Directed synthesis, structure and properties of multifunctional materials

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Directed synthesis, structure and properties of multifunctional materials (en)
Усмерена синтеза, структура и својства мултифункционалних материјала (sr)
Usmerena sinteza, struktura i svojstva multifunkcionalnih materijala (sr_RS)
Authors

Publications

New Electronic Interface Circuits for Humidity Measurement Based on the Current Processing Technique

Petrović, Predrag B.; Nikolić, Maria Vesna; Tatović, Mihajlo

(Sciendo, Warsaw, 2021)

TY  - JOUR
AU  - Petrović, Predrag B.
AU  - Nikolić, Maria Vesna
AU  - Tatović, Mihajlo
PY  - 2021
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1447
AB  - The paper describes a new electronic conditioning circuit based on the current-processing technique for accurate and reliable humidity measurement, without post-processing requirements. Pseudobrookite nanocrystalline (Fe2TiO5) thick film was used as capacitive humidity transducer in the proposed design. The interface integrated circuit was realized in TSMC 0.18 mu m CMOS technology, but commercial devices were used for practical realization. The sensing principle of the sensor was obtained by converting the information on environment humidity into a frequency variable square-wave electric current signal. The proposed solution features high linearity, insensitivity to temperature, as well as low power consumption. The sensor has a linear function with relative humidity in the range of Relative Humidity (RH) 30-90 %, error below 1.5 %, and sensitivity 8.3 x 10(14) Hz/F evaluated over the full range of changes. A fast recovery without the need of any refreshing methods was observed with a change in RH. The total power dissipation of readout circuitry was 1 mW.
PB  - Sciendo, Warsaw
T2  - Measurement Science Review
T1  - New Electronic Interface Circuits for Humidity Measurement Based on the Current Processing Technique
EP  - 10
IS  - 1
SP  - 1
VL  - 21
DO  - 10.2478/msr-2021-0001
ER  - 
@article{
author = "Petrović, Predrag B. and Nikolić, Maria Vesna and Tatović, Mihajlo",
year = "2021",
abstract = "The paper describes a new electronic conditioning circuit based on the current-processing technique for accurate and reliable humidity measurement, without post-processing requirements. Pseudobrookite nanocrystalline (Fe2TiO5) thick film was used as capacitive humidity transducer in the proposed design. The interface integrated circuit was realized in TSMC 0.18 mu m CMOS technology, but commercial devices were used for practical realization. The sensing principle of the sensor was obtained by converting the information on environment humidity into a frequency variable square-wave electric current signal. The proposed solution features high linearity, insensitivity to temperature, as well as low power consumption. The sensor has a linear function with relative humidity in the range of Relative Humidity (RH) 30-90 %, error below 1.5 %, and sensitivity 8.3 x 10(14) Hz/F evaluated over the full range of changes. A fast recovery without the need of any refreshing methods was observed with a change in RH. The total power dissipation of readout circuitry was 1 mW.",
publisher = "Sciendo, Warsaw",
journal = "Measurement Science Review",
title = "New Electronic Interface Circuits for Humidity Measurement Based on the Current Processing Technique",
pages = "10-1",
number = "1",
volume = "21",
doi = "10.2478/msr-2021-0001"
}
Petrović, P. B., Nikolić, M. V.,& Tatović, M.. (2021). New Electronic Interface Circuits for Humidity Measurement Based on the Current Processing Technique. in Measurement Science Review
Sciendo, Warsaw., 21(1), 1-10.
https://doi.org/10.2478/msr-2021-0001
Petrović PB, Nikolić MV, Tatović M. New Electronic Interface Circuits for Humidity Measurement Based on the Current Processing Technique. in Measurement Science Review. 2021;21(1):1-10.
doi:10.2478/msr-2021-0001 .
Petrović, Predrag B., Nikolić, Maria Vesna, Tatović, Mihajlo, "New Electronic Interface Circuits for Humidity Measurement Based on the Current Processing Technique" in Measurement Science Review, 21, no. 1 (2021):1-10,
https://doi.org/10.2478/msr-2021-0001 . .
2
2

Structure and enhanced antimicrobial activity of mechanically activated nano TiO2

Pavlović, Vera P.; Vujančević, Jelena; Masković, Pavle; Ćirković, Jovana; Papan, Jelena M.; Kosanović, Darko; Dramicanin, Miroslav D.; Petrović, Predrag B.; Vlahović, Branislav; Pavlović, Vladimir B

(Wiley, Hoboken, 2019)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Masković, Pavle
AU  - Ćirković, Jovana
AU  - Papan, Jelena M.
AU  - Kosanović, Darko
AU  - Dramicanin, Miroslav D.
AU  - Petrović, Predrag B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1229
AB  - Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (E-g) and, consequently, to investigate changes in the E-g value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.
PB  - Wiley, Hoboken
T2  - Journal of the American Ceramic Society
T1  - Structure and enhanced antimicrobial activity of mechanically activated nano TiO2
EP  - 7745
IS  - 12
SP  - 7735
VL  - 102
DO  - 10.1111/jace.16668
ER  - 
@article{
author = "Pavlović, Vera P. and Vujančević, Jelena and Masković, Pavle and Ćirković, Jovana and Papan, Jelena M. and Kosanović, Darko and Dramicanin, Miroslav D. and Petrović, Predrag B. and Vlahović, Branislav and Pavlović, Vladimir B",
year = "2019",
abstract = "Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (E-g) and, consequently, to investigate changes in the E-g value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.",
publisher = "Wiley, Hoboken",
journal = "Journal of the American Ceramic Society",
title = "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2",
pages = "7745-7735",
number = "12",
volume = "102",
doi = "10.1111/jace.16668"
}
Pavlović, V. P., Vujančević, J., Masković, P., Ćirković, J., Papan, J. M., Kosanović, D., Dramicanin, M. D., Petrović, P. B., Vlahović, B.,& Pavlović, V. B.. (2019). Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society
Wiley, Hoboken., 102(12), 7735-7745.
https://doi.org/10.1111/jace.16668
Pavlović VP, Vujančević J, Masković P, Ćirković J, Papan JM, Kosanović D, Dramicanin MD, Petrović PB, Vlahović B, Pavlović VB. Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society. 2019;102(12):7735-7745.
doi:10.1111/jace.16668 .
Pavlović, Vera P., Vujančević, Jelena, Masković, Pavle, Ćirković, Jovana, Papan, Jelena M., Kosanović, Darko, Dramicanin, Miroslav D., Petrović, Predrag B., Vlahović, Branislav, Pavlović, Vladimir B, "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2" in Journal of the American Ceramic Society, 102, no. 12 (2019):7735-7745,
https://doi.org/10.1111/jace.16668 . .
12
4
12

Polyvinyl alcohol PVA with poly ethylene Glycol PEG added as a binder for the powder compaction

Labus, Nebojša J.; Marković, Smilja; Nikolić, Maria Vesna; Krstić, Jugoslav; Pavlović, Vladimir B

(Belgrade : Serbian Ceramic Society, 2018)

