Fe-Mo alloys were electrodeposited from a pyrophosphate bath using a single diode rectified AC current. Their composition and morphology were investigated by SEM, optical microscopy and EDS, in order to determine the influence of the deposition conditions on the morphology and composition of these alloys. It was shown that the electrodeposition parameters, such as: chemical bath composition and current density, influenced both the composition of the Fe Mo alloys and the current efficiency for their deposition, while the micro and macro-morphology did not change significantly with changing conditions of alloy electrodeposition. It was found that the electrodeposited Fe Mo alloys possessed a 0.15 V to 0.30 V lower overvoltage than mild steel for hydrogen evolution in ail electrolyte commonly used in commercial chlorate production, depending on the alloy composition, i.e., the conditions of alloy electrodeposition.
TY - JOUR
AU - Grgur, BN
AU - Krstajić, Nedeljko V
AU - Elezović, Nevenka R.
AU - Jović, Vladimir D
PY - 2005
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/114
AB - Fe-Mo alloys were electrodeposited from a pyrophosphate bath using a single diode rectified AC current. Their composition and morphology were investigated by SEM, optical microscopy and EDS, in order to determine the influence of the deposition conditions on the morphology and composition of these alloys. It was shown that the electrodeposition parameters, such as: chemical bath composition and current density, influenced both the composition of the Fe Mo alloys and the current efficiency for their deposition, while the micro and macro-morphology did not change significantly with changing conditions of alloy electrodeposition. It was found that the electrodeposited Fe Mo alloys possessed a 0.15 V to 0.30 V lower overvoltage than mild steel for hydrogen evolution in ail electrolyte commonly used in commercial chlorate production, depending on the alloy composition, i.e., the conditions of alloy electrodeposition.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - Electrodeposition and characterization of Fe-Mo alloys as cathodes for hydrogen evolution in the process of chlorate production
EP - 889
IS - 6
SP - 879
VL - 70
DO - 10.2298/JSC0506879G
ER -
@article{
author = "Grgur, BN and Krstajić, Nedeljko V and Elezović, Nevenka R. and Jović, Vladimir D",
year = "2005",
abstract = "Fe-Mo alloys were electrodeposited from a pyrophosphate bath using a single diode rectified AC current. Their composition and morphology were investigated by SEM, optical microscopy and EDS, in order to determine the influence of the deposition conditions on the morphology and composition of these alloys. It was shown that the electrodeposition parameters, such as: chemical bath composition and current density, influenced both the composition of the Fe Mo alloys and the current efficiency for their deposition, while the micro and macro-morphology did not change significantly with changing conditions of alloy electrodeposition. It was found that the electrodeposited Fe Mo alloys possessed a 0.15 V to 0.30 V lower overvoltage than mild steel for hydrogen evolution in ail electrolyte commonly used in commercial chlorate production, depending on the alloy composition, i.e., the conditions of alloy electrodeposition.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Electrodeposition and characterization of Fe-Mo alloys as cathodes for hydrogen evolution in the process of chlorate production",
pages = "889-879",
number = "6",
volume = "70",
doi = "10.2298/JSC0506879G"
}
Grgur, B., Krstajić, N. V., Elezović, N. R.,& Jović, V. D.. (2005). Electrodeposition and characterization of Fe-Mo alloys as cathodes for hydrogen evolution in the process of chlorate production. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 70(6), 879-889.
https://doi.org/10.2298/JSC0506879G
Grgur B, Krstajić NV, Elezović NR, Jović VD. Electrodeposition and characterization of Fe-Mo alloys as cathodes for hydrogen evolution in the process of chlorate production. in Journal of the Serbian Chemical Society. 2005;70(6):879-889.
doi:10.2298/JSC0506879G .
Grgur, BN, Krstajić, Nedeljko V, Elezović, Nevenka R., Jović, Vladimir D, "Electrodeposition and characterization of Fe-Mo alloys as cathodes for hydrogen evolution in the process of chlorate production" in Journal of the Serbian Chemical Society, 70, no. 6 (2005):879-889,
https://doi.org/10.2298/JSC0506879G . .
