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Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method

Vasiljević, Zorka Z; Dojčinović, Milena; Vujančević, Jelena; Jankovic-Castvan, I.; Ognjanović, M.; Tadić, Nenad B.; Stojadinović, S.; Branković, Goran; Nikolić, Maria Vesna

(Royal Soc, London, 2020)

TY  - JOUR
AU  - Vasiljević, Zorka Z
AU  - Dojčinović, Milena
AU  - Vujančević, Jelena
AU  - Jankovic-Castvan, I.
AU  - Ognjanović, M.
AU  - Tadić, Nenad B.
AU  - Stojadinović, S.
AU  - Branković, Goran
AU  - Nikolić, Maria Vesna
PY  - 2020
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1352
AB  - The aim of this work was to synthesize semiconducting oxide nanoparticles using a simple method with low production cost to be applied in natural sunlight for photocatalytic degradation of pollutants in waste water. Iron titanate (Fe2TiO5) nanoparticles with an orthorhombic structure were successfully synthesized using a modified sol-gel method and calcination at 750 degrees C. The as-prepared Fe2TiO5 nanoparticles exhibited a moderate specific surface area. The mesoporous Fe2TiO5 nanoparticles possessed strong absorption in the visible-light region and the band gap was estimated to be around 2.16 eV. The photocatalytic activity was evaluated by the degradation of methylene blue under natural sunlight. The effect of parameters such as the amount of catalyst, initial concentration of the dye and pH of the dye solution on the removal efficiency of methylene blue was investigated. Fe2TiO5 showed high degradation efficiency in a strong alkaline medium that can be the result of the facilitated formation of OH radicals due to an increased concentration of hydroxyl ions.
PB  - Royal Soc, London
T2  - Royal Society Open Science
T1  - Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method
IS  - 9
VL  - 7
DO  - 10.1098/rsos.200708
ER  - 
@article{
author = "Vasiljević, Zorka Z and Dojčinović, Milena and Vujančević, Jelena and Jankovic-Castvan, I. and Ognjanović, M. and Tadić, Nenad B. and Stojadinović, S. and Branković, Goran and Nikolić, Maria Vesna",
year = "2020",
abstract = "The aim of this work was to synthesize semiconducting oxide nanoparticles using a simple method with low production cost to be applied in natural sunlight for photocatalytic degradation of pollutants in waste water. Iron titanate (Fe2TiO5) nanoparticles with an orthorhombic structure were successfully synthesized using a modified sol-gel method and calcination at 750 degrees C. The as-prepared Fe2TiO5 nanoparticles exhibited a moderate specific surface area. The mesoporous Fe2TiO5 nanoparticles possessed strong absorption in the visible-light region and the band gap was estimated to be around 2.16 eV. The photocatalytic activity was evaluated by the degradation of methylene blue under natural sunlight. The effect of parameters such as the amount of catalyst, initial concentration of the dye and pH of the dye solution on the removal efficiency of methylene blue was investigated. Fe2TiO5 showed high degradation efficiency in a strong alkaline medium that can be the result of the facilitated formation of OH radicals due to an increased concentration of hydroxyl ions.",
publisher = "Royal Soc, London",
journal = "Royal Society Open Science",
title = "Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method",
number = "9",
volume = "7",
doi = "10.1098/rsos.200708"
}
Vasiljević, Z. Z., Dojčinović, M., Vujančević, J., Jankovic-Castvan, I., Ognjanović, M., Tadić, N. B., Stojadinović, S., Branković, G.,& Nikolić, M. V.. (2020). Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method. in Royal Society Open Science
Royal Soc, London., 7(9).
https://doi.org/10.1098/rsos.200708
Vasiljević ZZ, Dojčinović M, Vujančević J, Jankovic-Castvan I, Ognjanović M, Tadić NB, Stojadinović S, Branković G, Nikolić MV. Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method. in Royal Society Open Science. 2020;7(9).
doi:10.1098/rsos.200708 .
Vasiljević, Zorka Z, Dojčinović, Milena, Vujančević, Jelena, Jankovic-Castvan, I., Ognjanović, M., Tadić, Nenad B., Stojadinović, S., Branković, Goran, Nikolić, Maria Vesna, "Photocatalytic degradation of methylene blue under natural sunlight using iron titanate nanoparticles prepared by a modified sol-gel method" in Royal Society Open Science, 7, no. 9 (2020),
https://doi.org/10.1098/rsos.200708 . .
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From titania to titanates: Phase and morphological transition in less alkaline medium under mild conditions