TY  - CONF
AU  - Labus, Nebojša J.
AU  - Marković, Smilja
AU  - Nikolić, Maria Vesna
AU  - Krstić, Jugoslav
AU  - Pavlović, Vladimir B
PY  - 2018
UR  - https://dais.sanu.ac.rs/123456789/4099
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1638
AB  - During the compaction of the powder mixture of ZnO and Mn2O3 (MnCO3) and Fe2O3 compacts were find fragile for further handling. Poly vinyl alcohol PVA was used as a binder in an unusual 20% PVA content. We made as well 2% PVA with 0.6% Poly ethylene glycol PEG and 20% PVA with 6 % PEG. Binder was wrapped over the powder by suspension forming in the polymer water solution and drying afterwards until all water content evaporates. On the these obtained powders employed characterization techniques were: Fourier transformed Infra red FTIR spectra with ATR attenuated total reflection technique as well as differential thermal analysis DTA on the device with low temperature sensitivity and TEM transmition electron microscopy. All binder concentrations gave compacts with good mechanical properties, that can be handled with ease but with adding, a PEG as plasticizer the operating of the anvil and piston were extremely difficult due to friction.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
T1  - Polyvinyl alcohol PVA with poly ethylene Glycol PEG added as a binder for the powder compaction
EP  - 83
SP  - 83
UR  - https://hdl.handle.net/21.15107/rcub_dais_4099
ER  - 
@conference{
author = "Labus, Nebojša J. and Marković, Smilja and Nikolić, Maria Vesna and Krstić, Jugoslav and Pavlović, Vladimir B",
year = "2018",
abstract = "During the compaction of the powder mixture of ZnO and Mn2O3 (MnCO3) and Fe2O3 compacts were find fragile for further handling. Poly vinyl alcohol PVA was used as a binder in an unusual 20% PVA content. We made as well 2% PVA with 0.6% Poly ethylene glycol PEG and 20% PVA with 6 % PEG. Binder was wrapped over the powder by suspension forming in the polymer water solution and drying afterwards until all water content evaporates. On the these obtained powders employed characterization techniques were: Fourier transformed Infra red FTIR spectra with ATR attenuated total reflection technique as well as differential thermal analysis DTA on the device with low temperature sensitivity and TEM transmition electron microscopy. All binder concentrations gave compacts with good mechanical properties, that can be handled with ease but with adding, a PEG as plasticizer the operating of the anvil and piston were extremely difficult due to friction.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018",
title = "Polyvinyl alcohol PVA with poly ethylene Glycol PEG added as a binder for the powder compaction",
pages = "83-83",
url = "https://hdl.handle.net/21.15107/rcub_dais_4099"
}
Labus, N. J., Marković, S., Nikolić, M. V., Krstić, J.,& Pavlović, V. B.. (2018). Polyvinyl alcohol PVA with poly ethylene Glycol PEG added as a binder for the powder compaction. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
Belgrade : Serbian Ceramic Society., 83-83.
https://hdl.handle.net/21.15107/rcub_dais_4099
Labus NJ, Marković S, Nikolić MV, Krstić J, Pavlović VB. Polyvinyl alcohol PVA with poly ethylene Glycol PEG added as a binder for the powder compaction. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018. 2018;:83-83.
https://hdl.handle.net/21.15107/rcub_dais_4099 .
Labus, Nebojša J., Marković, Smilja, Nikolić, Maria Vesna, Krstić, Jugoslav, Pavlović, Vladimir B, "Polyvinyl alcohol PVA with poly ethylene Glycol PEG added as a binder for the powder compaction" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018 (2018):83-83,
https://hdl.handle.net/21.15107/rcub_dais_4099 .

Customizing nanotubular titania for photocatalytic activity

Vujancevic, Jelena; Bjelajac, Andjelika; Ćirković, Jovana; Pavlović, Vera; Horvath, Endre; Forro, Laszlo; Janackovic, Djordje; Pavlović, Vladimir

(Belgrade : Institute of Technical Sciences of SASA, 2018)

TY  - CONF
AU  - Vujancevic, Jelena
AU  - Bjelajac, Andjelika
AU  - Ćirković, Jovana
AU  - Pavlović, Vera
AU  - Horvath, Endre
AU  - Forro, Laszlo
AU  - Janackovic, Djordje
AU  - Pavlović, Vladimir
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/2960
AB  - Semiconductor TiO2 photocatalysis is a heterogeneous catalysis, where the photons of the sun or artificial light source are activating the catalyst that enters in reactions. The targeted real-world applications are in environmental protection and remediation such as wastewater treatment, air purification and decomposition of harmful organic pollutants. In this talk, I present the synthesis of nanotubular, thin TiO2 coatings with altered morphology and crystallinity made by anodization technique. The influence of the anodization parameters and post-synthesis annealing conditions on the photocatalytic methyl orange dye decomposition was assessed. Different morphology, crystallinity and introducing a dopant into lattice increase electron transport and electron lifetime which further improve photocatalytic activity.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia, 2018, 77-77
T1  - Customizing nanotubular titania for photocatalytic activity
SP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_2960
ER  - 
@conference{
author = "Vujancevic, Jelena and Bjelajac, Andjelika and Ćirković, Jovana and Pavlović, Vera and Horvath, Endre and Forro, Laszlo and Janackovic, Djordje and Pavlović, Vladimir",
year = "2018",
abstract = "Semiconductor TiO2 photocatalysis is a heterogeneous catalysis, where the photons of the sun or artificial light source are activating the catalyst that enters in reactions. The targeted real-world applications are in environmental protection and remediation such as wastewater treatment, air purification and decomposition of harmful organic pollutants. In this talk, I present the synthesis of nanotubular, thin TiO2 coatings with altered morphology and crystallinity made by anodization technique. The influence of the anodization parameters and post-synthesis annealing conditions on the photocatalytic methyl orange dye decomposition was assessed. Different morphology, crystallinity and introducing a dopant into lattice increase electron transport and electron lifetime which further improve photocatalytic activity.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia, 2018, 77-77",
title = "Customizing nanotubular titania for photocatalytic activity",
pages = "77",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_2960"
}
Vujancevic, J., Bjelajac, A., Ćirković, J., Pavlović, V., Horvath, E., Forro, L., Janackovic, D.,& Pavlović, V.. (2018). Customizing nanotubular titania for photocatalytic activity. in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia, 2018, 77-77
Belgrade : Institute of Technical Sciences of SASA., 77.
https://hdl.handle.net/21.15107/rcub_rimsi_2960
Vujancevic J, Bjelajac A, Ćirković J, Pavlović V, Horvath E, Forro L, Janackovic D, Pavlović V. Customizing nanotubular titania for photocatalytic activity. in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia, 2018, 77-77. 2018;:77.
https://hdl.handle.net/21.15107/rcub_rimsi_2960 .
Vujancevic, Jelena, Bjelajac, Andjelika, Ćirković, Jovana, Pavlović, Vera, Horvath, Endre, Forro, Laszlo, Janackovic, Djordje, Pavlović, Vladimir, "Customizing nanotubular titania for photocatalytic activity" in Program and the Book of Abstracts / Seventeenth Young Researchers' Conference Materials Sciences and Engineering, December 5-7, 2018, Belgrade, Serbia, 2018, 77-77 (2018):77,
https://hdl.handle.net/21.15107/rcub_rimsi_2960 .

Structure and photocatalytic properties of sintered TiO2 nanotube arrays

Vujančević, Jelena; Bjelajac, Anđelika; Ćirković, Jovana; Pavlović, Vera P.; Horvath, Endre; Forro, Laszlo; Vlahović, Branislav; Mitrić, Miodrag; Janacković, Đorđe; Pavlović, Vladimir B

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2018)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Bjelajac, Anđelika
AU  - Ćirković, Jovana
AU  - Pavlović, Vera P.
AU  - Horvath, Endre
AU  - Forro, Laszlo
AU  - Vlahović, Branislav
AU  - Mitrić, Miodrag
AU  - Janacković, Đorđe
AU  - Pavlović, Vladimir B
PY  - 2018
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1125
AB  - One-dimensional (1D) TiO2 nanotubes perpendicular to the substrate were obtained by electrochemical oxidation of titanium foil in an acid electrolyte. In order to alter the crystallinity and the morphology of films the as-anodized amorphous TiO2 nanotube films were sintered at elevated temperatures. The evolution of the morphology was visualized via scanning electron microscopy (SEM), while the crystalline structure was investigated by Xray diffraction (XRD) and Raman spectroscopy. The chemical composition was studied by Xray photoelectron spectroscopy (XPS). The effects of crystallinity and morphology of TiO2 nanotube (NTs) films on photocatalytic degradation of methyl orange (MO) in an aqueous solution under UV light irradiation were also investigated. The TiO2 nanotubes sintered at 650 degrees C for 30 min had the highest degree of crystallinity and exhibited the best photocatalytic activity among the studied TiO2 nanotube films.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Structure and photocatalytic properties of sintered TiO2 nanotube arrays
EP  - 50
IS  - 1
SP  - 39
VL  - 50
DO  - 10.2298/SOS1801039V
ER  - 
@article{
author = "Vujančević, Jelena and Bjelajac, Anđelika and Ćirković, Jovana and Pavlović, Vera P. and Horvath, Endre and Forro, Laszlo and Vlahović, Branislav and Mitrić, Miodrag and Janacković, Đorđe and Pavlović, Vladimir B",
year = "2018",
abstract = "One-dimensional (1D) TiO2 nanotubes perpendicular to the substrate were obtained by electrochemical oxidation of titanium foil in an acid electrolyte. In order to alter the crystallinity and the morphology of films the as-anodized amorphous TiO2 nanotube films were sintered at elevated temperatures. The evolution of the morphology was visualized via scanning electron microscopy (SEM), while the crystalline structure was investigated by Xray diffraction (XRD) and Raman spectroscopy. The chemical composition was studied by Xray photoelectron spectroscopy (XPS). The effects of crystallinity and morphology of TiO2 nanotube (NTs) films on photocatalytic degradation of methyl orange (MO) in an aqueous solution under UV light irradiation were also investigated. The TiO2 nanotubes sintered at 650 degrees C for 30 min had the highest degree of crystallinity and exhibited the best photocatalytic activity among the studied TiO2 nanotube films.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Structure and photocatalytic properties of sintered TiO2 nanotube arrays",
pages = "50-39",
number = "1",
volume = "50",
doi = "10.2298/SOS1801039V"
}
Vujančević, J., Bjelajac, A., Ćirković, J., Pavlović, V. P., Horvath, E., Forro, L., Vlahović, B., Mitrić, M., Janacković, Đ.,& Pavlović, V. B.. (2018). Structure and photocatalytic properties of sintered TiO2 nanotube arrays. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(1), 39-50.
https://doi.org/10.2298/SOS1801039V
Vujančević J, Bjelajac A, Ćirković J, Pavlović VP, Horvath E, Forro L, Vlahović B, Mitrić M, Janacković Đ, Pavlović VB. Structure and photocatalytic properties of sintered TiO2 nanotube arrays. in Science of Sintering. 2018;50(1):39-50.
doi:10.2298/SOS1801039V .
Vujančević, Jelena, Bjelajac, Anđelika, Ćirković, Jovana, Pavlović, Vera P., Horvath, Endre, Forro, Laszlo, Vlahović, Branislav, Mitrić, Miodrag, Janacković, Đorđe, Pavlović, Vladimir B, "Structure and photocatalytic properties of sintered TiO2 nanotube arrays" in Science of Sintering, 50, no. 1 (2018):39-50,
https://doi.org/10.2298/SOS1801039V . .
8
9
11

