TY  - JOUR
AU  - Ivanović, Tijana
AU  - Popović, Daniela Ž.
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran
AU  - Pastor, Ferenc
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2323
AB  - : Zero-current cell potential measurements were used
to determine the solution activity coefficient in a ternary system
{yKCl + (1 − y) KH2PO4}(aq) at temperature T = 298.15 K. The
cell of the type K−ISE|KCl(mKCl), KH2PO4(mKH2PO4
)|Ag|AgCl was
used in the total ionic strength range, Im = 0.0886−1.0046 mol
kg−1
. In order to generate a set of parameters that can be applied in
a wide range of mixed solution ionic strengths, the Pitzer,
Scatchard, and Clegg−Pitzer−Brimblecombe models were used to
fit all available experimental data, including cell potential and
isopiestic measurements from the literature. The experimental and
calculated values of thermodynamic properties for the studied
system are in excellent agreement. Potential interactions and solution structure were discussed by means of the excess free energy of
mixing via potential pairs, triplets, or quads for the investigated solution using the Scatchard model mixing parameters
PB  - ACS Publications
T2  - ACS Publications
T1  - Activity Coefficients of the System {yKCl + (1 − y)KH2PO4}(aq) at T = 298.15 K Determined by Cell Potential Measurements
VL  - 68
DO  - 10.1021/acs.jced.2c00704
ER  - 

@article{
author = "Ivanović, Tijana and Popović, Daniela Ž. and Miladinović, Jelena and Miladinović, Zoran and Pastor, Ferenc",
year = "2023",
abstract = ": Zero-current cell potential measurements were used
to determine the solution activity coefficient in a ternary system
{yKCl + (1 − y) KH2PO4}(aq) at temperature T = 298.15 K. The
cell of the type K−ISE|KCl(mKCl), KH2PO4(mKH2PO4
)|Ag|AgCl was
used in the total ionic strength range, Im = 0.0886−1.0046 mol
kg−1
. In order to generate a set of parameters that can be applied in
a wide range of mixed solution ionic strengths, the Pitzer,
Scatchard, and Clegg−Pitzer−Brimblecombe models were used to
fit all available experimental data, including cell potential and
isopiestic measurements from the literature. The experimental and
calculated values of thermodynamic properties for the studied
system are in excellent agreement. Potential interactions and solution structure were discussed by means of the excess free energy of
mixing via potential pairs, triplets, or quads for the investigated solution using the Scatchard model mixing parameters",
publisher = "ACS Publications",
journal = "ACS Publications",
title = "Activity Coefficients of the System {yKCl + (1 − y)KH2PO4}(aq) at T = 298.15 K Determined by Cell Potential Measurements",
volume = "68",
doi = "10.1021/acs.jced.2c00704"
}

Ivanović, T., Popović, D. Ž., Miladinović, J., Miladinović, Z.,& Pastor, F.. (2023). Activity Coefficients of the System {yKCl + (1 − y)KH2PO4}(aq) at T = 298.15 K Determined by Cell Potential Measurements. in ACS Publications
ACS Publications., 68.
https://doi.org/10.1021/acs.jced.2c00704

Ivanović T, Popović DŽ, Miladinović J, Miladinović Z, Pastor F. Activity Coefficients of the System {yKCl + (1 − y)KH2PO4}(aq) at T = 298.15 K Determined by Cell Potential Measurements. in ACS Publications. 2023;68.
doi:10.1021/acs.jced.2c00704 .

Ivanović, Tijana, Popović, Daniela Ž., Miladinović, Jelena, Miladinović, Zoran, Pastor, Ferenc, "Activity Coefficients of the System {yKCl + (1 − y)KH2PO4}(aq) at T = 298.15 K Determined by Cell Potential Measurements" in ACS Publications, 68 (2023),
https://doi.org/10.1021/acs.jced.2c00704 . .

TY  - JOUR
AU  - Pastor, Ferenc
AU  - Dojčinović, Biljana P.
AU  - Kodranov, Igor D.
AU  - Gorjanović, Stanislava Ž.
AU  - Ivanović, Tijana
AU  - Popović, Daniela Ž.
AU  - Miladinović, Jelena
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3095
AB  - Due to the similar chemical properties of Ni2+ and Co2+, several dozens of adsorptive stripping voltammetric (AdSV)
methods have been developed for their simultaneous determination. The question was would there be some benefits
if a stripping method made for simultaneous determination of Ni2+ and Co2+ will be optimized for the determination
of only one of them (Ni2+). It was found that the optimized method has for an order of magnitude lower LOQ (1.89 ×
10-10 M), an order of magnitude lower influence of Co2+, and the applicability of one calibration line for four orders
of magnitude of Ni2+ concentration. The influence of some common anions and cations has been examined. The
developed method was successfully applied for nickel content determination in real samples. The suitability of the
developed method for the determination of Co2+ from the same solution in the second run, upon optimizations of
deposition potential and time, was also explored. The LOQ obtained for Co2+ (3.61 × 10-11 M) is almost two orders
of magnitude lower than LOQ of the method for simultaneous determination of both cations and, its LOD and LOQ
are among few lowest obtained by AdSV methods for Co2+ determination. The developed method for Ni2+ and Co2+
determination from the same solution in two successive runs has significantly better analytical performances than
the starting method for their simultaneous determination in one run.
PB  - John Wiley and Sons Inc.
T2  - Electroanalysis
T1  - 2 in 1versus 1plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination
DO  - 10.1002/elan.202300259
ER  - 

@article{
author = "Pastor, Ferenc and Dojčinović, Biljana P. and Kodranov, Igor D. and Gorjanović, Stanislava Ž. and Ivanović, Tijana and Popović, Daniela Ž. and Miladinović, Jelena",
year = "2023",
abstract = "Due to the similar chemical properties of Ni2+ and Co2+, several dozens of adsorptive stripping voltammetric (AdSV)
methods have been developed for their simultaneous determination. The question was would there be some benefits
if a stripping method made for simultaneous determination of Ni2+ and Co2+ will be optimized for the determination
of only one of them (Ni2+). It was found that the optimized method has for an order of magnitude lower LOQ (1.89 ×
10-10 M), an order of magnitude lower influence of Co2+, and the applicability of one calibration line for four orders
of magnitude of Ni2+ concentration. The influence of some common anions and cations has been examined. The
developed method was successfully applied for nickel content determination in real samples. The suitability of the
developed method for the determination of Co2+ from the same solution in the second run, upon optimizations of
deposition potential and time, was also explored. The LOQ obtained for Co2+ (3.61 × 10-11 M) is almost two orders
of magnitude lower than LOQ of the method for simultaneous determination of both cations and, its LOD and LOQ
are among few lowest obtained by AdSV methods for Co2+ determination. The developed method for Ni2+ and Co2+
determination from the same solution in two successive runs has significantly better analytical performances than
the starting method for their simultaneous determination in one run.",
publisher = "John Wiley and Sons Inc.",
journal = "Electroanalysis",
title = "2 in 1versus 1plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination",
doi = "10.1002/elan.202300259"
}

Pastor, F., Dojčinović, B. P., Kodranov, I. D., Gorjanović, S. Ž., Ivanović, T., Popović, D. Ž.,& Miladinović, J.. (2023). 2 in 1versus 1plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination. in Electroanalysis
John Wiley and Sons Inc...
https://doi.org/10.1002/elan.202300259

Pastor F, Dojčinović BP, Kodranov ID, Gorjanović SŽ, Ivanović T, Popović DŽ, Miladinović J. 2 in 1versus 1plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination. in Electroanalysis. 2023;.
doi:10.1002/elan.202300259 .

