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Enhanced electrochemical response of carbon quantum dot modified electrodes

Само за регистроване кориснике
2018
Аутори
Algarra, Manuel
Gonzalez-Calabuig, A.
Radotić, Ksenija
Mutavdžić, Dragosav
Ania, C. O.
Lazaro-Martinez, Juan M.
Jimenez-Jimenez, Jose
Rodriguez-Castellon, Enrique
del, Valle, M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документу
Апстракт
A glassy carbon electrode (GCE) was surface-modified with carbon quantum dots (CQDs) and applied for the effective enhancement of the electrochemical signal for dopamine and uric acid determination. CQDs were prepared from graphite by a green modification of the Hummers method. They were characterized by FTIR-ATR, XPS, solid-state NMR, fluorescence and Raman spectroscopies. TPD-MS analysis was applied to characterize the functionalization of the surface. The CQDs were assembled on the glassy carbon electrode by adsorption because of the large number of carboxy groups on their surface warrants effective adsorption. The modified GCE exhibits a sensitivity that is almost 10 times better than of the bare GCE. The lower limits of detection are 1.3 mu M for uric acid and 2.7 mu M for dopamine.
Кључне речи:
Voltanunetry / Nanomaterial / Modified electrode / Carbon dot
Извор:
Talanta, 2018, 178, 679-685
Издавач:
  • Elsevier, Amsterdam
Финансирање / пројекти:
  • Испитивања односа структура-функција у ћелијском зиду биљака и измене структуре зида ензимским инжењерингом (RS-173017)
  • ANPCYTANPCyT [PICT 2012-0151]
  • Univ. Buenos AiresUniversity of Buenos Aires [UBACyT 2013-2016/043BA]
  • CONICETConsejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) [PIP 2014-2016/130]
  • Spanish MINECOSpanish Government [CTQ2013-41577-P, CTQ2015-68951-C3-3-R, CTM2014/56770-R]

DOI: 10.1016/j.talanta.2017.09.082

ISSN: 0039-9140

PubMed: 29136880

WoS: 000416615500090

Scopus: 2-s2.0-85032856402
[ Google Scholar ]
45
7
URI
http://rimsi.imsi.bg.ac.rs/handle/123456789/1127
Колекције
  • Radovi istraživača / Researchers’ publications
Институција/група
Institut za multidisciplinarna istraživanja
TY  - JOUR
AU  - Algarra, Manuel
AU  - Gonzalez-Calabuig, A.
AU  - Radotić, Ksenija
AU  - Mutavdžić, Dragosav
AU  - Ania, C. O.
AU  - Lazaro-Martinez, Juan M.
AU  - Jimenez-Jimenez, Jose
AU  - Rodriguez-Castellon, Enrique
AU  - del, Valle, M.
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1127
AB  - A glassy carbon electrode (GCE) was surface-modified with carbon quantum dots (CQDs) and applied for the effective enhancement of the electrochemical signal for dopamine and uric acid determination. CQDs were prepared from graphite by a green modification of the Hummers method. They were characterized by FTIR-ATR, XPS, solid-state NMR, fluorescence and Raman spectroscopies. TPD-MS analysis was applied to characterize the functionalization of the surface. The CQDs were assembled on the glassy carbon electrode by adsorption because of the large number of carboxy groups on their surface warrants effective adsorption. The modified GCE exhibits a sensitivity that is almost 10 times better than of the bare GCE. The lower limits of detection are 1.3 mu M for uric acid and 2.7 mu M for dopamine.
PB  - Elsevier, Amsterdam
T2  - Talanta
T1  - Enhanced electrochemical response of carbon quantum dot modified electrodes
EP  - 685
SP  - 679
VL  - 178
DO  - 10.1016/j.talanta.2017.09.082
ER  - 
@article{
author = "Algarra, Manuel and Gonzalez-Calabuig, A. and Radotić, Ksenija and Mutavdžić, Dragosav and Ania, C. O. and Lazaro-Martinez, Juan M. and Jimenez-Jimenez, Jose and Rodriguez-Castellon, Enrique and del, Valle, M.",
year = "2018",
abstract = "A glassy carbon electrode (GCE) was surface-modified with carbon quantum dots (CQDs) and applied for the effective enhancement of the electrochemical signal for dopamine and uric acid determination. CQDs were prepared from graphite by a green modification of the Hummers method. They were characterized by FTIR-ATR, XPS, solid-state NMR, fluorescence and Raman spectroscopies. TPD-MS analysis was applied to characterize the functionalization of the surface. The CQDs were assembled on the glassy carbon electrode by adsorption because of the large number of carboxy groups on their surface warrants effective adsorption. The modified GCE exhibits a sensitivity that is almost 10 times better than of the bare GCE. The lower limits of detection are 1.3 mu M for uric acid and 2.7 mu M for dopamine.",
publisher = "Elsevier, Amsterdam",
journal = "Talanta",
title = "Enhanced electrochemical response of carbon quantum dot modified electrodes",
pages = "685-679",
volume = "178",
doi = "10.1016/j.talanta.2017.09.082"
}
Algarra, M., Gonzalez-Calabuig, A., Radotić, K., Mutavdžić, D., Ania, C. O., Lazaro-Martinez, J. M., Jimenez-Jimenez, J., Rodriguez-Castellon, E.,& del, V. M.. (2018). Enhanced electrochemical response of carbon quantum dot modified electrodes. in Talanta
Elsevier, Amsterdam., 178, 679-685.
https://doi.org/10.1016/j.talanta.2017.09.082
Algarra M, Gonzalez-Calabuig A, Radotić K, Mutavdžić D, Ania CO, Lazaro-Martinez JM, Jimenez-Jimenez J, Rodriguez-Castellon E, del VM. Enhanced electrochemical response of carbon quantum dot modified electrodes. in Talanta. 2018;178:679-685.
doi:10.1016/j.talanta.2017.09.082 .
Algarra, Manuel, Gonzalez-Calabuig, A., Radotić, Ksenija, Mutavdžić, Dragosav, Ania, C. O., Lazaro-Martinez, Juan M., Jimenez-Jimenez, Jose, Rodriguez-Castellon, Enrique, del, Valle, M., "Enhanced electrochemical response of carbon quantum dot modified electrodes" in Talanta, 178 (2018):679-685,
https://doi.org/10.1016/j.talanta.2017.09.082 . .

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