Dilatometer as a scientific tool

Labus, Nebojša J.; Pavlović, Vladimir B; Vasiljević, Zorka Z; Nikolić, Maria Vesna

(Belgrade : Serbian Ceramic Society, 2017)

TY  - CONF
AU  - Labus, Nebojša J.
AU  - Pavlović, Vladimir B
AU  - Vasiljević, Zorka Z
AU  - Nikolić, Maria Vesna
PY  - 2017
UR  - https://dais.sanu.ac.rs/123456789/3681
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1637
AB  - Dilatometry is defined as the dimensional change of a solid specimen recorded during temperature schedule. Set of data obtained in such a manner are known as dilatogram. Dilatograms for different sort of materials represent an important trace for deduction of other materials properties than volume. Property parameters directly appointable from the dilatogram graph are: thermal expansion coefficient for the temperature interval, glass transition temperature, phasetransition temperature, sintering shrinkage and sintering temperature for maximal shrinkage rate, crystallization point temperature for amorphous bulk metallic glasses, defect annealing temperature. From dilatometric data we can also calculate more complex values such as the sintering activation energy, deduce sintering kinetic mechanisms, for the phase transition kinetic parameters and phase composition, defect concentration, materials thermal expansion coefficient at a particular temperature, solid state reaction kinetic parameters. Dilatometric devices regarding the construction are divided into contact and non contact ones, for they physically exert force on the specimen or not. Furthermore, contact dilatometric devices can be ascribed due to their construction as vertical and horizontal. This categorization leads to different and changeable contact force on the specimen. Vertical dilatometers usually use higher and temporarily changeable forces applied on the specimen. They can be, with suitable equipment, used for other mechanical properties determination than expansion, such as compressibility, tension or inflection. Non contact devices are divided into interferometric and optical. Interferometric ones use a two laser beams construction where for the length change measuring they count the number of wave lengths that are formed as a path difference between two beams. Optical devices, however, uses monochromatic light projected on the specimen that forms shadow recorded on an optical sensor. Obtained images are then analyzed for the specimen`s dimensional change.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
T1  - Dilatometer as a scientific tool
EP  - 49
SP  - 49
UR  - https://hdl.handle.net/21.15107/rcub_dais_3681
ER  - 
@conference{
author = "Labus, Nebojša J. and Pavlović, Vladimir B and Vasiljević, Zorka Z and Nikolić, Maria Vesna",
year = "2017",
abstract = "Dilatometry is defined as the dimensional change of a solid specimen recorded during temperature schedule. Set of data obtained in such a manner are known as dilatogram. Dilatograms for different sort of materials represent an important trace for deduction of other materials properties than volume. Property parameters directly appointable from the dilatogram graph are: thermal expansion coefficient for the temperature interval, glass transition temperature, phasetransition temperature, sintering shrinkage and sintering temperature for maximal shrinkage rate, crystallization point temperature for amorphous bulk metallic glasses, defect annealing temperature. From dilatometric data we can also calculate more complex values such as the sintering activation energy, deduce sintering kinetic mechanisms, for the phase transition kinetic parameters and phase composition, defect concentration, materials thermal expansion coefficient at a particular temperature, solid state reaction kinetic parameters. Dilatometric devices regarding the construction are divided into contact and non contact ones, for they physically exert force on the specimen or not. Furthermore, contact dilatometric devices can be ascribed due to their construction as vertical and horizontal. This categorization leads to different and changeable contact force on the specimen. Vertical dilatometers usually use higher and temporarily changeable forces applied on the specimen. They can be, with suitable equipment, used for other mechanical properties determination than expansion, such as compressibility, tension or inflection. Non contact devices are divided into interferometric and optical. Interferometric ones use a two laser beams construction where for the length change measuring they count the number of wave lengths that are formed as a path difference between two beams. Optical devices, however, uses monochromatic light projected on the specimen that forms shadow recorded on an optical sensor. Obtained images are then analyzed for the specimen`s dimensional change.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017",
title = "Dilatometer as a scientific tool",
pages = "49-49",
url = "https://hdl.handle.net/21.15107/rcub_dais_3681"
}
Labus, N. J., Pavlović, V. B., Vasiljević, Z. Z.,& Nikolić, M. V.. (2017). Dilatometer as a scientific tool. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
Belgrade : Serbian Ceramic Society., 49-49.
https://hdl.handle.net/21.15107/rcub_dais_3681
Labus NJ, Pavlović VB, Vasiljević ZZ, Nikolić MV. Dilatometer as a scientific tool. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017. 2017;:49-49.
https://hdl.handle.net/21.15107/rcub_dais_3681 .
Labus, Nebojša J., Pavlović, Vladimir B, Vasiljević, Zorka Z, Nikolić, Maria Vesna, "Dilatometer as a scientific tool" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 (2017):49-49,
https://hdl.handle.net/21.15107/rcub_dais_3681 .

Characterisation of Mn0.63Zn0.37Fe2O4 Powders After Intensive Milling and Subsequent Thermal Treatment

Labus, Nebojša J.; Vasiljević, Zorka Z; Aleksić, Obrad; Luković, Miloljub; Marković, Smilja; Pavlović, Vladimir B; Mentus, Slavko; Nikolić, Maria Vesna

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2017)