Pastor, Ferenc, Dojčinović, Biljana P., Kodranov, Igor D., Gorjanović, Stanislava Ž., Ivanović, Tijana, Popović, Daniela Ž., Miladinović, Jelena, "2 in 1versus 1plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination" in Electroanalysis (2023),
https://doi.org/10.1002/elan.202300259 . .

TY  - JOUR
AU  - Popović, Daniela Ž.
AU  - Ivanović, Tijana
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran
AU  - Pastor, Ferenc
AU  - Zlatić, Aleksandra
PY  - 2023
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3091
AB  - The mean ionic activity coefficients of NaCl in a ternary system {yNaCl + (1 – y)Na2HPO4}(aq)
were determined from measurements of the electromotive force (EMF) where the NaCl ionic strength
fraction was y = (0.3012; 0.4015; 0.5011; 0.5988; 0.7706; 0.8997) in the range of total ionic strength of the
solution Im = 0.0701–1.0161 mol kg–1 at temperature T = 298.15 K. A cell of the Na–ISE| ,Na2HPO4|AgCl|Ag, type was employed for the EMF measurements. The experimental results
from this work and the model of Pitzer’s were used to determine the mixing parameters. Good agreement
was found between the experimental and calculated values of the mean ionic activity coefficients of NaCl
with a standard deviation of fit 1.5 × 10–3. The values of the osmotic coefficients of the system {yNaCl +
(1 – y)Na2HPO4}(aq) were estimated on the basis of the determined parameters and compared with liter ature data. The differences in the osmotic coefficients between the estimated and experimental values were
negligible
PB  - Pleiades Publishing
T2  - Russian Journal of Physical Chemistry A
T1  - Activity Coefficients of the System {yNaCl + (1 – y)Na2HPO4}(aq)  at T = 298.15 K Determined by Electromotive Force Measurements
EP  - 2702
SP  - 2693
DO  - 10.1134/S0036024423120063
ER  - 

@article{
author = "Popović, Daniela Ž. and Ivanović, Tijana and Miladinović, Jelena and Miladinović, Zoran and Pastor, Ferenc and Zlatić, Aleksandra",
year = "2023",
abstract = "The mean ionic activity coefficients of NaCl in a ternary system {yNaCl + (1 – y)Na2HPO4}(aq)
were determined from measurements of the electromotive force (EMF) where the NaCl ionic strength
fraction was y = (0.3012; 0.4015; 0.5011; 0.5988; 0.7706; 0.8997) in the range of total ionic strength of the
solution Im = 0.0701–1.0161 mol kg–1 at temperature T = 298.15 K. A cell of the Na–ISE| ,Na2HPO4|AgCl|Ag, type was employed for the EMF measurements. The experimental results
from this work and the model of Pitzer’s were used to determine the mixing parameters. Good agreement
was found between the experimental and calculated values of the mean ionic activity coefficients of NaCl
with a standard deviation of fit 1.5 × 10–3. The values of the osmotic coefficients of the system {yNaCl +
(1 – y)Na2HPO4}(aq) were estimated on the basis of the determined parameters and compared with liter ature data. The differences in the osmotic coefficients between the estimated and experimental values were
negligible",
publisher = "Pleiades Publishing",
journal = "Russian Journal of Physical Chemistry A",
title = "Activity Coefficients of the System {yNaCl + (1 – y)Na2HPO4}(aq)  at T = 298.15 K Determined by Electromotive Force Measurements",
pages = "2702-2693",
doi = "10.1134/S0036024423120063"
}

Popović, D. Ž., Ivanović, T., Miladinović, J., Miladinović, Z., Pastor, F.,& Zlatić, A.. (2023). Activity Coefficients of the System {yNaCl + (1 – y)Na2HPO4}(aq)  at T = 298.15 K Determined by Electromotive Force Measurements. in Russian Journal of Physical Chemistry A
Pleiades Publishing., 2693-2702.
https://doi.org/10.1134/S0036024423120063

Popović DŽ, Ivanović T, Miladinović J, Miladinović Z, Pastor F, Zlatić A. Activity Coefficients of the System {yNaCl + (1 – y)Na2HPO4}(aq)  at T = 298.15 K Determined by Electromotive Force Measurements. in Russian Journal of Physical Chemistry A. 2023;:2693-2702.
doi:10.1134/S0036024423120063 .

Popović, Daniela Ž., Ivanović, Tijana, Miladinović, Jelena, Miladinović, Zoran, Pastor, Ferenc, Zlatić, Aleksandra, "Activity Coefficients of the System {yNaCl + (1 – y)Na2HPO4}(aq)  at T = 298.15 K Determined by Electromotive Force Measurements" in Russian Journal of Physical Chemistry A (2023):2693-2702,
https://doi.org/10.1134/S0036024423120063 . .

TY  - CONF
AU  - Popović, Daniela Ž.
AU  - Ivanović, Tijana G.
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran
AU  - Pastor, Ferenc
AU  - Zlatić, Aleksandra
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/3099
AB  - The mean ionic activity coefficients of NaCl in a ternary system {yNaCl+(1-y) Na_2 HPO_4 }(aq)were determined using electromotive force measurements (EMF) at T = 298.15 K. For EMF measurements, a cell of the type Na–ISE〖NaCl(m〗_NaCl), Na_2 HPO_4 〖(m〗_(KH_2 PO_4 ))AgAgCl  was employed with NaCl ionic strength fractions y = (0.3012; 0.5011; 0.7706) in the range of total ionic strength of the solution I = (0.0701 – 0.9315) mol·kg-1. The Extended Pitzer model was used to analyze experimental data for the mixed electrolyte solution, and good agreement between experimental and calculated values of thermodynamic properties was found with a standard deviation of the fit of 10-3 order.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings)
T1  - THERMODYNAMIC PROPERTIES OF THE SYSTEM  {yNaCl+(1–y)Na2HPO4}(aq) AT  T = 298.15 K BY ELECTROMOTIVE FORCE MEASUREMENTS
EP  - 248
SP  - 245
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_3099
ER  - 

