Cilense, Mario

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  • Cilense, Mario (11)
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Author's Bibliography

Hydrothermally assisted synthesis of YMnO3

Branković, Zorica; Branković, Goran; Počuča-Nešić, Milica; Marinković Stanojević, Zorica; Žunić, Milan; Luković Golić, Danijela; Tararam, R.; Cilense, Mario; Zaghete, M. A.; Jaglicic, Z.; Jagodic, M.; Varela, JA

(Elsevier Sci Ltd, Oxford, 2015)

TY  - JOUR
AU  - Branković, Zorica
AU  - Branković, Goran
AU  - Počuča-Nešić, Milica
AU  - Marinković Stanojević, Zorica
AU  - Žunić, Milan
AU  - Luković Golić, Danijela
AU  - Tararam, R.
AU  - Cilense, Mario
AU  - Zaghete, M. A.
AU  - Jaglicic, Z.
AU  - Jagodic, M.
AU  - Varela, JA
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/881
AB  - In this work single phase hexagonal YMnO3 powders were prepared starting from Y(CH3COO)(3)center dot xH(2)O, Mn(CH3COO)(2)center dot 4H(2)O, KMnO4 and KOH using methods of conventional (280 degrees C for 6 h) or microwave assisted hydrothermal synthesis (200 degrees C for 2 h) followed by calcination at 1200 degrees C for 2 h. According to FESEM analysis the calcined powders consisted of submicronic YMnO3 particles, which were uniform in shape and size. Ceramic samples were obtained by sintering the as-synthesized powders at 1400 degrees C for 2 h. XRD analysis confirmed the presence of the single phase hexagonal YMnO3. SEM analysis showed a dense and homogeneous microstructure with typical inter- and intra-grain cracks. Magnetic measurements indicated ferrimagnetic properties that were explained by non-stoichiometry of the obtained compound and an excess of manganese that was confirmed by ICP analysis.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Hydrothermally assisted synthesis of YMnO3
EP  - 14298
IS  - 10
SP  - 14293
VL  - 41
DO  - 10.1016/j.ceramint.2015.07.060
ER  - 
@article{
author = "Branković, Zorica and Branković, Goran and Počuča-Nešić, Milica and Marinković Stanojević, Zorica and Žunić, Milan and Luković Golić, Danijela and Tararam, R. and Cilense, Mario and Zaghete, M. A. and Jaglicic, Z. and Jagodic, M. and Varela, JA",
year = "2015",
abstract = "In this work single phase hexagonal YMnO3 powders were prepared starting from Y(CH3COO)(3)center dot xH(2)O, Mn(CH3COO)(2)center dot 4H(2)O, KMnO4 and KOH using methods of conventional (280 degrees C for 6 h) or microwave assisted hydrothermal synthesis (200 degrees C for 2 h) followed by calcination at 1200 degrees C for 2 h. According to FESEM analysis the calcined powders consisted of submicronic YMnO3 particles, which were uniform in shape and size. Ceramic samples were obtained by sintering the as-synthesized powders at 1400 degrees C for 2 h. XRD analysis confirmed the presence of the single phase hexagonal YMnO3. SEM analysis showed a dense and homogeneous microstructure with typical inter- and intra-grain cracks. Magnetic measurements indicated ferrimagnetic properties that were explained by non-stoichiometry of the obtained compound and an excess of manganese that was confirmed by ICP analysis.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Hydrothermally assisted synthesis of YMnO3",
pages = "14298-14293",
number = "10",
volume = "41",
doi = "10.1016/j.ceramint.2015.07.060"
}
Branković, Z., Branković, G., Počuča-Nešić, M., Marinković Stanojević, Z., Žunić, M., Luković Golić, D., Tararam, R., Cilense, M., Zaghete, M. A., Jaglicic, Z., Jagodic, M.,& Varela, J.. (2015). Hydrothermally assisted synthesis of YMnO3. in Ceramics International
Elsevier Sci Ltd, Oxford., 41(10), 14293-14298.
https://doi.org/10.1016/j.ceramint.2015.07.060
Branković Z, Branković G, Počuča-Nešić M, Marinković Stanojević Z, Žunić M, Luković Golić D, Tararam R, Cilense M, Zaghete MA, Jaglicic Z, Jagodic M, Varela J. Hydrothermally assisted synthesis of YMnO3. in Ceramics International. 2015;41(10):14293-14298.
doi:10.1016/j.ceramint.2015.07.060 .
Branković, Zorica, Branković, Goran, Počuča-Nešić, Milica, Marinković Stanojević, Zorica, Žunić, Milan, Luković Golić, Danijela, Tararam, R., Cilense, Mario, Zaghete, M. A., Jaglicic, Z., Jagodic, M., Varela, JA, "Hydrothermally assisted synthesis of YMnO3" in Ceramics International, 41, no. 10 (2015):14293-14298,
https://doi.org/10.1016/j.ceramint.2015.07.060 . .
11
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13

Lead-free BaBi4Ti4O15 ceramics: Effect of synthesis methods on phase formation and electrical properties

Bobić, Jelena; Vijatović Petrović, Mirjana; Ilić, Nikola; Palaimiene, E.; Grigalaitis, R.; Paiva-Santos, C. O.; Cilense, Mario; Stojanović, Biljana D

(Elsevier Sci Ltd, Oxford, 2015)

