2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
Само за регистроване кориснике
2021
Аутори
Ristic, PredragFilipović, Nenad
Blagojević, Vladimir
Ćirković, Jovana
Hollo, Berta Barta
Dokic, Veljko R.
Donnard, Morgan
Gulea, Mihaela
Marjanović, Ivana
Klisuric, Olivera R.
Todorović, Tamara R.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound ...4, which can be correlated to its largest lattice volume.
Кључне речи:
coordination Polymers / X-ray Diffraction / Thermal Properties / photocatalysisИзвор:
Crystengcomm, 2021, 23, 27, 4799-4815Издавач:
- Royal Soc Chemistry, Cambridge
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200175 (Институт техничких наука САНУ, Београд) (RS-MESTD-inst-2020-200175)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200125 (Универзитет у Новом Саду, Природно-математички факултет) (RS-MESTD-inst-2020-200125)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
DOI: 10.1039/d1ce00394a
ISSN: 1466-8033
WoS: 000664682100001
Scopus: 2-s2.0-85110010702
Институција/група
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Ristic, Predrag AU - Filipović, Nenad AU - Blagojević, Vladimir AU - Ćirković, Jovana AU - Hollo, Berta Barta AU - Dokic, Veljko R. AU - Donnard, Morgan AU - Gulea, Mihaela AU - Marjanović, Ivana AU - Klisuric, Olivera R. AU - Todorović, Tamara R. PY - 2021 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1461 AB - Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound 4, which can be correlated to its largest lattice volume. PB - Royal Soc Chemistry, Cambridge T2 - Crystengcomm T1 - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior EP - 4815 IS - 27 SP - 4799 VL - 23 DO - 10.1039/d1ce00394a ER -
@article{ author = "Ristic, Predrag and Filipović, Nenad and Blagojević, Vladimir and Ćirković, Jovana and Hollo, Berta Barta and Dokic, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisuric, Olivera R. and Todorović, Tamara R.", year = "2021", abstract = "Four silver-based coordination polymers, {[Ag(L1)(2)]NO3}(infinity) (1), {[Ag(L1)(2)]ClO4}(infinity) (2), {[Ag(L2)(2)]NO3 center dot H2O}(infinity) (3) and {[Ag(L2)(2)]ClO4}(infinity) (4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds 1 and 2 are two-dimensional, while 3 and 4 are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in 1 and 2 have an sql topology, while 3 and 4 exhibit a dia topology. Thermal analysis shows that 3 loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min(-1). The best result was obtained for compound 4, which can be correlated to its largest lattice volume.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Crystengcomm", title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior", pages = "4815-4799", number = "27", volume = "23", doi = "10.1039/d1ce00394a" }
Ristic, P., Filipović, N., Blagojević, V., Ćirković, J., Hollo, B. B., Dokic, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisuric, O. R.,& Todorović, T. R.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in Crystengcomm Royal Soc Chemistry, Cambridge., 23(27), 4799-4815. https://doi.org/10.1039/d1ce00394a
Ristic P, Filipović N, Blagojević V, Ćirković J, Hollo BB, Dokic VR, Donnard M, Gulea M, Marjanović I, Klisuric OR, Todorović TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in Crystengcomm. 2021;23(27):4799-4815. doi:10.1039/d1ce00394a .
Ristic, Predrag, Filipović, Nenad, Blagojević, Vladimir, Ćirković, Jovana, Hollo, Berta Barta, Dokic, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisuric, Olivera R., Todorović, Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in Crystengcomm, 23, no. 27 (2021):4799-4815, https://doi.org/10.1039/d1ce00394a . .