@conference{
author = "Popović, Daniela Ž. and Ivanović, Tijana G. and Miladinović, Jelena and Miladinović, Zoran and Pastor, Ferenc and Zlatić, Aleksandra",
year = "2022",
abstract = "The mean ionic activity coefficients of NaCl in a ternary system {yNaCl+(1-y) Na_2 HPO_4 }(aq)were determined using electromotive force measurements (EMF) at T = 298.15 K. For EMF measurements, a cell of the type Na–ISE〖NaCl(m〗_NaCl), Na_2 HPO_4 〖(m〗_(KH_2 PO_4 ))AgAgCl  was employed with NaCl ionic strength fractions y = (0.3012; 0.5011; 0.7706) in the range of total ionic strength of the solution I = (0.0701 – 0.9315) mol·kg-1. The Extended Pitzer model was used to analyze experimental data for the mixed electrolyte solution, and good agreement between experimental and calculated values of thermodynamic properties was found with a standard deviation of the fit of 10-3 order.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings)",
title = "THERMODYNAMIC PROPERTIES OF THE SYSTEM  {yNaCl+(1–y)Na2HPO4}(aq) AT  T = 298.15 K BY ELECTROMOTIVE FORCE MEASUREMENTS",
pages = "248-245",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_3099"
}

Popović, D. Ž., Ivanović, T. G., Miladinović, J., Miladinović, Z., Pastor, F.,& Zlatić, A.. (2022). THERMODYNAMIC PROPERTIES OF THE SYSTEM  {yNaCl+(1–y)Na2HPO4}(aq) AT  T = 298.15 K BY ELECTROMOTIVE FORCE MEASUREMENTS. in Physical chemistry 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings)
Society of Physical Chemists of Serbia., 245-248.
https://hdl.handle.net/21.15107/rcub_rimsi_3099

Popović DŽ, Ivanović TG, Miladinović J, Miladinović Z, Pastor F, Zlatić A. THERMODYNAMIC PROPERTIES OF THE SYSTEM  {yNaCl+(1–y)Na2HPO4}(aq) AT  T = 298.15 K BY ELECTROMOTIVE FORCE MEASUREMENTS. in Physical chemistry 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings). 2022;:245-248.
https://hdl.handle.net/21.15107/rcub_rimsi_3099 .

Popović, Daniela Ž., Ivanović, Tijana G., Miladinović, Jelena, Miladinović, Zoran, Pastor, Ferenc, Zlatić, Aleksandra, "THERMODYNAMIC PROPERTIES OF THE SYSTEM  {yNaCl+(1–y)Na2HPO4}(aq) AT  T = 298.15 K BY ELECTROMOTIVE FORCE MEASUREMENTS" in Physical chemistry 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings) (2022):245-248,
https://hdl.handle.net/21.15107/rcub_rimsi_3099 .

TY  - JOUR
AU  - Ivanović, Tijana
AU  - Popović, D.Ž.
AU  - Miladinović, Jelena
AU  - Miladinović, Zoran P.
AU  - Pastor, Ferenc
AU  - Nikolić, A.
PY  - 2022
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1518
AB  - The mean activity coefficients of KCl in the ternary system {y KCl + (1 – y) K2HPO4}(aq) were experimentally determined at T = (298.15 ± 0.01) K by the electromotive force measurement (EMF method) using the cell of the type, K–ISE∣KCl(mKCl), K2HPO4(mK2HPO4)∣Ag∣AgCl (ISE = ion-selective electrode), in the range of total ionic strength of the solution Im = (0.10 to 1.00) mol·kg−1 at different ionic strength fractions of KCl being y = (0.1011; 0.1997; 0.3016; 0.4027; 0.5006; 0.6018; 0.7018; 0.8051; 0.8988; 1). In addition, the osmotic coefficients of the system have been measured at the same temperature by the isopiestic vapor pressure method over the range of ionic strengths from (0.96698 to 2.21602) mol⋅kg−1 using KCl(aq) as the reference solution, at ionic strength fractions of KCl being y = (0.2063; 0.3849; 0.6099; 0.8011; 1). Values of the mean ionic activity coefficients of KCl and osmotic coefficients in the system {yKCl+(1–y)K2HPO4}(aq) were treated by an extended form of Pitzer's ion-interaction model, Scatchard's neutral-electrolyte model and Clegg–Pitzer–Brimblecombe's equations based on the mole-fraction-composition scale. All three models gave similar quality representations of both sets of experimental results. There are two sets of previously published isopiestic data that were taken into consideration during treatment. The model parameters were fitted and optimized to all available thermodynamic data from EMF and isopiestic measurements to obtain an accurate and self-consistent description of properties and to form a set of parameters that can be used in a wide range of ionic strength of the system. The standard deviation of the fit for the ionic strength range from Im = (0.0897 to 10.4350) mol·kg−1 with two optimized mixing parameters of Pitzer's model without higher–order electrostatic terms was for the mean ionic activity coefficients of KCl and osmotic coefficients, s.d. (γ±) = 3.5⋅10–3 and s.d. (ϕ) = 4.7⋅10–3 respectively, with two optimized mixing parameters of the Scatchard model standard deviations were s.d. (γ±) = 4.9⋅10–3 and s.d. (ϕ) = 5.0⋅10–3 and with Clegg–Pitzer–Brimblecombe's model higher–order electrostatic terms not included, standard deviations were s.d. (γ±) = 4.2⋅10–3 and s.d. (ϕ) = 4.8⋅10–3.
PB  - Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - Isopiestic determination of osmotic coefficients in the ionic strength range Im = (0.9670–2.2160) mol⋅kg−1 and activity coefficients determined by electromotive force measurements in the range Im = (0.0897–1.0054) mol⋅kg−1 of the {yKCl + (1 – y) K2HPO4}(a
VL  - 353
DO  - 10.1016/j.molliq.2022.118767
ER  - 

@article{
author = "Ivanović, Tijana and Popović, D.Ž. and Miladinović, Jelena and Miladinović, Zoran P. and Pastor, Ferenc and Nikolić, A.",
year = "2022",
abstract = "The mean activity coefficients of KCl in the ternary system {y KCl + (1 – y) K2HPO4}(aq) were experimentally determined at T = (298.15 ± 0.01) K by the electromotive force measurement (EMF method) using the cell of the type, K–ISE∣KCl(mKCl), K2HPO4(mK2HPO4)∣Ag∣AgCl (ISE = ion-selective electrode), in the range of total ionic strength of the solution Im = (0.10 to 1.00) mol·kg−1 at different ionic strength fractions of KCl being y = (0.1011; 0.1997; 0.3016; 0.4027; 0.5006; 0.6018; 0.7018; 0.8051; 0.8988; 1). In addition, the osmotic coefficients of the system have been measured at the same temperature by the isopiestic vapor pressure method over the range of ionic strengths from (0.96698 to 2.21602) mol⋅kg−1 using KCl(aq) as the reference solution, at ionic strength fractions of KCl being y = (0.2063; 0.3849; 0.6099; 0.8011; 1). Values of the mean ionic activity coefficients of KCl and osmotic coefficients in the system {yKCl+(1–y)K2HPO4}(aq) were treated by an extended form of Pitzer's ion-interaction model, Scatchard's neutral-electrolyte model and Clegg–Pitzer–Brimblecombe's equations based on the mole-fraction-composition scale. All three models gave similar quality representations of both sets of experimental results. There are two sets of previously published isopiestic data that were taken into consideration during treatment. The model parameters were fitted and optimized to all available thermodynamic data from EMF and isopiestic measurements to obtain an accurate and self-consistent description of properties and to form a set of parameters that can be used in a wide range of ionic strength of the system. The standard deviation of the fit for the ionic strength range from Im = (0.0897 to 10.4350) mol·kg−1 with two optimized mixing parameters of Pitzer's model without higher–order electrostatic terms was for the mean ionic activity coefficients of KCl and osmotic coefficients, s.d. (γ±) = 3.5⋅10–3 and s.d. (ϕ) = 4.7⋅10–3 respectively, with two optimized mixing parameters of the Scatchard model standard deviations were s.d. (γ±) = 4.9⋅10–3 and s.d. (ϕ) = 5.0⋅10–3 and with Clegg–Pitzer–Brimblecombe's model higher–order electrostatic terms not included, standard deviations were s.d. (γ±) = 4.2⋅10–3 and s.d. (ϕ) = 4.8⋅10–3.",
publisher = "Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "Isopiestic determination of osmotic coefficients in the ionic strength range Im = (0.9670–2.2160) mol⋅kg−1 and activity coefficients determined by electromotive force measurements in the range Im = (0.0897–1.0054) mol⋅kg−1 of the {yKCl + (1 – y) K2HPO4}(a",
volume = "353",
doi = "10.1016/j.molliq.2022.118767"
}

