Tuning of BiFeO3 multiferroic properties by light doping with Nb
Само за регистроване кориснике
2018
Аутори
Radojković, AleksandarLuković Golić, Danijela
Ćirković, Jovana
Marinković Stanojević, Zorica
Pajić, Damir
Toric, Filip
Dapčević, Aleksandra
Vulić, Predrag
Branković, Zorica
Branković, Goran
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Bulk ceramic samples of BiFeO3 were light doped (up to 1%) with Nb5+ in the place of Fe3+ (B-site doping) and their multiferroic properties were investigated using XRD, SEM, polarization (PMTS) and magnetization (SQUID) techniques. It is shown that even the small percentages of doping can notably change electric and magnetic behavior. Electric conductivity differs by two orders of magnitude between samples doped with 0.2% and 1% Nb. The ferroelectric behavior strongly depended on conduction mechanism, and transition from space-charge-limited current (SCLC) conduction to trap-filled limited (TFL) conduction regime reflected on a change in hysteresis patterns, particularly for the samples with 0.2% and 0.5% Nb. Separation of ZFC-FC magnetization curves occurred for all Nb concentrations and increased with Nb doping. Weak ferromagnetic behavior and the increase of remnant magnetization with Nb concentration was observed from the hysteresis measurements. Coercive field changed drastically ...compared to the pure BiFeO3, namely, the sample with 1% Nb exhibited very high coercive magnetic field of 10 kOe.
Кључне речи:
Magnetic properties C / Ferroelectric properties C / Bismuth ferriteИзвор:
Ceramics International, 2018, 44, 14, 16739-16744Издавач:
- Elsevier Sci Ltd, Oxford
Финансирање / пројекти:
- 0-3D наноструктуре за примену у електроници и обновљивим изворима енергије: синтеза, карактеризација и процесирање (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
- Croatian Science Foundation [UIP-2014-09-8276]
DOI: 10.1016/j.ceramint.2018.06.103
ISSN: 0272-8842
WoS: 000442714100079
Scopus: 2-s2.0-85048728559
Институција/група
Institut za multidisciplinarna istraživanjaTY - JOUR AU - Radojković, Aleksandar AU - Luković Golić, Danijela AU - Ćirković, Jovana AU - Marinković Stanojević, Zorica AU - Pajić, Damir AU - Toric, Filip AU - Dapčević, Aleksandra AU - Vulić, Predrag AU - Branković, Zorica AU - Branković, Goran PY - 2018 UR - http://rimsi.imsi.bg.ac.rs/handle/123456789/1162 AB - Bulk ceramic samples of BiFeO3 were light doped (up to 1%) with Nb5+ in the place of Fe3+ (B-site doping) and their multiferroic properties were investigated using XRD, SEM, polarization (PMTS) and magnetization (SQUID) techniques. It is shown that even the small percentages of doping can notably change electric and magnetic behavior. Electric conductivity differs by two orders of magnitude between samples doped with 0.2% and 1% Nb. The ferroelectric behavior strongly depended on conduction mechanism, and transition from space-charge-limited current (SCLC) conduction to trap-filled limited (TFL) conduction regime reflected on a change in hysteresis patterns, particularly for the samples with 0.2% and 0.5% Nb. Separation of ZFC-FC magnetization curves occurred for all Nb concentrations and increased with Nb doping. Weak ferromagnetic behavior and the increase of remnant magnetization with Nb concentration was observed from the hysteresis measurements. Coercive field changed drastically compared to the pure BiFeO3, namely, the sample with 1% Nb exhibited very high coercive magnetic field of 10 kOe. PB - Elsevier Sci Ltd, Oxford T2 - Ceramics International T1 - Tuning of BiFeO3 multiferroic properties by light doping with Nb EP - 16744 IS - 14 SP - 16739 VL - 44 DO - 10.1016/j.ceramint.2018.06.103 ER -
@article{ author = "Radojković, Aleksandar and Luković Golić, Danijela and Ćirković, Jovana and Marinković Stanojević, Zorica and Pajić, Damir and Toric, Filip and Dapčević, Aleksandra and Vulić, Predrag and Branković, Zorica and Branković, Goran", year = "2018", abstract = "Bulk ceramic samples of BiFeO3 were light doped (up to 1%) with Nb5+ in the place of Fe3+ (B-site doping) and their multiferroic properties were investigated using XRD, SEM, polarization (PMTS) and magnetization (SQUID) techniques. It is shown that even the small percentages of doping can notably change electric and magnetic behavior. Electric conductivity differs by two orders of magnitude between samples doped with 0.2% and 1% Nb. The ferroelectric behavior strongly depended on conduction mechanism, and transition from space-charge-limited current (SCLC) conduction to trap-filled limited (TFL) conduction regime reflected on a change in hysteresis patterns, particularly for the samples with 0.2% and 0.5% Nb. Separation of ZFC-FC magnetization curves occurred for all Nb concentrations and increased with Nb doping. Weak ferromagnetic behavior and the increase of remnant magnetization with Nb concentration was observed from the hysteresis measurements. Coercive field changed drastically compared to the pure BiFeO3, namely, the sample with 1% Nb exhibited very high coercive magnetic field of 10 kOe.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Ceramics International", title = "Tuning of BiFeO3 multiferroic properties by light doping with Nb", pages = "16744-16739", number = "14", volume = "44", doi = "10.1016/j.ceramint.2018.06.103" }
Radojković, A., Luković Golić, D., Ćirković, J., Marinković Stanojević, Z., Pajić, D., Toric, F., Dapčević, A., Vulić, P., Branković, Z.,& Branković, G.. (2018). Tuning of BiFeO3 multiferroic properties by light doping with Nb. in Ceramics International Elsevier Sci Ltd, Oxford., 44(14), 16739-16744. https://doi.org/10.1016/j.ceramint.2018.06.103
Radojković A, Luković Golić D, Ćirković J, Marinković Stanojević Z, Pajić D, Toric F, Dapčević A, Vulić P, Branković Z, Branković G. Tuning of BiFeO3 multiferroic properties by light doping with Nb. in Ceramics International. 2018;44(14):16739-16744. doi:10.1016/j.ceramint.2018.06.103 .
Radojković, Aleksandar, Luković Golić, Danijela, Ćirković, Jovana, Marinković Stanojević, Zorica, Pajić, Damir, Toric, Filip, Dapčević, Aleksandra, Vulić, Predrag, Branković, Zorica, Branković, Goran, "Tuning of BiFeO3 multiferroic properties by light doping with Nb" in Ceramics International, 44, no. 14 (2018):16739-16744, https://doi.org/10.1016/j.ceramint.2018.06.103 . .