On the azo dyes derived from benzoic and cinnamic acids used as photosensitizers in dye-sensitized solar cells
2019
Autori
Matović, LukaTasić, Nikola
Trisović, Nemanja
Ladarević, Jelena
Vitnik, Vesna
Vitnik, Zeljko
Grgur, Branimir
Mijin, Dušan
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
In order to get a better insight into the relationship between molecular structure and photovoltaic performance, six monoazo dye molecules containing benzoic and cinnamic acid moieties were synthesized and their photovoltaic properties were studied. Three of them have not been previously used in solar cells. Spectroscopic measurements of the investigated compounds coupled with theoretical calculations were performed. Short-circuit current density, open-circuit voltage, and fill-factor were determined. It was found that a larger amount of short-circuit current density will be generated if the HOMO-LUMO energy gap is lower, determined by the stability of the molecule and the electronic effect of the donor moiety. Among both series of synthesized dye molecules, the highest obtained values of short-circuit current density were achieved with (2-hydroxynaphthalene-1-ylazo)benzoic acid and (2-hydroxynaphthalene-1-ylazo)cinnamic acid, and thus they were regarded as promising candidates for app...lication in dye-sensitized solar cells.
Ključne reči:
tautomerism / solvatochromism / short-circuit current / quantum chemical calculation / Dye-sensitized solar cells / azo dyesIzvor:
Turkish Journal of Chemistry, 2019, 43, 4, 1183-1203Izdavač:
- Scientific Technical Research Council Turkey-Tubitak, Ankara
Finansiranje / projekti:
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-Basic Research (BR or ON)-172013)
- Racionalni dizajn i sinteza biološki aktivnih i koordinacionih jedinjenja i funkcionalnih materijala, relevantnih u (bio)nanotehnologiji (RS-MESTD-Basic Research (BR or ON)-172035)
- 0-3D nanostrukture za primenu u elektronici i obnovljivim izvorima energije: sinteza, karakterizacija i procesiranje (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
DOI: 10.3906/kim-1903-76
ISSN: 1300-0527
WoS: 000478961000017
Scopus: 2-s2.0-85071853304
Institucija/grupa
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Matović, Luka AU - Tasić, Nikola AU - Trisović, Nemanja AU - Ladarević, Jelena AU - Vitnik, Vesna AU - Vitnik, Zeljko AU - Grgur, Branimir AU - Mijin, Dušan PY - 2019 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1250 AB - In order to get a better insight into the relationship between molecular structure and photovoltaic performance, six monoazo dye molecules containing benzoic and cinnamic acid moieties were synthesized and their photovoltaic properties were studied. Three of them have not been previously used in solar cells. Spectroscopic measurements of the investigated compounds coupled with theoretical calculations were performed. Short-circuit current density, open-circuit voltage, and fill-factor were determined. It was found that a larger amount of short-circuit current density will be generated if the HOMO-LUMO energy gap is lower, determined by the stability of the molecule and the electronic effect of the donor moiety. Among both series of synthesized dye molecules, the highest obtained values of short-circuit current density were achieved with (2-hydroxynaphthalene-1-ylazo)benzoic acid and (2-hydroxynaphthalene-1-ylazo)cinnamic acid, and thus they were regarded as promising candidates for application in dye-sensitized solar cells. PB - Scientific Technical Research Council Turkey-Tubitak, Ankara T2 - Turkish Journal of Chemistry T1 - On the azo dyes derived from benzoic and cinnamic acids used as photosensitizers in dye-sensitized solar cells EP - 1203 IS - 4 SP - 1183 VL - 43 DO - 10.3906/kim-1903-76 ER -
@article{ author = "Matović, Luka and Tasić, Nikola and Trisović, Nemanja and Ladarević, Jelena and Vitnik, Vesna and Vitnik, Zeljko and Grgur, Branimir and Mijin, Dušan", year = "2019", abstract = "In order to get a better insight into the relationship between molecular structure and photovoltaic performance, six monoazo dye molecules containing benzoic and cinnamic acid moieties were synthesized and their photovoltaic properties were studied. Three of them have not been previously used in solar cells. Spectroscopic measurements of the investigated compounds coupled with theoretical calculations were performed. Short-circuit current density, open-circuit voltage, and fill-factor were determined. It was found that a larger amount of short-circuit current density will be generated if the HOMO-LUMO energy gap is lower, determined by the stability of the molecule and the electronic effect of the donor moiety. Among both series of synthesized dye molecules, the highest obtained values of short-circuit current density were achieved with (2-hydroxynaphthalene-1-ylazo)benzoic acid and (2-hydroxynaphthalene-1-ylazo)cinnamic acid, and thus they were regarded as promising candidates for application in dye-sensitized solar cells.", publisher = "Scientific Technical Research Council Turkey-Tubitak, Ankara", journal = "Turkish Journal of Chemistry", title = "On the azo dyes derived from benzoic and cinnamic acids used as photosensitizers in dye-sensitized solar cells", pages = "1203-1183", number = "4", volume = "43", doi = "10.3906/kim-1903-76" }
Matović, L., Tasić, N., Trisović, N., Ladarević, J., Vitnik, V., Vitnik, Z., Grgur, B.,& Mijin, D.. (2019). On the azo dyes derived from benzoic and cinnamic acids used as photosensitizers in dye-sensitized solar cells. in Turkish Journal of Chemistry Scientific Technical Research Council Turkey-Tubitak, Ankara., 43(4), 1183-1203. https://doi.org/10.3906/kim-1903-76
Matović L, Tasić N, Trisović N, Ladarević J, Vitnik V, Vitnik Z, Grgur B, Mijin D. On the azo dyes derived from benzoic and cinnamic acids used as photosensitizers in dye-sensitized solar cells. in Turkish Journal of Chemistry. 2019;43(4):1183-1203. doi:10.3906/kim-1903-76 .
Matović, Luka, Tasić, Nikola, Trisović, Nemanja, Ladarević, Jelena, Vitnik, Vesna, Vitnik, Zeljko, Grgur, Branimir, Mijin, Dušan, "On the azo dyes derived from benzoic and cinnamic acids used as photosensitizers in dye-sensitized solar cells" in Turkish Journal of Chemistry, 43, no. 4 (2019):1183-1203, https://doi.org/10.3906/kim-1903-76 . .