Ivanović, T., Popović, D.Ž., Miladinović, J., Miladinović, Z. P., Pastor, F.,& Nikolić, A.. (2022). Isopiestic determination of osmotic coefficients in the ionic strength range Im = (0.9670–2.2160) mol⋅kg−1 and activity coefficients determined by electromotive force measurements in the range Im = (0.0897–1.0054) mol⋅kg−1 of the {yKCl + (1 – y) K2HPO4}(a. in Journal of Molecular Liquids
Elsevier B.V.., 353.
https://doi.org/10.1016/j.molliq.2022.118767

Ivanović T, Popović D, Miladinović J, Miladinović ZP, Pastor F, Nikolić A. Isopiestic determination of osmotic coefficients in the ionic strength range Im = (0.9670–2.2160) mol⋅kg−1 and activity coefficients determined by electromotive force measurements in the range Im = (0.0897–1.0054) mol⋅kg−1 of the {yKCl + (1 – y) K2HPO4}(a. in Journal of Molecular Liquids. 2022;353.
doi:10.1016/j.molliq.2022.118767 .

Ivanović, Tijana, Popović, D.Ž., Miladinović, Jelena, Miladinović, Zoran P., Pastor, Ferenc, Nikolić, A., "Isopiestic determination of osmotic coefficients in the ionic strength range Im = (0.9670–2.2160) mol⋅kg−1 and activity coefficients determined by electromotive force measurements in the range Im = (0.0897–1.0054) mol⋅kg−1 of the {yKCl + (1 – y) K2HPO4}(a" in Journal of Molecular Liquids, 353 (2022),
https://doi.org/10.1016/j.molliq.2022.118767 . .

TY  - JOUR
AU  - Karaman, Maja
AU  - Tesanović, Kristina
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Simonović, Mladen
AU  - Glumac, Miodrag
AU  - Pejin, Boris
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1510
AB  - This study was focused on in vitro screening of the total antioxidant activity of the selected extracts of the mushroom Coprinus comatus and quinic acid, one of their antidiabetic ingredients, by an uncommon electrochemical assay. Indeed, direct current (DC) polarographic HydroxoPerhydroxo Mercury(II) Complex (HPMC) assay based on decrease of anodic limiting current originating from HPMC formation in alkaline solutions of hydrogen peroxide at potential of mercury dissolution, observed upon gradual addition of antioxidants, was applied herein for the estimation of the natural products' antioxidativity. Quinic acid was found to exhibit most promising antioxidant potential (4.0 +/- 0.2%mu L-1) being approximate to 2-fold more active than the screened C. comatus extract samples. Actually, such a finding puts some light on the antioxidativity of cyclic polyols, well understimated class of organic compounds, compared to aromatic (poly)phenolics. As a low cost, easy-to handle and accurate this polarographic assay may be thoroughly recommended for much broader use.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Natural Product Research
T1  - Polarography as a technique of choice for the evaluation of total antioxidant activity: The case study of selected Coprinus Comatus extracts and quinic acid, their antidiabetic ingredient
EP  - 1716
IS  - 10
SP  - 1711
VL  - 35
DO  - 10.1080/14786419.2019.1628753
ER  - 

@article{
author = "Karaman, Maja and Tesanović, Kristina and Gorjanović, Stanislava and Pastor, Ferenc and Simonović, Mladen and Glumac, Miodrag and Pejin, Boris",
year = "2021",
abstract = "This study was focused on in vitro screening of the total antioxidant activity of the selected extracts of the mushroom Coprinus comatus and quinic acid, one of their antidiabetic ingredients, by an uncommon electrochemical assay. Indeed, direct current (DC) polarographic HydroxoPerhydroxo Mercury(II) Complex (HPMC) assay based on decrease of anodic limiting current originating from HPMC formation in alkaline solutions of hydrogen peroxide at potential of mercury dissolution, observed upon gradual addition of antioxidants, was applied herein for the estimation of the natural products' antioxidativity. Quinic acid was found to exhibit most promising antioxidant potential (4.0 +/- 0.2%mu L-1) being approximate to 2-fold more active than the screened C. comatus extract samples. Actually, such a finding puts some light on the antioxidativity of cyclic polyols, well understimated class of organic compounds, compared to aromatic (poly)phenolics. As a low cost, easy-to handle and accurate this polarographic assay may be thoroughly recommended for much broader use.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Natural Product Research",
title = "Polarography as a technique of choice for the evaluation of total antioxidant activity: The case study of selected Coprinus Comatus extracts and quinic acid, their antidiabetic ingredient",
pages = "1716-1711",
number = "10",
volume = "35",
doi = "10.1080/14786419.2019.1628753"
}

Karaman, M., Tesanović, K., Gorjanović, S., Pastor, F., Simonović, M., Glumac, M.,& Pejin, B.. (2021). Polarography as a technique of choice for the evaluation of total antioxidant activity: The case study of selected Coprinus Comatus extracts and quinic acid, their antidiabetic ingredient. in Natural Product Research
Taylor & Francis Ltd, Abingdon., 35(10), 1711-1716.
https://doi.org/10.1080/14786419.2019.1628753

Karaman M, Tesanović K, Gorjanović S, Pastor F, Simonović M, Glumac M, Pejin B. Polarography as a technique of choice for the evaluation of total antioxidant activity: The case study of selected Coprinus Comatus extracts and quinic acid, their antidiabetic ingredient. in Natural Product Research. 2021;35(10):1711-1716.
doi:10.1080/14786419.2019.1628753 .

Karaman, Maja, Tesanović, Kristina, Gorjanović, Stanislava, Pastor, Ferenc, Simonović, Mladen, Glumac, Miodrag, Pejin, Boris, "Polarography as a technique of choice for the evaluation of total antioxidant activity: The case study of selected Coprinus Comatus extracts and quinic acid, their antidiabetic ingredient" in Natural Product Research, 35, no. 10 (2021):1711-1716,
https://doi.org/10.1080/14786419.2019.1628753 . .

