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Preparation, sintering and electrical properties of nano-grained multidoped ceria

Bošković, Snežana B; Zec, Slavica P; Branković, Goran; Branković, Zorica; Devečerski, Aleksandar B; Matović, Branko; Aldinger, F

(Elsevier Sci Ltd, Oxford, 2010)

TY  - JOUR
AU  - Bošković, Snežana B
AU  - Zec, Slavica P
AU  - Branković, Goran
AU  - Branković, Zorica
AU  - Devečerski, Aleksandar B
AU  - Matović, Branko
AU  - Aldinger, F
PY  - 2010
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/411
AB  - Multiply doped ceria nanopowders were synthesized by applying MGNP (modified glycine/nitrate procedure). The overall concentration of dopants was kept constant (x = 0.2) whereby Gd ion as the main dopant was gradually substituted by Sm and by Sm + Y. The compositions of solid solutions were calculated by applying defect model introducing anion vacancy radius. Characterization of powders involved BET, TEM, XRD and chemical analyses. Densification was performed at 1500 degrees C, in an oxygen atmosphere for 1 h. The results showed that with increasing number of dopants, specific surface area of powders increased, followed by decrease of crystallite and grain sizes. Densification degree was also found to rise with increasing number of dopants. According to impedance measurements it was found that ionic conductivity was the highest 1.14 x 10(-3) S cm(-1) at 450 degrees C in sample doped with Gd, Sm and Y simultaneously.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Preparation, sintering and electrical properties of nano-grained multidoped ceria
EP  - 127
IS  - 1
SP  - 121
VL  - 36
DO  - 10.1016/j.ceramint.2009.07.015
ER  - 
@article{
author = "Bošković, Snežana B and Zec, Slavica P and Branković, Goran and Branković, Zorica and Devečerski, Aleksandar B and Matović, Branko and Aldinger, F",
year = "2010",
abstract = "Multiply doped ceria nanopowders were synthesized by applying MGNP (modified glycine/nitrate procedure). The overall concentration of dopants was kept constant (x = 0.2) whereby Gd ion as the main dopant was gradually substituted by Sm and by Sm + Y. The compositions of solid solutions were calculated by applying defect model introducing anion vacancy radius. Characterization of powders involved BET, TEM, XRD and chemical analyses. Densification was performed at 1500 degrees C, in an oxygen atmosphere for 1 h. The results showed that with increasing number of dopants, specific surface area of powders increased, followed by decrease of crystallite and grain sizes. Densification degree was also found to rise with increasing number of dopants. According to impedance measurements it was found that ionic conductivity was the highest 1.14 x 10(-3) S cm(-1) at 450 degrees C in sample doped with Gd, Sm and Y simultaneously.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Preparation, sintering and electrical properties of nano-grained multidoped ceria",
pages = "127-121",
number = "1",
volume = "36",
doi = "10.1016/j.ceramint.2009.07.015"
}
Bošković, S. B., Zec, S. P., Branković, G., Branković, Z., Devečerski, A. B., Matović, B.,& Aldinger, F.. (2010). Preparation, sintering and electrical properties of nano-grained multidoped ceria. in Ceramics International
Elsevier Sci Ltd, Oxford., 36(1), 121-127.
https://doi.org/10.1016/j.ceramint.2009.07.015
Bošković SB, Zec SP, Branković G, Branković Z, Devečerski AB, Matović B, Aldinger F. Preparation, sintering and electrical properties of nano-grained multidoped ceria. in Ceramics International. 2010;36(1):121-127.
doi:10.1016/j.ceramint.2009.07.015 .
Bošković, Snežana B, Zec, Slavica P, Branković, Goran, Branković, Zorica, Devečerski, Aleksandar B, Matović, Branko, Aldinger, F, "Preparation, sintering and electrical properties of nano-grained multidoped ceria" in Ceramics International, 36, no. 1 (2010):121-127,
https://doi.org/10.1016/j.ceramint.2009.07.015 . .
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