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Visible-light photocatalytic degradation of mordant blue 9 by BiVO4 nanopowder

Jovanović, Jelena; Jelić, Stefan; Ćirković, Jovana; Radojković, Aleksandar; Branković, Goran; Branković, Zorica

(Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia, 2022)

TY  - CONF
AU  - Jovanović, Jelena
AU  - Jelić, Stefan
AU  - Ćirković, Jovana
AU  - Radojković, Aleksandar
AU  - Branković, Goran
AU  - Branković, Zorica
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1751
AB  - The photocatalytic degradation of highly toxic azo dye Mordant Blue 9 (MB 9) was investigated using single-phase monoclinic BiVO4 nanopowder as a photocatalyst under the simulated solar irradiation. The photodegradation process as a function of different pH values of aqueous dye solution (pH = 1 – 13) and irradiation time was investigated, and the complete degradation mechanism was proposed. MB 9 was resistant to direct photolysis and the BiVO4 nanoparticles exhibited higher photocatalytic activity in a basic medium than in neutral and acid media. Photodegradation of the dye molecules occurred primarily due to a reaction with the photo-generated holes and OH– anions forming ∙OH radicals. The alkaline pH range favors the formation of more ∙OH radicals through the oxidation of hydroxide ions existing at the BiVO4 surface, thus the effectiveness of the photocatalytic process significantly increased. BiVO4 photocatalyst was stable and active under simulated solar irradiation over four consecutive cycles, which confirms its good photocatalytic properties.
PB  - Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia
C3  - The 6 th Conference of The Serbian Society for Ceramic Materials: 6CSCS-2022, Belgrade, Serbia
T1  - Visible-light photocatalytic degradation of mordant blue 9 by BiVO4 nanopowder
VL  - 55
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1751
ER  - 
@conference{
author = "Jovanović, Jelena and Jelić, Stefan and Ćirković, Jovana and Radojković, Aleksandar and Branković, Goran and Branković, Zorica",
year = "2022",
abstract = "The photocatalytic degradation of highly toxic azo dye Mordant Blue 9 (MB 9) was investigated using single-phase monoclinic BiVO4 nanopowder as a photocatalyst under the simulated solar irradiation. The photodegradation process as a function of different pH values of aqueous dye solution (pH = 1 – 13) and irradiation time was investigated, and the complete degradation mechanism was proposed. MB 9 was resistant to direct photolysis and the BiVO4 nanoparticles exhibited higher photocatalytic activity in a basic medium than in neutral and acid media. Photodegradation of the dye molecules occurred primarily due to a reaction with the photo-generated holes and OH– anions forming ∙OH radicals. The alkaline pH range favors the formation of more ∙OH radicals through the oxidation of hydroxide ions existing at the BiVO4 surface, thus the effectiveness of the photocatalytic process significantly increased. BiVO4 photocatalyst was stable and active under simulated solar irradiation over four consecutive cycles, which confirms its good photocatalytic properties.",
publisher = "Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia",
journal = "The 6 th Conference of The Serbian Society for Ceramic Materials: 6CSCS-2022, Belgrade, Serbia",
title = "Visible-light photocatalytic degradation of mordant blue 9 by BiVO4 nanopowder",
volume = "55",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1751"
}
Jovanović, J., Jelić, S., Ćirković, J., Radojković, A., Branković, G.,& Branković, Z.. (2022). Visible-light photocatalytic degradation of mordant blue 9 by BiVO4 nanopowder. in The 6 th Conference of The Serbian Society for Ceramic Materials: 6CSCS-2022, Belgrade, Serbia
Institut za multidisciplinarna istraživanja Kneza Višeslava 1, 11000 Belgrade, Serbia., 55.
https://hdl.handle.net/21.15107/rcub_rimsi_1751
Jovanović J, Jelić S, Ćirković J, Radojković A, Branković G, Branković Z. Visible-light photocatalytic degradation of mordant blue 9 by BiVO4 nanopowder. in The 6 th Conference of The Serbian Society for Ceramic Materials: 6CSCS-2022, Belgrade, Serbia. 2022;55.
https://hdl.handle.net/21.15107/rcub_rimsi_1751 .
Jovanović, Jelena, Jelić, Stefan, Ćirković, Jovana, Radojković, Aleksandar, Branković, Goran, Branković, Zorica, "Visible-light photocatalytic degradation of mordant blue 9 by BiVO4 nanopowder" in The 6 th Conference of The Serbian Society for Ceramic Materials: 6CSCS-2022, Belgrade, Serbia, 55 (2022),
https://hdl.handle.net/21.15107/rcub_rimsi_1751 .