Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study
2017
Authors
Đorđević, Ivana S.Mitrović, Jelena
Todorović, Tamara R.
Filipović, Nenad R.
Rodic, Marko
Lolic, Aleksandar
Portalone, Gustavo
Zlatović, Mario
Grubisic, Sonja
Article (Published version)
Metadata
Show full item recordAbstract
Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.
Keywords:
X-ray crystal structure / Schiff base / Fukui / DFT / cobalt(III) / antioxidant activitySource:
Journal of the Serbian Chemical Society, 2017, 82, 7-8, 825-839Publisher:
- Srpsko hemijsko društvo, Beograd
Funding / projects:
- Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-MESTD-Basic Research (BR or ON)-172035)
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-MESTD-Basic Research (BR or ON)-172055)
DOI: 10.2298/JSC170412062D
ISSN: 0352-5139
WoS: 000410203200005
Scopus: 2-s2.0-85029451534
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Institution/Community
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Đorđević, Ivana S. AU - Mitrović, Jelena AU - Todorović, Tamara R. AU - Filipović, Nenad R. AU - Rodic, Marko AU - Lolic, Aleksandar AU - Portalone, Gustavo AU - Zlatović, Mario AU - Grubisic, Sonja PY - 2017 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1032 AB - Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated. PB - Srpsko hemijsko društvo, Beograd T2 - Journal of the Serbian Chemical Society T1 - Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study EP - 839 IS - 7-8 SP - 825 VL - 82 DO - 10.2298/JSC170412062D ER -
@article{ author = "Đorđević, Ivana S. and Mitrović, Jelena and Todorović, Tamara R. and Filipović, Nenad R. and Rodic, Marko and Lolic, Aleksandar and Portalone, Gustavo and Zlatović, Mario and Grubisic, Sonja", year = "2017", abstract = "Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.", publisher = "Srpsko hemijsko društvo, Beograd", journal = "Journal of the Serbian Chemical Society", title = "Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study", pages = "839-825", number = "7-8", volume = "82", doi = "10.2298/JSC170412062D" }
Đorđević, I. S., Mitrović, J., Todorović, T. R., Filipović, N. R., Rodic, M., Lolic, A., Portalone, G., Zlatović, M.,& Grubisic, S.. (2017). Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study. in Journal of the Serbian Chemical Society Srpsko hemijsko društvo, Beograd., 82(7-8), 825-839. https://doi.org/10.2298/JSC170412062D
Đorđević IS, Mitrović J, Todorović TR, Filipović NR, Rodic M, Lolic A, Portalone G, Zlatović M, Grubisic S. Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study. in Journal of the Serbian Chemical Society. 2017;82(7-8):825-839. doi:10.2298/JSC170412062D .
Đorđević, Ivana S., Mitrović, Jelena, Todorović, Tamara R., Filipović, Nenad R., Rodic, Marko, Lolic, Aleksandar, Portalone, Gustavo, Zlatović, Mario, Grubisic, Sonja, "Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study" in Journal of the Serbian Chemical Society, 82, no. 7-8 (2017):825-839, https://doi.org/10.2298/JSC170412062D . .