TY  - JOUR
AU  - Labus, Nebojša J.
AU  - Vasiljević, Zorka Z
AU  - Aleksić, Obrad
AU  - Luković, Miloljub
AU  - Marković, Smilja
AU  - Pavlović, Vladimir B
AU  - Mentus, Slavko
AU  - Nikolić, Maria Vesna
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1102
AB  - Commercial Mn-Zn powder (Mn0.63Zn0.37Fe2O4, 93 wt. % and Fe2O3 7 wt. %) was milled 0.5, 1, 2 and 4 hours in a planetary ball mill. The goal was to observe intensive milling influences on oxidation and reduction processes that will happen during subsequent heating. Powders were characterized with XRD, SEM and particle seizer. Subsequent heating was monitored on TGA/DTA in an air atmosphere. After compaction of the milled powders, sintering was also performed in a dilatometric device. Sintered specimens were characterized micro structurally with SEM on a fresh breakage. Obtained differential TGA diagrams suggest intensive changes during prolonged milling of the oxidation kinetics on heating. Ferrite powders changed with milling as well as with second run heating were characterized to enable determination of the potentially best ratio of milling and heating to be applied to obtain the desired microstructure.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Characterisation of Mn0.63Zn0.37Fe2O4 Powders After Intensive Milling and Subsequent Thermal Treatment
EP  - 467
IS  - 4
SP  - 455
VL  - 49
DO  - 10.2298/SOS1704455L
ER  - 
@article{
author = "Labus, Nebojša J. and Vasiljević, Zorka Z and Aleksić, Obrad and Luković, Miloljub and Marković, Smilja and Pavlović, Vladimir B and Mentus, Slavko and Nikolić, Maria Vesna",
year = "2017",
abstract = "Commercial Mn-Zn powder (Mn0.63Zn0.37Fe2O4, 93 wt. % and Fe2O3 7 wt. %) was milled 0.5, 1, 2 and 4 hours in a planetary ball mill. The goal was to observe intensive milling influences on oxidation and reduction processes that will happen during subsequent heating. Powders were characterized with XRD, SEM and particle seizer. Subsequent heating was monitored on TGA/DTA in an air atmosphere. After compaction of the milled powders, sintering was also performed in a dilatometric device. Sintered specimens were characterized micro structurally with SEM on a fresh breakage. Obtained differential TGA diagrams suggest intensive changes during prolonged milling of the oxidation kinetics on heating. Ferrite powders changed with milling as well as with second run heating were characterized to enable determination of the potentially best ratio of milling and heating to be applied to obtain the desired microstructure.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Characterisation of Mn0.63Zn0.37Fe2O4 Powders After Intensive Milling and Subsequent Thermal Treatment",
pages = "467-455",
number = "4",
volume = "49",
doi = "10.2298/SOS1704455L"
}
Labus, N. J., Vasiljević, Z. Z., Aleksić, O., Luković, M., Marković, S., Pavlović, V. B., Mentus, S.,& Nikolić, M. V.. (2017). Characterisation of Mn0.63Zn0.37Fe2O4 Powders After Intensive Milling and Subsequent Thermal Treatment. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 49(4), 455-467.
https://doi.org/10.2298/SOS1704455L
Labus NJ, Vasiljević ZZ, Aleksić O, Luković M, Marković S, Pavlović VB, Mentus S, Nikolić MV. Characterisation of Mn0.63Zn0.37Fe2O4 Powders After Intensive Milling and Subsequent Thermal Treatment. in Science of Sintering. 2017;49(4):455-467.
doi:10.2298/SOS1704455L .
Labus, Nebojša J., Vasiljević, Zorka Z, Aleksić, Obrad, Luković, Miloljub, Marković, Smilja, Pavlović, Vladimir B, Mentus, Slavko, Nikolić, Maria Vesna, "Characterisation of Mn0.63Zn0.37Fe2O4 Powders After Intensive Milling and Subsequent Thermal Treatment" in Science of Sintering, 49, no. 4 (2017):455-467,
https://doi.org/10.2298/SOS1704455L . .
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Two Step Sintering of ZnTiO3 nanopowder

Labus, Nebojša J.; Vasiljević, Zorka Z; Vasiljević-Radović, Dana; Rakic, Srdan; Nikolić, Maria Vesna

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2017)

TY  - JOUR
AU  - Labus, Nebojša J.
AU  - Vasiljević, Zorka Z
AU  - Vasiljević-Radović, Dana
AU  - Rakic, Srdan
AU  - Nikolić, Maria Vesna
PY  - 2017
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1087
AB  - Metastable nanopowder ZnTiO3 was pressed into cylindrical compacts at 200 MPa. Compacts were treated by conventional heating with isothermal holding at 931 degrees C for 10 minutes, 25 minutes and 40 minutes. ZnTiO3 compacts were also heated with a two-step sintering schedule with maximal 913 degrees C and isothermal holding at 896 degrees C, for approximately the same holding times as the isothermal schedule. Shrinkage during heating was monitored with a dilatometric device, while microstructure was determined with atomic force microscopy. XRD patterns were collected for the most interesting samples. Microstructures of sintered specimens showed differences introduced during the last sintering stage by the two different heating schedules. Goal of the presented work was to discuss the possible sintering mechanisms for the two step sintering schedulle according to the presented results.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Two Step Sintering of ZnTiO3 nanopowder
EP  - 60
IS  - 1
SP  - 51
VL  - 49
DO  - 10.2298/SOS1701051L
ER  - 
@article{
author = "Labus, Nebojša J. and Vasiljević, Zorka Z and Vasiljević-Radović, Dana and Rakic, Srdan and Nikolić, Maria Vesna",
year = "2017",
abstract = "Metastable nanopowder ZnTiO3 was pressed into cylindrical compacts at 200 MPa. Compacts were treated by conventional heating with isothermal holding at 931 degrees C for 10 minutes, 25 minutes and 40 minutes. ZnTiO3 compacts were also heated with a two-step sintering schedule with maximal 913 degrees C and isothermal holding at 896 degrees C, for approximately the same holding times as the isothermal schedule. Shrinkage during heating was monitored with a dilatometric device, while microstructure was determined with atomic force microscopy. XRD patterns were collected for the most interesting samples. Microstructures of sintered specimens showed differences introduced during the last sintering stage by the two different heating schedules. Goal of the presented work was to discuss the possible sintering mechanisms for the two step sintering schedulle according to the presented results.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Two Step Sintering of ZnTiO3 nanopowder",
pages = "60-51",
number = "1",
volume = "49",
doi = "10.2298/SOS1701051L"
}
Labus, N. J., Vasiljević, Z. Z., Vasiljević-Radović, D., Rakic, S.,& Nikolić, M. V.. (2017). Two Step Sintering of ZnTiO3 nanopowder. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 49(1), 51-60.
https://doi.org/10.2298/SOS1701051L
Labus NJ, Vasiljević ZZ, Vasiljević-Radović D, Rakic S, Nikolić MV. Two Step Sintering of ZnTiO3 nanopowder. in Science of Sintering. 2017;49(1):51-60.
doi:10.2298/SOS1701051L .
Labus, Nebojša J., Vasiljević, Zorka Z, Vasiljević-Radović, Dana, Rakic, Srdan, Nikolić, Maria Vesna, "Two Step Sintering of ZnTiO3 nanopowder" in Science of Sintering, 49, no. 1 (2017):51-60,
https://doi.org/10.2298/SOS1701051L . .
1
3
3

Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines

Filipović, Nenad R.; Bjelogrlic, Snežana; Todorović, Tamara R.; Blagojević, Vladimir A.; Muller, Christian D.; Marinković, Aleksandar; Vujcic, Miroslava; Janović, Barbara; Malešević, Aleksandar; Begović, Nebojša; Sencanski, Milan; Minic, Dragica

(Royal Soc Chemistry, Cambridge, 2016)

