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The Relationship of Physicochemical Properties to the Antioxidative Activity of Free Amino Acids in Fenton System
dc.creator | Milić Komić, Sonja | |
dc.creator | Bogdanović Pristov, Jelena | |
dc.creator | Mutavdžić, Dragosav | |
dc.creator | Savić, Aleksandar G | |
dc.creator | Spasić, Mihajlo | |
dc.creator | Spasojević, Ivan | |
dc.date.accessioned | 2022-04-05T14:55:15Z | |
dc.date.available | 2022-04-05T14:55:15Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0013-936X | |
dc.identifier.uri | http://rimsi.imsi.bg.ac.rs/handle/123456789/853 | |
dc.description.abstract | Herein we compared antioxidative activities (AA) of 25 free L-amino acids (FAA) against Fenton system-mediated hydroxyl radical (HO center dot) production in aqueous solution, and examined the relation between AA and a set of physicochemical properties. The tank order according -to AA was: Tip > notleucine > Phe, Lett > Ile > His >3,4-dihydrOxyphenylalanine, Arg > Val > Lys, Tyr, Pro > hydtoxyproline > alpha-aminobutyric acid > Gln, Thr, Ser > Glu, Ala, Gly, Asn, Asp. Sulfur-containing FAA generated different secondary reactive products, which were discriminated by the means of electron paramagnetic resonance spin-trapping spectroscopy. AA showed a general positive correlation with hydrophobicity. However, when taken separately, uncharged FAA exhibited strong positive correlation of AA with hydrophobicity whereas charged FAA showed negative or no significant correlation depending on the scale applied. A general strong negative correlation was found between AA and polarity. Steric parameters and hydration numbers correlated positively with AA of rtoripolar side-chain FAA. In addition) a decrease of temperature which promotes hydrophobic hydration resulted in increased AA. This implies that HO-provoked oxidation of FAA is strongly affected by hydrophobic hydration. Our findings are important for the understanding of oxidation processes in natural and waste waters. | en |
dc.publisher | Amer Chemical Soc, Washington | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173017/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43010/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173014/RS// | |
dc.rights | restrictedAccess | |
dc.source | Environmental Science & Technology | |
dc.subject | Electron paramagnetic resonance spectroscopy / Hydration / Hydrophobicity / Monomers / Peptides and proteins | |
dc.title | The Relationship of Physicochemical Properties to the Antioxidative Activity of Free Amino Acids in Fenton System | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 4254 | |
dc.citation.issue | 7 | |
dc.citation.other | 49(7): 4245-4254 | |
dc.citation.rank | aM21 | |
dc.citation.spage | 4245 | |
dc.citation.volume | 49 | |
dc.identifier.doi | 10.1021/es5053396 | |
dc.identifier.pmid | 25764263 | |
dc.identifier.scopus | 2-s2.0-84926443752 | |
dc.identifier.wos | 000352659000030 | |
dc.type.version | publishedVersion |