Synthesis procedure and properties of NiFe2O4 – BaTiO3 composites
Аутори
Vijatović Petrović, MirjanaBobić, Jelena
Curecheriu, Lavinia-Petronela
Koruza, Jurij
Stojanović, Biljana
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
NiFe2O4 (NF) powder was prepared by auto combustion method starting from nickel and iron nitrates. After the process of self-ignition, fine precursor powder was thermally treated at 1000 oC for 1h forming the nickel ferrite powder [1]. XRD analysis proved the formation of well crystallized nickel-ferrite cubic spinel structure. Particle size distribution measurements showed the existence of agglomerates. SEM micrographs presented nanometer particles from 100 to 500 nm. DBET calculated from specific surface area was ~ 700 nm and factor of agglomeration of obtained NF powder was ~ 27 %.
Cubic barium titanate (BT) powder was prepared by soft chemical method (modified Pechini process). Spherical particles of around 75 nm were obtained in the BT powder [2].
Composites (NF-BT) with the general formula x NiFe2O4 – (1-x) BaTiO3 (x = 0.2, 0.3, 0.5) powders were prepared by mixing previously obtained powders of nickel ferrite and barium titanate in planetary ball mill for 24h. As a milling m...edium were used tungsten carbide balls and iso-propanol. Powder was pressed and sintered at 1170 oC for 4 h and from X-ray measurements the presence of NF and BT phases was detected. No secondary phases were found. Magnetic measurements of composite materials were carried out and presented in Table 1. Saturation magnetization moment of composite materials decrease with barium titanate amount and the fields at which saturation occur increase with BT content. The coercivity HC (Oe) increases with barium titanate concentration in obtained multiferroic material.
Кључне речи:
NiFe2O4 / auto combustion / modified Pechini process / The coercivity HC / multiferroic materialИзвор:
Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59, 2012Издавач:
- Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59
Финансирање / пројекти:
- Синтеза нанопрахова и процесирање керамике и нанокомпозита са специфичним електричним и магнетним својствима за примену у интегрисаним пасивним компонентама (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45021)
Институција/група
Institut za multidisciplinarna istraživanjaTY - CONF AU - Vijatović Petrović, Mirjana AU - Bobić, Jelena AU - Curecheriu, Lavinia-Petronela AU - Koruza, Jurij AU - Stojanović, Biljana PY - 2012 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/3053 AB - NiFe2O4 (NF) powder was prepared by auto combustion method starting from nickel and iron nitrates. After the process of self-ignition, fine precursor powder was thermally treated at 1000 oC for 1h forming the nickel ferrite powder [1]. XRD analysis proved the formation of well crystallized nickel-ferrite cubic spinel structure. Particle size distribution measurements showed the existence of agglomerates. SEM micrographs presented nanometer particles from 100 to 500 nm. DBET calculated from specific surface area was ~ 700 nm and factor of agglomeration of obtained NF powder was ~ 27 %. Cubic barium titanate (BT) powder was prepared by soft chemical method (modified Pechini process). Spherical particles of around 75 nm were obtained in the BT powder [2]. Composites (NF-BT) with the general formula x NiFe2O4 – (1-x) BaTiO3 (x = 0.2, 0.3, 0.5) powders were prepared by mixing previously obtained powders of nickel ferrite and barium titanate in planetary ball mill for 24h. As a milling medium were used tungsten carbide balls and iso-propanol. Powder was pressed and sintered at 1170 oC for 4 h and from X-ray measurements the presence of NF and BT phases was detected. No secondary phases were found. Magnetic measurements of composite materials were carried out and presented in Table 1. Saturation magnetization moment of composite materials decrease with barium titanate amount and the fields at which saturation occur increase with BT content. The coercivity HC (Oe) increases with barium titanate concentration in obtained multiferroic material. PB - Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59 C3 - Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59 T1 - Synthesis procedure and properties of NiFe2O4 – BaTiO3 composites UR - https://hdl.handle.net/21.15107/rcub_rimsi_3053 ER -
@conference{ author = "Vijatović Petrović, Mirjana and Bobić, Jelena and Curecheriu, Lavinia-Petronela and Koruza, Jurij and Stojanović, Biljana", year = "2012", abstract = "NiFe2O4 (NF) powder was prepared by auto combustion method starting from nickel and iron nitrates. After the process of self-ignition, fine precursor powder was thermally treated at 1000 oC for 1h forming the nickel ferrite powder [1]. XRD analysis proved the formation of well crystallized nickel-ferrite cubic spinel structure. Particle size distribution measurements showed the existence of agglomerates. SEM micrographs presented nanometer particles from 100 to 500 nm. DBET calculated from specific surface area was ~ 700 nm and factor of agglomeration of obtained NF powder was ~ 27 %. Cubic barium titanate (BT) powder was prepared by soft chemical method (modified Pechini process). Spherical particles of around 75 nm were obtained in the BT powder [2]. Composites (NF-BT) with the general formula x NiFe2O4 – (1-x) BaTiO3 (x = 0.2, 0.3, 0.5) powders were prepared by mixing previously obtained powders of nickel ferrite and barium titanate in planetary ball mill for 24h. As a milling medium were used tungsten carbide balls and iso-propanol. Powder was pressed and sintered at 1170 oC for 4 h and from X-ray measurements the presence of NF and BT phases was detected. No secondary phases were found. Magnetic measurements of composite materials were carried out and presented in Table 1. Saturation magnetization moment of composite materials decrease with barium titanate amount and the fields at which saturation occur increase with BT content. The coercivity HC (Oe) increases with barium titanate concentration in obtained multiferroic material.", publisher = "Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59", journal = "Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59", title = "Synthesis procedure and properties of NiFe2O4 – BaTiO3 composites", url = "https://hdl.handle.net/21.15107/rcub_rimsi_3053" }
Vijatović Petrović, M., Bobić, J., Curecheriu, L., Koruza, J.,& Stojanović, B.. (2012). Synthesis procedure and properties of NiFe2O4 – BaTiO3 composites. in Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59 Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59.. https://hdl.handle.net/21.15107/rcub_rimsi_3053
Vijatović Petrović M, Bobić J, Curecheriu L, Koruza J, Stojanović B. Synthesis procedure and properties of NiFe2O4 – BaTiO3 composites. in Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59. 2012;. https://hdl.handle.net/21.15107/rcub_rimsi_3053 .
Vijatović Petrović, Mirjana, Bobić, Jelena, Curecheriu, Lavinia-Petronela, Koruza, Jurij, Stojanović, Biljana, "Synthesis procedure and properties of NiFe2O4 – BaTiO3 composites" in Workshop of the COST MP0904 Action, 24-26 September, 2012, Iasi, Romania, Programme and book of abstracts, p59 (2012), https://hdl.handle.net/21.15107/rcub_rimsi_3053 .