TY  - JOUR
AU  - Bobić, Jelena
AU  - Vijatović Petrović, Mirjana
AU  - Ilić, Nikola
AU  - Palaimiene, E.
AU  - Grigalaitis, R.
AU  - Paiva-Santos, C. O.
AU  - Cilense, Mario
AU  - Stojanović, Biljana D
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/834
AB  - The processing of ferroelectric BaBi4Ti4O15 (BBT) ceramics from powders prepared by conventional solid state reaction (SSR) and mechanochemical activation (MA) has been investigated. It was shown that MA synthesis reduces the synthesis temperature of BBT powders, leading to smaller particles with reduced anisotropy and consequently to smaller grain size of ceramics. Dielectric properties were investigated in a wide range of temperatures (20-800 degrees C) and frequencies (1.21 kHz to 1 MHz). The relative dielectric permittivity at Curie temperature was higher for solid state obtained ceramics than for the mechanically treated ones. The conductivity of sintered samples was studied, suggesting decreasing of conductivity of BBT-MA in comparison with BBT-SS ceramics. The influence of the grain and the grain boundaries contribution to the dielectric behavior in both ceramics was analyzed through impedance spectroscopy. A well-defined ferroelectric hysteresis loop was obtained for both samples.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Lead-free BaBi4Ti4O15 ceramics: Effect of synthesis methods on phase formation and electrical properties
EP  - 316
IS  - 1
SP  - 309
VL  - 41
DO  - 10.1016/j.ceramint.2014.08.073
ER  - 
@article{
author = "Bobić, Jelena and Vijatović Petrović, Mirjana and Ilić, Nikola and Palaimiene, E. and Grigalaitis, R. and Paiva-Santos, C. O. and Cilense, Mario and Stojanović, Biljana D",
year = "2015",
abstract = "The processing of ferroelectric BaBi4Ti4O15 (BBT) ceramics from powders prepared by conventional solid state reaction (SSR) and mechanochemical activation (MA) has been investigated. It was shown that MA synthesis reduces the synthesis temperature of BBT powders, leading to smaller particles with reduced anisotropy and consequently to smaller grain size of ceramics. Dielectric properties were investigated in a wide range of temperatures (20-800 degrees C) and frequencies (1.21 kHz to 1 MHz). The relative dielectric permittivity at Curie temperature was higher for solid state obtained ceramics than for the mechanically treated ones. The conductivity of sintered samples was studied, suggesting decreasing of conductivity of BBT-MA in comparison with BBT-SS ceramics. The influence of the grain and the grain boundaries contribution to the dielectric behavior in both ceramics was analyzed through impedance spectroscopy. A well-defined ferroelectric hysteresis loop was obtained for both samples.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Lead-free BaBi4Ti4O15 ceramics: Effect of synthesis methods on phase formation and electrical properties",
pages = "316-309",
number = "1",
volume = "41",
doi = "10.1016/j.ceramint.2014.08.073"
}
Bobić, J., Vijatović Petrović, M., Ilić, N., Palaimiene, E., Grigalaitis, R., Paiva-Santos, C. O., Cilense, M.,& Stojanović, B. D.. (2015). Lead-free BaBi4Ti4O15 ceramics: Effect of synthesis methods on phase formation and electrical properties. in Ceramics International
Elsevier Sci Ltd, Oxford., 41(1), 309-316.
https://doi.org/10.1016/j.ceramint.2014.08.073
Bobić J, Vijatović Petrović M, Ilić N, Palaimiene E, Grigalaitis R, Paiva-Santos CO, Cilense M, Stojanović BD. Lead-free BaBi4Ti4O15 ceramics: Effect of synthesis methods on phase formation and electrical properties. in Ceramics International. 2015;41(1):309-316.
doi:10.1016/j.ceramint.2014.08.073 .
Bobić, Jelena, Vijatović Petrović, Mirjana, Ilić, Nikola, Palaimiene, E., Grigalaitis, R., Paiva-Santos, C. O., Cilense, Mario, Stojanović, Biljana D, "Lead-free BaBi4Ti4O15 ceramics: Effect of synthesis methods on phase formation and electrical properties" in Ceramics International, 41, no. 1 (2015):309-316,
https://doi.org/10.1016/j.ceramint.2014.08.073 . .
15
1
14

Stability, characterization and functionality of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta cermet anodes for IT-SOFC application

Žunić, Milan; Branković, Goran; Basoli, Francesco; Cilense, Mario; Longo, Elson; Varela, JA

(Elsevier Science Sa, Lausanne, 2014)