TY  - JOUR
AU  - Ivanović, Tijana
AU  - Popović, Daniela Z.
AU  - Miladinović, Jelena
AU  - Rard, Joseph A.
AU  - Miladinović, Zoran P.
AU  - Pastor, Ferenc
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1341
AB  - Isopiestic measurements have been made at 55 compositions of the {yK(2)HPO(4) + (1 - y)KH2PO4}(aq) system at T = (298.15 +/- 0.01) K, 11 for each of the limiting binary solutions and 33 for mixture compositions at K2HPO4 stoichiometric ionic strength fractions y = (0.23330, 0.47671, and 0.73177), using KCl(aq) as the reference standard. Model parameters for the binary subsystems were evaluated at this temperature for an extended form of Pitzer's ion-interaction model and also for the Clegg, Pitzer and Brimblecombe model based on the mole-fraction-composition scale, using the present isopiestic results along with critically-assessed osmotic coefficients for both of these aqueous electrolytes as extracted from the published literature. The thermodynamic models for KH2PO4(aq) extend to slightly above the saturated solution molality at T = (298.15 +/- 0.01) K, whereas those for K2HPO4(aq) extend to m = 9.7429 mol.kg(-1), which is the molality of the saturated solution, also at T = (298.15 +/- 0.01) K. These results yield the CODATA-compatible standard Gibbs energy of formation Delta(f)G(m)(o)(K2HPO4 center dot 3H(2)O; cr; 298.15 K) = -(2367.70 +/- 1.60) kJ.mol(-1). The 33 osmotic coefficients for the ternary mixtures were likewise represented with these models, using both the usual Pitzer mixing terms and also Scatchard's neutral-electrolyte model mixing terms for the extended ion-interaction model. Two mixing parameters are needed for each of the three models for {yK(2)HPO(4) + (1 - y)KH2PO4}(aq), and both of these ion-interaction models give similar high-quality representations of the experimental results. However, the Clegg, Pitzer and Brimblecombe model had more difficulty in representing the osmotic coefficients of K2HPO4(aq), especially below 3 mol.kg(-1), and consequently the corresponding mixture model with two mixing parameters is slightly less accurate for representing the osmotic coefficients. The maximum difference in calculated values of the mean molality-based activity coefficients for the two recommended extended Pitzer models with the different types of mixing terms are 0.0061 for the trace activity coefficient of K2HPO4(aq) in KH2PO4(aq) but with much better agreement at most mixture compositions.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Isopiestic determination of the osmotic and activity coefficients of {yK(2)HPO(4) + (1-y)KH2PO4}(aq) at T=298.15 K
VL  - 142
DO  - 10.1016/j.jct.2019.105945
ER  - 

@article{
author = "Ivanović, Tijana and Popović, Daniela Z. and Miladinović, Jelena and Rard, Joseph A. and Miladinović, Zoran P. and Pastor, Ferenc",
year = "2020",
abstract = "Isopiestic measurements have been made at 55 compositions of the {yK(2)HPO(4) + (1 - y)KH2PO4}(aq) system at T = (298.15 +/- 0.01) K, 11 for each of the limiting binary solutions and 33 for mixture compositions at K2HPO4 stoichiometric ionic strength fractions y = (0.23330, 0.47671, and 0.73177), using KCl(aq) as the reference standard. Model parameters for the binary subsystems were evaluated at this temperature for an extended form of Pitzer's ion-interaction model and also for the Clegg, Pitzer and Brimblecombe model based on the mole-fraction-composition scale, using the present isopiestic results along with critically-assessed osmotic coefficients for both of these aqueous electrolytes as extracted from the published literature. The thermodynamic models for KH2PO4(aq) extend to slightly above the saturated solution molality at T = (298.15 +/- 0.01) K, whereas those for K2HPO4(aq) extend to m = 9.7429 mol.kg(-1), which is the molality of the saturated solution, also at T = (298.15 +/- 0.01) K. These results yield the CODATA-compatible standard Gibbs energy of formation Delta(f)G(m)(o)(K2HPO4 center dot 3H(2)O; cr; 298.15 K) = -(2367.70 +/- 1.60) kJ.mol(-1). The 33 osmotic coefficients for the ternary mixtures were likewise represented with these models, using both the usual Pitzer mixing terms and also Scatchard's neutral-electrolyte model mixing terms for the extended ion-interaction model. Two mixing parameters are needed for each of the three models for {yK(2)HPO(4) + (1 - y)KH2PO4}(aq), and both of these ion-interaction models give similar high-quality representations of the experimental results. However, the Clegg, Pitzer and Brimblecombe model had more difficulty in representing the osmotic coefficients of K2HPO4(aq), especially below 3 mol.kg(-1), and consequently the corresponding mixture model with two mixing parameters is slightly less accurate for representing the osmotic coefficients. The maximum difference in calculated values of the mean molality-based activity coefficients for the two recommended extended Pitzer models with the different types of mixing terms are 0.0061 for the trace activity coefficient of K2HPO4(aq) in KH2PO4(aq) but with much better agreement at most mixture compositions.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Isopiestic determination of the osmotic and activity coefficients of {yK(2)HPO(4) + (1-y)KH2PO4}(aq) at T=298.15 K",
volume = "142",
doi = "10.1016/j.jct.2019.105945"
}

Ivanović, T., Popović, D. Z., Miladinović, J., Rard, J. A., Miladinović, Z. P.,& Pastor, F.. (2020). Isopiestic determination of the osmotic and activity coefficients of {yK(2)HPO(4) + (1-y)KH2PO4}(aq) at T=298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 142.
https://doi.org/10.1016/j.jct.2019.105945

Ivanović T, Popović DZ, Miladinović J, Rard JA, Miladinović ZP, Pastor F. Isopiestic determination of the osmotic and activity coefficients of {yK(2)HPO(4) + (1-y)KH2PO4}(aq) at T=298.15 K. in Journal of Chemical Thermodynamics. 2020;142.
doi:10.1016/j.jct.2019.105945 .

Ivanović, Tijana, Popović, Daniela Z., Miladinović, Jelena, Rard, Joseph A., Miladinović, Zoran P., Pastor, Ferenc, "Isopiestic determination of the osmotic and activity coefficients of {yK(2)HPO(4) + (1-y)KH2PO4}(aq) at T=298.15 K" in Journal of Chemical Thermodynamics, 142 (2020),
https://doi.org/10.1016/j.jct.2019.105945 . .