TY  - JOUR
AU  - Filipović, Nenad R.
AU  - Bjelogrlic, Snežana
AU  - Todorović, Tamara R.
AU  - Blagojević, Vladimir A.
AU  - Muller, Christian D.
AU  - Marinković, Aleksandar
AU  - Vujcic, Miroslava
AU  - Janović, Barbara
AU  - Malešević, Aleksandar
AU  - Begović, Nebojša
AU  - Sencanski, Milan
AU  - Minic, Dragica
PY  - 2016
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/972
AB  - A new Ni(II) complex, [Ni(L)(H2O)] (1), with diethyl 3,3'-(2,2'-(1,1'-(pyridine-2,6-diyl) bis(ethan-1-yl-1-ylidene)) bis(hydrazin-1-yl-2-ylidene)) bis(3-oxopropanoate) ligand (H2L) was synthesized as a potential chemotherapeutic agent. Polidentate ligand was coordinated to Ni(II) NNN-tridentately, in dianionic form, while monodentate water coordination completed square-planar geometry around metal. Structure in the solution was determined by NMR spectroscopy and the same coordination mode was observed in the solid state using IR spectroscopy and further verified by DFT calculations and electrochemical studies. Thermal stability of 1 was determined in both air and nitrogen atmosphere. Anticancer activity of 1 was investigated on acute monocytic leukemia (THP-1) and pancreatic adenocarcinoma (AsPC-1) cell lines. On THP-1 cells 1 induced powerful apoptotic response (ED50 = 10 +/- 3 mu M), which was revealed to be only partially caspase-dependent, with activation of caspase-8 as the dominant course. This suggested that experimentally validated covalent binding of 1 to DNA is not the only mechanism responsible for programmed cell death. This was supported with experiments on AsPC-1 cells. Although treatment of those cells with 1 resulted in poor apoptotic response, cell cycle changes showed concentration-dependent shifts indicating a dual mechanism of activity. This study also reviews the results of preliminary biological screening, which demonstrates that 1 displays a unique pattern of anticancer activity with at least two mechanisms involved.
PB  - Royal Soc Chemistry, Cambridge
T2  - RSC Advances
T1  - Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines
EP  - 108740
IS  - 110
SP  - 108726
VL  - 6
DO  - 10.1039/c6ra24604d
ER  - 
@article{
author = "Filipović, Nenad R. and Bjelogrlic, Snežana and Todorović, Tamara R. and Blagojević, Vladimir A. and Muller, Christian D. and Marinković, Aleksandar and Vujcic, Miroslava and Janović, Barbara and Malešević, Aleksandar and Begović, Nebojša and Sencanski, Milan and Minic, Dragica",
year = "2016",
abstract = "A new Ni(II) complex, [Ni(L)(H2O)] (1), with diethyl 3,3'-(2,2'-(1,1'-(pyridine-2,6-diyl) bis(ethan-1-yl-1-ylidene)) bis(hydrazin-1-yl-2-ylidene)) bis(3-oxopropanoate) ligand (H2L) was synthesized as a potential chemotherapeutic agent. Polidentate ligand was coordinated to Ni(II) NNN-tridentately, in dianionic form, while monodentate water coordination completed square-planar geometry around metal. Structure in the solution was determined by NMR spectroscopy and the same coordination mode was observed in the solid state using IR spectroscopy and further verified by DFT calculations and electrochemical studies. Thermal stability of 1 was determined in both air and nitrogen atmosphere. Anticancer activity of 1 was investigated on acute monocytic leukemia (THP-1) and pancreatic adenocarcinoma (AsPC-1) cell lines. On THP-1 cells 1 induced powerful apoptotic response (ED50 = 10 +/- 3 mu M), which was revealed to be only partially caspase-dependent, with activation of caspase-8 as the dominant course. This suggested that experimentally validated covalent binding of 1 to DNA is not the only mechanism responsible for programmed cell death. This was supported with experiments on AsPC-1 cells. Although treatment of those cells with 1 resulted in poor apoptotic response, cell cycle changes showed concentration-dependent shifts indicating a dual mechanism of activity. This study also reviews the results of preliminary biological screening, which demonstrates that 1 displays a unique pattern of anticancer activity with at least two mechanisms involved.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "RSC Advances",
title = "Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines",
pages = "108740-108726",
number = "110",
volume = "6",
doi = "10.1039/c6ra24604d"
}
Filipović, N. R., Bjelogrlic, S., Todorović, T. R., Blagojević, V. A., Muller, C. D., Marinković, A., Vujcic, M., Janović, B., Malešević, A., Begović, N., Sencanski, M.,& Minic, D.. (2016). Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines. in RSC Advances
Royal Soc Chemistry, Cambridge., 6(110), 108726-108740.
https://doi.org/10.1039/c6ra24604d
Filipović NR, Bjelogrlic S, Todorović TR, Blagojević VA, Muller CD, Marinković A, Vujcic M, Janović B, Malešević A, Begović N, Sencanski M, Minic D. Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines. in RSC Advances. 2016;6(110):108726-108740.
doi:10.1039/c6ra24604d .
Filipović, Nenad R., Bjelogrlic, Snežana, Todorović, Tamara R., Blagojević, Vladimir A., Muller, Christian D., Marinković, Aleksandar, Vujcic, Miroslava, Janović, Barbara, Malešević, Aleksandar, Begović, Nebojša, Sencanski, Milan, Minic, Dragica, "Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines" in RSC Advances, 6, no. 110 (2016):108726-108740,
https://doi.org/10.1039/c6ra24604d . .
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Fabrication, characterization and photoelectrochemical behavior of Fe2TiO5 screen printed thick films

Vasiljević, Zorka Z; Aleksić, Obrad S.; Luković, Miloljub D.; Vujković, Milica; Pavlović, Vladimir B; Labus, Nebojša; Nikolić, Maria Vesna

(Belgrade : Institute of Technical Sciences of the Serbian Academz of Sciences and Arts, 2016)

TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Aleksić, Obrad S.
AU  - Luković, Miloljub D.
AU  - Vujković, Milica
AU  - Pavlović, Vladimir B
AU  - Labus, Nebojša
AU  - Nikolić, Maria Vesna
PY  - 2016
AB  - Pseudobrookite paste was composed of a mixture of starting nanopowders of hematite (α-Fe2O3) and anatase (TiO2) in the molar ratio 1:1.5, organic vehicle and glass frit. The paste was screen printed on on fluorine-doped tin oxide (FTO) glass substrate using screen printing technology. Structural, morphological and optical studies have been carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). The photo-electrochemical performance of Fe2TiO5 screen printed thick film was examined under xenon lamp illumination in 1 M NaOH electrolyte.
PB  - Belgrade : Institute of Technical Sciences of the Serbian Academz of Sciences and Arts
C3  - Program and the Book of Abstracts / Fifteenth Young Researchers' Conference Materials Sciences and Engineering, December 7-9, 2016, Belgrade, 2016, 45-45
T1  - Fabrication, characterization and photoelectrochemical behavior of Fe2TiO5 screen printed thick films
UR  - https://hdl.handle.net/21.15107/rcub_rimsi_1109
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Aleksić, Obrad S. and Luković, Miloljub D. and Vujković, Milica and Pavlović, Vladimir B and Labus, Nebojša and Nikolić, Maria Vesna",
year = "2016",
abstract = "Pseudobrookite paste was composed of a mixture of starting nanopowders of hematite (α-Fe2O3) and anatase (TiO2) in the molar ratio 1:1.5, organic vehicle and glass frit. The paste was screen printed on on fluorine-doped tin oxide (FTO) glass substrate using screen printing technology. Structural, morphological and optical studies have been carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). The photo-electrochemical performance of Fe2TiO5 screen printed thick film was examined under xenon lamp illumination in 1 M NaOH electrolyte.",
publisher = "Belgrade : Institute of Technical Sciences of the Serbian Academz of Sciences and Arts",
journal = "Program and the Book of Abstracts / Fifteenth Young Researchers' Conference Materials Sciences and Engineering, December 7-9, 2016, Belgrade, 2016, 45-45",
title = "Fabrication, characterization and photoelectrochemical behavior of Fe2TiO5 screen printed thick films",
url = "https://hdl.handle.net/21.15107/rcub_rimsi_1109"
}
Vasiljević, Z. Z., Aleksić, O. S., Luković, M. D., Vujković, M., Pavlović, V. B., Labus, N.,& Nikolić, M. V.. (2016). Fabrication, characterization and photoelectrochemical behavior of Fe2TiO5 screen printed thick films. in Program and the Book of Abstracts / Fifteenth Young Researchers' Conference Materials Sciences and Engineering, December 7-9, 2016, Belgrade, 2016, 45-45
Belgrade : Institute of Technical Sciences of the Serbian Academz of Sciences and Arts..
https://hdl.handle.net/21.15107/rcub_rimsi_1109
Vasiljević ZZ, Aleksić OS, Luković MD, Vujković M, Pavlović VB, Labus N, Nikolić MV. Fabrication, characterization and photoelectrochemical behavior of Fe2TiO5 screen printed thick films. in Program and the Book of Abstracts / Fifteenth Young Researchers' Conference Materials Sciences and Engineering, December 7-9, 2016, Belgrade, 2016, 45-45. 2016;.
https://hdl.handle.net/21.15107/rcub_rimsi_1109 .
Vasiljević, Zorka Z, Aleksić, Obrad S., Luković, Miloljub D., Vujković, Milica, Pavlović, Vladimir B, Labus, Nebojša, Nikolić, Maria Vesna, "Fabrication, characterization and photoelectrochemical behavior of Fe2TiO5 screen printed thick films" in Program and the Book of Abstracts / Fifteenth Young Researchers' Conference Materials Sciences and Engineering, December 7-9, 2016, Belgrade, 2016, 45-45 (2016),
https://hdl.handle.net/21.15107/rcub_rimsi_1109 .

Structural and Electronic Properties of Pseudobrookite

Vasiljević, Zorka Z; Nikolić, Maria Vesna; Aleksić, Obrad S.; Labus, Nebojša J.; Luković, Miloljub; Marković, Smilja; Nikolić, Pantelija M.