TY  - JOUR
AU  - Žunić, Milan
AU  - Branković, Goran
AU  - Basoli, Francesco
AU  - Cilense, Mario
AU  - Longo, Elson
AU  - Varela, JA
PY  - 2014
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/813
AB  - There are many of properties of anodes based on proton conductors, like microstructure, conductivity and chemical stability, which should be optimized. In this work we were dealing with the influence of niobium on the chemical stability, microstructural and electrical characteristics of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta (NiO-BCNYx) anodes. Four anode substrates NiO-BCNYx of different Nb concentration were prepared using the method of evaporation and decomposition of solutions and suspensions (EDSS). Sintered anode substrates were reduced and their microstructural and electrical properties were examined before and after reduction as a function of the amount of niobium. Chemical stability tests showed strong influence of Nb amount on the chemical stability of anodes in the CO2. Microstructural properties of the anode pellets before and after testing in CO2 were investigated using X-ray diffraction analysis. Electrical properties of anode samples were examined by impedance spectroscopy measurements and the conductivity values of reduced anodes were more than 50 S cm (1) at 600 degrees C confirming percolation through Ni particles. Fuel cells were fabricated with aim to examine the functionality of anodes. During the fuel cell test the cell with Ni-BCNY10 anode achieved the highest performance, demonstrating a peak power density of 164 mW cm (2) at 650 degrees C, which confirmed the functionality of Ni-BCNY anodes.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Stability, characterization and functionality of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta cermet anodes for IT-SOFC application
EP  - 13
SP  - 7
VL  - 609
DO  - 10.1016/j.jallcom.2014.04.175
ER  - 
@article{
author = "Žunić, Milan and Branković, Goran and Basoli, Francesco and Cilense, Mario and Longo, Elson and Varela, JA",
year = "2014",
abstract = "There are many of properties of anodes based on proton conductors, like microstructure, conductivity and chemical stability, which should be optimized. In this work we were dealing with the influence of niobium on the chemical stability, microstructural and electrical characteristics of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta (NiO-BCNYx) anodes. Four anode substrates NiO-BCNYx of different Nb concentration were prepared using the method of evaporation and decomposition of solutions and suspensions (EDSS). Sintered anode substrates were reduced and their microstructural and electrical properties were examined before and after reduction as a function of the amount of niobium. Chemical stability tests showed strong influence of Nb amount on the chemical stability of anodes in the CO2. Microstructural properties of the anode pellets before and after testing in CO2 were investigated using X-ray diffraction analysis. Electrical properties of anode samples were examined by impedance spectroscopy measurements and the conductivity values of reduced anodes were more than 50 S cm (1) at 600 degrees C confirming percolation through Ni particles. Fuel cells were fabricated with aim to examine the functionality of anodes. During the fuel cell test the cell with Ni-BCNY10 anode achieved the highest performance, demonstrating a peak power density of 164 mW cm (2) at 650 degrees C, which confirmed the functionality of Ni-BCNY anodes.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Stability, characterization and functionality of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta cermet anodes for IT-SOFC application",
pages = "13-7",
volume = "609",
doi = "10.1016/j.jallcom.2014.04.175"
}
Žunić, M., Branković, G., Basoli, F., Cilense, M., Longo, E.,& Varela, J.. (2014). Stability, characterization and functionality of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta cermet anodes for IT-SOFC application. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 609, 7-13.
https://doi.org/10.1016/j.jallcom.2014.04.175
Žunić M, Branković G, Basoli F, Cilense M, Longo E, Varela J. Stability, characterization and functionality of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta cermet anodes for IT-SOFC application. in Journal of Alloys and Compounds. 2014;609:7-13.
doi:10.1016/j.jallcom.2014.04.175 .
Žunić, Milan, Branković, Goran, Basoli, Francesco, Cilense, Mario, Longo, Elson, Varela, JA, "Stability, characterization and functionality of proton conducting NiO-BaCe0.85-xNbxY0.15O3-delta cermet anodes for IT-SOFC application" in Journal of Alloys and Compounds, 609 (2014):7-13,
https://doi.org/10.1016/j.jallcom.2014.04.175 . .
4
3
4

Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO-BaCe0.9-xInxY0.1O3-delta cermet anodes for IT-SOFC application

Žunić, Milan; Branković, Goran; Foschini, Cesar Renato; Cilense, Mario; Longo, Elson; Varela, JA

(Elsevier Science Sa, Lausanne, 2013)

TY  - JOUR
AU  - Žunić, Milan
AU  - Branković, Goran
AU  - Foschini, Cesar Renato
AU  - Cilense, Mario
AU  - Longo, Elson
AU  - Varela, JA
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/712
AB  - Optimization of the major properties of anodes based on proton conductors, such as microstructure, conductivity and chemical stability, is yet to be achieved. In this study we investigated the influence of indium on the chemical stability, microstructural and electrical characteristics of proton conducting NiO-BaCe0.9 xInxY0.1O3 delta (NiO-BCIYx) anodes. Four compositions of cermet anode substrates NiO-BCIYx were prepared using the method of evaporation and decomposition of solutions and suspensions (EDSS). Sintered anode substrates were reduced and their microstructural and electrical properties were examined before and after reduction as a function of the amount of indium. Anode substrates tested on chemical stability in the CO2 atmosphere showed high stability compared to anode substrates based on commonly used doped barium cerates. Microstructural properties of the anode pellets before and after testing in CO2 were investigated using X-ray diffraction analysis. Impedance spectroscopy measurements were used for evaluation of electrical properties of the anode pellets and the conductivity values of reduced anodes of more than 14 S cm (1) at 600 degrees C confirmed percolations through Ni particles. Under fuel cell operating conditions, the cell with a Ni-BCIY20 anode achieved the highest performance, demonstrating a peak power density 223 mW/cm(2) at 700 degrees C confirming the functionality of Ni-BCIY anodes.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO-BaCe0.9-xInxY0.1O3-delta cermet anodes for IT-SOFC application
EP  - 260
SP  - 254
VL  - 563
DO  - 10.1016/j.jallcom.2013.02.122
ER  - 
@article{
author = "Žunić, Milan and Branković, Goran and Foschini, Cesar Renato and Cilense, Mario and Longo, Elson and Varela, JA",
year = "2013",
abstract = "Optimization of the major properties of anodes based on proton conductors, such as microstructure, conductivity and chemical stability, is yet to be achieved. In this study we investigated the influence of indium on the chemical stability, microstructural and electrical characteristics of proton conducting NiO-BaCe0.9 xInxY0.1O3 delta (NiO-BCIYx) anodes. Four compositions of cermet anode substrates NiO-BCIYx were prepared using the method of evaporation and decomposition of solutions and suspensions (EDSS). Sintered anode substrates were reduced and their microstructural and electrical properties were examined before and after reduction as a function of the amount of indium. Anode substrates tested on chemical stability in the CO2 atmosphere showed high stability compared to anode substrates based on commonly used doped barium cerates. Microstructural properties of the anode pellets before and after testing in CO2 were investigated using X-ray diffraction analysis. Impedance spectroscopy measurements were used for evaluation of electrical properties of the anode pellets and the conductivity values of reduced anodes of more than 14 S cm (1) at 600 degrees C confirmed percolations through Ni particles. Under fuel cell operating conditions, the cell with a Ni-BCIY20 anode achieved the highest performance, demonstrating a peak power density 223 mW/cm(2) at 700 degrees C confirming the functionality of Ni-BCIY anodes.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO-BaCe0.9-xInxY0.1O3-delta cermet anodes for IT-SOFC application",
pages = "260-254",
volume = "563",
doi = "10.1016/j.jallcom.2013.02.122"
}
Žunić, M., Branković, G., Foschini, C. R., Cilense, M., Longo, E.,& Varela, J.. (2013). Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO-BaCe0.9-xInxY0.1O3-delta cermet anodes for IT-SOFC application. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 563, 254-260.
https://doi.org/10.1016/j.jallcom.2013.02.122
Žunić M, Branković G, Foschini CR, Cilense M, Longo E, Varela J. Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO-BaCe0.9-xInxY0.1O3-delta cermet anodes for IT-SOFC application. in Journal of Alloys and Compounds. 2013;563:254-260.
doi:10.1016/j.jallcom.2013.02.122 .
Žunić, Milan, Branković, Goran, Foschini, Cesar Renato, Cilense, Mario, Longo, Elson, Varela, JA, "Influence of the indium concentration on microstructural and electrical properties of proton conducting NiO-BaCe0.9-xInxY0.1O3-delta cermet anodes for IT-SOFC application" in Journal of Alloys and Compounds, 563 (2013):254-260,
https://doi.org/10.1016/j.jallcom.2013.02.122 . .
8
6
9