TY  - JOUR
AU  - Ivanović, Tijana
AU  - Popović, Daniela Z.
AU  - Miladinović, Jelena
AU  - Rard, Joseph A.
AU  - Miladinović, Zoran P.
AU  - Pastor, Ferenc
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1334
AB  - Isopiestic measurements have been made for aqueous solutions of the common sodium cation mixtures of NaH2PO4 and Na2HPO4 at T = 298.15 +/- 0.01 K, at NaH2PO4 ionic strength fractions y = (0, 0.24851, 0.49862, 0.74544, and 1), where the ionic strength fractions were calculated by assuming complete electrolytic dissociation of NaH2PO4 as 1:1 and Na2HPO4 as 2:1 electrolytes; CaCl2(aq) was used as the reference standard solution. Model parameters for an extended form of Pitzer's ion-interaction model and also for the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale were evaluated at T = 298.15 K for both NaH2PO4(aq) and Na2HPO4(aq) using the isopiestic results from this study (17 values each) together with numerous critically assessed osmotic coefficients for both electrolytes taken from the published literature. The thermodynamic models for NaH2PO4(aq) extend to m = 7.5 mol.kg(-1), whereas those for Na2HPO4(aq) extend to m = 2.6050 mol.kg(-1), which is well above the solubility limit for the thermodynamically stable phase Na2HPO4 center dot 12H(2)O(cr). The 51 osmotic coefficients for the ternary mixtures were treated with these two models together with Scatchard's neutral-electrolyte model; one previous set of osmotic coefficient values for {yNaH(2)PO(4) + (1 - y)Na2HPO4}(aq) mixtures was found in the literature [Scharge, T.; et al. J. Chem. Thermodyn. 2015, 80, 172-183], and hence an analysis and comparison were made of our results with theirs.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Isopiestic Determination of Osmotic and Activity Coefficients of the {yNaH(2)PO(4) + (1-y)Na2HPO4}(aq) System at T=298.15 K
EP  - 5153
IS  - 11
SP  - 5137
VL  - 65
DO  - 10.1021/acs.jced.0c00281
ER  - 

@article{
author = "Ivanović, Tijana and Popović, Daniela Z. and Miladinović, Jelena and Rard, Joseph A. and Miladinović, Zoran P. and Pastor, Ferenc",
year = "2020",
abstract = "Isopiestic measurements have been made for aqueous solutions of the common sodium cation mixtures of NaH2PO4 and Na2HPO4 at T = 298.15 +/- 0.01 K, at NaH2PO4 ionic strength fractions y = (0, 0.24851, 0.49862, 0.74544, and 1), where the ionic strength fractions were calculated by assuming complete electrolytic dissociation of NaH2PO4 as 1:1 and Na2HPO4 as 2:1 electrolytes; CaCl2(aq) was used as the reference standard solution. Model parameters for an extended form of Pitzer's ion-interaction model and also for the Clegg-Pitzer-Brimblecombe equations based on the mole-fraction-composition scale were evaluated at T = 298.15 K for both NaH2PO4(aq) and Na2HPO4(aq) using the isopiestic results from this study (17 values each) together with numerous critically assessed osmotic coefficients for both electrolytes taken from the published literature. The thermodynamic models for NaH2PO4(aq) extend to m = 7.5 mol.kg(-1), whereas those for Na2HPO4(aq) extend to m = 2.6050 mol.kg(-1), which is well above the solubility limit for the thermodynamically stable phase Na2HPO4 center dot 12H(2)O(cr). The 51 osmotic coefficients for the ternary mixtures were treated with these two models together with Scatchard's neutral-electrolyte model; one previous set of osmotic coefficient values for {yNaH(2)PO(4) + (1 - y)Na2HPO4}(aq) mixtures was found in the literature [Scharge, T.; et al. J. Chem. Thermodyn. 2015, 80, 172-183], and hence an analysis and comparison were made of our results with theirs.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Isopiestic Determination of Osmotic and Activity Coefficients of the {yNaH(2)PO(4) + (1-y)Na2HPO4}(aq) System at T=298.15 K",
pages = "5153-5137",
number = "11",
volume = "65",
doi = "10.1021/acs.jced.0c00281"
}

Ivanović, T., Popović, D. Z., Miladinović, J., Rard, J. A., Miladinović, Z. P.,& Pastor, F.. (2020). Isopiestic Determination of Osmotic and Activity Coefficients of the {yNaH(2)PO(4) + (1-y)Na2HPO4}(aq) System at T=298.15 K. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 65(11), 5137-5153.
https://doi.org/10.1021/acs.jced.0c00281

Ivanović T, Popović DZ, Miladinović J, Rard JA, Miladinović ZP, Pastor F. Isopiestic Determination of Osmotic and Activity Coefficients of the {yNaH(2)PO(4) + (1-y)Na2HPO4}(aq) System at T=298.15 K. in Journal of Chemical and Engineering Data. 2020;65(11):5137-5153.
doi:10.1021/acs.jced.0c00281 .

Ivanović, Tijana, Popović, Daniela Z., Miladinović, Jelena, Rard, Joseph A., Miladinović, Zoran P., Pastor, Ferenc, "Isopiestic Determination of Osmotic and Activity Coefficients of the {yNaH(2)PO(4) + (1-y)Na2HPO4}(aq) System at T=298.15 K" in Journal of Chemical and Engineering Data, 65, no. 11 (2020):5137-5153,
https://doi.org/10.1021/acs.jced.0c00281 . .

TY  - JOUR
AU  - Janjusević, Ljiljana
AU  - Pejin, Boris
AU  - Kaisarević, Sonja
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Tesanović, Kristina
AU  - Karaman, Maja
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1154
AB  - This study aimed to estimate antiradical, antioxidant (AO) and cytotoxic activities of the fungus Trametes versicolor ethanol fruiting body extract. The extract was found to effectively scavenge both O-2(center dot-) and NO center dot (29.62 and 52.48g/mL, respectively). It also showed a good AO activity in the polarographic HPMC assay (950%/mL). p-Hydroxybenzoic acid may be one of the responsible compounds for the afore-mentioned activities. The same extract also exhibited a concentration-dependent cytotoxicity against MCF-7 and HepG2 tumour cell lines reaching IC50 values of 123.51 and 134.29g/mL, respectively with no cytotoxic activity against normal MRC-5 cells. Gentisic, syringic and protocatechuic acids may be among the bioactive principles for the observed cytotoxicity. Taken all together, T. versicolor ethanol extract can be considered as a promising candidate for development of health promoting food supplement. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Natural Product Research
T1  - Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement
EP  - 967
IS  - 8
SP  - 963
VL  - 32
DO  - 10.1080/14786419.2017.1366484
ER  - 

@article{
author = "Janjusević, Ljiljana and Pejin, Boris and Kaisarević, Sonja and Gorjanović, Stanislava and Pastor, Ferenc and Tesanović, Kristina and Karaman, Maja",
year = "2018",
abstract = "This study aimed to estimate antiradical, antioxidant (AO) and cytotoxic activities of the fungus Trametes versicolor ethanol fruiting body extract. The extract was found to effectively scavenge both O-2(center dot-) and NO center dot (29.62 and 52.48g/mL, respectively). It also showed a good AO activity in the polarographic HPMC assay (950%/mL). p-Hydroxybenzoic acid may be one of the responsible compounds for the afore-mentioned activities. The same extract also exhibited a concentration-dependent cytotoxicity against MCF-7 and HepG2 tumour cell lines reaching IC50 values of 123.51 and 134.29g/mL, respectively with no cytotoxic activity against normal MRC-5 cells. Gentisic, syringic and protocatechuic acids may be among the bioactive principles for the observed cytotoxicity. Taken all together, T. versicolor ethanol extract can be considered as a promising candidate for development of health promoting food supplement. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Natural Product Research",
title = "Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement",
pages = "967-963",
number = "8",
volume = "32",
doi = "10.1080/14786419.2017.1366484"
}

Janjusević, L., Pejin, B., Kaisarević, S., Gorjanović, S., Pastor, F., Tesanović, K.,& Karaman, M.. (2018). Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement. in Natural Product Research
Taylor & Francis Ltd, Abingdon., 32(8), 963-967.
https://doi.org/10.1080/14786419.2017.1366484

Janjusević L, Pejin B, Kaisarević S, Gorjanović S, Pastor F, Tesanović K, Karaman M. Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement. in Natural Product Research. 2018;32(8):963-967.
doi:10.1080/14786419.2017.1366484 .