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2015)

TY  - CONF
AU  - Vasiljević, Zorka Z
AU  - Nikolić, Maria Vesna
AU  - Aleksić, Obrad S.
AU  - Labus, Nebojša J.
AU  - Luković, Miloljub
AU  - Marković, Smilja
AU  - Nikolić, Pantelija M.
PY  - 2015
UR  - https://dais.sanu.ac.rs/123456789/15425
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1633
AB  - Starting powders of TiO2 (anatase) and Fe2O3 (hematite) were mixed in the molar ratio 1:1. Pseudobrookite powder was obtained by a combined milling/calcination procedure. Particle size distribution was analyzed on a laser particle size analyzer and correlated with XRD and SEM analysis. The band gap was determined using UV/Vis spectroscopy. Green samples were sintered in a dilatometer and at 1000oC for 2h in air. Thermal diffusivity was determined from photoacoustic measurements. Electrical conductivity measurements were performed. The aim was to obtain pseudobrookite with properties suitable for polymer paste for thick films to be applied as gas sensors.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - Programme and the Book of Abstracts / 3rd Conference of the Serbian Society for Ceramic Materials, 3CSCS-2015, June 15-17, 2015, Belgrade, Serbia
T1  - Structural and Electronic Properties of Pseudobrookite
EP  - 99
SP  - 98
UR  - https://hdl.handle.net/21.15107/rcub_dais_15425
ER  - 
@conference{
author = "Vasiljević, Zorka Z and Nikolić, Maria Vesna and Aleksić, Obrad S. and Labus, Nebojša J. and Luković, Miloljub and Marković, Smilja and Nikolić, Pantelija M.",
year = "2015",
abstract = "Starting powders of TiO2 (anatase) and Fe2O3 (hematite) were mixed in the molar ratio 1:1. Pseudobrookite powder was obtained by a combined milling/calcination procedure. Particle size distribution was analyzed on a laser particle size analyzer and correlated with XRD and SEM analysis. The band gap was determined using UV/Vis spectroscopy. Green samples were sintered in a dilatometer and at 1000oC for 2h in air. Thermal diffusivity was determined from photoacoustic measurements. Electrical conductivity measurements were performed. The aim was to obtain pseudobrookite with properties suitable for polymer paste for thick films to be applied as gas sensors.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "Programme and the Book of Abstracts / 3rd Conference of the Serbian Society for Ceramic Materials, 3CSCS-2015, June 15-17, 2015, Belgrade, Serbia",
title = "Structural and Electronic Properties of Pseudobrookite",
pages = "99-98",
url = "https://hdl.handle.net/21.15107/rcub_dais_15425"
}
Vasiljević, Z. Z., Nikolić, M. V., Aleksić, O. S., Labus, N. J., Luković, M., Marković, S.,& Nikolić, P. M.. (2015). Structural and Electronic Properties of Pseudobrookite. in Programme and the Book of Abstracts / 3rd Conference of the Serbian Society for Ceramic Materials, 3CSCS-2015, June 15-17, 2015, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 98-99.
https://hdl.handle.net/21.15107/rcub_dais_15425
Vasiljević ZZ, Nikolić MV, Aleksić OS, Labus NJ, Luković M, Marković S, Nikolić PM. Structural and Electronic Properties of Pseudobrookite. in Programme and the Book of Abstracts / 3rd Conference of the Serbian Society for Ceramic Materials, 3CSCS-2015, June 15-17, 2015, Belgrade, Serbia. 2015;:98-99.
https://hdl.handle.net/21.15107/rcub_dais_15425 .
Vasiljević, Zorka Z, Nikolić, Maria Vesna, Aleksić, Obrad S., Labus, Nebojša J., Luković, Miloljub, Marković, Smilja, Nikolić, Pantelija M., "Structural and Electronic Properties of Pseudobrookite" in Programme and the Book of Abstracts / 3rd Conference of the Serbian Society for Ceramic Materials, 3CSCS-2015, June 15-17, 2015, Belgrade, Serbia (2015):98-99,
https://hdl.handle.net/21.15107/rcub_dais_15425 .

Reheating of Zinc-titanate Sintered Specimens

Labus, Nebojša J.; Mentus, S.; Rakic, S.; Đurić, Zorka Z; Vujančević, Jelena; Nikolić, Maria Vesna

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2015)

TY  - JOUR
AU  - Labus, Nebojša J.
AU  - Mentus, S.
AU  - Rakic, S.
AU  - Đurić, Zorka Z
AU  - Vujančević, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2015
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/845
AB  - The scope of this work was observing dimensional and heat transfer changes in ZnTiO3 samples during heating in nitrogen and air atmosphere. Interactions of bulk specimens with gaseous surrounding induce microstructure changes during heating. Sintered ZnTiO3 nanopowder samples were submitted to subsequent heating. Dilatation curves and thermogravimetric with simultaneous differential thermal analysis TGA/DTA curves were recorded. Reheating was performed in air and nitrogen atmospheres. Reheated samples obtained at different characteristic temperatures in air were analyzed by X-ray diffraction (XRD). Microstructures obtained by scanning electron microscopy (SEM) of reheated sintered samples are presented and compared. Reheating in a different atmosphere induced different microstructures. The goal was indicating possible causes leading to the microstructure changes.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Reheating of Zinc-titanate Sintered Specimens
EP  - 81
IS  - 1
SP  - 71
VL  - 47
DO  - 10.2298/SOS1501071L
ER  - 
@article{
author = "Labus, Nebojša J. and Mentus, S. and Rakic, S. and Đurić, Zorka Z and Vujančević, Jelena and Nikolić, Maria Vesna",
year = "2015",
abstract = "The scope of this work was observing dimensional and heat transfer changes in ZnTiO3 samples during heating in nitrogen and air atmosphere. Interactions of bulk specimens with gaseous surrounding induce microstructure changes during heating. Sintered ZnTiO3 nanopowder samples were submitted to subsequent heating. Dilatation curves and thermogravimetric with simultaneous differential thermal analysis TGA/DTA curves were recorded. Reheating was performed in air and nitrogen atmospheres. Reheated samples obtained at different characteristic temperatures in air were analyzed by X-ray diffraction (XRD). Microstructures obtained by scanning electron microscopy (SEM) of reheated sintered samples are presented and compared. Reheating in a different atmosphere induced different microstructures. The goal was indicating possible causes leading to the microstructure changes.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Reheating of Zinc-titanate Sintered Specimens",
pages = "81-71",
number = "1",
volume = "47",
doi = "10.2298/SOS1501071L"
}
Labus, N. J., Mentus, S., Rakic, S., Đurić, Z. Z., Vujančević, J.,& Nikolić, M. V.. (2015). Reheating of Zinc-titanate Sintered Specimens. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 47(1), 71-81.
https://doi.org/10.2298/SOS1501071L
Labus NJ, Mentus S, Rakic S, Đurić ZZ, Vujančević J, Nikolić MV. Reheating of Zinc-titanate Sintered Specimens. in Science of Sintering. 2015;47(1):71-81.
doi:10.2298/SOS1501071L .
Labus, Nebojša J., Mentus, S., Rakic, S., Đurić, Zorka Z, Vujančević, Jelena, Nikolić, Maria Vesna, "Reheating of Zinc-titanate Sintered Specimens" in Science of Sintering, 47, no. 1 (2015):71-81,
https://doi.org/10.2298/SOS1501071L . .
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3
4

Influence of Nitrogen and Air Atmosphere During Thermal Treatment on Micro and Nano Sized Powders and Sintered TiO2 Specimens

Labus, Nebojša J.; Mentus, S.; Đurić, Zorka Z; Nikolić, Maria Vesna

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2014)