High-voltage electrophoretic deposition of preferentially oriented films from multiferroic YMn2O5 nanopowders

Branković, Goran; Branković, Zorica; Sequinel, T; Žunić, Milan; Vuković, Marina; Tasić, Nikola; Marinković, Bojan A; Cilense, Mario; Varela, JA; Longo, Elson

(Elsevier Sci Ltd, Oxford, 2013)

TY  - JOUR
AU  - Branković, Goran
AU  - Branković, Zorica
AU  - Sequinel, T
AU  - Žunić, Milan
AU  - Vuković, Marina
AU  - Tasić, Nikola
AU  - Marinković, Bojan A
AU  - Cilense, Mario
AU  - Varela, JA
AU  - Longo, Elson
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/674
AB  - Processing of the YMn2O5 powder is very challenging, since it decomposes to YMnO3 and Mn3O4 at temperatures close to 1180 degrees C, while samples consolidation commonly demands high temperatures. The main goal of this work is to investigate a possibility to prepare thick films of YMn2O5, since their deposition generally requires significantly lower temperatures. Multiferroic YMn2O5 was synthesized by the hydrothermal method from Y(CH3COO)(3) center dot xH(2)O, Mn(CH3COO)(2) center dot 4H(2)O and KMnO4 precursors. XRD, FE-SEM and TEM analysis showed that the obtained powder was monophasic, with orthorhombic crystal structure and columnar particle shape with mean diameter and length of around 20 and 50 nm, respectively. The obtained powder was suspended in isopropyl alcohol with addition of appropriate binder and deflocculant. This suspension was used for electrophoretic deposition of YMn2O5 thick films under the high-voltage conditions and electric fields ranging from 250 to 2125 V/cm. The films obtained at 1000 V/cm and higher electric fields showed good adhesion, particle packing, homogeneity and very low porosity. It was shown that the deposition in extremely high electric fields (K-C=2125 V/cm) can influence the crystal orientation of the films, resulting in formation of preferentially oriented films.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - High-voltage electrophoretic deposition of preferentially oriented films from multiferroic YMn2O5 nanopowders
EP  - 2068
IS  - 2
SP  - 2065
VL  - 39
DO  - 10.1016/j.ceramint.2012.08.060
ER  - 
@article{
author = "Branković, Goran and Branković, Zorica and Sequinel, T and Žunić, Milan and Vuković, Marina and Tasić, Nikola and Marinković, Bojan A and Cilense, Mario and Varela, JA and Longo, Elson",
year = "2013",
abstract = "Processing of the YMn2O5 powder is very challenging, since it decomposes to YMnO3 and Mn3O4 at temperatures close to 1180 degrees C, while samples consolidation commonly demands high temperatures. The main goal of this work is to investigate a possibility to prepare thick films of YMn2O5, since their deposition generally requires significantly lower temperatures. Multiferroic YMn2O5 was synthesized by the hydrothermal method from Y(CH3COO)(3) center dot xH(2)O, Mn(CH3COO)(2) center dot 4H(2)O and KMnO4 precursors. XRD, FE-SEM and TEM analysis showed that the obtained powder was monophasic, with orthorhombic crystal structure and columnar particle shape with mean diameter and length of around 20 and 50 nm, respectively. The obtained powder was suspended in isopropyl alcohol with addition of appropriate binder and deflocculant. This suspension was used for electrophoretic deposition of YMn2O5 thick films under the high-voltage conditions and electric fields ranging from 250 to 2125 V/cm. The films obtained at 1000 V/cm and higher electric fields showed good adhesion, particle packing, homogeneity and very low porosity. It was shown that the deposition in extremely high electric fields (K-C=2125 V/cm) can influence the crystal orientation of the films, resulting in formation of preferentially oriented films.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "High-voltage electrophoretic deposition of preferentially oriented films from multiferroic YMn2O5 nanopowders",
pages = "2068-2065",
number = "2",
volume = "39",
doi = "10.1016/j.ceramint.2012.08.060"
}
Branković, G., Branković, Z., Sequinel, T., Žunić, M., Vuković, M., Tasić, N., Marinković, B. A., Cilense, M., Varela, J.,& Longo, E.. (2013). High-voltage electrophoretic deposition of preferentially oriented films from multiferroic YMn2O5 nanopowders. in Ceramics International
Elsevier Sci Ltd, Oxford., 39(2), 2065-2068.
https://doi.org/10.1016/j.ceramint.2012.08.060
Branković G, Branković Z, Sequinel T, Žunić M, Vuković M, Tasić N, Marinković BA, Cilense M, Varela J, Longo E. High-voltage electrophoretic deposition of preferentially oriented films from multiferroic YMn2O5 nanopowders. in Ceramics International. 2013;39(2):2065-2068.
doi:10.1016/j.ceramint.2012.08.060 .
Branković, Goran, Branković, Zorica, Sequinel, T, Žunić, Milan, Vuković, Marina, Tasić, Nikola, Marinković, Bojan A, Cilense, Mario, Varela, JA, Longo, Elson, "High-voltage electrophoretic deposition of preferentially oriented films from multiferroic YMn2O5 nanopowders" in Ceramics International, 39, no. 2 (2013):2065-2068,
https://doi.org/10.1016/j.ceramint.2012.08.060 . .
1
1
1

Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis

Bobić, Jelena; Stojanović, Biljana D; Paiva-Santos, C. O.; Živković, L. J.; Vijatović Petrović, Mirjana; Cilense, Mario

(Taylor & Francis Ltd, Abingdon, 2008)

TY  - JOUR
AU  - Bobić, Jelena
AU  - Stojanović, Biljana D
AU  - Paiva-Santos, C. O.
AU  - Živković, L. J.
AU  - Vijatović Petrović, Mirjana
AU  - Cilense, Mario
PY  - 2008
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/278
AB  - Bi4Ti4O15 [BBT], a member of Aurivillius bismuth-based layer-structure perovskites, was prepared from stoichiometric amounts of BaTiO3 [BT] and Bi4Ti3O12 [BIT] obtained via mechanochemical synthesis. Mechanochemical synthesis was performed in air atmosphere in a planetary ball mill. BBT ceramics were sintered at 1100C for 4 h without pre-calcination step within heating rate 10C/min. The formation of phase and crystal structure of BT, BIT and BBT were approved using X-ray analysis. The morphology of obtained powders and microstructure were exhamined using scanning electron microscopy. The electrical properties of sintered samples were carried out.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Ferroelectrics
T1  - Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis
EP  - 391
SP  - 383
VL  - 368
DO  - 10.1080/00150190802368305
ER  - 
@article{
author = "Bobić, Jelena and Stojanović, Biljana D and Paiva-Santos, C. O. and Živković, L. J. and Vijatović Petrović, Mirjana and Cilense, Mario",
year = "2008",
abstract = "Bi4Ti4O15 [BBT], a member of Aurivillius bismuth-based layer-structure perovskites, was prepared from stoichiometric amounts of BaTiO3 [BT] and Bi4Ti3O12 [BIT] obtained via mechanochemical synthesis. Mechanochemical synthesis was performed in air atmosphere in a planetary ball mill. BBT ceramics were sintered at 1100C for 4 h without pre-calcination step within heating rate 10C/min. The formation of phase and crystal structure of BT, BIT and BBT were approved using X-ray analysis. The morphology of obtained powders and microstructure were exhamined using scanning electron microscopy. The electrical properties of sintered samples were carried out.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Ferroelectrics",
title = "Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis",
pages = "391-383",
volume = "368",
doi = "10.1080/00150190802368305"
}
Bobić, J., Stojanović, B. D., Paiva-Santos, C. O., Živković, L. J., Vijatović Petrović, M.,& Cilense, M.. (2008). Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis. in Ferroelectrics
Taylor & Francis Ltd, Abingdon., 368, 383-391.
https://doi.org/10.1080/00150190802368305
Bobić J, Stojanović BD, Paiva-Santos CO, Živković LJ, Vijatović Petrović M, Cilense M. Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis. in Ferroelectrics. 2008;368:383-391.
doi:10.1080/00150190802368305 .
Bobić, Jelena, Stojanović, Biljana D, Paiva-Santos, C. O., Živković, L. J., Vijatović Petrović, Mirjana, Cilense, Mario, "Structure and Properties of Barium Bismuth Titanate Prepared by Mechanochemical Synthesis" in Ferroelectrics, 368 (2008):383-391,
https://doi.org/10.1080/00150190802368305 . .
6
2
6

Barium strontium titanate powders prepared by spray pyrolysis

Branković, Goran; Branković, Zorica; Goes, MS; Paiva-Santos, C. O.; Cilense, Mario; Varela, JA; Longo, Elson

(Elsevier Science Sa, Lausanne, 2005)