Janjusević, Ljiljana, Pejin, Boris, Kaisarević, Sonja, Gorjanović, Stanislava, Pastor, Ferenc, Tesanović, Kristina, Karaman, Maja, "Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement" in Natural Product Research, 32, no. 8 (2018):963-967,
https://doi.org/10.1080/14786419.2017.1366484 . .

TY  - JOUR
AU  - Hadzibrahimović, Mirzeta
AU  - Sužnjević, Desanka
AU  - Pastor, Ferenc
AU  - Cvetić-Antić, Tijana
AU  - Žižić, Milan
AU  - Zakrzewska, Joanna
AU  - Zivić, Miroslav
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1064
AB  - The possibility of reduction of vanadate monomer in the mycelium of fungus Phycomyces blakesleeanus was investigated in this study by means of polarography. Control experiments were performed with vanadyl [V(IV)] and vanadate [V(V)] in 10 mM Hepes, pH 7.2. Addition of P. blakesleeanus mycelium resulted in disappearance of all V(IV) polarographic waves recorded in the control. This points to the uptake of all available V(IV) by the mycelium, up to 185 A mu mol/g(FW), and suggests P. blakesleeanus as a potential agent in V(IV) bioremediation. Polarographic measurements of mycelium with low concentrations (0.1-1 mM) of V(V), that only allows the presence of monomer, showed that fungal mycelia removes around 27% of V(V) from the extracellular solution. Uptake was saturated at 104 +/- 2 A mu mol/g(FW) which indicates excellent bioaccumulation capability of P. blakesleeanus. EPR, V-51 NMR and polarographic experiments showed no indications of any measurable extracellular complexation of V(V) monomer with fungal exudates, reduction by the mycelium or adsorption to the cell wall. Therefore, in contrast to vanadium oligomers, vanadate monomer interactions with the mycelium are restricted to its transport into the fungal cell, probably by a phosphate transporter.
PB  - Springer, Dordrecht
T2  - Antonie Van Leeuwenhoek International Journal of General and Molecular Microbiology
T1  - The interactions of vanadate monomer with the mycelium of fungus Phycomyces blakesleeanus: reduction or uptake?
EP  - 373
IS  - 3
SP  - 365
VL  - 110
DO  - 10.1007/s10482-016-0808-0
ER  - 

@article{
author = "Hadzibrahimović, Mirzeta and Sužnjević, Desanka and Pastor, Ferenc and Cvetić-Antić, Tijana and Žižić, Milan and Zakrzewska, Joanna and Zivić, Miroslav",
year = "2017",
abstract = "The possibility of reduction of vanadate monomer in the mycelium of fungus Phycomyces blakesleeanus was investigated in this study by means of polarography. Control experiments were performed with vanadyl [V(IV)] and vanadate [V(V)] in 10 mM Hepes, pH 7.2. Addition of P. blakesleeanus mycelium resulted in disappearance of all V(IV) polarographic waves recorded in the control. This points to the uptake of all available V(IV) by the mycelium, up to 185 A mu mol/g(FW), and suggests P. blakesleeanus as a potential agent in V(IV) bioremediation. Polarographic measurements of mycelium with low concentrations (0.1-1 mM) of V(V), that only allows the presence of monomer, showed that fungal mycelia removes around 27% of V(V) from the extracellular solution. Uptake was saturated at 104 +/- 2 A mu mol/g(FW) which indicates excellent bioaccumulation capability of P. blakesleeanus. EPR, V-51 NMR and polarographic experiments showed no indications of any measurable extracellular complexation of V(V) monomer with fungal exudates, reduction by the mycelium or adsorption to the cell wall. Therefore, in contrast to vanadium oligomers, vanadate monomer interactions with the mycelium are restricted to its transport into the fungal cell, probably by a phosphate transporter.",
publisher = "Springer, Dordrecht",
journal = "Antonie Van Leeuwenhoek International Journal of General and Molecular Microbiology",
title = "The interactions of vanadate monomer with the mycelium of fungus Phycomyces blakesleeanus: reduction or uptake?",
pages = "373-365",
number = "3",
volume = "110",
doi = "10.1007/s10482-016-0808-0"
}

Hadzibrahimović, M., Sužnjević, D., Pastor, F., Cvetić-Antić, T., Žižić, M., Zakrzewska, J.,& Zivić, M.. (2017). The interactions of vanadate monomer with the mycelium of fungus Phycomyces blakesleeanus: reduction or uptake?. in Antonie Van Leeuwenhoek International Journal of General and Molecular Microbiology
Springer, Dordrecht., 110(3), 365-373.
https://doi.org/10.1007/s10482-016-0808-0

Hadzibrahimović M, Sužnjević D, Pastor F, Cvetić-Antić T, Žižić M, Zakrzewska J, Zivić M. The interactions of vanadate monomer with the mycelium of fungus Phycomyces blakesleeanus: reduction or uptake?. in Antonie Van Leeuwenhoek International Journal of General and Molecular Microbiology. 2017;110(3):365-373.
doi:10.1007/s10482-016-0808-0 .

Hadzibrahimović, Mirzeta, Sužnjević, Desanka, Pastor, Ferenc, Cvetić-Antić, Tijana, Žižić, Milan, Zakrzewska, Joanna, Zivić, Miroslav, "The interactions of vanadate monomer with the mycelium of fungus Phycomyces blakesleeanus: reduction or uptake?" in Antonie Van Leeuwenhoek International Journal of General and Molecular Microbiology, 110, no. 3 (2017):365-373,
https://doi.org/10.1007/s10482-016-0808-0 . .

