević, Jovan N., "Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts" in Electrochimica Acta, 268 (2018):494-502,
https://doi.org/10.1016/j.electacta.2018.02.121 . .

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