TY  - JOUR
AU  - Branković, Goran
AU  - Branković, Zorica
AU  - Goes, MS
AU  - Paiva-Santos, C. O.
AU  - Cilense, Mario
AU  - Varela, JA
AU  - Longo, Elson
PY  - 2005
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/125
AB  - Ultasonic spray pyrolysis (SP) has been investigated for the production of the barium strontium titanate (BST) powders from the polymeric precursors. The processing parameters, such as flux of aerosol and temperature profile inside the furnace, were optimized to obtain single phase BST. The powders were characterized by the methods of X-ray diffraction analysis, SEM, EDS and TEM. The obtained powders were submicronic, consisting of spherical, polycrystalline particles, with internal nanocrystalline structure. Crystallite size of 10 nut, calculated using Rietveld refinement, is in a good agreement with results of HRTEM.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Science and Engineering B-Solid State Materials for Advanced Technology
T1  - Barium strontium titanate powders prepared by spray pyrolysis
EP  - 144
IS  - 2
SP  - 140
VL  - 122
DO  - 10.1016/j.mseb.2005.05.016
ER  - 
@article{
author = "Branković, Goran and Branković, Zorica and Goes, MS and Paiva-Santos, C. O. and Cilense, Mario and Varela, JA and Longo, Elson",
year = "2005",
abstract = "Ultasonic spray pyrolysis (SP) has been investigated for the production of the barium strontium titanate (BST) powders from the polymeric precursors. The processing parameters, such as flux of aerosol and temperature profile inside the furnace, were optimized to obtain single phase BST. The powders were characterized by the methods of X-ray diffraction analysis, SEM, EDS and TEM. The obtained powders were submicronic, consisting of spherical, polycrystalline particles, with internal nanocrystalline structure. Crystallite size of 10 nut, calculated using Rietveld refinement, is in a good agreement with results of HRTEM.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Science and Engineering B-Solid State Materials for Advanced Technology",
title = "Barium strontium titanate powders prepared by spray pyrolysis",
pages = "144-140",
number = "2",
volume = "122",
doi = "10.1016/j.mseb.2005.05.016"
}
Branković, G., Branković, Z., Goes, M., Paiva-Santos, C. O., Cilense, M., Varela, J.,& Longo, E.. (2005). Barium strontium titanate powders prepared by spray pyrolysis. in Materials Science and Engineering B-Solid State Materials for Advanced Technology
Elsevier Science Sa, Lausanne., 122(2), 140-144.
https://doi.org/10.1016/j.mseb.2005.05.016
Branković G, Branković Z, Goes M, Paiva-Santos CO, Cilense M, Varela J, Longo E. Barium strontium titanate powders prepared by spray pyrolysis. in Materials Science and Engineering B-Solid State Materials for Advanced Technology. 2005;122(2):140-144.
doi:10.1016/j.mseb.2005.05.016 .
Branković, Goran, Branković, Zorica, Goes, MS, Paiva-Santos, C. O., Cilense, Mario, Varela, JA, Longo, Elson, "Barium strontium titanate powders prepared by spray pyrolysis" in Materials Science and Engineering B-Solid State Materials for Advanced Technology, 122, no. 2 (2005):140-144,
https://doi.org/10.1016/j.mseb.2005.05.016 . .
30
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35

Mechanochemical synthesis of CaTiO3 from CaCO3-TiO2 mixture

Vukotić, Vesna M; Srećković, Tatjana; Marinković Stanojević, Zorica; Branković, Goran; Cilense, Mario; Arandjelović, D.

(Trans Tech Publications Ltd, 2004)

TY  - JOUR
AU  - Vukotić, Vesna M
AU  - Srećković, Tatjana
AU  - Marinković Stanojević, Zorica
AU  - Branković, Goran
AU  - Cilense, Mario
AU  - Arandjelović, D.
PY  - 2004
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/105
AB  - The synthesis of calcium titanate, CaTiO3, was performed by mechanical activation and thermal treatment. Milling for up to 360 minutes in a planetary ball mill mechanically activated an equimolar mixture of CaCO3 and TiO2 powders. A small amount of mechanically activated mixtures was pressed into briquettes and calcined at 850degreesC for two hours. The effect of mechanical activation on the solid-state reaction was studied using X-ray powder diffraction and differential thermal analysis. The change of morphology and size of powder particles due to milling, were determined by SEM, while BET analysis was used to determine the specific surface area of the powder. The sintering process was followed by a dilatometer during thermal treatment up to 1300degreesC. The main conclusion of the analysis of conducted investigations is that CaTiO3 ceramics can be obtained from an activated mixture at a much lower temperature than reported in the literature owing to acceleration of the chemical reaction and sintering.
PB  - Trans Tech Publications Ltd
T2  - Materials Science Forum
T1  - Mechanochemical synthesis of CaTiO3 from CaCO3-TiO2 mixture
EP  - 434
SP  - 429
VL  - 453-454
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_105
ER  - 
@article{
author = "Vukotić, Vesna M and Srećković, Tatjana and Marinković Stanojević, Zorica and Branković, Goran and Cilense, Mario and Arandjelović, D.",
year = "2004",
abstract = "The synthesis of calcium titanate, CaTiO3, was performed by mechanical activation and thermal treatment. Milling for up to 360 minutes in a planetary ball mill mechanically activated an equimolar mixture of CaCO3 and TiO2 powders. A small amount of mechanically activated mixtures was pressed into briquettes and calcined at 850degreesC for two hours. The effect of mechanical activation on the solid-state reaction was studied using X-ray powder diffraction and differential thermal analysis. The change of morphology and size of powder particles due to milling, were determined by SEM, while BET analysis was used to determine the specific surface area of the powder. The sintering process was followed by a dilatometer during thermal treatment up to 1300degreesC. The main conclusion of the analysis of conducted investigations is that CaTiO3 ceramics can be obtained from an activated mixture at a much lower temperature than reported in the literature owing to acceleration of the chemical reaction and sintering.",
publisher = "Trans Tech Publications Ltd",
journal = "Materials Science Forum",
title = "Mechanochemical synthesis of CaTiO3 from CaCO3-TiO2 mixture",
pages = "434-429",
volume = "453-454",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_105"
}
Vukotić, V. M., Srećković, T., Marinković Stanojević, Z., Branković, G., Cilense, M.,& Arandjelović, D.. (2004). Mechanochemical synthesis of CaTiO3 from CaCO3-TiO2 mixture. in Materials Science Forum
Trans Tech Publications Ltd., 453-454, 429-434.
https://hdl.handle.net/21.15107/rcub_rimsi_105
Vukotić VM, Srećković T, Marinković Stanojević Z, Branković G, Cilense M, Arandjelović D. Mechanochemical synthesis of CaTiO3 from CaCO3-TiO2 mixture. in Materials Science Forum. 2004;453-454:429-434.
https://hdl.handle.net/21.15107/rcub_rimsi_105 .
Vukotić, Vesna M, Srećković, Tatjana, Marinković Stanojević, Zorica, Branković, Goran, Cilense, Mario, Arandjelović, D., "Mechanochemical synthesis of CaTiO3 from CaCO3-TiO2 mixture" in Materials Science Forum, 453-454 (2004):429-434,
https://hdl.handle.net/21.15107/rcub_rimsi_105 .
9

