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2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
dc.creator | Ristic, Predrag | |
dc.creator | Filipović, Nenad | |
dc.creator | Blagojević, Vladimir | |
dc.creator | Ćirković, Jovana | |
dc.creator | Hollo, Berta Barta | |
dc.creator | Dokic, Veljko R. | |
dc.creator | Donnard, Morgan | |
dc.creator | Gulea, Mihaela | |
dc.creator | Marjanović, Ivana | |
dc.creator | Klisuric, Olivera R. | |
dc.creator | Todorović, Tamara R. | |
dc.date.accessioned | 2022-04-05T15:35:58Z | |
dc.date.available | 2022-04-05T15:35:58Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 1466-8033 | |
dc.identifier.uri | http://rimsi.imsi.bg.ac.rs/handle/123456789/1461 | |
dc.description.abstract | Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound 4, which can be correlated to its largest lattice volume. | en |
dc.publisher | Royal Soc Chemistry, Cambridge | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200168/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200116/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200175/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200125/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS// | |
dc.rights | restrictedAccess | |
dc.source | Crystengcomm | |
dc.subject | coordination Polymers | |
dc.subject | X-ray Diffraction | |
dc.subject | Thermal Properties | |
dc.subject | photocatalysis | |
dc.title | 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 4815 | |
dc.citation.issue | 27 | |
dc.citation.other | 23(27): 4799-4815 | |
dc.citation.rank | M21~ | |
dc.citation.spage | 4799 | |
dc.citation.volume | 23 | |
dc.identifier.doi | 10.1039/d1ce00394a | |
dc.identifier.scopus | 2-s2.0-85110010702 | |
dc.identifier.wos | 000664682100001 | |
dc.type.version | publishedVersion |