Magneto-structural coorelations in chlorido-bridged copper(II) complexes
Magnetno-strukturne korelacije kod bakar(II) kompleksa sa hloridnim ligandima u mostu
Апстракт
A considerable amount of work has been carried out aiming at correlating structures of a large
variety of chlorido-bridged copper(II) complexes and their magnetic properties. Magnetic
properties of such systems depend on the nature of terminal ligands, the coordination geometry
around the copper atoms, and structural distortions from an ideal geometry. Copper(II)
complexes with the condensation derivative of methyl hydrazinoacetate and 2-acetylpyridine
were synthesized and characterized by a single crystal X-ray diffraction. Magnetic properties of
both complexes are discussed based on X-ray structures and SQUID measurements. Magnetostructural
comparisons to structurally similar copper(II) complexes are provided, and a possible
correlation has been established.
Obimna istraživanja su izvršena u cilju korelacije strukture i magnetnih svojstava velikog broja
različitih bakar(II) kompleksa sa hloridnim ligandima u mostu. Magnetna svojstva ovakvih
sistema zavise od prirode terminalnih liganada, koordinacione geometrije oko atoma bakra i
strukturnih distorzija od idealne geometrije. Sintetisana su dva bakar(II) kompleksa sa
kondenzacionim derivatom metilhidrazinoacetata i 2-acetilpiridina koja su okarakterisana
metodom difrakcije X-zraka sa monokristala. Diskutovana su magnetna svojstva kompleksa na
osnovu rezultata rendgenske strukturne analize i magnetnih merenja merenja SQUID tehnikom.
Izvršena su magnetno-strukturna poređenja sa strukturno sličnim bakar(II) kompleksima i
uspostavljena je moguća korelacija između strukture i magnetnih svojstava kompleksa.
Кључне речи:
Cu, complex, magnetic propertiesИзвор:
Fourth Conference of Young Chemists of Serbia, Belgrade, Serbia., 2016, 7-Издавач:
- Serbian Chemical Society
- Serbian Young Chemists' Club
Институција/група
Institut za multidisciplinarna istraživanjaTY - CONF AU - Ristić, Predrag AU - Malešević, Aleksandar AU - Filipović, Nenad AU - Todorović, Tamara PY - 2016 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/2302 AB - A considerable amount of work has been carried out aiming at correlating structures of a large variety of chlorido-bridged copper(II) complexes and their magnetic properties. Magnetic properties of such systems depend on the nature of terminal ligands, the coordination geometry around the copper atoms, and structural distortions from an ideal geometry. Copper(II) complexes with the condensation derivative of methyl hydrazinoacetate and 2-acetylpyridine were synthesized and characterized by a single crystal X-ray diffraction. Magnetic properties of both complexes are discussed based on X-ray structures and SQUID measurements. Magnetostructural comparisons to structurally similar copper(II) complexes are provided, and a possible correlation has been established. AB - Obimna istraživanja su izvršena u cilju korelacije strukture i magnetnih svojstava velikog broja različitih bakar(II) kompleksa sa hloridnim ligandima u mostu. Magnetna svojstva ovakvih sistema zavise od prirode terminalnih liganada, koordinacione geometrije oko atoma bakra i strukturnih distorzija od idealne geometrije. Sintetisana su dva bakar(II) kompleksa sa kondenzacionim derivatom metilhidrazinoacetata i 2-acetilpiridina koja su okarakterisana metodom difrakcije X-zraka sa monokristala. Diskutovana su magnetna svojstva kompleksa na osnovu rezultata rendgenske strukturne analize i magnetnih merenja merenja SQUID tehnikom. Izvršena su magnetno-strukturna poređenja sa strukturno sličnim bakar(II) kompleksima i uspostavljena je moguća korelacija između strukture i magnetnih svojstava kompleksa. PB - Serbian Chemical Society PB - Serbian Young Chemists' Club C3 - Fourth Conference of Young Chemists of Serbia, Belgrade, Serbia. T1 - Magneto-structural coorelations in chlorido-bridged copper(II) complexes T1 - Magnetno-strukturne korelacije kod bakar(II) kompleksa sa hloridnim ligandima u mostu SP - 7 UR - https://hdl.handle.net/21.15107/rcub_rimsi_2302 ER -
@conference{ author = "Ristić, Predrag and Malešević, Aleksandar and Filipović, Nenad and Todorović, Tamara", year = "2016", abstract = "A considerable amount of work has been carried out aiming at correlating structures of a large variety of chlorido-bridged copper(II) complexes and their magnetic properties. Magnetic properties of such systems depend on the nature of terminal ligands, the coordination geometry around the copper atoms, and structural distortions from an ideal geometry. Copper(II) complexes with the condensation derivative of methyl hydrazinoacetate and 2-acetylpyridine were synthesized and characterized by a single crystal X-ray diffraction. Magnetic properties of both complexes are discussed based on X-ray structures and SQUID measurements. Magnetostructural comparisons to structurally similar copper(II) complexes are provided, and a possible correlation has been established., Obimna istraživanja su izvršena u cilju korelacije strukture i magnetnih svojstava velikog broja različitih bakar(II) kompleksa sa hloridnim ligandima u mostu. Magnetna svojstva ovakvih sistema zavise od prirode terminalnih liganada, koordinacione geometrije oko atoma bakra i strukturnih distorzija od idealne geometrije. Sintetisana su dva bakar(II) kompleksa sa kondenzacionim derivatom metilhidrazinoacetata i 2-acetilpiridina koja su okarakterisana metodom difrakcije X-zraka sa monokristala. Diskutovana su magnetna svojstva kompleksa na osnovu rezultata rendgenske strukturne analize i magnetnih merenja merenja SQUID tehnikom. Izvršena su magnetno-strukturna poređenja sa strukturno sličnim bakar(II) kompleksima i uspostavljena je moguća korelacija između strukture i magnetnih svojstava kompleksa.", publisher = "Serbian Chemical Society, Serbian Young Chemists' Club", journal = "Fourth Conference of Young Chemists of Serbia, Belgrade, Serbia.", title = "Magneto-structural coorelations in chlorido-bridged copper(II) complexes, Magnetno-strukturne korelacije kod bakar(II) kompleksa sa hloridnim ligandima u mostu", pages = "7", url = "https://hdl.handle.net/21.15107/rcub_rimsi_2302" }
Ristić, P., Malešević, A., Filipović, N.,& Todorović, T.. (2016). Magneto-structural coorelations in chlorido-bridged copper(II) complexes. in Fourth Conference of Young Chemists of Serbia, Belgrade, Serbia. Serbian Chemical Society., 7. https://hdl.handle.net/21.15107/rcub_rimsi_2302
Ristić P, Malešević A, Filipović N, Todorović T. Magneto-structural coorelations in chlorido-bridged copper(II) complexes. in Fourth Conference of Young Chemists of Serbia, Belgrade, Serbia.. 2016;:7. https://hdl.handle.net/21.15107/rcub_rimsi_2302 .
Ristić, Predrag, Malešević, Aleksandar, Filipović, Nenad, Todorović, Tamara, "Magneto-structural coorelations in chlorido-bridged copper(II) complexes" in Fourth Conference of Young Chemists of Serbia, Belgrade, Serbia. (2016):7, https://hdl.handle.net/21.15107/rcub_rimsi_2302 .