Simović, Bojana; Dapčević, Aleksandra; Zdravković, Jelena; Tasić, Nikola; Kovac, Sabina; Krstic, Jugoslav; Branković, Goran

(Elsevier Science Sa, Lausanne, 2019)

TY  - JOUR
AU  - Simović, Bojana
AU  - Dapčević, Aleksandra
AU  - Zdravković, Jelena
AU  - Tasić, Nikola
AU  - Kovac, Sabina
AU  - Krstic, Jugoslav
AU  - Branković, Goran
PY  - 2019
UR  - http://rimsi.imsi.bg.ac.rs/handle/123456789/1283
AB  - In this work, nine products were prepared by modifying the experimental conditions (6, 12 and 18 hat 110, 135 and 160 degrees C) of hydrothermal treatment of starting nanoanatase in significantly less concentrated alkaline medium than usual in order to obtain a pure titanate phase. The nanocrystalline samples were characterized by XRPD, FESEM, HRTEM/SAED, EDS, TG, FT-IR, UV-Vis and BET analyses. The results revealed that the structure, texture, morphology and band gap energy of samples strongly depend on conditions of hydrothermal treatment. The intensification of hydrothermal treatment significantly increases the solubility of TiO2 promoting the changes in morphology from nearly spherical titania nanoparticles to elongated titanate nanosheets. The single titanate phase was obtained after energetically the most intensive treatment, i.e. 18 hat 160 degrees C. The step-by-step optimization was thus necessary to finally distinguish the titanates from titania in terms of structural and spectral properties and to finally allow the clarification of long-standing confusion between titania and titanates. The obtained single titanate phase was furtherly used to fabricate a humidity sensor, which showed remarkably rapid response and quick recovery time.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - From titania to titanates: Phase and morphological transition in less alkaline medium under mild conditions
EP  - 819
SP  - 810
VL  - 781
DO  - 10.1016/j.jallcom.2018.12.039
ER  - 
@article{
author = "Simović, Bojana and Dapčević, Aleksandra and Zdravković, Jelena and Tasić, Nikola and Kovac, Sabina and Krstic, Jugoslav and Branković, Goran",
year = "2019",
abstract = "In this work, nine products were prepared by modifying the experimental conditions (6, 12 and 18 hat 110, 135 and 160 degrees C) of hydrothermal treatment of starting nanoanatase in significantly less concentrated alkaline medium than usual in order to obtain a pure titanate phase. The nanocrystalline samples were characterized by XRPD, FESEM, HRTEM/SAED, EDS, TG, FT-IR, UV-Vis and BET analyses. The results revealed that the structure, texture, morphology and band gap energy of samples strongly depend on conditions of hydrothermal treatment. The intensification of hydrothermal treatment significantly increases the solubility of TiO2 promoting the changes in morphology from nearly spherical titania nanoparticles to elongated titanate nanosheets. The single titanate phase was obtained after energetically the most intensive treatment, i.e. 18 hat 160 degrees C. The step-by-step optimization was thus necessary to finally distinguish the titanates from titania in terms of structural and spectral properties and to finally allow the clarification of long-standing confusion between titania and titanates. The obtained single titanate phase was furtherly used to fabricate a humidity sensor, which showed remarkably rapid response and quick recovery time.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "From titania to titanates: Phase and morphological transition in less alkaline medium under mild conditions",
pages = "819-810",
volume = "781",
doi = "10.1016/j.jallcom.2018.12.039"
}
Simović, B., Dapčević, A., Zdravković, J., Tasić, N., Kovac, S., Krstic, J.,& Branković, G.. (2019). From titania to titanates: Phase and morphological transition in less alkaline medium under mild conditions. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 781, 810-819.
https://doi.org/10.1016/j.jallcom.2018.12.039
Simović B, Dapčević A, Zdravković J, Tasić N, Kovac S, Krstic J, Branković G. From titania to titanates: Phase and morphological transition in less alkaline medium under mild conditions. in Journal of Alloys and Compounds. 2019;781:810-819.
doi:10.1016/j.jallcom.2018.12.039 .
Simović, Bojana, Dapčević, Aleksandra, Zdravković, Jelena, Tasić, Nikola, Kovac, Sabina, Krstic, Jugoslav, Branković, Goran, "From titania to titanates: Phase and morphological transition in less alkaline medium under mild conditions" in Journal of Alloys and Compounds, 781 (2019):810-819,
https://doi.org/10.1016/j.jallcom.2018.12.039 . .
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