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Effects of Ag+ Ion Doping on UV Radiation Absorption and Luminescence Profiles of Fluorapatite Nanomaterials Obtained by Neutralization Method
dc.creator | Milojkov, D. V. | |
dc.creator | Stanic, Vojislav | |
dc.creator | Dimović, S. D. | |
dc.creator | Mutavdžić, Dragosav | |
dc.creator | Živkovic-Radovanović, V. | |
dc.creator | Janjic, Goran V. | |
dc.creator | Radotić, Ksenija | |
dc.date.accessioned | 2022-04-05T15:20:31Z | |
dc.date.available | 2022-04-05T15:20:31Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 0587-4246 | |
dc.identifier.uri | http://rimsi.imsi.bg.ac.rs/handle/123456789/1230 | |
dc.description.abstract | In the present study we have analyzed effects of Ag+ ions doping on energetic profiles of nanophosphors materials based on fluorapatite crystal system. The UV radiation absorption and luminescence properties of monophase fluorapatite (FAP) and Ag+ doped fluorapatite (AgFAP) nanomaterials obtained by neutralization method were investigated using the photoluminescence spectrophotometry. The excitation-emission profiles of nanomaterials were analyzed statistically by MCR-ALS method and number of fluorophores was extracted. FAP lattice absorbed light at 350 nm in the UVA part of spectrum, and with increasing concentration of Ag+ ions new absorption maximum appeared at 270 nm in the UVC part. Fluorescence of FAP nanoparticles was in violet region of visible part of the spectrum, with a red shift to the green region when Ag+ was doped in lattice. MCR-ALS analyses of fluorescence spectra confirm formation of two maxima, at 484 and 505 nm, as a consequence of Ag+ ions doping in FAP lattice at Cal (4f) sites. The results of quantum chemical calculations showed that an Ag+ ion is stronger bonded to the binding site 1 (-1352.6 kcal/mol) than to the binding site 2 (-1249.0 kcal/mol). Considering that AgFAP1 nanopowder absorbs photons over all part of UV radiation spectrum, this material might be used as potential radiation protective nanomaterial. | en |
dc.publisher | Polish Acad Sciences Inst Physics, Warsaw | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173017/RS// | |
dc.rights | openAccess | |
dc.source | Acta Physica Polonica A | |
dc.subject | nanophosphors materials | |
dc.subject | photoluminescence spectrophotometry | |
dc.subject | excitation-emission profiles | |
dc.subject | multivariate curve resolution-alternating least squares | |
dc.title | Effects of Ag+ Ion Doping on UV Radiation Absorption and Luminescence Profiles of Fluorapatite Nanomaterials Obtained by Neutralization Method | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 91 | |
dc.citation.issue | 1 | |
dc.citation.other | 136(1): 86-91 | |
dc.citation.rank | M23 | |
dc.citation.spage | 86 | |
dc.citation.volume | 136 | |
dc.identifier.doi | 10.12693/APhysPolA.136.86 | |
dc.identifier.fulltext | http://rimsi.imsi.bg.ac.rs/bitstream/id/187/1227.pdf | |
dc.identifier.scopus | 2-s2.0-85074542549 | |
dc.identifier.wos | 000495444100013 | |
dc.type.version | publishedVersion |