Influence of the common varistor dopants (CoO, Cr2O3 and Nb2O5) on the structural properties of SnO2 ceramics

Branković, Goran; Branković, Zorica; Davolos, MR; Cilense, Mario; Varela, JA

(Elsevier Science Inc, New York, 2004)

TY  - JOUR
AU  - Branković, Goran
AU  - Branković, Zorica
AU  - Davolos, MR
AU  - Cilense, Mario
AU  - Varela, JA
PY  - 2004
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/98
AB  - The influence of dopants commonly used in SnO2 varistor ceramics, such as CoO, Cr2O3 or Nb2O5, on the structural properties of SnO2 was investigated. Several SnO2-based ceramics containing only one of the dopants were prepared and characterized. Spectroscopic investigations [visible, near infrared (IR) and IR region] were performed to obtain information about dopants valence states inside the ceramics, as well as about their influence on electronic structure of the material. Structural properties were investigated by X-ray diffraction analysis and mechanisms of dopant incorporation were proposed. Obtained results were confirmed with results of the electrical measurements. Microstructural changes in doped ceramics were investigated by scanning electron microscopy (SEM) analysis that showed great differences in densities, grain size, and morphology of the SnO2 ceramics depending on type of dopants and their distribution.
PB  - Elsevier Science Inc, New York
T2  - Materials Characterization
T1  - Influence of the common varistor dopants (CoO, Cr2O3 and Nb2O5) on the structural properties of SnO2 ceramics
EP  - 251
IS  - 4-5
SP  - 243
VL  - 52
DO  - 10.1016/j.matchar.2002.11.001
ER  - 
@article{
author = "Branković, Goran and Branković, Zorica and Davolos, MR and Cilense, Mario and Varela, JA",
year = "2004",
abstract = "The influence of dopants commonly used in SnO2 varistor ceramics, such as CoO, Cr2O3 or Nb2O5, on the structural properties of SnO2 was investigated. Several SnO2-based ceramics containing only one of the dopants were prepared and characterized. Spectroscopic investigations [visible, near infrared (IR) and IR region] were performed to obtain information about dopants valence states inside the ceramics, as well as about their influence on electronic structure of the material. Structural properties were investigated by X-ray diffraction analysis and mechanisms of dopant incorporation were proposed. Obtained results were confirmed with results of the electrical measurements. Microstructural changes in doped ceramics were investigated by scanning electron microscopy (SEM) analysis that showed great differences in densities, grain size, and morphology of the SnO2 ceramics depending on type of dopants and their distribution.",
publisher = "Elsevier Science Inc, New York",
journal = "Materials Characterization",
title = "Influence of the common varistor dopants (CoO, Cr2O3 and Nb2O5) on the structural properties of SnO2 ceramics",
pages = "251-243",
number = "4-5",
volume = "52",
doi = "10.1016/j.matchar.2002.11.001"
}
Branković, G., Branković, Z., Davolos, M., Cilense, M.,& Varela, J.. (2004). Influence of the common varistor dopants (CoO, Cr2O3 and Nb2O5) on the structural properties of SnO2 ceramics. in Materials Characterization
Elsevier Science Inc, New York., 52(4-5), 243-251.
https://doi.org/10.1016/j.matchar.2002.11.001
Branković G, Branković Z, Davolos M, Cilense M, Varela J. Influence of the common varistor dopants (CoO, Cr2O3 and Nb2O5) on the structural properties of SnO2 ceramics. in Materials Characterization. 2004;52(4-5):243-251.
doi:10.1016/j.matchar.2002.11.001 .
Branković, Goran, Branković, Zorica, Davolos, MR, Cilense, Mario, Varela, JA, "Influence of the common varistor dopants (CoO, Cr2O3 and Nb2O5) on the structural properties of SnO2 ceramics" in Materials Characterization, 52, no. 4-5 (2004):243-251,
https://doi.org/10.1016/j.matchar.2002.11.001 . .
35
33
38

Pyrosol preparation and structural characterization of SnO2 thin films

Tucić, Aleksandar; Marinković Stanojević, Zorica; Mančić, Lidija T; Cilense, Mario; Milošević, Olivera

(Elsevier Science Sa, Lausanne, 2003)

