Transformation of Cs-LTA type of zeolite to pollucite phase using hot pressing method
Само за регистроване кориснике
2017
Аутори
Omerasevic, MiaRužić, Jovana
Orlić, Jovana
Baščarević, Zvezdana
Savić-Biserčić, Marjetka
Matović, Ljiljana
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Cesium aluminosilicate phases are of the great interest as possible hosts for Cs immobilization in radioactive waste management. Cs-exchanged form of Na, Ca-LTA type of zeolite (Cs-LTA) was prepared by standard procedure of ion exchange. In order to obtain pollucite this Cs-LTA zeolite was pressurless sintered and hot pressed at certain temperatures. XRD analyses were used to study structural changes of Cs-LTA before and after thermal treatments. Pressurless sintered sample recrystallized into pollucite phase after heat treatment at 1000 °C (3 h) (PLS1000) and hot pressed sample at 750 °C (3 h) using pressure of 35 MPa (HP750), indicating reduced temperature of 250 degrees. HP750 has higher density than PLS1000 which leads to higher value of compressive strength. The HP750 showed better resistance to Cs leaching than the PLS1000. Obtained results of HP750 sample indicate that these ceramic forms, based on pollucite phase, are promising for the permanent immobilization of Cs radionuclid...es.
Кључне речи:
cesium aluminosilicate / radioactive waste managementИзвор:
4th Conference of The Serbian Society for Ceramic Materials, 2017, 68-68Издавач:
- Institute for Multidisciplinary Research, University of Belgrade
Институција/група
Institut za multidisciplinarna istraživanjaTY - CONF AU - Omerasevic, Mia AU - Ružić, Jovana AU - Orlić, Jovana AU - Baščarević, Zvezdana AU - Savić-Biserčić, Marjetka AU - Matović, Ljiljana PY - 2017 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/2981 AB - Cesium aluminosilicate phases are of the great interest as possible hosts for Cs immobilization in radioactive waste management. Cs-exchanged form of Na, Ca-LTA type of zeolite (Cs-LTA) was prepared by standard procedure of ion exchange. In order to obtain pollucite this Cs-LTA zeolite was pressurless sintered and hot pressed at certain temperatures. XRD analyses were used to study structural changes of Cs-LTA before and after thermal treatments. Pressurless sintered sample recrystallized into pollucite phase after heat treatment at 1000 °C (3 h) (PLS1000) and hot pressed sample at 750 °C (3 h) using pressure of 35 MPa (HP750), indicating reduced temperature of 250 degrees. HP750 has higher density than PLS1000 which leads to higher value of compressive strength. The HP750 showed better resistance to Cs leaching than the PLS1000. Obtained results of HP750 sample indicate that these ceramic forms, based on pollucite phase, are promising for the permanent immobilization of Cs radionuclides. PB - Institute for Multidisciplinary Research, University of Belgrade C3 - 4th Conference of The Serbian Society for Ceramic Materials T1 - Transformation of Cs-LTA type of zeolite to pollucite phase using hot pressing method EP - 68 SP - 68 UR - https://hdl.handle.net/21.15107/rcub_rimsi_2981 ER -
@conference{ author = "Omerasevic, Mia and Ružić, Jovana and Orlić, Jovana and Baščarević, Zvezdana and Savić-Biserčić, Marjetka and Matović, Ljiljana", year = "2017", abstract = "Cesium aluminosilicate phases are of the great interest as possible hosts for Cs immobilization in radioactive waste management. Cs-exchanged form of Na, Ca-LTA type of zeolite (Cs-LTA) was prepared by standard procedure of ion exchange. In order to obtain pollucite this Cs-LTA zeolite was pressurless sintered and hot pressed at certain temperatures. XRD analyses were used to study structural changes of Cs-LTA before and after thermal treatments. Pressurless sintered sample recrystallized into pollucite phase after heat treatment at 1000 °C (3 h) (PLS1000) and hot pressed sample at 750 °C (3 h) using pressure of 35 MPa (HP750), indicating reduced temperature of 250 degrees. HP750 has higher density than PLS1000 which leads to higher value of compressive strength. The HP750 showed better resistance to Cs leaching than the PLS1000. Obtained results of HP750 sample indicate that these ceramic forms, based on pollucite phase, are promising for the permanent immobilization of Cs radionuclides.", publisher = "Institute for Multidisciplinary Research, University of Belgrade", journal = "4th Conference of The Serbian Society for Ceramic Materials", title = "Transformation of Cs-LTA type of zeolite to pollucite phase using hot pressing method", pages = "68-68", url = "https://hdl.handle.net/21.15107/rcub_rimsi_2981" }
Omerasevic, M., Ružić, J., Orlić, J., Baščarević, Z., Savić-Biserčić, M.,& Matović, L.. (2017). Transformation of Cs-LTA type of zeolite to pollucite phase using hot pressing method. in 4th Conference of The Serbian Society for Ceramic Materials Institute for Multidisciplinary Research, University of Belgrade., 68-68. https://hdl.handle.net/21.15107/rcub_rimsi_2981
Omerasevic M, Ružić J, Orlić J, Baščarević Z, Savić-Biserčić M, Matović L. Transformation of Cs-LTA type of zeolite to pollucite phase using hot pressing method. in 4th Conference of The Serbian Society for Ceramic Materials. 2017;:68-68. https://hdl.handle.net/21.15107/rcub_rimsi_2981 .
Omerasevic, Mia, Ružić, Jovana, Orlić, Jovana, Baščarević, Zvezdana, Savić-Biserčić, Marjetka, Matović, Ljiljana, "Transformation of Cs-LTA type of zeolite to pollucite phase using hot pressing method" in 4th Conference of The Serbian Society for Ceramic Materials (2017):68-68, https://hdl.handle.net/21.15107/rcub_rimsi_2981 .