BiFeO3 powders were synthesized by sonochemically assisted hydrothermal and hydro-evaporation methods. The X-ray diffraction confirmed the presence of secondary phases, Bi25FeO39 and Bi2Fe4O9, in as prepared BiFeO3 powders. Optimization of sintering conditions indicated that temperature of 800 degrees C and time of 2 h after pressing at 9 t/cm(2) provided ceramics samples with"the highest density (up to 96% of theoretical density) and the lowest content of secondary phases. Ferroelectric and magnetic characterization was performed on two selected ceramics samples with the highest densities. Ceramics obtained from the powder synthesized by the hydrothermal method showed greater lattice distortion along [1 1 1] axis and smaller grains, which resulted in larger values of electric polarization at room temperature. It also exhibited less Fe(3d)-O(2p) orbital overlapping due to a larger Fe-O-Fe bond angle, causing lower antiferromagnetic ordering and weak ferromagnetic behavior at low temper...atures.
TY - JOUR
AU - Luković Golić, Danijela
AU - Radojković, Aleksandar
AU - Ćirković, Jovana
AU - Dapčević, Aleksandra
AU - Pajić, Damir
AU - Tasić, Nikola
AU - Savić, Slavica M.
AU - Počuča-Nešić, Milica
AU - Marković, Smilja
AU - Branković, Goran
AU - Marinković-Stanojević, Zorica
AU - Branković, Zorica
PY - 2016
UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1017
AB - BiFeO3 powders were synthesized by sonochemically assisted hydrothermal and hydro-evaporation methods. The X-ray diffraction confirmed the presence of secondary phases, Bi25FeO39 and Bi2Fe4O9, in as prepared BiFeO3 powders. Optimization of sintering conditions indicated that temperature of 800 degrees C and time of 2 h after pressing at 9 t/cm(2) provided ceramics samples with"the highest density (up to 96% of theoretical density) and the lowest content of secondary phases. Ferroelectric and magnetic characterization was performed on two selected ceramics samples with the highest densities. Ceramics obtained from the powder synthesized by the hydrothermal method showed greater lattice distortion along [1 1 1] axis and smaller grains, which resulted in larger values of electric polarization at room temperature. It also exhibited less Fe(3d)-O(2p) orbital overlapping due to a larger Fe-O-Fe bond angle, causing lower antiferromagnetic ordering and weak ferromagnetic behavior at low temperatures.
PB - Elsevier Sci Ltd, Oxford
T2 - Journal of the European Ceramic Society
T1 - Structural, ferroelectric and magnetic properties of BiFeO3 synthesized by sonochemically assisted hydrothermal and hydro-evaporation chemical methods
EP - 1631
IS - 7
SP - 1623
VL - 36
DO - 10.1016/j.jeurceramsoc.2016.01.031
ER -
@article{
author = "Luković Golić, Danijela and Radojković, Aleksandar and Ćirković, Jovana and Dapčević, Aleksandra and Pajić, Damir and Tasić, Nikola and Savić, Slavica M. and Počuča-Nešić, Milica and Marković, Smilja and Branković, Goran and Marinković-Stanojević, Zorica and Branković, Zorica",
year = "2016",
abstract = "BiFeO3 powders were synthesized by sonochemically assisted hydrothermal and hydro-evaporation methods. The X-ray diffraction confirmed the presence of secondary phases, Bi25FeO39 and Bi2Fe4O9, in as prepared BiFeO3 powders. Optimization of sintering conditions indicated that temperature of 800 degrees C and time of 2 h after pressing at 9 t/cm(2) provided ceramics samples with"the highest density (up to 96% of theoretical density) and the lowest content of secondary phases. Ferroelectric and magnetic characterization was performed on two selected ceramics samples with the highest densities. Ceramics obtained from the powder synthesized by the hydrothermal method showed greater lattice distortion along [1 1 1] axis and smaller grains, which resulted in larger values of electric polarization at room temperature. It also exhibited less Fe(3d)-O(2p) orbital overlapping due to a larger Fe-O-Fe bond angle, causing lower antiferromagnetic ordering and weak ferromagnetic behavior at low temperatures.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Journal of the European Ceramic Society",
title = "Structural, ferroelectric and magnetic properties of BiFeO3 synthesized by sonochemically assisted hydrothermal and hydro-evaporation chemical methods",
pages = "1631-1623",
number = "7",
volume = "36",
doi = "10.1016/j.jeurceramsoc.2016.01.031"
}
Luković Golić, D., Radojković, A., Ćirković, J., Dapčević, A., Pajić, D., Tasić, N., Savić, S. M., Počuča-Nešić, M., Marković, S., Branković, G., Marinković-Stanojević, Z.,& Branković, Z.. (2016). Structural, ferroelectric and magnetic properties of BiFeO3 synthesized by sonochemically assisted hydrothermal and hydro-evaporation chemical methods. in Journal of the European Ceramic Society
Elsevier Sci Ltd, Oxford., 36(7), 1623-1631.
https://doi.org/10.1016/j.jeurceramsoc.2016.01.031
Luković Golić D, Radojković A, Ćirković J, Dapčević A, Pajić D, Tasić N, Savić SM, Počuča-Nešić M, Marković S, Branković G, Marinković-Stanojević Z, Branković Z. Structural, ferroelectric and magnetic properties of BiFeO3 synthesized by sonochemically assisted hydrothermal and hydro-evaporation chemical methods. in Journal of the European Ceramic Society. 2016;36(7):1623-1631.
doi:10.1016/j.jeurceramsoc.2016.01.031 .
Luković Golić, Danijela, Radojković, Aleksandar, Ćirković, Jovana, Dapčević, Aleksandra, Pajić, Damir, Tasić, Nikola, Savić, Slavica M., Počuča-Nešić, Milica, Marković, Smilja, Branković, Goran, Marinković-Stanojević, Zorica, Branković, Zorica, "Structural, ferroelectric and magnetic properties of BiFeO3 synthesized by sonochemically assisted hydrothermal and hydro-evaporation chemical methods" in Journal of the European Ceramic Society, 36, no. 7 (2016):1623-1631,
https://doi.org/10.1016/j.jeurceramsoc.2016.01.031 . .