TY  - JOUR
AU  - Tucić, Aleksandar
AU  - Marinković Stanojević, Zorica
AU  - Mančić, Lidija T
AU  - Cilense, Mario
AU  - Milošević, Olivera
PY  - 2003
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/86
AB  - Polycrystalline tin oxide thin films were prepared from ethanol solution Of SnCl2.H2O (concentrations: 0.05, 0.1, 0.2 and 0.4 mol/dm(3)) at different substrate temperatures ranging from 300 to 450 degreesC. The kinetic deposition processes were studied in terms of various process parameters. The crystal phases, crystalline structure, grain size and surface morphology are revealed in accordance to X-ray diffractometry and scanning electron microscopy (SEM). Texture coefficients (TCs) for (110), (2 0 0), (2 11) and (3 0 1) reflections of the tetragonal SnO2 were calculated. Structural characteristics of deposited films with respect to varying precursor chemistry and substrate temperature are presented and discussed.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Materials Processing Technology
T1  - Pyrosol preparation and structural characterization of SnO2 thin films
EP  - 45
SP  - 41
VL  - 143
DO  - 10.1016/S0924-0136(03)00316-9
ER  - 
@article{
author = "Tucić, Aleksandar and Marinković Stanojević, Zorica and Mančić, Lidija T and Cilense, Mario and Milošević, Olivera",
year = "2003",
abstract = "Polycrystalline tin oxide thin films were prepared from ethanol solution Of SnCl2.H2O (concentrations: 0.05, 0.1, 0.2 and 0.4 mol/dm(3)) at different substrate temperatures ranging from 300 to 450 degreesC. The kinetic deposition processes were studied in terms of various process parameters. The crystal phases, crystalline structure, grain size and surface morphology are revealed in accordance to X-ray diffractometry and scanning electron microscopy (SEM). Texture coefficients (TCs) for (110), (2 0 0), (2 11) and (3 0 1) reflections of the tetragonal SnO2 were calculated. Structural characteristics of deposited films with respect to varying precursor chemistry and substrate temperature are presented and discussed.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Materials Processing Technology",
title = "Pyrosol preparation and structural characterization of SnO2 thin films",
pages = "45-41",
volume = "143",
doi = "10.1016/S0924-0136(03)00316-9"
}
Tucić, A., Marinković Stanojević, Z., Mančić, L. T., Cilense, M.,& Milošević, O.. (2003). Pyrosol preparation and structural characterization of SnO2 thin films. in Journal of Materials Processing Technology
Elsevier Science Sa, Lausanne., 143, 41-45.
https://doi.org/10.1016/S0924-0136(03)00316-9
Tucić A, Marinković Stanojević Z, Mančić LT, Cilense M, Milošević O. Pyrosol preparation and structural characterization of SnO2 thin films. in Journal of Materials Processing Technology. 2003;143:41-45.
doi:10.1016/S0924-0136(03)00316-9 .
Tucić, Aleksandar, Marinković Stanojević, Zorica, Mančić, Lidija T, Cilense, Mario, Milošević, Olivera, "Pyrosol preparation and structural characterization of SnO2 thin films" in Journal of Materials Processing Technology, 143 (2003):41-45,
https://doi.org/10.1016/S0924-0136(03)00316-9 . .
13
13

Mechanochemical synthesis of PZT powders

Branković, Zorica; Branković, Goran; Jovalekic, C; Maniette, Y; Cilense, Mario; Varela, JA

(Elsevier Science Sa, Lausanne, 2003)

TY  - JOUR
AU  - Branković, Zorica
AU  - Branković, Goran
AU  - Jovalekic, C
AU  - Maniette, Y
AU  - Cilense, Mario
AU  - Varela, JA
PY  - 2003
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/84
AB  - PZT ceramic powders were successfully prepared from the mixture of PbO, ZrO2 and TiO2 by mechanochemical synthesis in a planetary ball mill, under different milling conditions. Phase evolution during synthesis was monitored by X-ray diffraction analysis. Intensive milling resulted in formation of the nanocrystalline, perovskite PZT powders after 1 h of milling. This is a significant improvement in comparison to milling conditions reported by other authors. Depending on milling parameters the presence of some other phases, such as unreacted ZrO2, was also detected in some samples. The changes in powder size and morphology due to intensive milling, were determined by SEM and TEM, while BET analysis was used to determine specific surface area of the powders. Conclusions about processes taking place during mechanochemical synthesis of PZT powders were made based on the results of characterization.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing
T1  - Mechanochemical synthesis of PZT powders
EP  - 248
IS  - 1-2
SP  - 243
VL  - 345
DO  - 10.1016/S0921-5093(02)00475-6
ER  - 
@article{
author = "Branković, Zorica and Branković, Goran and Jovalekic, C and Maniette, Y and Cilense, Mario and Varela, JA",
year = "2003",
abstract = "PZT ceramic powders were successfully prepared from the mixture of PbO, ZrO2 and TiO2 by mechanochemical synthesis in a planetary ball mill, under different milling conditions. Phase evolution during synthesis was monitored by X-ray diffraction analysis. Intensive milling resulted in formation of the nanocrystalline, perovskite PZT powders after 1 h of milling. This is a significant improvement in comparison to milling conditions reported by other authors. Depending on milling parameters the presence of some other phases, such as unreacted ZrO2, was also detected in some samples. The changes in powder size and morphology due to intensive milling, were determined by SEM and TEM, while BET analysis was used to determine specific surface area of the powders. Conclusions about processes taking place during mechanochemical synthesis of PZT powders were made based on the results of characterization.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing",
title = "Mechanochemical synthesis of PZT powders",
pages = "248-243",
number = "1-2",
volume = "345",
doi = "10.1016/S0921-5093(02)00475-6"
}
Branković, Z., Branković, G., Jovalekic, C., Maniette, Y., Cilense, M.,& Varela, J.. (2003). Mechanochemical synthesis of PZT powders. in Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing
Elsevier Science Sa, Lausanne., 345(1-2), 243-248.
https://doi.org/10.1016/S0921-5093(02)00475-6
Branković Z, Branković G, Jovalekic C, Maniette Y, Cilense M, Varela J. Mechanochemical synthesis of PZT powders. in Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing. 2003;345(1-2):243-248.
doi:10.1016/S0921-5093(02)00475-6 .
Branković, Zorica, Branković, Goran, Jovalekic, C, Maniette, Y, Cilense, Mario, Varela, JA, "Mechanochemical synthesis of PZT powders" in Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing, 345, no. 1-2 (2003):243-248,
https://doi.org/10.1016/S0921-5093(02)00475-6 . .
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