TY  - JOUR
AU  - Labus, Nebojša J.
AU  - Mentus, S.
AU  - Đurić, Zorka Z
AU  - Nikolić, Maria Vesna
PY  - 2014
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/748
AB  - The influence of air and nitrogen atmosphere during heating on TiO2 nano and micro sized powders as well as sintered polycrystalline specimens was analyzed. Sintering of TiO2 nano and micro powders in air atmosphere was monitored in a dilatometer. Non compacted nano and micro powders were analyzed separately in air and nitrogen atmospheres during heating using thermo gravimetric (TG) and differential thermal analysis (DTA). The anatase to rutile phase transition temperature interval is influenced by the powder particle size and atmosphere change. At lower temperatures for nano TiO2 powder a second order phase transition was detected by both thermal techniques. Polycrystalline specimens obtained by sintering from nano powders were reheated in the dilatometer in nitrogen and air atmosphere, and their shrinkage is found to be different. Powder particle size influence, as well as the air and nitrogen atmosphere influence was discussed.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Influence of Nitrogen and Air Atmosphere During Thermal Treatment on Micro and Nano Sized Powders and Sintered TiO2 Specimens
EP  - 375
IS  - 3
SP  - 365
VL  - 46
DO  - 10.2298/SOS1403365L
ER  - 
@article{
author = "Labus, Nebojša J. and Mentus, S. and Đurić, Zorka Z and Nikolić, Maria Vesna",
year = "2014",
abstract = "The influence of air and nitrogen atmosphere during heating on TiO2 nano and micro sized powders as well as sintered polycrystalline specimens was analyzed. Sintering of TiO2 nano and micro powders in air atmosphere was monitored in a dilatometer. Non compacted nano and micro powders were analyzed separately in air and nitrogen atmospheres during heating using thermo gravimetric (TG) and differential thermal analysis (DTA). The anatase to rutile phase transition temperature interval is influenced by the powder particle size and atmosphere change. At lower temperatures for nano TiO2 powder a second order phase transition was detected by both thermal techniques. Polycrystalline specimens obtained by sintering from nano powders were reheated in the dilatometer in nitrogen and air atmosphere, and their shrinkage is found to be different. Powder particle size influence, as well as the air and nitrogen atmosphere influence was discussed.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Influence of Nitrogen and Air Atmosphere During Thermal Treatment on Micro and Nano Sized Powders and Sintered TiO2 Specimens",
pages = "375-365",
number = "3",
volume = "46",
doi = "10.2298/SOS1403365L"
}
Labus, N. J., Mentus, S., Đurić, Z. Z.,& Nikolić, M. V.. (2014). Influence of Nitrogen and Air Atmosphere During Thermal Treatment on Micro and Nano Sized Powders and Sintered TiO2 Specimens. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 46(3), 365-375.
https://doi.org/10.2298/SOS1403365L
Labus NJ, Mentus S, Đurić ZZ, Nikolić MV. Influence of Nitrogen and Air Atmosphere During Thermal Treatment on Micro and Nano Sized Powders and Sintered TiO2 Specimens. in Science of Sintering. 2014;46(3):365-375.
doi:10.2298/SOS1403365L .
Labus, Nebojša J., Mentus, S., Đurić, Zorka Z, Nikolić, Maria Vesna, "Influence of Nitrogen and Air Atmosphere During Thermal Treatment on Micro and Nano Sized Powders and Sintered TiO2 Specimens" in Science of Sintering, 46, no. 3 (2014):365-375,
https://doi.org/10.2298/SOS1403365L . .
2
2

Raman Responses in Mechanically Activated BaTiO3

Pavlović, Vera P.; Nikolić, Maria Vesna; Pavlović, Vladimir B; Blanusa, Jovan L; Stevanović, Suzana; Mitic, Vojislav V; Šćepanović, Maja; Vlahović, Branislav

(Wiley, Hoboken, 2014)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Nikolić, Maria Vesna
AU  - Pavlović, Vladimir B
AU  - Blanusa, Jovan L
AU  - Stevanović, Suzana
AU  - Mitic, Vojislav V
AU  - Šćepanović, Maja
AU  - Vlahović, Branislav
PY  - 2014
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/761
AB  - The structure and lattice dynamics of mechanically activated BaTiO3 was investigated in this study. Phonon behavior and crystal structure stability of the obtained nanocrystalline BaTiO3 were discussed from the view point of crystallite size effects and microstrains induced by mechanical activation. A systematic study of Raman responses indicates that mechanical activation has a distinct influence on BaTiO3 lattice spectra affecting the intensity, width, and position of Raman modes. The measured Raman spectra were deconvoluted and phonon parameters were estimated. It has been established that applied mechanical activation leads to a significant decrease in the mean crystallites size, but nevertheless enables formation of tetragonal nanocrystalline BaTiO3.
PB  - Wiley, Hoboken
T2  - Journal of the American Ceramic Society
T1  - Raman Responses in Mechanically Activated BaTiO3
EP  - 608
IS  - 2
SP  - 601
VL  - 97
DO  - 10.1111/jace.12423
ER  - 
@article{
author = "Pavlović, Vera P. and Nikolić, Maria Vesna and Pavlović, Vladimir B and Blanusa, Jovan L and Stevanović, Suzana and Mitic, Vojislav V and Šćepanović, Maja and Vlahović, Branislav",
year = "2014",
abstract = "The structure and lattice dynamics of mechanically activated BaTiO3 was investigated in this study. Phonon behavior and crystal structure stability of the obtained nanocrystalline BaTiO3 were discussed from the view point of crystallite size effects and microstrains induced by mechanical activation. A systematic study of Raman responses indicates that mechanical activation has a distinct influence on BaTiO3 lattice spectra affecting the intensity, width, and position of Raman modes. The measured Raman spectra were deconvoluted and phonon parameters were estimated. It has been established that applied mechanical activation leads to a significant decrease in the mean crystallites size, but nevertheless enables formation of tetragonal nanocrystalline BaTiO3.",
publisher = "Wiley, Hoboken",
journal = "Journal of the American Ceramic Society",
title = "Raman Responses in Mechanically Activated BaTiO3",
pages = "608-601",
number = "2",
volume = "97",
doi = "10.1111/jace.12423"
}
Pavlović, V. P., Nikolić, M. V., Pavlović, V. B., Blanusa, J. L., Stevanović, S., Mitic, V. V., Šćepanović, M.,& Vlahović, B.. (2014). Raman Responses in Mechanically Activated BaTiO3. in Journal of the American Ceramic Society
Wiley, Hoboken., 97(2), 601-608.
https://doi.org/10.1111/jace.12423
Pavlović VP, Nikolić MV, Pavlović VB, Blanusa JL, Stevanović S, Mitic VV, Šćepanović M, Vlahović B. Raman Responses in Mechanically Activated BaTiO3. in Journal of the American Ceramic Society. 2014;97(2):601-608.
doi:10.1111/jace.12423 .
Pavlović, Vera P., Nikolić, Maria Vesna, Pavlović, Vladimir B, Blanusa, Jovan L, Stevanović, Suzana, Mitic, Vojislav V, Šćepanović, Maja, Vlahović, Branislav, "Raman Responses in Mechanically Activated BaTiO3" in Journal of the American Ceramic Society, 97, no. 2 (2014):601-608,
https://doi.org/10.1111/jace.12423 . .
19
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Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods

Labus, Nebojša J.; Krstić, Jugoslav; Peleš, Adriana; Živojinović, Jelena; Nikolić, Maria Vesna

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Labus, Nebojša J.
AU  - Krstić, Jugoslav
AU  - Peleš, Adriana
AU  - Živojinović, Jelena
AU  - Nikolić, Maria Vesna
PY  - 2013
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1639
AB  - Nanopowder density, as well as compact density, is due to powder particle size, different in their values, compared to micron powders. Also, the technique used for density determination induces large mutual value discrepancies. Scanning electron micrographs of as received powder are presented as an illustration of the shape and size of powder particles and agglomerates. The density of the loose powder pretreated differently was determined using mercury porosimetry and He pycnometry. The methods used for determining the apparent density of the compacts were pycnometry with water as the wetting liquid, mercury porosimetry and also a new approach using a combination of mercury pycnometry along with nitrogen adsorption. Bulk densities of compacts were determined by dimension measurement and mercury pycnometry. Conclusions about nanopowder usage as a charge for dry compaction as well as the most appropriate way for the determination of compact and powder densities are shown.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
T1  - Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods
EP  - 18
SP  - 18
UR  - https://hdl.handle.net/21.15107/rcub_dais_411
ER  - 
@conference{
author = "Labus, Nebojša J. and Krstić, Jugoslav and Peleš, Adriana and Živojinović, Jelena and Nikolić, Maria Vesna",
year = "2013",
abstract = "Nanopowder density, as well as compact density, is due to powder particle size, different in their values, compared to micron powders. Also, the technique used for density determination induces large mutual value discrepancies. Scanning electron micrographs of as received powder are presented as an illustration of the shape and size of powder particles and agglomerates. The density of the loose powder pretreated differently was determined using mercury porosimetry and He pycnometry. The methods used for determining the apparent density of the compacts were pycnometry with water as the wetting liquid, mercury porosimetry and also a new approach using a combination of mercury pycnometry along with nitrogen adsorption. Bulk densities of compacts were determined by dimension measurement and mercury pycnometry. Conclusions about nanopowder usage as a charge for dry compaction as well as the most appropriate way for the determination of compact and powder densities are shown.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade",
title = "Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods",
pages = "18-18",
url = "https://hdl.handle.net/21.15107/rcub_dais_411"
}
Labus, N. J., Krstić, J., Peleš, A., Živojinović, J.,& Nikolić, M. V.. (2013). Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade
Belgrade : Serbian Ceramic Society., 18-18.
https://hdl.handle.net/21.15107/rcub_dais_411
Labus NJ, Krstić J, Peleš A, Živojinović J, Nikolić MV. Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade. 2013;:18-18.
https://hdl.handle.net/21.15107/rcub_dais_411 .
Labus, Nebojša J., Krstić, Jugoslav, Peleš, Adriana, Živojinović, Jelena, Nikolić, Maria Vesna, "Density of the ZnTiO3 nanopowder as a loose powder and as a compact obtained by different methods" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : II Serbian Ceramic Society Conference, Sep 30th-Oct 1st, 2013, Belgrade (2013):18-18,
https://hdl.handle.net/21.15107/rcub_dais_411 .