TY  - JOUR
AU  - Gorjanović, Stanislava Z
AU  - Pastor, Ferenc
AU  - Vasic, Radica
AU  - Novaković, Miroslav M
AU  - Simonović, Mladen
AU  - Milić Komić, Sonja
AU  - Sužnjević, Desanka
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/682
AB  - Antioxidant (AO) activity of extracts of hop cones (Serbian domestic varieties) and commercial hop products (Saaz, Spalter, Spalter select, and Magnum pellets) was determined by parallel application of recently developed direct current (DC) polarographic and widely used DPPH assay. Correlations between 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging and total phenolics (TPC) determined by the Folin-Ciocalteu assay (FC) (0.99), and between H2O2 scavenging,: (HPS) and humulone content (H) determined by conductometric method (0.94), total resins (TR) (0.85), and hop storage index (HIS) (-0.90), were found statistically significant at p  lt  0.05 level while complete lack of HPS correlation with TPC and DPPH was observed. To obtain an insight into differences between results of AO assays applied, activity of individual compounds, prevalent hop phenolics, and bitter acids was determined. By far superior HPS activity of humulone was followed by catechin, quercetin, xanthohumol, lupulone, and rutin. In contrast, DPPH scavenging activity of phenolics (quercetin > catechin > rutin > xantohumol) was found substantially higher than activity of bitter acids. According to ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), higher AO activity was ascribed to phenolics, while almost neglecting humulone. Besides reliability, low cost, and an easy-to-handle procedure, an ability to recognize humulone as the major contributor of hop AO activity could allow DC polarographic assay to be applied in analysis of various hop-derived products.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Agricultural and Food Chemistry
T1  - Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds
EP  - 9096
IS  - 38
SP  - 9089
VL  - 61
DO  - 10.1021/jf401718z
ER  - 

@article{
author = "Gorjanović, Stanislava Z and Pastor, Ferenc and Vasic, Radica and Novaković, Miroslav M and Simonović, Mladen and Milić Komić, Sonja and Sužnjević, Desanka",
year = "2013",
abstract = "Antioxidant (AO) activity of extracts of hop cones (Serbian domestic varieties) and commercial hop products (Saaz, Spalter, Spalter select, and Magnum pellets) was determined by parallel application of recently developed direct current (DC) polarographic and widely used DPPH assay. Correlations between 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging and total phenolics (TPC) determined by the Folin-Ciocalteu assay (FC) (0.99), and between H2O2 scavenging,: (HPS) and humulone content (H) determined by conductometric method (0.94), total resins (TR) (0.85), and hop storage index (HIS) (-0.90), were found statistically significant at p  lt  0.05 level while complete lack of HPS correlation with TPC and DPPH was observed. To obtain an insight into differences between results of AO assays applied, activity of individual compounds, prevalent hop phenolics, and bitter acids was determined. By far superior HPS activity of humulone was followed by catechin, quercetin, xanthohumol, lupulone, and rutin. In contrast, DPPH scavenging activity of phenolics (quercetin > catechin > rutin > xantohumol) was found substantially higher than activity of bitter acids. According to ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), higher AO activity was ascribed to phenolics, while almost neglecting humulone. Besides reliability, low cost, and an easy-to-handle procedure, an ability to recognize humulone as the major contributor of hop AO activity could allow DC polarographic assay to be applied in analysis of various hop-derived products.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Agricultural and Food Chemistry",
title = "Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds",
pages = "9096-9089",
number = "38",
volume = "61",
doi = "10.1021/jf401718z"
}

Gorjanović, S. Z., Pastor, F., Vasic, R., Novaković, M. M., Simonović, M., Milić Komić, S.,& Sužnjević, D.. (2013). Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds. in Journal of Agricultural and Food Chemistry
Amer Chemical Soc, Washington., 61(38), 9089-9096.
https://doi.org/10.1021/jf401718z

Gorjanović SZ, Pastor F, Vasic R, Novaković MM, Simonović M, Milić Komić S, Sužnjević D. Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds. in Journal of Agricultural and Food Chemistry. 2013;61(38):9089-9096.
doi:10.1021/jf401718z .

Gorjanović, Stanislava Z, Pastor, Ferenc, Vasic, Radica, Novaković, Miroslav M, Simonović, Mladen, Milić Komić, Sonja, Sužnjević, Desanka, "Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds" in Journal of Agricultural and Food Chemistry, 61, no. 38 (2013):9089-9096,
https://doi.org/10.1021/jf401718z . .

TY  - JOUR
AU  - Milić Komić, Sonja
AU  - Potkonjak, Nebojša I
AU  - Gorjanović, Stanislava Z
AU  - Veljović-Jovanović, Sonja
AU  - Pastor, Ferenc
AU  - Sužnjević, Desanka
PY  - 2011
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/462
AB  - The behavior of chlorogenic acid (CGA) and its interaction with Hg(II), Pb(II), Cu(II), Cd(II) and Zn(II) has been studied using direct current (DC) and differential-pulse polarography (DPP). Adsorptive and kinetic/catalytic anodic waves of CGA have been detected at -0.02 and -0.18 V vs. SCE, respectively; Hg(I)-CGA surface disproportionation has been assumed. Reduction of Hg(II)-ions, added in the buffered solution of CGA (pH 7.5), occurs rather than complexation, while the complex forming ability of CGA towards Pb(II) and Cu(II) has been observed. Stoichiometry 1?:?1 for Pb(II)-CGA, and 1?:?1 and 1?:?2 for Cu(II)-CGA has been established applying Jobs method of continuous variation on DPP data. UV-vis spectrophotometric measurements additionally confirmed the existence and stoichiometry of Cu(II) complexes.
PB  - Wiley-Blackwell, Malden
T2  - Electroanalysis
T1  - A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions
EP  - 2940
IS  - 12
SP  - 2935
VL  - 23
DO  - 10.1002/elan.201100476
ER  - 

@article{
author = "Milić Komić, Sonja and Potkonjak, Nebojša I and Gorjanović, Stanislava Z and Veljović-Jovanović, Sonja and Pastor, Ferenc and Sužnjević, Desanka",
year = "2011",
abstract = "The behavior of chlorogenic acid (CGA) and its interaction with Hg(II), Pb(II), Cu(II), Cd(II) and Zn(II) has been studied using direct current (DC) and differential-pulse polarography (DPP). Adsorptive and kinetic/catalytic anodic waves of CGA have been detected at -0.02 and -0.18 V vs. SCE, respectively; Hg(I)-CGA surface disproportionation has been assumed. Reduction of Hg(II)-ions, added in the buffered solution of CGA (pH 7.5), occurs rather than complexation, while the complex forming ability of CGA towards Pb(II) and Cu(II) has been observed. Stoichiometry 1?:?1 for Pb(II)-CGA, and 1?:?1 and 1?:?2 for Cu(II)-CGA has been established applying Jobs method of continuous variation on DPP data. UV-vis spectrophotometric measurements additionally confirmed the existence and stoichiometry of Cu(II) complexes.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions",
pages = "2940-2935",
number = "12",
volume = "23",
doi = "10.1002/elan.201100476"
}

Milić Komić, S., Potkonjak, N. I., Gorjanović, S. Z., Veljović-Jovanović, S., Pastor, F.,& Sužnjević, D.. (2011). A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions. in Electroanalysis
Wiley-Blackwell, Malden., 23(12), 2935-2940.
https://doi.org/10.1002/elan.201100476

Milić Komić S, Potkonjak NI, Gorjanović SZ, Veljović-Jovanović S, Pastor F, Sužnjević D. A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions. in Electroanalysis. 2011;23(12):2935-2940.
doi:10.1002/elan.201100476 .

Milić Komić, Sonja, Potkonjak, Nebojša I, Gorjanović, Stanislava Z, Veljović-Jovanović, Sonja, Pastor, Ferenc, Sužnjević, Desanka, "A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions" in Electroanalysis, 23, no. 12 (2011):2935-2940,
https://doi.org/10.1002/elan.201100476 . .