Synthesis of Barium-zinc-titanate Ceramics

Obradović, Nina; Nikolić, Maria Vesna; Nikolić, Nenad; Filipović, Suzana Z; Mitrić, Miodrag; Pavlović, Vladimir B; Nikolić, Pantelija M.; Đorđević, Antonije R; Ristic, Momcilo M.

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2012)

TY  - JOUR
AU  - Obradović, Nina
AU  - Nikolić, Maria Vesna
AU  - Nikolić, Nenad
AU  - Filipović, Suzana Z
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir B
AU  - Nikolić, Pantelija M.
AU  - Đorđević, Antonije R
AU  - Ristic, Momcilo M.
PY  - 2012
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/604
AB  - Mixtures of BaCO3, ZnO and TiO2 powders, with molar ratio of 1:2:4, were mechanically activated for 20, 40 and minutes in a planetary ball mill. The resulting powders were compacted into pellets and isothermally sintered at 1250 degrees C for 2h with a heating rate of 10 degrees C/min. X-ray diffraction analysis of obtained powders and sintered samples was performed in order to investigate changes of the phase composition. The microstructure of sintered samples was examined by scanning electron microscopy. The photoacoustic phase and amplitude spectra of sintered samples were measured as a function of the laser beam modulating frequency using a transmission detection configuration. Fitting of experimental data enabled determination of photoacoustic properties including thermal diffusivity. Based on the results obtained correlation between thermal diffusivity and experimental conditions, as well the samples microstructure characteristics, was discussed.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Synthesis of Barium-zinc-titanate Ceramics
EP  - 71
IS  - 1
SP  - 65
VL  - 44
DO  - 10.2298/SOS1201065O
ER  - 
@article{
author = "Obradović, Nina and Nikolić, Maria Vesna and Nikolić, Nenad and Filipović, Suzana Z and Mitrić, Miodrag and Pavlović, Vladimir B and Nikolić, Pantelija M. and Đorđević, Antonije R and Ristic, Momcilo M.",
year = "2012",
abstract = "Mixtures of BaCO3, ZnO and TiO2 powders, with molar ratio of 1:2:4, were mechanically activated for 20, 40 and minutes in a planetary ball mill. The resulting powders were compacted into pellets and isothermally sintered at 1250 degrees C for 2h with a heating rate of 10 degrees C/min. X-ray diffraction analysis of obtained powders and sintered samples was performed in order to investigate changes of the phase composition. The microstructure of sintered samples was examined by scanning electron microscopy. The photoacoustic phase and amplitude spectra of sintered samples were measured as a function of the laser beam modulating frequency using a transmission detection configuration. Fitting of experimental data enabled determination of photoacoustic properties including thermal diffusivity. Based on the results obtained correlation between thermal diffusivity and experimental conditions, as well the samples microstructure characteristics, was discussed.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Synthesis of Barium-zinc-titanate Ceramics",
pages = "71-65",
number = "1",
volume = "44",
doi = "10.2298/SOS1201065O"
}
Obradović, N., Nikolić, M. V., Nikolić, N., Filipović, S. Z., Mitrić, M., Pavlović, V. B., Nikolić, P. M., Đorđević, A. R.,& Ristic, M. M.. (2012). Synthesis of Barium-zinc-titanate Ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 44(1), 65-71.
https://doi.org/10.2298/SOS1201065O
Obradović N, Nikolić MV, Nikolić N, Filipović SZ, Mitrić M, Pavlović VB, Nikolić PM, Đorđević AR, Ristic MM. Synthesis of Barium-zinc-titanate Ceramics. in Science of Sintering. 2012;44(1):65-71.
doi:10.2298/SOS1201065O .
Obradović, Nina, Nikolić, Maria Vesna, Nikolić, Nenad, Filipović, Suzana Z, Mitrić, Miodrag, Pavlović, Vladimir B, Nikolić, Pantelija M., Đorđević, Antonije R, Ristic, Momcilo M., "Synthesis of Barium-zinc-titanate Ceramics" in Science of Sintering, 44, no. 1 (2012):65-71,
https://doi.org/10.2298/SOS1201065O . .
3
2
5

Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive

Obradović, Nina; Đorđević, Nataša G; Filipović, Suzana Z; Nikolić, Nenad; Kosanović, Darko; Mitrić, Miodrag; Marković, Smilja; Pavlović, Vladimir B

(Elsevier, Amsterdam, 2012)

TY  - JOUR
AU  - Obradović, Nina
AU  - Đorđević, Nataša G
AU  - Filipović, Suzana Z
AU  - Nikolić, Nenad
AU  - Kosanović, Darko
AU  - Mitrić, Miodrag
AU  - Marković, Smilja
AU  - Pavlović, Vladimir B
PY  - 2012
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/523
AB  - Due to its outstanding electrical characteristics, such as the low temperature expansion coefficient, low dielectric constant and good mechanical properties, cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2), is a very attractive high-temperature ceramic material. In order to accelerate the process of sintering, 2.50 mass% Bi2O3 has been added to the starting mixtures. Liquid phase sintering caused by the presence of bismuth-oxide lowers the temperature of cordierite formation. The mechanical activation of the starting mixtures (0-56 min in vibro-mill) additionally lowers sintering temperatures. The sintering process was performed at 1200, 1300, 1350 and 1400 degrees C, for 2 h. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders and sintered materials was analyzed by the X-ray diffraction method. Furthermore, scanning electron microscopy (SEM) was used in the analysis of the powder morphology.
PB  - Elsevier, Amsterdam
T2  - Powder Technology
T1  - Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive
EP  - 161
SP  - 157
VL  - 218
DO  - 10.1016/j.powtec.2011.12.012
ER  - 
@article{
author = "Obradović, Nina and Đorđević, Nataša G and Filipović, Suzana Z and Nikolić, Nenad and Kosanović, Darko and Mitrić, Miodrag and Marković, Smilja and Pavlović, Vladimir B",
year = "2012",
abstract = "Due to its outstanding electrical characteristics, such as the low temperature expansion coefficient, low dielectric constant and good mechanical properties, cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2), is a very attractive high-temperature ceramic material. In order to accelerate the process of sintering, 2.50 mass% Bi2O3 has been added to the starting mixtures. Liquid phase sintering caused by the presence of bismuth-oxide lowers the temperature of cordierite formation. The mechanical activation of the starting mixtures (0-56 min in vibro-mill) additionally lowers sintering temperatures. The sintering process was performed at 1200, 1300, 1350 and 1400 degrees C, for 2 h. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders and sintered materials was analyzed by the X-ray diffraction method. Furthermore, scanning electron microscopy (SEM) was used in the analysis of the powder morphology.",
publisher = "Elsevier, Amsterdam",
journal = "Powder Technology",
title = "Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive",
pages = "161-157",
volume = "218",
doi = "10.1016/j.powtec.2011.12.012"
}
Obradović, N., Đorđević, N. G., Filipović, S. Z., Nikolić, N., Kosanović, D., Mitrić, M., Marković, S.,& Pavlović, V. B.. (2012). Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive. in Powder Technology
Elsevier, Amsterdam., 218, 157-161.
https://doi.org/10.1016/j.powtec.2011.12.012
Obradović N, Đorđević NG, Filipović SZ, Nikolić N, Kosanović D, Mitrić M, Marković S, Pavlović VB. Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive. in Powder Technology. 2012;218:157-161.
doi:10.1016/j.powtec.2011.12.012 .
Obradović, Nina, Đorđević, Nataša G, Filipović, Suzana Z, Nikolić, Nenad, Kosanović, Darko, Mitrić, Miodrag, Marković, Smilja, Pavlović, Vladimir B, "Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive" in Powder Technology, 218 (2012):157-161,
https://doi.org/10.1016/j.powtec.2011.12.012 . .
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